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Quantum mechanical treatment of N and CO molecules, RKR Franck-Condon factors for gamma and beta band systems of NO, and wave functions and energy curves of LiH and BH
Coude spectrograms of comet Kohoutek obtained with the ESO 152-cm telescope in La Silla, Chile are discussed. Emission features of the C3, CH, and CO(+) molecules found in the blue region of the spectrum are considered along with measured emissions in the visual region of the spectrum. The observational and cometary data are given in tabular form.
Sounding-rocket and satellite UV observations of interstellar gas clouds are reviewed with major attention given to Copernicus observations of interstellar absorption lines. Analysis of typical absorption-line data is outlined, and observations are reviewed for atomic hydrogen as well as interstellar H2, HD, and CO molecules. Investigations of atomic abundances in H I regions are summarized, measurements of atomic deuterium abundances in the interstellar gas are examined, and the properties of ionized interstellar gas are described. Theoretical analyses of the physical state of the interstellar gas are summarized with respect to ionization by energetic radiation, cool H I clouds, and the intercloud medium. The data obtained thus far are shown to indicate mean temperatures of about 80 K, particle densities between 10 and 1000 per cu cm, and a depletion of heavy elements that becomes greatly enhanced with increasing condensation temperature for those H I regions with strong H2 lines.
Self-consistent Hartree-Fock-Slater molecular cluster models for the chemisorption of carbon monoxide on a (100) transition metal surface are presented. Energy levels and charge distribution for the CO:Ni5 cluster in C sub 4v symmetry are obtained, and the variation of binding energies with height of the CO molecule above the surface of nickel is studied in detail. Comparison is made with experimental binding energy spectra and with the multiple-scattering results of Batra and Bagus. The redistribution in energy of free-atom valence levels is studied by means of local-densities-of-states diagrams.
Far-infrared maps and multifrequency photometry are presented for M51 and its companion galaxy NGC 5195. Dust reradiates about half the starlight of the M51 + NGC 5195 system to produce the observed far-infrared (80-200 microns) luminosity of 3 x 10 to the 10th solar luminosities. Observed with 49-arcsec resolution and covering 37 arcmin-squared, the maps show that roughly 70% of this luminosity is produced by the 5 arcmin (approximately 15 kpc) wide far-infrared disk of M51. Comparable luminosities emitted from the central regions (diameters = 49 arcsec or 2.3 kpc) of M51 and NGC 5195 contribute the remaining 30% (approximately 1 x 10 to the 10th solar luminosities). The photometry reveals a difference in energetics at the galactic scale; dust producing the central luminosity of NGC 5195 classified as Ip-Ep, Irr II or SBa(r) is much less abundant and considerably warmer than the approximately 20 K dust producing the central luminosity of M51 (Sc I). Far-infrared properties are given for several galactic scale complexes of star formation in M51. Relationships are discussed for selected maps of optical starlight and emissions from these components of M51's interstellar medium: dust grains, CO molecules, hydrogen atoms, electrons, and H II regions.
The largest fraction of the matter returned by stars to the interstellar medium is probably provided by red giants. The carbon star IRC +10216 is an example of an evolved giant with a large mass loss rate. One plausible mechanism for the acceleration of the gas in stars like IRC +10216 is radiation pressure on dust grains which then collide with and transfer their momentum to the gas. However, at the present time neither infrared nor microwave observations provide a clear picture of the distribution of matter near cool red giant stars. There exists one method which may be used to obtain more information about the distribution of matter very close to the star. This method involves the measurement of the spatial extent of near-infrared lines by employing a combination of very high spatial and high spectral resolution. The present investigation is concerned with an application of this method. Speckle interferometry is used to measure the radial distribution of CO molecules on angular scales of 1 sec near IRC +10216.
The assumptions of Ayres' model of the upper solar atmosphere are examined. It is found that the bistable character of his model is postulated - through the assumptions concerning the opacity sources and the effect of mechanical waves, which are allowed to destroy the CO molecules but not to heat the gas. The neglect of cooling by metal lines is based on their reduced local cooling rate, but it ignores the increased depth over which this cooling occurs. Thus, the bifurcated model of the upper solar atmosphere consists of two models, one cold at the temperature minimum, with a kinetic temperature of 2900 K, and the other hot, with a temperature of 4900 K.
