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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Synthesis, magnetization, and heat capacity of triangular lattice materials NaErSe 2 and KErSe 2

In this paper we report the synthesis, magnetization, and heat capacity of the frustrated magnets A ErSe 2 ( A = Na , K ) which contain perfect triangular lattices of Er 3 + . The magnetization data suggests no long-range magnetic order exists in A ErSe 2 ( A = Na , K ), which is consistent with the heat capacity measurements. Large anisotropy is observed between the magnetization within the a b plane and along the c axis of both compounds. When the magnetic field is applied along the a b plane, anomalies are observed at 1.8 μ B in NaErSe 2 at 0.2 T and 2.1 μ B in KErSe 2 at 0.18 T. Unlike NaErSe 2 , a plateaulike field-induced metamagnetic transition is observed for H ∥ c below 1 K in KErSe 2 . Two broad peaks are observed in the heat capacity below 10 K indicating possible crystal electric field (CEF) effects and magnetic entropy released under different magnetic fields. All results indicate that A ErSe 2 are strongly anisotropic, frustrated magnets with field-induced transition at low temperature. The lack of signatures for long-range magnetic order implies that these materials are candidates for hosting a quantum spin liquid ground state.

36 MATERIALS SCIENCE↗
DOE OSTI2016

A combined experimental and computational thermodynamic investigation of the U-Th-O system

Here, the thermodynamics of the U–Th–O system have been assessed using the Calphad method. The compound energy formalism (CEF) and a partially ionic two-sublattice liquid model (TSLM) were used for the fluorite U 1–y Th y O 2±x , γ-(U,Th) 4 O 9 , and the U–Th–O melt. The O 2 activity of fluorite U 1–y Th y O 2±x with temperature and composition was determined by thermogravimetric analysis. Thermodynamic studies for the Th–O binary and U–Th–O ternary available in the open literature were critically reviewed. A self-consistent data set was selected and compiled with the equilibrium oxygen pressures determined by thermogravimetry in order to optimize the adjustable parameters of models selected to represent the phases in the Th–O and U–Th–O systems.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Modernization of PLC-Based Control Systems at SNS

When the SNS site was built around 20 years ago, the Conventional Facilities (CF) control systems were de-signed using 2 communication protocols to allow pro-grammable logic controllers (PLCs) to interface with motors, variable frequency drives (VFDs), and remote input and output (I/O) devices. The protocol chosen to control motors and VFDs is DeviceNet, a CANbus-based protocol developed by Allen-Bradley, a subsidiary of Rockwell Automation. The protocol chosen to communi-cate with remote I/O is ControlNet, another protocol developed by Allen-Bradley. Both of these protocols are obsolete and present reliability and maintainability is-sues, particularly DeviceNet. As the Control Systems Section at SNS is working to modernize control systems throughout the machine, a major goal for PLC-based systems is to remove the obsolete communication proto-cols in favor of standard, ubiquitous Ethernet. To this end, any new VFDs installed use Ethernet communica-tion. Many VFDs are currently being replaced in the Central Utilities Building (CUB) and the Central Exhaust Facility (CEF) and are being removed from DeviceNet in favor of Ethernet communication. Planning is underway to retrofit Eaton Intelligent Technology motor control centers (MCCs) in the Target Building to remove particu-larly troublesome DeviceNet adaptors and replace them with Ethernet adaptors for each motor starter. The Con-trolNet network in the CUB has been demolished, with I/O drops integrated into a local Ethernet network, im-proving sustainability and maintainability.

Beaushaw, Isaiah [ORNL]↗
DOE OSTI2017

Transactive Campus Energy Systems: Final Report

Transactive energy refers to the combination of economic and control techniques to improve grid reliability and efficiency. The fundamental purpose of transactive energy management is to seamlessly coordinate the operation of large numbers of new intelligent assets—such as distributed solar, energy storage and responsive building loads—to provide the flexibility needed to operate the power grid reliably and at minimum cost, particularly one filled with intermittent renewable generation such as the Pacific Northwest. It addresses the key challenge of providing smooth, stable, and predictable “control” of these assets, despite the fact that most are neither owned nor directly controlled by the power grid. The Clean Energy and Transactive Campus (CETC) work described in this report was done as part of a Cooperative Research and Development Agreement (CRADA) between the U.S. Department of Energy’s Pacific Northwest National Laboratory (PNNL) and the Washington State Department of Commerce (Commerce) through the Clean Energy Fund (CEF). The project team consisted of PNNL, the University of Washington (UW) and Washington State University (WSU), to connect the PNNL, UW, and WSU campuses to form a multi-campus testbed for transaction-based energy management—transactive—solutions. Building on the foundational transactive system established by the Pacific Northwest Smart Grid Demonstration (PNWSGD), the purpose of the project was to construct the testbed as both a regional flexibility resource and as a platform for research and development (R&D) on buildings/grid integration and information-based energy efficiency. This report provides a summary of the various tasks performed under the CRADA.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2018

