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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Nanocomposite battery electrode particles with changing properties

Battery electrode compositions and methods of fabrication are provided that utilize composite particles. Each of the composite particles may comprise, for example, a high-capacity active material and a porous, electrically-conductive scaffolding matrix material. The active material may store and release ions during battery operation, and may exhibit (i) a specific capacity of at least 220 mAh/g as a cathode active material or (ii) a specific capacity of at least 400 mAh/g as an anode active material. The active material may be disposed in the pores of the scaffolding matrix material. According to various designs, each composite particle may exhibit at least one material property that changes from the center to the perimeter of the scaffolding matrix material.

Yushin, Gleb↗
DOE OSTI2023

Aligned carbon fibers-carbon nanotube-polymer-based composite as lithium-ion battery current collector

High energy density demand is pushing the development of high-voltage cathode materials, which necessitates improved electrochemical stability of other battery components such as binders, electrolytes, and current collectors. Current collectors are considered to be an inactive component but still play an essential role. In this study, a metal-free composite film containing directionally aligned carbon fiber (CF), carbon nanotube (CNT), and polymer (P) was developed to replace aluminum foil as a cathode current collector, which relies on forming an Al 2 O 3 layer to ensure electrochemical stability at high voltage. Here, each component in the new cathode current collector played a functional role. The CNTs provided uniform current densities, and CFs improved the electronic conductivity and mechanical strength of the composite material. The polymer enhanced the adhesion of the cathode coating with the current collector and provided an impervious support to the cathode materials. The CF-CNT-P composite demonstrated excellent electrochemical and thermal stability. Cathodes coated on the CF-CNT-P composite exhibited lower charge transfer resistance, improved rate capability, and improved cyclic stability compared with the cathodes deposited on conventional aluminum foil. Additionally, the composite current collector was lighter (1.81 mg/cm 2 and 15 µm thick) than the commonly used aluminum foil (4.35 mg/cm2 and 15 µm thick), which can increase the cell energy density. Additionally, the CF-CNT-P did not need to be separated from the cathode coating during recycling and can be burnt out with binder, simplifying the recycling process.

25 ENERGY STORAGE↗
DOE OSTI2021

Quantifying the reaction mechanisms of a high-capacity CuP 2 /C composite anode for potassium ion batteries

Introducing metals into phosphorus to form metal phosphide materials as anodes for potassium ion batteries (PIBs) is an effective strategy to improve the electronic conductivity and alleviate the volume change during cycling, although with a compromise of capacity. Here in this paper, we explore a CuP 2 /C composite as a novel anode for PIBs, which delivers a high reversible capacity of >450 mA h g -1 . Unexpectedly, our results reveal that the POx components existing in the prepared composite are reversible, through a quantitative analysis via high-resolution solid-state 31 P NMR and synchrotron X-ray diffraction tests. Their potassiation products K 3 PO 4 and K 4 P 2 O 7 can react with K–P alloys and turn back to PO x during depotassiation, which probably accounts for the high capacity of the prepared material. The results also illustrate a crystallization–amorphization evolution process during cycling involving nanocrystalline α-K 4 P 6 , K 4 P 3 and KP, and amorphous K 4 P 6 , KP and K 3 P phases, among which, the amorphous phases are identified for the first time.

25 ENERGY STORAGE↗
DOE OSTI2025

Effective Li-Ion Transport Quantification in Composite Cathodes for All-Solid-State Batteries via Multiscale Modeling and Experiments

The tortuosity factor of composite cathodes significantly affects the rate performance of all-solid-state batteries (ASSBs) and has significant differences from systems with liquid electrolytes. Here, in this work, we report a simulation-experiment combined approach that quantifies the effective Li-ion transport in an ASSB composite cathode, which links tortuosity factor on ∼ μm scale to terminal voltage during cycling at the cell level (on ∼ cm scale). Two independent approaches of tortuosity factor quantification are considered: fitting electrochemical cycling data and verifying at different cycling rates and calculating from segmented tomography images, with the tortuosity factor quantified from both methods reaching self-consistency. The simulated terminal voltage using the quantified tortuosity factor has a small relative error of <3% compared to the experimental measurements. We find a significantly reduced value of the Bruggeman exponent of the catholyte phase (1.75), and using shape analysis, we show that rod-shaped catholyte particles play an important role in lowering the tortuosity factor.

