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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Electric Vehicles for Fleets

Electric vehicles (EVs) can fulfill many daily driving needs, making them a great solution for fleets. They offer several benefits and can fill roles in light-duty, medium-/heavy-duty (MD/HD), and even off-road applications. The unique fleet environment presents considerations beyond those that consumers must address before going electric. For example, fleet managers must understand the impacts of charging multiple vehicles while maintaining fleet operations. Larger MD/HD vehicles bring additional factors to consider.

ADVANCED PROPULSION SYSTEMS↗

Morphological Modulation of TiO 2 Nanotube via Optimal Anodization Condition for Solar Water Oxidation

With the depletion of fossil fuels and the rising global demand for energy, photoelectrochemical (PEC) water splitting presents a promising solution to avert an energy crisis. Titanium dioxide (TiO 2 ), an n -type semiconductor, has gained popularity as a photoanode due to its remarkable PEC properties. Nevertheless, inherent challenges such as a wide band gap (~3.2 eV), charge recombination, and slow oxygen evolution reaction (OER) rates at the surface limit its practical application by constraining light absorption. To overcome these limitations, we have developed TiO 2 nanotubes (NTs) using a facile anodization method. This study examines the impact of anodization growth parameters on solar water oxidation performance. Specifically, TiO 2 NTs with modified anodization time (referred to as TiO 2 -6) showed a 3.5-fold increase in photocurrent density compared to the as-grown TiO 2 NTs. Furthermore, electrochemical analyses, such as electrochemical impedance spectroscopy (EIS), indicated a significant decrease in charge transfer resistance following the adjustment of on-off anodization time. Additionally, the TiO 2 -6 photoanode demonstrated a higher electrochemically active surface area (ECSA) than other samples. Therefore, optimal nanostructuring parameters are crucial for enhancing the PEC properties of TiO 2 NTs. Overall, our findings offer valuable insights for fabricating high-quality TiO 2 NTs photoanodes, contributing to developing efficient PEC systems for sustainable energy production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Impacts and emerging research opportunities in Vehicle-Grid Integration for transportation: A review

This review provides a comprehensive examination of Vehicle-Grid Integration (VGI) technologies and their impacts on transportation systems, with a particular emphasis on the transportation-energy nexus. It systematically explores how VGI affects key transportation applications such as charging infrastructure planning, electric vehicle (EV) routing, smart charging coordination, shared mobility, and dynamic pricing. By synthesizing recent literature from both transportation and energy systems perspectives, this study highlights how advanced methodologies, such as reinforcement learning, game theory, and optimization techniques, are used to model the complex interactions between EVs, mobility patterns, and distributed energy systems. Furthermore, the review also identifies critical challenges, including behavioral factors, data limitations, and system scalability. Drawing on these insights, the paper outlines emerging research opportunities to support the design of integrated, resilient, and user-centric VGI solutions that advance sustainable mobility and energy system efficiency.

Charging coordination↗

Mosaic Cu I –Cu II –In III 2D Perovskites: Pressure–Dependence of the Intervalence Charge Transfer and a Mechanochemical Alloying Method

The perovskite (BA) 4 [Cu II (Cu I In III ) 0.5 ]Cl 8 (1 BA ; BA + =butylammonium) allows us to study the high-pressure structural, optical, and transport properties of a mixed-valence 2D perovskite. Compressing 1 BA reduces the onset energy of Cu I/II intervalence charge transfer from 1.2 eV at ambient pressure to 0.2 eV at 21 GPa. The electronic conductivity of 1 BA increases by 4 orders of magnitude upon compression to 20 GPa, when the activation energy for conduction decreases to 0.16 eV. In contrast, Cu II perovskites achieve similar conductivity at ≈50 GPa. The solution-state synthesis of these perovskites is complicated, with more undesirable side products likely from the precursor mixtures containing three different metal ions. Finally, to circumvent this problem, we demonstrate an efficient mechanochemical synthesis to expand this family of halide perovskites with complex composition by simply pulverizing together powders of 2D Cu II single perovskites and Cu I In III double perovskites.

