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At least 91 records · Page 5

Condensation and fractionation of rare earths in the solar nebula

The condensation behavior of the rare earth elements in the solar nebula is calculated on the basis of the most recent thermodynamic data in order to construct a model explaining group II rare earth element patterns in Allende inclusions. Models considered all involve the removal of large fractions of the more refractory heavy rare earth elements in an early condensate, followed by the condensation of the remainder at a lower temperature. It is shown that the model of Boynton (1975) in which one rare earth element component is dissolved nonideally in perovskite according to relative activity coefficients can not reasonably be made to fit the observed group II patterns. A model in which two rare earth components control the patterns and dissolve ideally in perovskite is proposed and shown to be able to account for the 20 patterns by variations of the perovskite removal temperature and the relative proportions of the two components.

Davis, A. M.↗

Elimination of secular terms from the differential equations for the elements of perturbed two-body motion

In 1961, Sperling linearized and regularized the differential equations of motion of the two-body problem by changing the independent variable from time to fictitious time by Sundman's transformation (r = dt/ds) and by embedding the two-body energy integral and the Laplace vector. In 1968, Burdet developed a perturbation theory which was uniformly valid for all types of orbits using a variation of parameters approach on the elements which appeared in Sperling's equations for the two-body solution. In 1973, Bond and Hanssen improved Burdet's set of differential equations by embedding the total energy (which is a constant when the potential function is explicitly dependent upon time.) The Jacobian constant was used as an element to replace the total energy in a reformulation of the differential equations of motion. In the process, another element which is proportional to a component of the angular momentum was introduced. Recently trajectories computed during numerical studies of atmospheric entry from circular orbits and low thrust beginning in near-circular orbits exhibited numerical instability when solved by the method of Bond and Gottlieb (1989) for long time intervals. It was found that this instability was due to secular terms which appear on the righthand sides of the differential equations of some of the elements. In this paper, this instability is removed by the introduction of another vector integral called the delta integral (which replaces the Laplace Vector) and another scalar integral which removes the secular terms. The introduction of these integrals requires a new derivation of the differential equations for most of the elements. For this rederivation, the Lagrange method of variation of parameters is used, making the development more concise. Numerical examples of this improvement are presented.

Bond, Victor R.↗

Trace element distributions in primitive achondrites

The primitive achondrites have approximately chondritic bulk chemical composition but achondritic textures. Clayton et al. show that nine of these meteorites, the acapulcoites and the lodranites, have similar oxygen isotopic compositions. The acapulcoites appear to be highly metamorphosed, but undifferentiated meteorites of chondritic composition; whereas, the lodranites appear to have lost a feldspathic partial melt. In order to learn more about metamorphic processes and partial melt removal, we have measured the trace element compositions of constituent phases of a number of primitive achondrites by ion microprobe. We have analyzed two acapulcoites, Acapulco and ALH81261 (paired with ALH77081), and three londranites, Lodran, LEW88280, and MAC88177. In addition, we analyzed LEW88663, which has the bulk composition, mineral chemistry, and oxygen isotopic composition of L-chondrites, but is metal-free and has an achondrite texture; and Divnoe, a plagioclase-poor, olivine-rich primitive achondrite with an oxygen isotopic composition similar to that of the group IAB iron meteorites. These meteorites show a variety of REE patterns in their constituent phases, and there are consistent differences between acapulcoites and lodranites that are consistent with removal of a LREE- and Eu-enriched melt that is apparently responsible for the low plagioclase content of lodranites.