Yao, Archie Mingze [Univ. of Michigan, Ann Arbor, ↗
DOE OSTI2022

Battery aging mode identification across NMC compositions and designs using machine learning

A comprehensive understanding of lithium-ion battery (LiB) lifespan is the key to designing durable batteries and optimizing use protocols. Although battery lifetime prediction methods are flourishing, diagnosis of the root causes of aging and degradation have not yet been well developed nor studied for a broad mixture of designs and use cases. Here, we create a machine-learning (ML)-based framework that distinguishes aging modes using multiple electrochemical signatures recorded cycle-by-cycle. The predominant aging behaviors include a combination of loss of active materials in cathode (LAMPE) and a loss of Li inventory (LLI) in Li plating or solid electrolyte interphase (SEI) formation, manifested from 44 batteries representing two cathode chemistries, two electrode loadings, and five charging rates. Here, the aging mode classification accuracy is 86% using features within the first 50 cycles and increases to 88% beyond 225 cycles. The same features can quantify the percentage of end-of-life LAMPE with only 4.3% of error.

25 ENERGY STORAGE↗
DOE OSTI2026

Electrostatic‐Attraction‐Driven Self‐Assembled Graphene‐Disordered Rocksalt Composite Cathode for Lithium‐Ion Batteries

Disordered rocksalt cathodes hold promise for achieving high-capacity lithium-ion batteries while using low-cost, earth-abundant elements. However, their electrochemical performance remains critically limited by their poor electronic conductivity. Conventional strategies such as high-energy ball milling with excess carbon additives can improve conductivity but remain challenging to scale and often produce defects and increase surface area, thereby accelerating capacity degradation. Herein, we report an alternative approach of electrostatic-attraction-driven self-assembly to fabricate Li 1.2 Mn 0.6 Ti 0.2 O 1.8 F 0.2 (LMTOF) particles uniformly wrapped with electronically conductive graphene sheets without associated materials degradation. The graphene-wrapped LMTOF demonstrates significantly improved cycling stability (89% capacity retention after 100 cycles) and superior rate capability compared with an LMTOF-carbon composite electrode fabricated using the conventional high-energy ball-milling process. Post-cycling analysis reveals reduced oxygen evolution, suppressed unwanted side reactions, and improved structural integrity for the graphene-LMTOF composite. This work highlights the advantages of solution-based carbon wrapping and offers a scalable strategy to prepare high-performance DRX cathodes for lithium-ion batteries.

carbon composite↗
DOE OSTI2020

Stable lithium fluoride-based cathodes for metal and metal-ion batteries

A battery electrode composition is provided that comprises composite particles. Each composite particle may comprise, for example, active lithium fluoride/metal nanocomposite material optionally embedded into a nanoporous, electrically-conductive skeleton matrix material particle(s), where each of these composite particles is further encased in a Li-ion permeable, chemically and mechanically robust, protective outer shell that is impermeable to electrolyte solvent molecules. The active lithium fluoride/metal nanocomposite material is provided to store and release Li ions during battery operation.

25 ENERGY STORAGE↗
DOE OSTI2021

Polyfluorinated carbonate electrolyte for high-voltage lithium batteries

A non-aqueous solvent composition for a lithium battery comprises a fluorinated solvent mixture that consists essentially of a 1,2-difluoroethylene carbonate and a fluoro-substituted dialkyl carbonate in a respective weight ratio of about 1:3 to about 1:1, and optionally up to about 30 wt % of an additional organic solvent. An electrolyte for a lithium ion battery comprises a lithium salt dissolved in a non-aqueous solvent composition comprising the fluorinated solvent mixture.

