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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Comparison of Surface Ground Temperature from Satellite Observations and the Off-Line Land Surface GEOS Assimilation System

The surface ground temperature (Tg) is an important meteorological variable, because it represents an integrated thermal state of the land surface determined by a complex surface energy budget. Furthermore, Tg affects both the surface sensible and latent heat fluxes. Through these fluxes. the surface budget is coupled with the atmosphere above. Accurate Tg data are useful for estimating the surface radiation budget and fluxes, as well as soil moisture. Tg is not included in conventional synoptical weather station reports. Currently, satellites provide Tg estimates globally. It is necessary to carefully consider appropriate methods of using these satellite data in a data assimilation system. Recently, an Off-line Land surface GEOS Assimilation (OLGA) system was implemented at the Data Assimilation Office at NASA-GSFC. One of the goals of OLGA is to assimilate satellite-derived Tg data. Prior to the Tg assimilation, a thorough investigation of satellite- and model-derived Tg, including error estimates, is required. In this study we examine the Tg from the n Project (ISCCP DI) data and the OLGA simulations. The ISCCP data used here are 3-hourly DI data (2.5x2.5 degree resolution) for 1992 summer months (June, July, and August) and winter months (January and February). The model Tg for the same periods were generated by OLGA. The forcing data for this OLGA 1992 simulation were generated from the GEOS-1 Data Assimilation System (DAS) at Data Assimilation Office NASA-GSFC. We examine the discrepancies between ISCCP and OLGA Tg with a focus on its spatial and temporal characteristics, particularly on the diurnal cycle. The error statistics in both data sets, including bias, will be estimated. The impact of surface properties, including vegetation cover and type, topography, etc, on the discrepancies will be addressed.

Yang, R.↗
NASA NTRS2002

X-ray Spectroscopy of Low-Luminosity Active Galactic Nuclei with XMM

The measurement of black hole masses in nearby galaxies has transformed our understanding of these systems, allowing us to quantify the relevant scales of power, length and time and explore how the activity of black holes is linked to their environments and to the evolution of their host galaxies. In this project, Dr. Tiziana Di Matteo has the primary responsibility for developing and investigating theoretical models for the origin of the X-ray emission observed in low-luminosity AGN. Dr. Di Matteo has been involved in interpreting X-ray data and assessing accretion models throughout the project.

DiMatteo, Tiziana↗
NASA NTRS2002

Intercontinental Bistatic Radar Test Observation of Asteroid 1998 WT24

We describe the first intercontinental planetary radar test performed in Italy observing the near Earth asteroid (NEA) 33342 (1998 WT24) in December 2001 by means of the bistatic configurations Goldstone (California, USA)-Medicina (Italy) and Evpatoria (Ukraine)-Medicina. The experiment goal was to characterize the system for realtime radar follow-up observations of NEAs and artificial orbiting debris, in the framework of a feasibility study which aims at using the Sardinia Radio Telescope, at present under construction, also as a planetary radar facility. We report the preliminary results of the radar observations carried out by the IRA-CNR (Instituto di Radioastronomia - Consiglio Nazionale delle Ricerche) and the OATo (Osservatorio Astronomico di Torino) groups, aimed at exploring the scientific potentials of a new space radar program, using the existing facilities in Italy. The planetary radar technique is uniquely capable of investigating geometry and surface properties of various solar system objects, demonstrating advantages over the optical methods in its high spatial resolution and ability to obtain three-dimensional images. A single radar detection allows to obtain extremely accurate orbital elements, improving the instantaneous positional uncertainties by orders of magnitude with respect to an optically determined orbit. Radar is a powerful means to spatially resolve NEAs by measuring the distribution of the echo power in time delay (range) and Doppler frequency (line-of-sight velocity) with extreme precision in each coordinate, as it provides detailed information about the target physical properties like size, shape, rotation, near-surface bulk density and roughness and internal density distribution. The Medicina 32m antenna had been successfully used for the first time as the receiving part of a bistatic configuration during a test experiment (September 2001) held to check the capabilities of the entire data acquisition system. This test was possible thanks to the collaboration undertaken with the Evpatoria radar station, and consisted in the observation of the ETALON-1 low orbit satellite

Righini, S.↗
NASA NTRS2002

Dissociative Ionization of Benzene by Electron Impact

We report a theoretical study of the dissociative ionization (DI) of benzene from the low-lying ionization channels. Our approach makes use of the fact that electron motion is much faster than nuclear motion and DI is treated as a two-step process. The first step is electron-impact ionization resulting in an ion with the same nuclear geometry as the neutral molecule. In the second step the nuclei relax from the initial geometry and undergo unimolecular dissociation. For the ionization process we use the improved binary-encounter dipole (iBED) model. For the unimolecular dissociation step, we study the steepest descent reaction path to the minimum of the ion potential energy surface. The path is used to analyze the probability of unimolecular dissociation and to determine the product distributions. Our analysis of the dissociation products and the thresholds of the productions are compared with the result dissociative photoionization measurements of Feng et al. The partial oscillator strengths from Feng et al. are then used in the iBED cross section calculations.