2D perovskite↗

High-Power Electric Vehicle Charging Hub Integration Platform (eCHIP): Design Guidelines and Specifications for DC Distribution-Based Charging Hub

Managed under U.S. Department of Energy (DOE)-funded EVs@Scale Consortium, High-Power Electric Vehicle Charging Hub Integration Platform (eCHIP) project aims to design and develop a high-power, interoperable charging experimental platform to research, develop, and demonstrate the integration and control approaches for a DC distribution-based high-power charging (HPC) system. The eCHIP project addresses the crucial need to design and validate efficient, low-cost, reliable, and interoperable solutions for DC-coupled charging hub ('DC hub' for short). This report explains the design, development, and implementation process of the experimental platform for the DC hub. The utilization of DC distribution holds significant potential for enhancing the operation of an HPC station architecture. However, there are challenges establishing the DC hub, including interoperability, commoditization, distributed energy resource integration, stability, DC protection, and lack of common system level controllers. To address these challenges, a testing setup is required that accommodates commercial off-the-shelf (COTS) products as well as novel, in-house designed solutions to evaluate different use cases at rated power and voltage levels.

33 ADVANCED PROPULSION SYSTEMS↗

Binding of an adatom to a simple metal surface

The density functional formalism of Hohenberg and Kohn is used to investigate the energies, charge densities and forces which hold an adatom on the surface of a simple metal. The valence wavefunction of the adatom is fitted to the Herman-Skillman solutions at large distance and is simplified somewhat in the core region. The field of the ion is represented by the Ashcroft pseudopotential. For the metal the jellium model is used. Detailed calculations are carried out for a sodium adatom on a sodium surface. Simply juxtaposing adatom and surface gives a binding energy of about 1/3 eV. This value is approximately twice the surface energy per atom in the close-packed plane. Charge redistributions as determined variationally increase the binding energy by about 10%. The equilibrium distance for the adatom turns out to be 1.66 A from the surface, as compared with 1.52 A, the observed value for one-half the distance between the close-packed planes.

Huntington, H. B.↗

Hydrazine-free precursor for solution-processed all-inorganic Se and Se 1− x Te x photovoltaics

Selenium (Se) has reemerged as a promising absorber material for indoor and tandem photovoltaics (PVs), and its alloys with Te (Se 1−x Te x ) offer a widely tunable bandgap. Solution processing of this materials system offers a route to low-cost fabrication. However, solution processing of Se has, thus far, only used hydrazine, which is an extremely hazardous solvent. In this work, we prepare and isolate propylammonium poly-Se and poly-Se–Te precursors from a safer thiol-amine solvent system. We formulate molecular inks by dissolving the precursor in dimethylformamide (DMF) with a monoethanolamine (EA) additive and process high-quality Se and Se 1−x Te x films with bandgaps ranging from 1.20 eV to 1.86 eV. We fabricate PVs from these films using TiO 2 and MoO 3 charge transport layers (CTLs) to achieve power conversion efficiencies as high as 2.73% for Se and 2.33% for Se 0.7 Te 0.3 under solar simulation. Se devices show excellent stability with no degradation after 1 month in air, enabled by the excellent stability of Se and the use of inorganic CTLs. This work represents an important step towards low-cost solution-phase processing of Se and Se 1−x Te x alloys for PVs and photodetectors with low toxicity and high bandgap tunability.

