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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Overview of the Airborne Tropical TRopopause EX

The NASA Airborne Tropical TRopopause EXperiment (ATTREX) is a series of airborne campaigns focused on understanding physical processes in the Tropical Tropopause Layer (TTL) and their role in atmospheric chemistry and climate. ATTREX is using the high-altitude, long-duration NASA Global Hawk Unmanned Air System to make in situ and remote-sensing measurements spanning the Pacific. A particular ATIREX emphasis is to better understand the dehydration of air as it passes through the cold tropical tropopause region. The ATTREX payload contains 12 in situ and remote sensing instruments that measure water vapor, clouds, multiple gaseous tracers (CO, CO2, CH4, NMHC, SF6, CFCs, N2O), reactive chemical compounds (O3, BrO, NO2), meteorological parameters, and radiative fluxes. ATTREX flight series have been conducted in the fall of 2011 from Armstrong Flight Research Center (AFRC) in California, in the winter of 2013 from AFRC, and in the winter/spring of 2014 from Guam. The first two f light series provided extensive sampling of the central and eastern Pacific, whereas the last flight series permitted sampling in the western Pacific. The sampling strategy has primarily involved repeated ascents and descents through the depth of the TTL (about 13-19 km). Over 100 TTL profiles were obtained on each flight series. The ATTREX dataset includes TTL water vapor measurements with unprecedented accuracy, ice crystal size distributions and habits. The cloud and water measurements provide unique information about TTL cloud formation, the persistence of supersaturation with respect to ice, and dehydration. The plethora of tracers measured on the Global Hawk flights are providing unique information about TTL transport pathways and time scales. The meteorological measurements are revealing dynamical phenomena controlling the TTL thermal structure, and the radiation measurements are providing information about heating rates associated with TTL clouds and water vapor. This presentation will provide an overview of the ATTREX flights, examples of measurements from the flights, and plans for modeling/analysis of the ATTREX dataset.

Airborne↗
NASA NTRS2015

Overview of the NASA Airborne Tropical TRopopause EXperiment (ATTREX)

The NASA Airborne Tropical TRopopause EXperiment (ATTREX) is a series of airborne campaigns focused on understanding physical processes in the Tropical Tropopause Layer (TTL) and their role in atmospheric chemistry and climate. ATTREX is using the high-altitude, long-duration NASA Global Hawk Unmanned Air System to make in situ and remote-sensing measurements spanning the Pacific. A particular ATTREX emphasis is to better understand the dehydration of air as it passes through the cold tropical tropopause region. The ATTREX payload contains 12 in situ and remote sensing instruments that measure water vapor, clouds, multiple gaseous tracers (CO, CO2, CH4, NMHC, SF6, CFCs, N2O), reactive chemical compounds (O3, BrO, NO2), meteorological parameters, and radiative fluxes.ATTREX flight series have been conducted in the fall of 2011 from Armstrong Flight Research Center (AFRC) in California, in the winter of 2013 from AFRC, and in the winterspring of 2014 from Guam. The first two flight series provided extensive sampling of the central and eastern Pacific, whereas the last flight series permitted sampling in the western Pacific. The sampling strategy has primarily involved repeated ascents and descents through the depth of the TTL (about 13-19 km). Over 100 TTL profiles were obtained on each flight series. The ATTREX dataset includes TTL water vapor measurements with unprecedented accuracy, ice crystal size distributions and habits. The cloud and water measurements provide unique information about TTL cloud formation, the persistence of supersaturation with respect to ice, and dehydration. The plethora of tracers measured on the Global Hawk flights are providing unique information about TTL transport pathways and time scales. The meteorological measurements are revealing dynamical phenomena controlling the TTL thermal structure, and the radiation measurements are providing information about heating rates associated with TTL clouds and water vapor.This presentation will provide an overview of the ATTREX flights, examples of measurements from the flights, and plans for modelinganalysis of the ATTREX dataset.