Huo, Winifred↗
NASA NTRS2003

Dissociative Ionization and Product Distributions of Benzene and Pyridine by Electron Impact

We report a theoretical study of the dissociative ionization (DI) and product distributions of benzene (C6H6) and pyridine (C5H5N) from their low-lying ionization channels. Our approach makes use of the fact that electronic motion is much faster than nuclear motion allowing DI to be treated as a two-step process. The first step is the electron-impact ionization resulting in an ion with the same nuclear geometry as the neutral molecule. In the second step, the nuclei relax from the initial geometry and undergo unimolecular dissociation. For the ionization process we use the improved binary-encounter dipole (iBED) model [W.M. Huo, Phys. Rev. A64,042719-I (2001)]. For the unimolecular dissociation, we use multiconfigurational self-consistent field (MCSCF) methods to determine the steepest descent pathways to the possible product channels. More accurate methods are then used to obtain better energetics of the paths which are used to determine unimolecular dissociation probabilities and product distributions. Our analysis of the dissociation products and the thresholds of their productions for benzene are compared with the recent dissociative photoionization meausurements of benzene by Feng et al. [R. Feng, G. Cooper, C.E. Brion, J. Electron Spectrosc. Relat. Phenom. 123,211 (2002)] and the dissociative photoionization measurements of pyridine by Tixier et al. [S. Tixier, G. Cooper, R. Feng, C.E. Brion, J. Electron Spectrosc. Relat. Phenom. 123,185 (2002)] using dipole (e,e+ion) coincidence spectroscopy.

Dateo, Christopher E.↗
NASA NTRS2003

Subgrid Scale Modeling in Solar Convection Simulations using the ASH Code

The turbulent solar convection zone has remained one of the most challenging and important subjects in physics. Understanding the complex dynamics in the solar con- vection zone is crucial for gaining insight into the solar dynamo problem. Many solar observatories have generated revealing data with great details of large scale motions in the solar convection zone. For example, a strong di erential rotation is observed: the angular rotation is observed to be faster at the equator than near the poles not only near the solar surface, but also deep in the convection zone. On the other hand, due to the wide range of dynamical scales of turbulence in the solar convection zone, both theory and simulation have limited success. Thus, cutting edge solar models and numerical simulations of the solar convection zone have focused more narrowly on a few key features of the solar convection zone, such as the time-averaged di erential rotation. For example, Brun & Toomre (2002) report computational finding of differential rotation in an anelastic model for solar convection. A critical shortcoming in this model is that the viscous dissipation is based on application of mixing length theory to stellar dynamics with some ad hoc parameter tuning. The goal of our work is to implement the subgrid scale model developed at CTR into the solar simulation code and examine how the differential rotation will be a affected as a result. Specifically, we implement a Smagorinsky-Lilly subgrid scale model into the ASH (anelastic spherical harmonic) code developed over the years by various authors. This paper is organized as follows. In x2 we briefly formulate the anelastic system that describes the solar convection. In x3 we formulate the Smagorinsky-Lilly subgrid scale model for unstably stratifed convection. We then present some preliminary results in x4, where we also provide some conclusions and future directions.

Young, Y.-N.↗
NASA NTRS2004

Assessment of LAURA for Laminar Supersonic Shallow Cavities

The ability of the Laura flow solver to predict local heating augmentation factors for shallow cavities is assessed. This assessment is part of a larger e ort within the Space Shuttle return-to-flight program to develop technologies to support on-orbit tile repair decisions. The comparison is made against global phosphor thermography images taken in the Langley Aerothermodynamic Laboratory 20-Inch Mach 6 Air Tunnel. The cavities are rectangular in shape, with lengths L/H of 14 20 and depths H/ of 1.1 5.2. The fully laminar results, for Re = 300, show good agreement between the data sets. For Re = 503, the wind tunnel data indicates boundary layer transition with turbulent flow both within and downstream of the cavity. The turbulent flow structures are significantly di erent from the laminar predictions, with order of magnitude increases in the heating augmentations. Because of the di erent flow structures, no simple bump factor can be used to correct the laminar calculations to account for the turbulent heating levels. A fine gradation in wind tunnel cases will be required to clearly delineate the laminar-to-turbulent transition point, and hence the limits of applicability of the laminar numerical approach.