36 MATERIALS SCIENCE↗

Federal Home-to-Work Electric Vehicle Program Guide

This document serves as a comprehensive resource for Federal agencies in developing their own program resources that promote the efficient and effective use of electric vehicles (EVs) for home-to-work travel while ensuring compliance with Federal regulations and sustainability objectives. One mission of the U.S. Department of Energy's Federal Energy Management Program (FEMP) Fleet program is to help federal fleet managers meet or exceed statutory requirements related to energy and environmental performance while improving overall fleet efficiency, reducing costs, and meeting mission requirements. To further this mission, FEMP provides resources to support Federal agencies with increasing alternative fuel vehicle (AFV) acquisitions and reducing petroleum use. EVs are AFVs and help agencies meet federal fleet requirements. Federal fleets include government-owned EVs used for home-to-work travel. The purpose of this document is to serve as a guide for Federal agencies in developing their own internal program documents to manage government-owned EVs used for home-to-work travel. Federal agencies should consult their counsel and consider their own policies and authorities in the implementation of any policies or best practices regarding government-owned EVs used for home-to-work travel. The guide provides key considerations for agencies, including launching a pilot program to fine-tune best practices, conducting a cost-benefit analysis to compare home versus public charging, and exploring cost-effective solutions, such as installing standard outlets instead of dedicated charging stations. The guide underscores the importance of legal and financial considerations, such as verifying agency authority to install home charging infrastructure at an employee's home, ensuring the availability and appropriateness of using agency funds for home charging infrastructure, and understanding the tax implications of reimbursements.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

A Unified Design Theory for Multi-Port Polyphase Transformers Enabling Scalable Power-Multiplexed EV Fleet Charging Systems

This paper presents a unified analytical design theory for multi-port polyphase transformers, targeting scalable and isolated high-power Electric Vehicle (EV) fleet charging systems with power multiplexing capability. As fleet electrification accelerates, conventional one-to-one charger architectures face significant challenges in infrastructure cost, peak power demand, and low utilization of installed power electronics. Power-multiplexed charging architectures, which dynamically distribute power from a shared pool of converter modules across multiple vehicles, have emerged as a promising solution. However, such architectures require scalable, isolated multi-port power interfaces capable of routing energy among multiple inputs and outputs, whose design remains complex and dependent on iterative modeling. To address this gap, the proposed theory provides closed-form expressions for self-inductance, leakage inductance, and mutual coupling terms for arbitrary multi-phase, multi-port transformer structures. The formulation enables direct synthesis of isolated multi-input and multi-output resonant converter systems without reliance on geometry-specific finite-element analysis or extensive parameter extraction. This capability is particularly critical for power-multiplexed systems, where modular converter structures must interface with multiple vehicles while maintaining galvanic isolation and flexible power allocation. The effectiveness of the proposed framework is demonstrated through the design of a 360 kW multi-phase system operating over a 700–900 VDC input and 400–1250 VDC output range. PLECS simulation results confirm accurate prediction of system behavior and validate the applicability of the approach to multi-port, power-multiplexed charging scenarios. The proposed method significantly reduces design complexity while enabling scalable, cost-effective, and fully utilized EV fleet charging infrastructure.

Asa, Erdem [ORNL] (ORCID:0000000190884812)↗

High-heat transfer lithium-ion batteries: A new era in battery thermal management

Despite advances in lithium-ion battery technology, critical challenges remain that must be addressed to accelerate electric vehicle (EV) adoption and global energy transformation. Significantly improved battery thermal management (BTM) is key to overcoming these challenges. BTM approaches focus on increasing heat transfer coefficients via air, liquid, or refrigerant cooling, but less attention is given to reducing the battery's thermal resistance, a major bottleneck for heat transfer. This work introduces a novel approach to reduce battery thermal resistance by integrating in-plane heat transfer with optimized cell geometry, minimized thermal resistances, and reduced interfacial resistances, representing a departure from previous methods. The standard prismatic can cell incorporating this technology is referred to as the high heat transfer (HHT) battery. An equivalent resistance battery thermal model is developed for speed and accuracy, validated against experimental data in the literature, demonstrating strong correlation and ensuring reliable predictions for real-world performance. Thermal performance metrics of the conventional and HHT batteries are compared using a parametric study with air, liquid, and refrigerant boundary conditions across a range of aspect ratios. The HHT battery shows a heat removal rate up to 20 times higher than a conventional battery. These findings suggest that HHT technology could be transformative for EV battery performance, enabling fast charging, mitigating thermal runaway, extending battery life, reducing cold-weather power loss, increasing reliability, lowering costs, and enabling higher energy density, all critical for EV adoption and energy transformation. Future work will focus on prototyping and real-world testing to refine these findings for commercial-scale applications.