Jensen, Eric J.↗
NASA NTRS2018

Organic Ices in Titan's Stratosphere

Titan’s stratospheric ice clouds are by far the most complex of any observed in the solar system, with over a dozen organic vapors condensing out to form a suite of pure and co-condensed ices, typically observed at high winter polar latitudes. Once these stratospheric ices are formed, they will diffuse throughout Titan’s lower atmosphere and most will eventually precipitate to the surface, where they are expected to contribute to Titan’s regolith. Early and important contributions were first made by the InfraRed Interferometer Spectrometer (IRIS) on Voyager 1, followed by notable contributions from IRIS’ successor, the Cassini Composite InfraRed Spectrometer (CIRS), and to a lesser extent, from Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) instruments. All three remote sensing instruments made new ice cloud discoveries, combined with monitoring the seasonal behaviors and time evolution throughout Cassini’s 13-year mission tenure. A significant advance by CIRS was the realization that co-condensing chemical compounds can account for many of the CIRS-observed stratospheric ice cloud spectral features, especially for some that were previously puzzling, even though some of the observed spectral features are still not well understood. Relevant laboratory transmission spectroscopy efforts began just after the Voyager encounters, and have accelerated in the last few years due to new experimental efforts aimed at simulating co-condensed ices in Titan’s stratosphere. This review details the current state of knowledge regarding the organic ice clouds in Titan’s stratosphere, with perspectives from both observational and experimental standpoints.

Astronomy↗
NASA NTRS2018

Organic Ices in Titan's Stratosphere

Titan’s stratospheric ice clouds are by far the most complex of any observed in the solar system, with over a dozen organic vapors condensing out to form a suite of pure and co-condensed ices, typically observed at high winter polar latitudes. Once these stratospheric ices are formed, they will diffuse throughout Titan’s lower atmosphere and most will eventually precipitate to the surface, where they are expected to contribute to Titan’s regolith. Early and important contributions were first made by the InfraRed Interferometer Spectrometer (IRIS) on Voyager 1, followed by notable contributions from IRIS’ successor, the Cassini Composite InfraRed Spectrometer (CIRS), and to a lesser extent, from Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) instruments. All three remote sensing instruments made new ice cloud discoveries, combined with monitoring the seasonal behaviors and time evolution throughout Cassini’s 13-year mission tenure. A significant advance by CIRS was the realization that co-condensing chemical compounds can account for many of the CIRS-observed stratospheric ice cloud spectral features, especially for some that were previously puzzling, even though some of the observed spectral features are still not well understood. Relevant laboratory transmission spectroscopy efforts began just after the Voyager encounters, and have accelerated in the last few years due to new experimental efforts aimed at simulating co-condensed ices in Titan’s stratosphere. This review details the current state of knowledge regarding the organic ice clouds in Titan’s stratosphere, with perspectives from both observational and experimental standpoints.

C. M. Anderson↗
NASA NTRS2018

Organic Ices in Titan’s Stratosphere

Titan’s stratospheric ice clouds are by far the most complex of any observed in the solar system, with over a dozen organic vapors condensing out to form a suite of pure and co-condensed ices, typically observed at high winter polar latitudes. Once these stratospheric ices are formed, they will diffuse throughout Titan’s lower atmosphere and most will eventually precipitate to the surface, where they are expected to contribute to Titan’s regolith. Early and important contributions were first made by the InfraRed Interferometer Spectrometer (IRIS) on Voyager 1, followed by notable contributions from IRIS’ successor, the Cassini Composite InfraRed Spectrometer (CIRS), and to a lesser extent, from Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) instruments. All three remote sensing instruments made new ice cloud discoveries, combined with monitoring the seasonal behaviors and time evolution throughout Cassini’s 13-year mission tenure. A significant advance by CIRS was the realization that co-condensing chemical compounds can account for many of the CIRS-observed stratospheric ice cloud spectral features, especially for some that were previously puzzling, even though some of the observed spectral features are still not well understood. Relevant laboratory transmission spectroscopy efforts began just after the Voyager encounters, and have accelerated in the last few years due to new experimental efforts aimed at simulating co-condensed ices in Titan’s stratosphere. This review details the current state of knowledge regarding the organic ice clouds in Titan’s stratosphere, with perspectives from both an observational and experimental standpoint.