Wood, William A.↗
NASA NTRS1999

Multi-Body Analysis of the 1/5 Scale Wind Tunnel Model of the V-22 Tiltrotor

The paper presents a multi-body analysis of the 1/5 scale wind tunnel model of the V-22 tiltrotor, the Wing and Rotor Aeroelastic Testing System (WRATS), currently tested at NASA Langley Research Center. An original multi-body formulation has been developed at the Dipartimento di Ingegneria Aerospaziale of the Politecnico di Milano, Italy. It is based on the direct writing of the equilibrium equations of independent rigid bodies, connected by kinematic constraints that result in the addition of algebraic constraint equations, and by dynamic constraints, that directly contribute to the equilibrium equations. The formulation has been extended to the simultaneous solution of interdisciplinary problems by modeling electric and hydraulic networks, for aeroservoelastic problems. The code has been tailored to the modeling of rotorcrafts while preserving a complete generality. A family of aerodynamic elements has been introduced to model high aspect aerodynamic surfaces, based on the strip theory, with quasi-steady aerodynamic coefficients, compressibility, post-stall interpolation of experimental data, dynamic stall modeling, and radial flow drag. Different models for the induced velocity of the rotor can be used, from uniform velocity to dynamic in flow. A complete dynamic and aeroelastic analysis of the model of the V-22 tiltrotor has been performed, to assess the validity of the formulation and to exploit the unique features of multi-body analysis with respect to conventional comprehensive rotorcraft codes; These are the ability to model the exact kinematics of mechanical systems, and the possibility to simulate unusual maneuvers and unusual flight conditions, that are particular to the tiltrotor, e.g. the conversion maneuver. A complete modal validation of the analytical model has been performed, to assess the ability to reproduce the correct dynamics of the system with a relatively coarse beam model of the semispan wing, pylon and rotor. Particular care has been used to model the kinematics of the gimbal joint, that characterizes the rotor hub, and of the control system, consisting in the entire swashplate mechanism. The kinematics of the fixed and the rotating plates have been modeled, with variable length control links used to input the controls, the rotating flexible links, the pitch horns and the pitch bearings. The investigations took advantage of concurring wind tunnel test runs, that were performed in August 1998, and allowed the acquisition of data specific to the multi-body analysis.

Ghiringhelli, G. L.↗
NASA NTRS1991

Neuroendocrine abnormalities in patients with traumatic brain injury

This article provides an overview of hypothalamic and pituitary alterations in brain trauma, including the incidence of hypothalamic-pituitary damage, injury mechanisms, features of the hypothalamic-pituitary defects, and major hypothalamic-pituitary disturbances in brain trauma. While hypothalamic-pituitary lesions have been commonly described at postmortem examination, only a limited number of clinical cases of traumatic hypothalamic-pituitary dysfunction have been reported, probably because head injury of sufficient severity to cause hypothalamic and pituitary damage usually leads to early death. With the improvement in rescue measures, an increasing number of severely head-injured patients with hypothalamic-pituitary dysfunction will survive to be seen by clinicians. Patterns of endocrine abnormalities following brain trauma vary depending on whether the injury site is in the hypothalamus, the anterior or posterior pituitary, or the upper or lower portion of the pituitary stalk. Injury predominantly to the hypothalamus can produce dissociated ACTH-cortisol levels with no response to insulin-induced hypoglycemia and a limited or failed metopirone test, hypothyroxinemia with a preserved thyroid-stimulating hormone response to thyrotropin-releasing hormone, low gonadotropin levels with a normal response to gonadotropin-releasing hormone, a variable growth hormone (GH) level with a paradoxical rise in GH after glucose loading, hyperprolactinemia, the syndrome of inappropriate ADH secretion (SIADH), temporary or permanent diabetes insipidus (DI), disturbed glucose metabolism, and loss of body temperature control. Severe damage to the lower pituitary stalk or anterior lobe can cause low basal levels of all anterior pituitary hormones and eliminate responses to their releasing factors. Only a few cases showed typical features of hypothalamic or pituitary dysfunction. Most severe injuries are sufficient to damage both structures and produce a mixed endocrine picture. Increased intracranial pressure, which releases vasopressin by altering normal hypothalamic anatomy, may represent a unique type of stress to neuroendocrine systems and may contribute to adrenal secretion by a mechanism that requires intact brainstem function. Endocrine function should be monitored in brain-injured patients with basilar skull fractures and protracted posttraumatic amnesia, and patients with SIADH or DI should be closely monitored for other endocrine abnormalities.