Davis, Andrew M.↗

A new material for removing heavy metals from water

The NASA Lewis Research Center developed and is patenting a new high capacity ion exchange material (IEM) that removes toxic metals from contaminated water in laboratory tests. The IEM can be made into many forms, such as thin films, coatings, pellets, and fibers. As a result, it can be adapted to many applications to purify contaminated water wherever it is found, be it in waste water treatment systems, lakes, ponds, industrial plants, or in homes. Laboratory tests have been conducted on aqueous solutions containing only one of the following metal cations: lead, copper, mercury, cadmium, silver, chromium (III), nickel, zinc, and yttrium. Tests were also conducted with: (1) calcium present to determine its effects on the uptake of cadmium and copper, and (2) uranium and lanthanides which are stand-ins for other radioactive elements, (3) drinking water for the removal of copper and lead, and (3) others compositions. The results revealed that the IEM removes all these cations, even in the presence of the calcium. Of particular interest are the results of the tests with the drinking water: the lead concentration was reduced from 142 ppb down to 2.8 ppb (well below the accepted EPA standard).

Philipp, Warren H., Jr.↗

International Space Station Bacteria Filter Element Service Life Evaluation

The International Space Station (ISS) uses high-efficiency particulate air filters to remove particulate matter from the cabin atmosphere. Known as bacteria filter elements (BFEs), there are 13 elements deployed on board the ISS's U.S. segment in the flight 4R assembly level. The preflight service life prediction of 1 yr for the BFEs is based upon engineering analysis of data collected during developmental testing that used a synthetic dust challenge. While this challenge is considered reasonable and conservative from a design perspective, an understanding of the actual filter loading is required to best manage the critical ISS program resources. Testing was conducted on BFEs returned from the ISS to refine the service life prediction. Results from this testing and implications to ISS resource management are provided.

Perry, J. L.↗

Constraints on the Nature and Distribution of Iridium Host Phases at the Cretaceous-Tertiary Boundary: Implications for Projectile Identity and dispersal on impact

Among Cretaceous-Tertiary boundary sites worldwide, variations in the concentrations and ratios of elements commonly enriched in meteorites complicate traditional geochemical attempts at impactor identification. Yet they may provide constraints on the physical and chemical processes associated with large-body disruption and dispersal, as well as with diagenesis of projectile components. To this end, we continue our efforts to identify the mineral host-phases of projectile-derived elements, particularly for Ir, and to document their partitioning between crater deposits and ejecta resulting from the Chicxulub basin-forming impact. Building on earlier work, we used INAA to measure Ir concentrations in successively smaller splits of finely powdered impact melt breccia from the Chicxulub Crater in Mexico (sample Y6Nl9-R(b)), and K/T boundary fish clay from Stevns Klint, Denmark (sample FC-1, split from 40 kg of homogenized material intended as an analytical standard). Results for the Chicxulub sample show a heterogeneous Ir distribution and document that at least five discrete Ir-bearing host phases were isolated in subsequent splits, having Ir masses equivalent to pure Ir spheres from about 0.8 to about 3.5 mm in diameter. Three of these are within a sufficiently reduced mass of powder to warrant searching for them using backscattered electron microscopy. In contrast, successively smaller splits of the Stevns Klint fish clay show no statistically significant deviation from the reported value of 32 +/- 2 ng/g Ir, suggesting a uniform Ir host-phase distribution. For the smallest split obtained thus far (100 +/- 40 ng/g Ir), a pure Ir sphere of equivalent Ir mass would be <0.05 min in diameter. (n.b. Although homogenizing and sieving of FC-1 to <75 min obviously obscured variations in stratigraphic distribution, it is unlikely to have affected the size-frequency distribution of Ir host phases.) We previously identified micrometer-scale Ir host phases by electron microscopy in melt-rock samples from two widely separated drill holes at the Chicxulub Basin, including a replicate split of Y6-NI9-R. One is an aggregate of subhedral Ir metal grains enclosed in silicate, in which no other Pt group elements (PGE) were detected. A second particle with twice the mass as the first, concentrated predominantly in a single grain, is associated with minor concentrations of Os, Ru, and Pt, and with adhering particles of corundum and perovskite. A third Ir-rich particle, with a greater apparent Os concentration, was identified before being lost as a result of charging under the electron beam. In addition to demonstrating the preservation of projectile components within the Chicxulub Crater, analogous phase associations in Ca- and Al-rich inclusions (CAI) from C2 and C3 chondrites suggest to us that these melt-rock Ir host phases are relics from a carbonaceous chondrite K/T boundary impactor Although the obviously low Ru/Ir ratios of the Chicxulub Ir host phases are qualitatively consistent with suggested PGE fractionation with distance during condensation in an ejecta cloud, it seems difficult to explain the accumulation of the about 3 x 10(exp 11) Ir atoms required to form a about 10(exp -10) g nugget of pure Ir metal within a jet of vaporized projectile expanding at 1-4 km/s, or to effectively exclude or remove commonly alloyed PGE and siderophile elements by fractionation processes resulting from condensation, oxidation, sulfidization, exsolution, or autometamorphism during cooling of the melt. We do not dismiss the importance of these processes entirely; on the contrary, other geochemical and mineralogical aspects of the melt rocks require them, and condensation from the expanding ejecta cloud appears to best explain the primary Ir host-phase distribution in the fish clay, as well as the high Ir concentrations associated with spinel-bearing spheroids at the K/T boundary in the Pacific Ocean . If the "relict" hypothesis is correct, micronuggets of other PGEs and alloys, not detected by our INAA screening, should also occur in the melt rocks. Possibly, the discrete host phases with lesser Ir masses are such alloys with subordinate Ir, rather than simply smaller, predominantly Ir-bearing particles. A CAI source for the relics would be consistent with either a comet or an asteroid K/T impact at Chicxulub. (Additional information contained in the original.)