Ices↗
NASA NTRS2020

Returning Samples from Enceladus for Life Detection

Evidence suggests that Saturn’s icy moon Enceladus has a subsurface ocean that sources plumes of water vapor and ice vented to space from its south pole. In situ analyses of this material by the Cassini spacecraft have shown that the ocean contains key ingredients for life (elements H, C, N, O and possibly S; simple and complex organic compounds; chemical disequilibria at water-rock interfaces; clement temperature, pressure, and pH). The Cassini discoveries make Enceladus’ interior a prime locale for life detection beyond Earth. Scant material exchange with the inner Solar System makes it likely that such life would have emerged independently of life on Earth. Thus, its discovery would illuminate life’s universal characteristics. The alternative result of an upper bound on a detectable biosphere in an otherwise habitable environment would likewise considerably advance our understanding of the prevalence of life beyond Earth. Here we outline the rationale for returning vented ocean samples, accessible from Enceladus’ surface or low altitudes, to Earth for life detection. Returning samples allows analyses using laboratory instruments that cannot be flown, with decades or more to adapt and repeat analyses. We describe an example set of measurements to estimate the amount of sample to be returned and discuss possible mission architectures and collection approaches. We then turn to the challenges of preserving sample integrity and implementing planetary protection policy. We conclude by placing such a mission in the broader context of Solar System exploration.

Enceladus↗
NASA NTRS1995

Preparation of Thermoelectric Materials from Melts

The most common methods to prepare semiconductors are based on use of melts or vapor phase. A tendency to use thin film structures in modern semiconducting devices brought a variety of technologies based on vapor phase deposition. The preparation of chemical compounds and solid solutions from a melt begins with melting the elemental constituents together. Melt technology and techniques are discussed.

thermoelectric↗
NASA NTRS2023

Spacecraft Water Exposure Guidelines: Revision A

The enclosed table lists official Spacecraft Water Exposure Guidelines (SWEGs), which are guideline values set by the NASA/JSC Toxicology Group in cooperation with the National Research Council Committee on Toxicology (NRCCOT) or through publication in the peer‐reviewed scientific literature. Based on documented guidance (NRC, 2000), NASA has established SWEGs for 30 chemical compounds that are particularly relevant to water systems on the International Space Station (ISS) as well as on spacecraft for deep‐space exploration. Summaries of these SWEGs are presented in tabular form as part of this publication.

SWEGs↗
NASA NTRS1993

Thermodynamic analysis of chemical compatibility of several compounds with Fe-Cr-Al alloys

Chemical compatibility between Fe-19.8Cr-4.8Al (weight percent), which is the base composition for the commercial superalloy MA956, and several carbides, borides, nitrides, oxides, and silicides was analyzed from thermodynamic considerations. The effect of addition of minor alloying elements, such as Ti, Y, and Y2O3, to the Fe-Cr-Al alloy on chemical compatibility between the alloy and various compounds was also analyzed. Several chemically compatible compounds that can be potential reinforcement materials and/or interface coating materials for Fe-Cr-Al based composites were identified.

Misra, Ajay K.↗
NASA NTRS1985

Anti-Fog Compound

Tracer Chemical Corporation's TRX Anti-Fog Composition is an inexpensive product which prevents condensation on plastic and glass surfaces. It was the result from a Tech Briefs article detailing a Johnson Space Center compound.

Source record↗
NASA NTRS2005

In situ Analysis of Organic Compounds on Mars using Chemical Derivatization and Gas Chromatography Mass Spectrometry

One of the core science objectives of NASA's 2009 Mars Science Laboratory (MSL) mission is to determine the past or present habitability of Mars. The search for key organic compounds relevant to terrestrial life will be an important part of that assessment. We have developed a protocol for the analysis of amino acids and carboxylic acids in Mars analogue materials using gas chromatography mass spectrometry (GCMS). As shown, a variety of carboxylic acids were readily identified in soil collected from the Atacama Desert in Chile at part-per-billion levels by GCMS after extraction and chemical derivatization using the reagent N,N-tert.-butyl (dimethylsilyl) trifluoroacetamide (MTBSTFA). Several derivatized amino acids including glycine and alanine were also detected by GCMS in the Atacama soil at lower concentrations (chromatogram not shown). Lacking derivatization capability, the Viking pyrolysis GCMS instruments could not have detected amino acids and carboxylic acids, since these non-volatile compounds require chemical transformation into volatile species that are stable in a GC column. We are currently optimizing the chemical extraction and derivatization technique for in situ GCMS analysis on Mars. Laboratory results of analyses of Atacama Desert samples and other Mars analogue materials using this protocol will be presented.

