On the determination of high-pressure mass diffusion coefficients for binary mixtures
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A diffusion experiment for glasses was formulated, such theoretical and earth bound results as were available were outlined, and the preliminary earth based experimental work in preparation for a weightless experiment was done. The fundamental premise of the work was that diffusion studies of the glass forming ion can be conducted in zero-g environments, and diffusion data obtained from these experiments are unique and valuable because of earth based experimental difficulties.
The consequences of this finding on future comparisons between microgravity data and simulations are discussed in the context of determining from this comparison the thermal diffusion factor.
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The interdiffusion coefficient of FeNi in fcc taenite (gamma) of Fe-Ni and Fe-Ni-0.2 P alloys was measured as a function of temperature between 600 and 900 C. This temperature range is directly applicable to the nucleation and growth of the Widmanstatten pattern in iron meteorites and metal regions of stony and stony-iron meteorites. Diffusion couples were made from FeNi or FeNiP alloys which ensured that the couples were in the taenite phase at the diffusion temperature. The presence or absence of grain boundary diffusion was determined by measuring the Ni profile normal to the existing grain boundaries with the AEM. Ignoring any variation of interdiffusion coefficient with composition, the measured data was plotted versus the reciprocal of the diffusion temperature. The FeNi data generally follow the extrapolated Goldstein, et al. (1965) data from high temperatures. The FeNiP data indicates that small additions of P (0.2 wt%) cause a 3 to 10 fold increase in the FeNi interdifussion coefficient increasing with decreasing temperature. This increase is about the same as that predicted by Narayan and Goldstein (1983) at the Widmanstatten growth temperature.
Radar observations show that thin, persistent layers of turbulence occur sporadically in the troposphere and stratosphere. Two probabilistic approaches are used to show that the vertical eddy diffusivity due to such layers is of the order of 0.2-0.3 sq m/sec in the lower stratosphere. An actual realization of turbulent layers, derived from the radar observations at Arecibo, is used in a numerical approach to obtain a profile of eddy diffusivity. It is suggested that turbulence plays a significant role in the vertical transport of trace constituents in the stratosphere.
The results of numerical models or of new observational programs are checked by comparing them with past observations. In view of the differing analysis techniques or differing data samples, the eddy diffusivities presented here agree remarkably well with past estimates. However, in the application of K-values to two-dimensional models, the actual magnitude of the diffusivities is no more important than their spatial patterns, i.e., their gradients with height and latitude. It should thus be noted that the present patterns are often much different from those of past results.
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Results from numerical simulations of cosmic-ray modulations by the solar wind are presented which show that the scattering mean free path should be larger than the particle gyroradius in the average magnetic field. It is found that the difference between drift and no-drift solutions is not as great as in previous simulations, which violated the mean free path constraint stated. Profound effects are still noted for the drifts, which determine the origin of the bulk of the cosmic rays seen at any given time in the inner solar system. Accordingly, during the 1975 solar minimum, the positively charged cosmic rays seen in the inner solar system came primarily from the outer boundary near the heliospheric poles while negative particles came from the equatorial regions of the boundary.
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A hybrid method is presented for the estimation of parameters, combining the output-least-squares and the equation-error approaches. The mathematical framework is given by an augmented Lagrangian formulation. The resulting algorithm has proved to be very effective numerically.
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The time evolution of excess C-14 in the stratosphere and the troposphere from October 1963 to December 1966 is investigated using the Caltech/JPL two-dimensioanal transport model, with transport coefficients taken from Yang and Tung (1989). It is found that the model successfully accounts for observations reported previously. It is calculated that excess C-14 is removed from the atmosphere with surface deposition velocities of 0.003 cm/sec in the Southern Hemisphere and 0.005 cm/sec in the Northern Hemisphere. This result is contrary to the current understanding that the oceans are the dominant sink for excess C-14.