Schuraytz, B. C.↗

A user's guide to the Mariner 9 television reduced data record

The Mariner 9 television experiment used two cameras to photograph Mars from an orbiting spacecraft. For quantitative analysis of the image data transmitted to earth, the pictures were processed by digital computer to remove camera-induced distortions. The removal process was performed by the JPL Image Processing Laboratory (IPL) using calibration data measured during prelaunch testing of the cameras. The Reduced Data Record (RDR) is the set of data which results from the distortion-removal, or decalibration, process. The principal elements of the RDR are numerical data on magnetic tape and photographic data. Numerical data are the result of correcting for geometric and photometric distortions and residual-image effects. Photographic data are reproduced on negative and positive transparency films, strip contact and enlargement prints, and microfiche positive transparency film. The photographic data consist of two versions of each TV frame created by applying two special enhancement processes to the numerical data.

Seidman, J. B.↗

Thermal Brushes For Memory-Metal Actuators

Thermoelectric elements with wire-brush contacts remove heat from or add heat to memory-metal actuators and thereby enable them to respond faster than previously possible. Memory-metal actuator formed to shape while hot, then to another shape while cold. When cold actuator heated so temperature rises above critical point, snaps from cold shape to hot shape. Upon cooling, actuator returns to cold shape, ready for another cycle. Clearly, faster actuator is heated and cooled, the faster it operates.

Wood, Charles↗

The evolution of power management architecture for missions to the outer planets

Outer planet spacecraft have unique requirements that differentiate them from inner planet and Earth orbiter spacecraft. To meet these requirements, the Voyager and Galileo Power Management And Distribution (PMAD) architectures employed shunt regulation and carried on the Mariner tradition of AC power distribution to many of the user loads. Also, autonomous fault recovery was achieved by automatic responses in hardware and software recovery routines. Finally, power distribution switching was expanded to allow for removal of the most trivial load element as the nuclear source depleted itself. The design cycle has begun for a third generation spacecraft set named Comet Rendezvous Asteroid Flyby (CRAF) and Cassini (a saturn orbiter). In their power systems, AC power distribution, relay/fuse load switching, and fault protection will give way to the advantages of DC power and solid state load switches.