Zhang, Zhengcheng↗
DOE OSTI2020

Encapsulated Sb and Sb 2 O 3 particles in waste-tire derived carbon as stable composite anodes for sodium-ion batteries

A conductive network of waste-tire derived carbon (WTC) was used to produce homogeneous Sb/WTC and Sb 2 O 3 /WTC composite materials via ball milling as promising anodes for sodium-ion batteries (SIBs). Highly reversible redox peaks at 0.81/0.71, 0.25 V for Sb/WTC and 0.80/0.76, 0.21/0.26 V for Sb 2 O 3 /WTC anodes have been observed related to Na + intercalation and deintercalation in carbon and Na–Sb and Na 3 Sb as plausible conversion/alloy reactions. Sodium half-cells delivered reversible discharge capacities of 206 mA h g -1 and 207 mA h g -1 at a current density of 37 mA g -1 for the composite Sb/WTC and Sb 2 O 3 /WTC materials, respectively. Both the Sb/WTC and Sb 2 O 3 /WTC composite materials showed impressive capacity retention with 85% and 88%, respectively after 100 cycles. Furthermore, rate capability studies at 60 °C yielded an enhanced capacity of 240 mA h g -1 for Sb/WTC and 300 mA h g -1 for Sb 2 O 3 /WTC at 37 mA g -1 .

25 ENERGY STORAGE↗
DOE OSTI2025

Advancements in active filler-contained polymer solid-state electrolytes for lithium-metal batteries: A concise review

Lithium-metal batteries (LMBs) usually are regarded as the pinnacle of next-generation energy storage due to the high specific capacity and low redox potential of the Li-metal anode. However, their development is hindered by safety hazards related to flammable electrolytes and uncontrolled side reactions within the battery. Both polymer and solid-state inorganic electrolytes, despite their potential, exhibit shortcomings that limit their practical applications. Active filler-containing polymer electrolytes (AFPEs) offer a promising solution by combining the benefits of both types. Enhanced by supramolecular interactions between the polymer matrix and active fillers, AFPEs demonstrate superior electrochemical performance over traditional polymer electrolytes. This review discusses the progress in active fillers and various polymer matrices, examining the factors that enhance performance, particularly ionic conductivity. It also outlines the future research directions of AFPEs, aiming to broaden the application of solid electrolytes in high-performance LMBs.

All solid-state batteries↗
DOE OSTI2020

Well-to-Wheels Analysis of Zero-Emission Plug-In Battery Electric Vehicle Technology for Medium- and Heavy-Duty Trucks

Conventional diesel medium- and heavy-duty vehicles (MHDVs) create large amount of air emissions. With the advancement in technology and reduction in the cost of batteries, plug-in battery electric vehicles (BEVs) are increasingly attractive options for improving energy efficiency and reducing air emissions of MHDVs. In this paper, we compared the well-to-wheels (WTW) greenhouse gases (GHGs) and criteria air pollutant emissions of MHD BEVs with their conventional diesel counterparts across weight classes and vocations. We expanded the Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET) model to conduct the WTW analysis of MHDVs. The fuel economy for a wide range of MHDV weight classes and vocations, over various driving cycles, was evaluated using a high-fidelity vehicle dynamic simulation software (Autonomie). The environmental impacts of MHD BEVs are sensitive to the source of electricity used to recharge their batteries. The WTW results show that MHD BEVs significantly improve environmental sustainability of MHDVs by providing deep reductions in WTW GHGs, nitrogen oxides, volatile organic compounds, and carbon monoxide emissions, compared to conventional diesel counterparts. Increasing shares of renewable and natural gas technologies in future national and regional electricity generation are expected to reduce WTW particulate matters and sulfur oxide emissions for further improvement of the environmental performance of MHD BEVs.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2022

Non-Conductive Polymers Enable Higher Ionic Conductivities and Suppress Reactivity in Hybrid Sulfide-Polymer Solid State Electrolytes