25 ENERGY STORAGE↗

V2XConnect: Harmonizing the Landscape of Bidirectional Charging Codes, Standards, and Communication Protocols

The utility grid is constantly evolving with new generation sources and diverse loads from backup generators, backup batteries, rooftop photovoltaics (PV), and flexible charging loads. Each of these technologies presents consumers with an opportunity to work with their local utility to promote grid stability, reliability, and affordability. Through a wide range of programs, utilities are incentivizing the use of these resources to benefit the grid. However, especially for devices with inverters that supply power back to the grid, it is important that these assets comply with local grid codes to ensure human safety, power quality, and grid reliability. One of the most promising of these new technologies is the bidirectional electric vehicle (EV) coupled with bidirectional electric vehicle supply equipment (EVSE). This report introduces the technologies that enable bidirectional charging and how these systems operate. It then outlines the necessary interconnection codes and industry standards that govern the operations of grid-tied inverters, including those in bidirectional charging. A key challenge is then outlined from the complex landscape of communication protocols and proprietary systems designed to coordinate these grid assets. Finally, a single gateway solution is proposed to harmonize communications between all assets across an entire site for a cohesive response to grid codes and utility programs that is flexible enough to support a range of market options.

33 ADVANCED PROPULSION SYSTEMS↗

Mosaic Cu I −Cu II −In III 2D Perovskites: Pressure‐Dependence of the Intervalence Charge Transfer and a Mechanochemical Alloying Method

Abstract The perovskite (BA) 4 [Cu II (Cu I In III ) 0.5 ]Cl 8 ( 1 BA ; BA + =butylammonium) allows us to study the high‐pressure structural, optical, and transport properties of a mixed‐valence 2D perovskite. Compressing 1 BA reduces the onset energy of Cu I/II intervalence charge transfer from 1.2 eV at ambient pressure to 0.2 eV at 21 GPa. The electronic conductivity of 1 BA increases by 4 orders of magnitude upon compression to 20 GPa, when the activation energy for conduction decreases to 0.16 eV. In contrast, Cu II perovskites achieve similar conductivity at ≈50 GPa. The solution‐state synthesis of these perovskites is complicated, with more undesirable side products likely from the precursor mixtures containing three different metal ions. To circumvent this problem, we demonstrate an efficient mechanochemical synthesis to expand this family of halide perovskites with complex composition by simply pulverizing together powders of 2D Cu II single perovskites and Cu I In III double perovskites.

Li, Jiayi↗

Optimized in situ crystal growth and disordered quasi-one-dimensional magnetism in Li 2 Mn 2 ( MoO 4 ) 3

We present that the quasi-one-dimensional structure of Li 2 Mn 2 ( MoO 4 ) 3 consists of three mutually distinct chains of Li 1 - x Mn x -centered polyhedra in which Mn ostensibly adopts a J = 5 / 2 Mn 2 + configuration. In situ x-ray scattering experiments carried out as crystallites emerge from a molten oxide solution facilitate the synthesis of large single crystals. Ex situ x-ray diffraction finds no evidence of long-range Li/Mn occupancy ordering, suggesting that the structure is effectively composed of finite chains of Mn moments of statistically varying lengths. UV/visible diffuse reflectance spectroscopy measurements establish a wide 3.43(12)-eV direct charge gap consistent with the local polyhedral coordination of the nominally Mn 2 + species. The temperature T dependence of the DC magnetic susceptibility χ reveals a fluctuating moment of only 2.74 μ B ± 0.01 μ B /Mn, dramatically reduced from the 5.9 μ B /Mn expected for Mn 2 + . Meanwhile, the Weiss temperature Θ W = - 89 ± 1 K reveals antiferromagnetic fluctuations that are stymied from reaching an ordered state apparently by the chemical disorder intrinsic to the polyhedral chains. Measurements of magnetization vs field H at T ≤ 10 K are far from saturation even at H = 5 T and are strongly non-Brillouin-like, instead scaling as H / T 0.24 ( 3 ) and suggesting the presence of quantum fluctuations associated with an eventual quasi-one-dimensional, disordered magnetic phase.