The line radiations emitted in the cooling gas behind a fast dissociative shock are studied. The intensities emitted in high rotational transitions of the neutral molecules CO, SiO, HCN, CN, NO, and SO are estimated, as well as in rovibrational transitions of the molecular ions HeH(+) and OH(+) in radio recombination lines of atomic hydrogen and in fine-structure transitions of C, C(+), O, and Si(+). The predictions are compared with the observed intensities of line emission from the Orion-KL region. For Orion-KL the observations do not exclude, but probably do not require, the presence of a fast dissociative shock. Emission from SiO in high-J rotational states and from vibrationally excited OH(+), HeH(+), HeH(+), and SO(+) may be detectable from dissociative shocks under suitable conditions of preshock density and shock velocity; such emission may prove to be a useful diagnostic probe of fast shock activity.
A source of hyperthermal, ground-state, impurity-free, atomic oxygen of an energy variable in the range 2-100 eV has been developed. Experimental results are presented of emission spectra in the wavelength range 250-850 nm produced by collisions of 5-eV O(3P) atoms with adsorbed NO and CO molecules on a MgF2 surface.
A cryogenic IR echelle grating spectrometer has been used to probe the nu = 1-0 rovibrational band of the CO molecule in Comet Austin. Line emission has been detected at the Doppler-shifted frequency expected for the cometary P(3) line, in scans which are noted to cover only the first 3000 sec of May 16, 1990 observations; this is suggested to be due to an outburst of comparable duration. No detections were made of the P(2) line, which was predicted by models to occur at the 3.5 sigma level even for relatively high coma temperatures. If the outburst was accompanied by enhanced dust production, an increase by a factor of 2.5 is consistent with the present observational data and CO/dust may have been enriched in the outbursting volume relative to the remainder of the nucleus.
We have mapped the Large Magellanic Cloud (the LMC) in the (C II) 158 microns fine-structure line with the Balloon-borne Infrared Carbon Explorer (BICE) system. The (C II) line emission was detected over most of the LMC. The mean (C II)/CO (J = 1-0) line intensity ratio was 23,000 18 times larger than the typical value observed in the Galactic plane (1300). This result implies that each clump of the molecular clouds in the LMC has a larger C(+) envelope relative to its CO core than those in our Galaxy. Lower dust abundance due to its lower metallicity allows UV photons, which convert CO molecules into C(+) ions, to penetrate deeper into the clumps in the LMC than in our Galaxy.
Most interstellar species have a large fraction of their electronic transitions at far ultraviolet wavelengths. Observations at these wavelengths reveal spectra rich in absorption lines seen against the continuum of a background source, such as a hot star in our Galaxy, a supernova in a nearby galaxy, or even a bright nucleus in an active galaxy. Most of the observations continue to be made with space-borne instruments, but recent work includes measurements of extragalactic material at large redshifts obtained at high resolution with large ground-based telescopes (e.g., the Keck Telescope). The combination of precise experimental oscillator strengths, large-scale computations, and astronomical spectra with high signal-to-noise ratios are yielding a set of self-consistent-values that span a range in strength in excess of 100 for more and more species. The large range is important for studies involving the different environments probed by the various background sources. This review highlights recent work on the atomic species. Si II, S I, and Fe II, and on the molecules, CO and C2.