DWPF Melter Off-Gas Chemistry Model for the Nitric-Glycolic Acid Flowsheet

The Defense Waste Processing Facility (DWPF) melter off-gas flammability model for the current nitric- formic acid (NFA) flowsheet was revised in Revision 0 to reflect the upcoming reductant change from formic to glycolic acid. The necessary data for the model revision was obtained during Phase 2 of the Cold-cap Evaluation Furnace (CEF) test, which was completed on March 21, 2014 after 24 days of round-the-clock feeding and pouring, including a total downtime of ~20 hours due to equipment failures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Washington Clean Energy Fund: Energy Storage System Performance Test Plans and Data Requirements

This report documents the test plans, including detailed duty cycles, used in evaluating the technical performance of five energy storage systems (ESSs) sponsored by the Washington State Clean Energy Fund (CEF). These ESSs were installed at three participating utilities’ (Avista, Snohomish Public Utility District or SnoPUD, and Puget Sound Energy or PSE) designated sites. Under each test plan, a number of baseline and use case tests are defined. This report documents the test plan for each utility, including duty cycles, data and performance reporting requirements. Baseline tests defined in this report mainly focus on determining an initial or reference performance for each ESS, which may be compared with the performance at any later time to assess the state of health of the ESS. Parameter values of a given ESS obtained from baseline tests are applied for different modeling purposes and use case tests. The stored energy capacity test is the first test conducted in the baseline test program, which generates data to calculate round trip efficiency (RTE). The response time and ramp rate tests provide the time required for an ESS to change from zero to full charging/discharging rate and hence the ramp rate, which is important in understanding ESS performance for applications calling for fast response. Internal resistance testing of ESS cells is also conducted in conjunction with the response time and ramp rate tests. Finally, the baseline tests include frequency regulation (FR) and peak shaving (PS) tests based on real-world duty cycles. Upon completion of the baseline tests, use case tests are conducted at each of the storage sites with duty cycles developed to meet the site-specific criteria and conditions. The use cases are grouped according to their intended target benefits within the electric infrastructure topology (e.g., transmission versus distribution). Although an ESS may be located on the low-voltage side of a substation that provides power to a distribution feeder, a use case that addresses bulk power services could still be provided and would be grouped under the transmission or bulk-power benefits. Use cases for ESS applications deep into the distribution circuit would be categorized under the distribution system cases.

25 ENERGY STORAGE↗
DOE OSTI2020

Development and Analysis of Control Strategies for a 1 MW/3.2 MWh Energy Storage System at Avista Utilities

This report documents the work performed by Pacific Northwest National Laboratory (PNNL) and Washington State University (WSU) supporting an effort to develop control strategies for a 1 MW/3.2 MWh energy storage system (ESS) at Avista Utilities (Avista). The ESS project is funded though the Washington Clean Energy Fund (CEF) program administered by the Washington State Department of Commerce (DOC). A tri-party Cooperative Research and Development Agreement (CRADA), namely the CRADA 360, was created in 2015 to facilitate this work.

25 ENERGY STORAGE↗
DOE OSTI2020

Washington Clean Energy Fund Grid Modernization Projects: Economic Analysis (Final Report)

As part of CEF Round 1 funding, Pacific Northwest National Laboratory (PNNL) was engaged by the U.S. Department of Energy (DOE) and the Washington Department of Commerce to work with Puget Sound Energy (PSE), Avista, and Snohomish Public Utility District (SnoPUD) in evaluating the economic and technical performance of each of their battery energy storage systems (BESSs). This report presents the final results of the economic assessment.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

Transactive Campus Energy Systems: An R&D Testbed for Renewables, Integration, Efficiency, and Grid Services (CRADA 356 / Amendment 1)

The Clean Energy and Transactive Campus (CETC) work described in this report was done as part of Amendment 1 to Campus Cooperative Research and Development Agreement (CRADA) 356, the Transactive Campus CRADA with the Washington State Department of Commerce (Commerce) between the U.S. Department of Energy’s (DOE’s), Pacific Northwest National Laboratory (PNNL) and the Commerce through the Clean Energy Fund (CEF). The original project team consisted of PNNL, the University of Washington (UW) and Washington State University (WSU), to connect the PNNL, UW, and WSU campuses to construct and operate the testbed as both a regional flexibility resource and as a platform for research and development (R&D) for buildings/grid integration. Building on the foundational transactive system established by the Pacific Northwest Smart Grid Demonstration (PNWSGD), the purpose of the project was to construct the testbed as both a regional flexibility resource and as a platform for R&D on buildings/grid integration and information-based energy efficiency. The testbed supports the integration of renewables and other regional needs, using the flexibility provided by building loads, energy storage, and smart inverters for batteries and photovoltaic (PV) solar systems, at four physical scales: multiple campuses, campus, microgrid and building.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2017

