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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Tuning the ferroelectric-to-paraelectric transition temperature and dipole orientation of group-IV monochalcogenide monolayers
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Effective restoration of dipole sum rules within the renormalized random-phase approximation
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Linearly polarized gluon distributions in the color dipole model
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Electric dipole moment induced by a QCD instanton in an external magnetic field
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Asymmetric Blockade and Multiqubit Gates via Dipole-Dipole Interactions
Because of their strong and tunable interactions, Rydberg atoms can be used to realize fast two-qubit entangling gates. We propose a generalization of a generic two-qubit Rydberg-blockade gate to multiqubit Rydberg-blockade gates that involve both many control qubits and many target qubits simultaneously. This is achieved by using strong microwave fields to dress nearby Rydberg states, leading to asymmetric blockade in which control-target interactions are much stronger than control-control and target-target interactions. Further, the implementation of these multiqubit gates can drastically simplify both quantum algorithms and state preparation. To illustrate this, we show that a 25-atom Greenberger-Horne-Zeilinger state can be created using only three gates with an error of 5.8%.
The 16 T dipole development program for FCC and HE-LHC
A future circular collider (FCC) with a center-of-mass energy of 100 TeV and a circumference of around 100 km, or an energy upgrade of the LHC (HE-LHC) to 27 TeV require bending magnets providing 16 T in a 50-mm aperture. Several development programs for these magnets, based on Nb$_3$Sn technology, are being pursued in Europe and in the U.S. In these programs, cos-theta, block-type, common-coil, and canted-cos-theta magnets are explored; first model magnets are under manufacture; limits on conductor stress levels are studied; and a conductor with enhanced characteristics is developed. This paper summarizes and discusses the status, plans, and preliminary results of these programs.
Magnetic dipole and electric dipole resonances in TiO2 microspheres at terahertz frequencies.
Abstract not provided.
Quantum phase transitions for two coupled cavities with dipole-interaction atoms
We investigate the quantum phase transitions for two weakly coupled atom-cavity sites. The interatomic dipole-dipole interaction is considered. Our numerical results show that the dipole-dipole interaction is a crucial parameter for the quantum phase transition. For small atom-cavity detuning, the ''superfluid'' becomes more and more obvious with the increase of the dipole-dipole interaction. In addition, the strong dipole-dipole interaction can lead the atomic excitation to be suppressed completely, and only the photonic excitation exists for the ground states. When the atom-cavity detuning is comparable with the dipole-dipole interaction, the dipole-dipole interaction enlarges the positive detunings, which is in favor of exhibiting superfluid photonic states. While for the negative detuning, the dipole-dipole interaction will reduce it, and contribute to the formation of the polaritonic insulator states. The cases for extended models have also been briefly analyzed. We also discuss how to find these novel phenomena in future experiments.
Full kinetic simulations of plasma flow interactions with meso- and microscale magnetic dipoles
We examined the plasma flow response to meso- and microscale magnetic dipoles by performing three-dimensional full particle-in-cell simulations. We particularly focused on the formation of a magnetosphere and its dependence on the intensity of the magnetic moment. The size of a magnetic dipole immersed in a plasma flow can be characterized by a distance L from the dipole center to the position where the pressure of the local magnetic field becomes equal to the dynamic pressure of the plasma flow under the magnetohydrodynamics (MHD) approximation. In this study, we are interested in a magnetic dipole whose L is smaller than the Larmor radius of ions r{sub iL} calculated with the unperturbed dipole field at the distance L from the center. In the simulation results, we confirmed the clear formation of a magnetosphere consisting of a magnetopause and a tail region in the density profile, although the spatial scale is much smaller than the MHD scale. One of the important findings in this study is that the spatial profiles of the plasma density as well as the current flows are remarkably affected by the finite Larmor radius effect of the plasma flow, which is different from the Earth's magnetosphere. The magnetopause found in the upstream region is located at a position much closer to the dipole center than L. In the equatorial plane, we also found an asymmetric density profile with respect to the plasma flow direction, which is caused by plasma gyration in the dipole field region. The ion current layers are created in the inner region of the dipole field, and the electron current also flows in the region beyond the ion current layer because ions with a large inertia can closely approach the dipole center. Unlike the ring current structure of the Earth's magnetosphere, the current layers in the microscale dipole fields are not circularly closed around the dipole center. Since the major current is caused by the particle gyrations, the current is independently determined to be in the direction of the electron and ion gyrations, which are the same in both the upstream and downstream regions. The present analysis on the formation of a magnetosphere in the regime of a microscale magnetic dipole is significant for understanding the solar wind response to the crustal magnetic anomalies on the Moon surface, such as were recently observed by spacecraft.
Tuning the melting point of selected ionic liquids through adjustment of the cation’s dipole moment.
In prior research with thermally robust salts [Cassity et al., PCCP, 2017, 19, 31560] it was noted that an increase in the dipole moment of the cation generally led to a decrease in the melting point. Molecular dynamics simulations of the liquid state revealed that an increased dipole moment reduces cation-cation repulsions through dipole-dipole alignment. This was believed to reduce the liquid phase enthalpy, which would tend to lower the melting point of the IL. Here, we also test this principle by replacing hydrogen atoms with fluorine atoms at selected positions within the cation. This allows us to alter the electrostatics of the cation without substantially affecting the sterics. Furthermore, the strength of the dipole moment can be controlled by choosing different positions within the cation for replacement. We studied variants of four different parent cations paired with bistriflimide and determined their melting points, and enthalpies and entropies of fusion through DSC experiments. The decreases in the melting point were determined to be enthalpically driven. We found that the dipole moment of the cation, as determined by quantum chemical calculations, is inversely correlated with the melting point of the given compound. Molecular dynamics simulations of the crystalline and solid states of two isomers showed differences in their enthalpies of fusion that closely matched those seen experimentally. Moreover, this reduction in the enthalpy of fusion was determined to be caused by an increase in the enthalpy of the crystalline state. We provide evidence that dipole-dipole interactions between cations leads to the formation of cationic domains in the crystalline state. These cationic associations partially block favourable cation–anion interactions, which are recovered upon melting. If, however, the dipole- dipole interactions between cations is too strong they have a tendency to form glasses. This study provides a design rule for lowering the melting point of structurally similar ILs by altering their dipole moment.