We present the results of a systematic survey of the chemical properties of two giant molecular cloud (GMC) cores in M17 and Cepheus A. In all, we have mapped the emission from 32 molecular transitions of 13 molecules and seven isotopic variants over a 4' x 5' region in each core. Each map includes known sites of massive star formation, as well as the more extended quiescent material. In M17 most molecules have emission peaks away from the H II region/molecular cloud interface, while two species, HC3N and CH3C2H, deviate from this structure with sharp maxima closer to this interface. In Cepheus A the core is influenced by a compact high-velocity molecular outflow and a more extended low-velocity flow. The molecular emission distributions in this source are generally quite similar, with most molecules peaking near the center of the core to the east of the compact H II region HW 2. A few molecules, SO, CH3OH, H13CN, and C18O, have more extended emission. Only two molecules, CO and HCO+, appear to trace the high- and low-velocity outflows; all other species are tracing the quiescent core. We have used the results of previous studies of the density and temperature of the dense gas in the same cloud cores to derive accurate abundances relative to CO for several positions in each core. The principal result is that the chemical composition of all the cores we have surveyed (which include OMC-1 as well as M17 and Cepheus A) show remarkable similarity, both within a given core and among the cores. This suggests that the chemical processes are similar in quiescent GMC core material. In M17 the lack of variation of molecular abundances is remarkable because the radiation field and the gas temperature are known to vary appreciably throughout the surveyed region, suggesting that the bulk of the emission arises from gas that is well shielded from radiation.
The carbon-to-oxygen ratio (C/O) in a planet provides critical information about its primordial origins and subsequent evolution. A primordial C/O greater than 0.8 causes a carbide-dominated interior as opposed to the silicate-dominated composition as found on Earth; the solar C/O is 0.54. Theory, shows that high C/O leads to a diversity of carbon-rich planets that can have very different interiors and atmospheres from those in the solar system. Here we report the detection of C/O greater than or equal to 1 in a planetary atmosphere. The transiting hot Jupiter WASP-12b has a dayside atmosphere depleted in water vapour and enhanced in methane by over two orders of magnitude compared to a solar-abundance chemical equilibrium model at the expected temperatures. The observed concentrations of the prominent molecules CO, CH4, and H2O are consistent with theoretical expectations for an atmosphere with the observed C/O = 1. The C/O ratios are not known for giant planets in the solar system, although they are expected to equal the solar value. If high C/O ratios are common, then extrasolar planets are likely very different in interior composition, and formed very differently, from expectations based on solar composition, potentially explaining the large diversity in observed radii. We also find that the extremely irradiated atmosphere (greater than 2500 K) of WASP-12b lacks a prominent thermal inversion, or a stratosphere, and has very efficient day-night energy circulation. The absence of a strong thermal inversion is in stark contrast to theoretical predictions for the most highly irradiated hot-Jupiter atmospheres.
Potential energy curves for the Chi (sup 1) Epsilon (sup plus), alpha (sup 3) II (sub r), alpha prime (sup 3) epsilon (sup plus), d (sup 3) delta, e (sup 3) Epsilon (sup minus), Alpha (sup 1) II, and Beta (sup 1) Epsilon (sup plus), electronic states of the CO molecule have been calculated by the Rydberg-Klein-Rees method. The curve for the A III state will have to bend sharply in the range between 1.9 and 2.1 angstroms or it will have to pass through a maximum to reach the proper dissociation limit.
Gas molecule clustering within nanopores holds significance in the fields of nanofluidics, biology, gas adsorption/desorption, and geological gas storage. However, the intricate roles of nanoconfinement and surface chemistry that govern the formation of gas clusters remain inadequately explored. In this study, through free energy calculation in molecular simulations, we systematically compared the tendencies of H 2 and CO 2 molecules to aggregate within hydrated hydrophobic pyrophyllite and hydrophilic gibbsite nanopores. The results indicate that nanoconfinement enhances gas dimer formation in the nanopores, irrespective of surface chemistry. However, surface hydrophilicity prohibits the formation of gas clusters larger than dimers, while large gas clusters form easily in hydrophobic nanopores. Despite H 2 and CO 2 both being non-polar, the larger quadrupole moment of CO 2 leads to a stronger preference for dimer/cluster formation compared to H 2 . Here, our results also indicate that gases prefer to enter the nanopores as individual molecules, but exit the nanopores as dimers/clusters. This investigation provides a mechanistic understanding of gas cluster formation within nanopores, which is relevant to various applications, including geological gas storage.
Metastable radiative lifetimes of molecular states of nitrogen and CO, using time of flight and high resolution electron gun techniques
Perturbation theory of heteronuclear diatomic molecules based on isoelectronic homonuclear molecules applied to carbon monoxide and nitrogen