Transactive Campus Energy Systems (Final Report)

Transactive energy refers to the combination of economic and control techniques to improve grid reliability and efficiency. The fundamental purpose of transactive energy management is to seamlessly coordinate the operation of large numbers of new intelligent assets—such as distributed solar, energy storage and responsive building loads—to provide the flexibility needed to operate the power grid reliably and at minimum cost, particularly one filled with intermittent renewable generation such as the Pacific Northwest. It addresses the key challenge of providing smooth, stable, and predictable “control” of these assets, despite the fact that most are neither owned nor directly controlled by the power grid. The Clean Energy and Transactive Campus (CETC) work described in this report was done as part of a Cooperative Research and Development Agreement (CRADA) between the U.S. Department of Energy’s Pacific Northwest National Laboratory (PNNL) and the Washington State Department of Commerce (Commerce) through the Clean Energy Fund (CEF). The project team consisted of PNNL, the University of Washington (UW) and Washington State University (WSU), to connect the PNNL, UW, and WSU campuses to form a multi-campus testbed for transaction-based energy management—transactive—solutions. Building on the foundational transactive system established by the Pacific Northwest Smart Grid Demonstration (PNWSGD), the purpose of the project was to construct the testbed as both a regional flexibility resource and as a platform for research and development (R&D) on buildings/grid integration and information-based energy efficiency. This report provides a summary of the various tasks performed under the CRADA.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

Avista CEF2 Shared Energy Economy: Modeling and Simulation

This research project supported Avista’s Shared Energy Economy (SEE) Project in Spokane’s University District (UDistrict), as funded by the WA Department of Commerce Clean Energy Fund (CEF) Phase 2. The SEE project comprises a microgrid with two campus buildings, two solar photovoltaic generators, and two batteries. The microgrid can operate grid-connected or off-grid. This research project included modeling the buildings and other microgrid components, simulating a transactive energy system, and supporting Avista’s testing of different use cases for the WA Department of Commerce. The main research finding is that buildings can be modeled successfully in a data-driven approach.

14 SOLAR ENERGY↗
DOE OSTI2017

Chloroplast ATP Synthase Modulation of the Thylakoid Proton Motive Force: Implications for Photosystem I and Photosystem II Photoprotection

In wild type plants, decreasing CO 2 lowers the activity of the chloroplast ATP synthase, slowing proton efflux from the thylakoid lumen resulting in buildup of thylakoid proton motive force (pmf). The resulting acidification of the lumen regulates both light harvesting, via the qE mechanism, and photosynthetic electron transfer through the cytochrome b 6 f complex. Here in this paper, we show that the cfq mutant of Arabidopsis, harboring single point mutation in its γ-subunit of the chloroplast ATP synthase, increases the specific activity of the ATP synthase and disables its down-regulation under low CO 2 . The increased thylakoid proton conductivity (g H + ) in cfq results in decreased pmf and lumen acidification, preventing full activation of qE and more rapid electron transfer through the b6f complex, particularly under low CO 2 and fluctuating light. These conditions favor the accumulation of electrons on the acceptor side of PSI, and result in severe loss of PSI activity. Comparing the current results with previous work on the pgr5 mutant suggests a general mechanism where increased PSI photodamage in both mutants is caused by loss of pmf, rather than inhibition of CEF per se. Overall, our results support a critical role for ATP synthase regulation in maintaining photosynthetic control of electron transfer to prevent photodamage.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2017