NASA Program Space Physiology and Countermeasures↗
NASA NTRS1992

Radiation Transport Around Axisymmetric Blunt Body Vehicles Using a Modified Differential Approximation

A moment method for computing 3-D radiative transport is applied to axisymmetric flows in thermochemical nonequilibrium. Such flows are representative of proposed aerobrake missions. The method uses the P-1 approximation to reduce the governing system of integro-di erential equations to a coupled set of partial di erential equations. A numerical solution method for these equations given actual variations of the radiation properties in thermochemical nonequilibrium blunt body flows is developed. Initial results from the method are shown and compared to tangent slab calculations. The agreement between the transport methods is found to be about 10 percent in the stagnation region, with the difference increasing along the flank of the vehicle.

Hartung, Lin C.↗
NASA NTRS2005

Modern Radar Techniques for Geophysical Applications: Two Examples

The last decade of the evolution of radar was heavily influenced by the rapid increase in the information processing capabilities. Advances in solid state radio HF devices, digital technology, computing architectures and software offered the designers to develop very efficient radars. In designing modern radars the emphasis goes towards the simplification of the system hardware, reduction of overall power, which is compensated by coding and real time signal processing techniques. Radars are commonly employed in geophysical radio soundings like probing the ionosphere; stratosphere-mesosphere measurement, weather forecast, GPR and radio-glaciology etc. In the laboratorio di Geofisica Ambientale of the Istituto Nazionale di Geofisica e Vulcanologia (INGV), Rome, Italy, we developed two pulse compression radars. The first is a HF radar called AIS-INGV; Advanced Ionospheric Sounder designed both for the purpose of research and for routine service of the HF radio wave propagation forecast. The second is a VHF radar called GLACIORADAR, which will be substituting the high power envelope radar used by the Italian Glaciological group. This will be employed in studying the sub glacial structures of Antarctica, giving information about layering, the bed rock and sub glacial lakes if present. These are low power radars, which heavily rely on advanced hardware and powerful real time signal processing. Additional information is included in the original extended abstract.

Arokiasamy, B. J.↗
NASA NTRS2004

Synthesis, Characterization, and Optical Properties of a Cyano-Functionalized 4,5,9,10-tetraaryl-l,6-dioxapyrene

5,10-Di(4-cyanophenyl)-4,9-di(4-methylphenyl)-1,6-dioxapyrene ( CN-diox), a symmetrically substituted 4,5,9,10-tetraaryldioxapyrene, was synthesized in seven steps from 1,4-dihydroxynaphthalene. The synthetic methodology incorporated a base-catalyzed ring-closure process followed by dehydration to introduce the first tetraaryl- 1,6-dioxapyrene. Crystal structure and electrochemical analysis were performed to directly compare the properties of CN-diox to previously reported dioxapyrene derivatives, specifically 1,6-dioxapyrene (Diox) and 4,9-diethyl-2,7-dimethyl- 1,6-dioxapyrene (Alkyl-diox). Optical spectroscopy studies were performed to evaluate the potential of the 1,6-dioxapyrenes as fluorescent probes. CN-diox revealed a broad absorption centered near 450 nm (epsilon = 31,900/M/cm) in THF with a corresponding fluorescence at 619 nm (Phi(sub f) = 0.011). This was in sharp contrast to both Diox and Alkyl-diox which displayed broad absorption bands near 400 nm (epsilon approx. 5,000-10,000/M/cm) in THF with corresponding fluorescence near 500 nm (Phi(sub f) = 0.059 and 0.082 for Diox and Alkyl-diox, respectively). The luminescence of CN-diox was found to be solvatochromic (lambda(sub max) = 619 nm-644 nm) with single exponential lifetimes of less than 1.3 ns. Neither Diox nor Alkyl-diox showed solvatochromic properties.