Glavin, D. P.↗
NASA NTRS1995

IMS software developments for the detection of chemical warfare agent

Interference compounds like gasoline, diesel, burning wood or fuel, etc. are presented in common battlefield situations. These compounds can cause detectors to respond as a false positive or interfere with the detector's ability to respond to target compounds such as chemical warfare agents. To ensure proper response of the ion mobility spectrometer to chemical warfare agents, two special software packages were developed and incorporated into the Bruker RAID-1. The programs suppress interferring signals caused by car exhaust or smoke gases resulting from burning materials and correct the influence of variable sample gas humidity which is important for detection and quantification of blister agents like mustard gas or lewisite.

Klepel, ST.↗
NASA NTRS2000

Theoretical Study of Indium Compounds of Interest for Organometallic Chemical Vapor Deposition

The structural. electronic and therinochemical properties of indium compounds which are of interest in halide transport and organometallic chemical vapor deposition processes have been studied by ab initio and statistical mechanics methods. The compounds reported include: indium halides and hydrides (InF, InCl, InCl3, InH, InH2, InH3); indium clusters (In2, In3); methylindium, dimethylindium, and their hydrogen derivatives [In(CH3), In(CH3)H, In(CH3)H2, In(CH3)2, In(CH3)2H]; dimethyl-indium dimer [In2(CH3)4], trimethyl-indium [In(CH3)3]; dehydrogenated methyl, dimethyl and trimethylindium [In(CH3)2CH2, In(CH3)CH2, In(CH2)], trimethylindium adducts with ammonia, trimethylamine and hydrazine [(CH3)3In:NH3, (CH3)3In:N(CH3)3, (CH3)3In:N(H2)N(H2)]; dimethylamino-indium and methylimino-indium [In(CH3)2(NH2), In(CH3)(NH)]; indium nitride and indium nitride dimer (InN, In2N2), indium phosphide, arsenide and antimonide ([InP, InAs, InSb). The predicted electronic properties are based on density functional theory calculations; the calculated thermodynamic properties are reported following the format of the JANAF (Joint Army, Navy, NASA, Air Force) Tables. Equilibrium compositions at two temperatures (298 and 1000 K) have been analyzed for groups of competing simultaneous reactions.

Cardelino, B. H.↗
NASA NTRS2008

Micro- and Nanostructured Metal Oxide Chemical Sensors for Volatile Organic Compounds

Aeronautic and space applications warrant the development of chemical sensors which operate in a variety of environments. This technical memorandum incorporates various kinds of chemical sensors and ways to improve their performance. The results of exploratory investigation of the binary composite polycrystalline thick-films such as SnO2-WO3, SnO2-In2O3, SnO2-ZnO for the detection of volatile organic compound (isopropanol) are reported. A short review of the present status of the new types of nanostructured sensors such as nanobelts, nanorods, nanotube, etc. based on metal oxides is presented.

Alim, M. A.↗
NASA NTRS1993

Model for the Vaporization of Mixed Organometallic Compounds in the Metalorganic Chemical Vapor Deposition of High Temperature Superconducting Films

A model of the vaporization and mass transport of mixed organometallics from a single source for thin film metalorganic chemical vapor deposition is presented. A stoichiometric gas phase can be obtained from a mixture of the organometallics in the desired mole ratios, in spite of differences in the volatilities of the individual compounds. Proper film composition and growth rates are obtained by controlling the velocity of a carriage containing the organometallics through the heating zone of a vaporizer.

Meng, Guangyao↗