Astrochemical Properties of Planck Cold Clumps

We observed 13 Planck cold clumps with the James Clerk Maxwell Telescope/SCUBA-2 and with the Nobeyama 45 m radio telescope. The N{sub 2}H{sup +} distribution obtained with the Nobeyama telescope is quite similar to SCUBA-2 dust distribution. The 82 GHz HC{sub 3}N, 82 GHz CCS, and 94 GHz CCS emission are often distributed differently with respect to the N{sub 2}H{sup +} emission. The CCS emission, which is known to be abundant in starless molecular cloud cores, is often very clumpy in the observed targets. We made deep single-pointing observations in DNC, HN{sup 13}C, N{sub 2}D{sup +}, and cyclic-C{sub 3}H{sub 2} toward nine clumps. The detection rate of N{sub 2}D{sup +} is 50%. Furthermore, we observed the NH{sub 3} emission toward 15 Planck cold clumps to estimate the kinetic temperature, and confirmed that most targets are cold (≲20 K). In two of the starless clumps we observed, the CCS emission is distributed as it surrounds the N{sub 2}H{sup +} core (chemically evolved gas), which resembles the case of L1544, a prestellar core showing collapse. In addition, we detected both DNC and N{sub 2}D{sup +}. These two clumps are most likely on the verge of star formation. We introduce the chemical evolution factor (CEF) for starless cores to describe the chemical evolutionary stage, and analyze the observed Planck cold clumps.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Revealing the Differences Between Free and Complexed Enzyme Mechanisms and Factors Contributing to Cell Wall Recalcitrance

Enzymatic depolymerization of polysaccharides is a key step in the production of fuels and chemicals from lignocellulosic biomass, and discovery of synergistic biomass-degrading enzyme paradigms will enable improved conversion processes. Historically, revealing insights into enzymatic saccharification mechanisms on plant cell walls has been hindered by uncharacterized substrates and low resolution imaging techniques. Also, translating findings between model substrates to intact biomass is critical for evaluating enzyme performance. Here we employ a fungal free enzyme cocktail, a complexed cellulosomal system, and a combination of the two to investigate saccharification mechanisms on cellulose I, II and III along with corn stover from Clean Fractionation (CF), which is an Organosolv pretreatment. The insoluble Cellulose Enriched Fraction (CEF) from CF contains mainly cellulose with minor amounts of residual hemicellulose and lignin, the amount of which depends on the CF pretreatment severity. Enzymatic digestions at both low and high-solids loadings demonstrate that CF reduces the amount of enzyme required to depolymerize polysaccharides relative to deacetylated, dilute acid pretreated corn stover. Transmission and scanning electron microscopy of the biomass provides evidence for the different mechanisms of enzymatic deconstruction between free and complexed enzyme systems, and reveals the basis for the synergistic relationship between the two enzyme paradigms on a process-relevant substrate for the first time. These results also demonstrate that the presence of lignin, rather than cellulose morphology, is more detrimental to cellulosome action than to free cellulases. As enzyme costs are a major economic driver for biorefineries, this study provides key inputs for the evaluation of CF as a pretreatment method for biomass conversion.

09 BIOMASS FUELS↗
DOE OSTI2014

Reactor Physics Measurements and Benchmark Specifications for Oak Ridge Highly Enriched Uranium Sphere (ORSphere)

In the early 1970s Dr. John T. Mihalczo (team leader), J.J. Lynn, and J.R. Taylor performed experiments at the Oak Ridge Critical Experiments Facility (ORCEF) with highly enriched uranium (HEU) metal (called Oak Ridge Alloy or ORALLOY) in an effort to recreate GODIVA I results with greater accuracy than those performed at Los Alamos National Laboratory in the 1950s. The purpose of the Oak Ridge ORALLOY Sphere (ORSphere) experiments was to estimate the unreflected and unmoderated critical mass of an idealized sphere of uranium metal corrected to a density, purity, and enrichment such that it could be compared with the GODIVA I experiments. Additionally, various material reactivity worths, the surface material worth coefficient, the delayed neutron fraction, the prompt neutron decay constant, relative fission density, and relative neutron importance were all measured. The critical assembly, material reactivity worths, the surface material worth coefficient, and the delayed neutron fraction were all evaluated as benchmark experiment measurements. The reactor physics measurements are the focus of this paper; although for clarity the critical assembly benchmark specifications are briefly discussed.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

Alternate Reductant Cold Cap Evaluation Furnace Phase I Testing

Savannah River Remediation (SRR) conducted a Systems Engineering Evaluation (SEE) to determine the optimum alternate reductant flowsheet for the Defense Waste Processing Facility (DWPF). Specifically, two proposed flowsheets (nitric–formic–glycolic and nitric–formic–sugar) were evaluated based upon results from preliminary testing. Comparison of the two flowsheets among evaluation criteria indicated a preference towards the nitric–formic–glycolic flowsheet. Further evaluation of this flowsheet eliminated the formic acid, and as a result, the nitric–glycolic flowsheet was recommended for further testing.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Experiments with HEU (93.14 wt.%) metal annuli with internal graphite cylinder

A variety of critical experiments were constructed of enriched uranium metal (oralloy ) during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, only three experimental configurations are described here. They are internal graphite reflected metal uranium assemblies with three different diameter HEU annuli (15-9 inches, 15-7 inches and 13-7 inches). These experiments can be found in Reference 1 and in their associated logbook

36 MATERIALS SCIENCE↗