Range and strength of mechanical interactions of force dipoles in elastic fiber networks
Mechanical forces generated by myosin II molecular motors drive diverse cellular processes, most notably shape change, division and locomotion. These forces may be transmitted over long range through the cytoskeletal medium – a disordered, viscoelastic network of biopolymers. The resulting cell size scale force chains can in principle mediate mechanical interactions between distant actomyosin units, leading to self-organized structural order in the cell cytoskeleton. Inspired by such force transmission through elastic structures in the cytoskeleton, we consider a percolated fiber lattice network, where fibers are represented as linear elastic elements that can both bend and stretch, and the contractile activity of myosin motors is represented by force dipoles. Then, by using a variety of metrics, we show how two such contractile force dipoles interact with each other through their mutual mechanical deformations of the elastic fiber network. As a prelude to two-dipole interactions, we quantify how forces propagate through the network from a single anisotropic force dipole by analyzing clusters of nodes connected by highly strained bonds, as well as through the decay rate of strain energy with distance from a force dipole. We show that predominant fiber bending screens out force propagation, resulting in reduced and strongly network configuration-dependent dipole interactions. On the other hand, stretching-dominated networks support longer-ranged inter-dipole interactions that recapitulate the predictions of linear elasticity theory. By characterizing the differences between tensile and compressive force propagation in the fiber network, we show how inter-dipole interaction depends on the dipoles’ mutual separation and orientation. The resulting elastic interaction energy may mediate a force between multiple distant dipoles, leading to their self-organization into ordered configurations. In conclusion, this provides a potential pathway for active mechanical force-driven structural order in elastic biopolymer networks.
IS THE TWO MICRON ALL SKY SURVEY CLUSTERING DIPOLE CONVERGENT?
There is a long-standing controversy about the convergence of the dipole moment of the galaxy angular distribution (the so-called clustering dipole). Is the dipole convergent at all, and if so, what is the scale of the convergence? We study the growth of the clustering dipole of galaxies as a function of the limiting flux of the sample from the Two Micron All Sky Survey (2MASS). Contrary to some earlier claims, we find that the dipole does not converge before the completeness limit of the 2MASS Extended Source Catalog, i.e., up to 13.5 mag in the near-infrared K{sub s} band (equivalent to an effective distance of 300 Mpc h{sup -1}). We compare the observed growth of the dipole with the theoretically expected, conditional one (i.e., given the velocity of the Local Group relative to the cosmic microwave background), for the {Lambda}CDM power spectrum and cosmological parameters constrained by the Wilkinson Microwave Anisotropy Probe. The observed growth turns out to be within 1{sigma} confidence level of its theoretical counterpart once the proper observational window of the 2MASS flux-limited catalog is included. For a contrast, if the adopted window is a top hat, then the predicted dipole grows significantly faster and converges (within the errors) to its final value for a distance of about 300 Mpc h{sup -1}. By comparing the observational windows, we show that for a given flux limit and a corresponding distance limit, the 2MASS flux-weighted window passes less large-scale signal than the top-hat one. We conclude that the growth of the 2MASS dipole for effective distances greater than 200 Mpc h{sup -1} is only apparent. On the other hand, for a distance of 80 Mpc h{sup -1} (mean depth of the 2MASS Redshift Survey) and the {Lambda}CDM power spectrum, the true dipole is expected to reach only {approx}80% of its final value. Eventually, since for the window function of 2MASS the predicted growth is consistent with the observed one, we can compare the two to evaluate {beta} {identical_to} {Omega}{sub m}{sup 0.55}/b. The result is {beta} = 0.38 {+-} 0.04, which leads to an estimate of the density parameter {Omega}{sub m} = 0.20 {+-} 0.08.
Breaking Radial Dipole Symmetry in Planar Macrocycles Modulates Edge‐to‐Edge Packing and Disrupts Cofacial Stacking
Dipolar interactions are ever-present in supramolecular architectures, though their impact is typically revealed by making dipoles stronger. While it is also possible to assess the role of dipoles by altering their orientations by using synthetic design, doing so without altering the molecular shape is not straightforward. We have now done this by flipping one triazole unit in a rigid macrocycle, tricarb. The macrocycle is composed of three carbazoles (2 Debye) and three triazoles (5 Debye) defining an array of dipoles aligned radially but organized alternately in and out. These dipoles are believed to dictate edge-to-edge tiling and face-to-face stacking. We modified our synthesis to prepare isosteric macrocycles with the orientation of one triazole dipole rotated 40°. The new dipole orientation guides edge-to-edge contacts to reorder the stability of two surface-bound 2D polymorphs. The impact on dipole-enhanced π stacking, however, was unexpected. Our stacking model identified an unchanged set of short-range (3.4 Å) anti-parallel dipole contacts. Despite this situation, the reduction in self-association was attributed to long-range (~6.4 Å) dipolar repulsions between π-stacked macrocycles. This work highlights our ability to control the build-up and symmetry of macrocyclic skeletons by synthetic design, and the work needed to further our understanding of how dipoles control self-assembly.