1-dimensional systems↗

Electric Drive Technology Trends, Challenges, and Opportunities for Future Electric Vehicles

The transition to electric road transport technologies requires electric traction drive systems to offer improved performances and capabilities, such as fuel efficiency (in terms of MPGe, i.e., miles per gallon of gasoline-equivalent), extended range, and fast-charging options. The enhanced electrification and transformed mobility are translating to a demand for higher power and more efficient electric traction drive systems that lead to better fuel economy for a given battery charge. To accelerate the mass-market adoption of electrified transportation, the U.S. Department of Energy (DOE), in collaboration with the automotive industry, has announced the technical targets for light-duty electric vehicles (EVs) for 2025. This article discusses the electric drive technology trends for passenger electric and hybrid EVs with commercially available solutions in terms of materials, electric machine and inverter designs, maximum speed, component cooling, power density, and performance. Additionally, the emerging materials and technologies for power electronics and electric motors are presented, identifying the challenges and opportunities for even more aggressive designs to meet the need for next-generation EVs. Some innovative drive and motor designs with the potential to meet the DOE 2025 targets are also discussed.

33 ADVANCED PROPULSION SYSTEMS↗

High-energy particle acceleration by explosive electromagnetic interaction in an accretion disk

By examining electromagnetic field evolution occurring in an accretion disk around a compact object, we arrive at an explosive mechanism of particle acceleration. Flux-freezing in the differentially rotating disk causes the seed and/or generated magnetic field to wrap up tightly, becoming highly sheared and locally predominantly azimuthal in orientation. We show how asymptotically nonlinear solutions for the electromagnetic fields may arise in isolated plasma blobs as a result of the driving of the fluid equations by the accretion flow. These fields are capable of rapidly accelerating charged particles from the disk. Acceleration through the present mechanism from AGN can give rise to energies beyond 10 exp 20 eV. Such a mechanism may present an explanation for the extragalactic origin of the most energetic observed cosmic rays.

Haswell, C. A.↗

Potential mapping with charged-particle beams

Experimental methods of mapping the equipotential surfaces near some structure of interest rely on the detection of charged particles which have traversed the regions of interest and are detected remotely. One method is the measurement of ion energies for ions created at a point of interest and expelled from the region by the fields. The ion energy at the detector in eV corresponds to the potential where the ion was created. An ionizing beam forms the ions from background neutrals. The other method is to inject charged particles into the region of interest and to locate their exit points. A set of several trajectories becomes a data base for a systematic mapping technique. An iterative solution of a boundary value problem establishes concepts and limitations pertaining to the mapping problem.

Robinson, J. W.↗

Concept Design of Active Shielding for Dynamic Wireless Charging of Light-duty EV

Dynamic wireless charging of electric vehicles is a flexible and state of the art charging technology with the potential capability of enabling fully automated in-motion charging. With charging power increasing to more than 100 kW for light duty vehicles, electromagnetic field (EMF) emission becomes a critical challenge. Due to the high costs of ferrite materials, this paper proposes an active shielding solution with multiple canceling coils installed on the ground side to supplement ferrite passive shielding to ensure electromagnetic safety. Two canceling coils are designed on two sides of the ground side coil. The canceling coils are small in size and 180 degree opposite in phase to the ground coil. Simulation and modeling shows that the canceling coils can reduce EMF emission from 37.2 µT to 18.2 µT at 0.8 m during 100 kW operation with only 2.5% of ground side current flowing in the canceling coils. These results have been preliminarily verified by inductance measurements and magnetic field measurement at 1.1 m distance without canceling coils. By further increasing the canceling coils’ currents to 4%, EMF emission can also be mitigated at 200 kW, although the canceling coils’ shape, position, and phase angle can be further optimized to improve the three-dimensional field distribution.

25 ENERGY STORAGE↗

Community Charging: Emerging Multifamily, Curbside, and Multimodal Practices

Approximately 44 million households—31% of the United States total—are in multifamily housing. This encompasses both rented and owned homes in apartment buildings, condominiums, townhouses, and mixed-use developments. Regardless of where they live, nearly one-third of Americans do not drive. As U.S. transportation is electrified, it will be imperative to support car-free or car-light households, as well as residents living in multifamily and rental housing, with tailored solutions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