Tyson, Daniel S.↗
NASA NTRS2005

Synthesis and Near IR Photoluminescence of Os(II) Bis(2,2'-bipyridine) (3,8-Diarylethynyl-1,10-phemanthroline) Complexes: Anomalous Behavior of the 3,8-Dinitrophenylethynyl-substituted Homologue

A large bathochromic shift (50 nm) and emission in the near infrared is observed by attaching arylethynyl groups at the 3,8-positions of the 1,10-phenanthroline ligand (phen) of [Os(bipy)2(phen)]2+ (where bipy = 2,2'-bipyridine). Thus [Os(bipy)2(3,8-di-4-methoxyphenylethynyl-1,10-phenathroline)]2+ emits at 795 nm, while [Os(bipy)2(3,8-diphenylethynyl-1,10-phenanthroline)]2+ emits at 815 nm. According to this trend it would have been expected that [Os(bipy)2(3,8-di-4-nitrophenylethynyl-1,10-phenathroline)]2+ emits farther in the near infrared. Nevertheless, this complex is not photoluminescent because of intramolecular electron transfer quenching of the MLCT excited state by the nitroaromatic group. These results set structural and redox potential standards in the design of near infrared emitters based on [Os(bipy)2(phen)]2+ type complexes.

Yang, Jinhua↗
NASA NTRS1994

Polybenzimidazole via aromatic nucleophilic displacement

Di(hydroxyphenyl)benzimidazole monomers were prepared from phenyl-4-hydroxybenzoate and aromatic bis(o-diamine)s. These monomers were used in the synthesis of soluble polybenzimidazoles. The reaction involved the aromatic nucleophilic displacement of various di(hydroxyphenyl)benzimidazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds in the presence of an alkali metal base. These polymers exhibited lower glass transition temperatures, improved solubility, and better compression moldability over their commercial counterparts.

Connell, John W.↗
NASA NTRS1983

Track recording plastic compositions

Improved nuclear track recording plastic compositions are provided which exhibit greatly decreased surface roughness when etched to produce visible tracks of energetic nuclear particles which have passed into and/or through said plastic. The improved compositions incorporate a small quantity of a phthalic acid ester into the major plastic component which is derived from the polymerization of monomeric di-ethylene glycol bis allyl carbonate. Di-substituted phthalic acid esters are preferred as the added component, with the further perference that the ester substituent has a chain length of 2 or more carbon atoms. The inclusion of the phthalic acid ester to an extent of from about 1-2% by weight of the plastic compositions is sufficient to drastically reduce the surface roughness ordinarily produced when the track recording plastic is contacted by etchants.

Tarle, Gregory↗
NASA NTRS1991

Polyphenylquinoxalines via aromatic nucleophilic displacement

Polyphenylquinoxalines are prepared by the nucleophilic displacement reaction of di(hydroxyphenyl)quinoxaline monomers with activated aromatic dihalides or dinitro compounds. The reactions are carried out in polar aprotic solvents during alkali metal bases at elevated temperatures under nitrogen. The di(hydroxyphenyl)quinoxaline monomers are prepared either by reacting stoichiometric quantities of aromatic bis(o-diamines) with a hydroxybenzil or by reacting o-phenylenediamine with a dihydroxybenzil or bis(hydroxyphenylglyoxylyl)benzene.

Hergenrother, Paul M.↗
NASA NTRS1990

Polyphenylquinoxalines via aromatic nucleophilic displacement

Polyphenylquinoxalines are prepared by the nucleophilic displacement reaction of di(hydroxyphenyl)quinoxaline monomers with activated aromatic dihalides or dinitro compounds. The reactions are carried out in polar aprotic solvents using alkali metal bases at elevated temperatures under nitrogen. The di(hydroxyphenyl)quinoxaline monomers are prepared either by reacting stoichiometric quantities of aromatic bis(o-diamines) with a hydroxybenzil or by reacting o-phenylenediamine with a dihydroxybenzil or bis(hydroxyphenylglyoxylyl)benzene.

Hergenrother, Paul M.↗
NASA NTRS2009

A Summary of NASA and USAF Hypergolic Propellant Related Spills And Fires

Hypergolic fluids are toxic liquids that react spontaneously and violently when they contact each other. These fluids are used in many different rocket and aircraft systems for propulsion and hydraulic power including, orbiting satellites, manned spacecraft, military aircraft, and deep space probes. Hypergolic fuels include hydrazine (N 2H4) and its derivatives including monomethylhydrazine (MMH), unsymmetrical di-methylhydrazine (UDMH), and Aerozine 50 (A-50), which is an equal mixture of N2H4 and UDMH. The oxidizer used with these fuels is usually nitrogen tetroxide (N2O4), also known as di-nitrogen tetroxide or NTO, and various blends of N2O4 with nitric oxide (NO). Several documented, unintentional hypergolic fluid spills and fires related to the Apollo Program, the Space Shuttle Program, and several other programs from approximately 1968 through the spring of 2009 have been studied for the primary purpose of extracting the lessons learned. Spill sites include KSC, JSC, WSTF, CCAFS, EAFB, McConnell AFB, and VAFB.

Nufer, B. M.↗