Hybrid ceramic-polymer solid state electrolytes are promising candidates to enable energy-dense lithium metal batteries by leveraging inorganic high ionic conductivity and flexible polymer mechanical properties. However, studies of hybrid electrolytes using sulfide-type inorganics such as Li3PS4 (LPS) have largely focused on combining the inorganic with commercial poly(ethylene oxide) (PEO). PEO has proven to be insufficient for use in hybrid systems because it reacts with LPS and provides a competing pathway for ion transport, therefore producing a hybrid with low conductivity. Our work shows that using nonconductive, nonpolar polyethylene (PE) in a hybrid electrolyte with LPS eliminates both polymer and inorganic degradation and remarkably exhibit higher conductivities than those containing PEO at different polymer and salt concentrations. Using tracer-exchange NMR, we observe that the nonconductive nature of PE allows for iontransport through the inorganic whereas PEO provides a separate, competing pathway for lithium transport. Furthermore, compared to pure LPS, these hybrids enable longer term lithium cycling at 60°C. Our work shows that the path to enabling conductive and stable sulfide hybrids for solid state lithium metal batteries may be through the use of nonconductive, nonreactive polymers.

batteries↗
DOE OSTI2022

Nanoengineering Porous Silica for Thermal Management

Thermal insulation of solid materials originates from the nanoscale porous architectures to regulate thermal management in energy-critical applications from energy-efficient buildings to heat-sensitive energy devices. Here, we show nanoengineering of porous silica materials to control the architecture transition from mesoporous to nanocage networks. A low thermal conductivity of such a porous silica network is achieved at 0.018 W/(m K) while exhibiting a porosity of 92.05%, specific surface area of 504 m 2 /g, and pore volume of 2.37 cm 3 /g after ambient pressure drying. Meanwhile, the crosslinking of the porous silica and ceramic fiber frameworks show a tensile Young’s modulus of 2.8 MPa while maintaining high thermal insulation, which provides an effective thermal runway mitigation strategy for rechargeable lithium-ion batteries. Furthermore, the nanoengineering strategy reported here would shed light on achieving superthermal insulation of nanostructures for energy-critical applications.

36 MATERIALS SCIENCE↗
DOE OSTI2020

High-Energy All-Solid-State Organic–Lithium Batteries Based on Ceramic Electrolytes

Recent studies have identified unique properties of organic battery electrode materials such as moderate redox potentials and mechanical softness which are uniquely beneficial for all-solid-state batteries based on ceramic electrolytes. Here, we further explore the promise of organic materials and demonstrate a sulfide electrolyte- based organic-lithium battery with a specific energy of 828 Wh kg –1 , rivaling the state-of- the-art of all-solid-state batteries. Two innovation steps are responsible for the accomplishment. First, the combination of lithium anode and the high-capacity cathode material pyrene-4,5,9,10-tetraone ensures a high theoretical specific energy. Second, the microstructure of the organic cathode is optimized with the introduction of cryomilling, a technique common to processing soft materials but not familiar to electrode fabrication. The cathode material utilization increases to 99.5% as a result, up from the 55–89% previously reported for ceramic electrolyte-based solid-state organic batteries. In conclusion, the improvement highlights the special requirements of solid-state organic electrodes for microstructural engineering while preserving the chemical integrity of components.

25 ENERGY STORAGE↗
DOE OSTI2025

Abstracts of the 2025 51st Annual NATAS Conference

The North American Thermal Analysis Society (NATAS) is pleased to announce its 51st Annual Conference, held jointly with the IX International Baekeland Symposium. This premier event unites scientists, practitioners, and students from academia, industry, and government to explore the forefront of materials science. The NATAS conference provides a dynamic forum for attendees to delve into the latest advancements in thermal analysis, rheology, and materials characterization. The technical program will highlight new developments in instrumentation and software, alongside practical applications across a wide range of industries. Concurrently, the Baekeland Symposium will showcase cutting-edge scientific, technical, and industrial innovations in the field of high-performance thermosetting polymers. The synergy of this joint meeting creates a unique platform for cross-disciplinary collaboration, fostering the exchange of novel ideas and sparking new research opportunities. Featuring technical presentations, poster sessions, and plenary lectures from renowned experts and emerging graduate students, the conference offers an ideal environment for networking and professional development. We invite you to join us to discover state-of-the-art techniques, discuss groundbreaking research, and connect with peers and leaders in the thermal and materials community.

batteries↗