Detwiler, R. C.↗

Desert Research and Technology Studies (RATS) 2007 Field Campaign Objectives and Results

Desert "RATS" (Research and Technology Studies) is a combined, multi-discipline group of inter-NASA center scientists and engineers, net-working and collaborating with representatives of industry and academia, for the purpose of conducting planetary surface exploration-focused remote field exercises. These integrated testing exercises conducted under representative analog Lunar and Mars surface terrain conditions, provide NASA the capability to validate experimental prototype hardware and software systems as well as to evaluate and develop mission operational techniques in order to identify and establish technical requirements and identify potential technology "gaps" applicable for future planetary human exploration. The 2007 D-RATS field campaign test activities were initiated based on the major themes and objectives of a notional 5-year plan developed for conducting relative analog test activities in support of the engineering evaluation and assessment of various system architectural requirements, conceptual prototype support equipment and selected technologies necessary for the establishment of a lunar outpost. Specifically, the major objectives included measuring task efficiency during robot, human, and human-robot interactive tasks associated with lunar outpost site surveying and reconnaissance activities and deployment of a representative solar panel power and distribution system. In addition, technology demonstrations were conducted with a new Lithium-ion battery and autonomous software to coordinate multiple robot activities. Secondary objectives were evaluating airlock concept mockups and prototype removable space suit over-garment elements for dust mitigation, and upgrades to the prototype extravehicular activities (EVA) communication and information system. Dry run test activities, prior to testing at a designated remote field site location, were initially conducted at the Johnson Space Center (JSC) Remote Field Demonstration Test Site. This is a multi-acre external test site located at JSC and has detailed representative terrain features simulating both Lunar and Mars surface characteristics. Both the local JSC and remote field test sites have terrain conditions that are representative and characteristic of both the Moon and Mars, such as strewn rock and volcanic ash fields, craters, rolling plains, hills, gullies, slopes, and outcrops. The D-RATS 2007 field campaign, representing the completion of its tenth year of analog testing, was conducted at the large Cinder Lake volcanic ash bed area adjacent to Flagstaff, Arizona.

Kosmo, Joseph↗

Results of the Trace Contaminant Control Trade Study for Space Suit Life Support Development

As the United States plans to return astronauts to the moon, designing the most effective and efficient life support systems is of extreme importance. The trace contaminant control system (TCCS) will be located within the Portable Life Support System (PLSS) of the Constellation Space Suit Element (CSSE), and is responsible for removing contaminants, which at increased levels can be hazardous to a crewmember s health. These contaminants come from several sources including metabolic production of the crewmember (breathing, sweating, etc.) and offgassing of the space suit material layers. This paper summarizes the results of a trade study that investigated TCC technologies used in NASA space suits and vehicles as well as commercial and academic applications, to identify the best technology options for the CSSE PLSS. The trade study also looked at the feasibility of regeneration of TCC technologies, specifically to determine the viability of vacuum regeneration for on-back, realtime EVA.

Jennings, Mallory A.↗

Results of the Trace Contaminant Control Trade Study for Space Suit Life Support Development

As the United States plans to return astronauts to the moon, designing the most effective and efficient life support systems is of extreme importance. The trace contaminant control system (TCCS) will be located within the Portable Life Support System (PLSS) of the Constellation Space Suit Element (CSSE), and is responsible for removing contaminants, which at increased levels can be hazardous to a crewmember's health. These contaminants come from several sources including metabolic production of the crewmember (breathing, sweating, etc.) and offgassing of the space suit material layers. This paper summarizes the results of a trade study that investigated TCC technologies used in NASA space suits and vehicles as well as commercial and academic applications, to identify the best technology options for the CSSE PLSS. The trade study also looked at the feasibility of regeneration of TCC technologies, specifically to determine the viability of vacuum regeneration for on-back, real-time EVA.

Paul, Heather L.↗

Memory-Efficient Onboard Rock Segmentation

Rockster-MER is an autonomous perception capability that was uploaded to the Mars Exploration Rover Opportunity in December 2009. This software provides the vision front end for a larger software system known as AEGIS (Autonomous Exploration for Gathering Increased Science), which was recently named 2011 NASA Software of the Year. As the first step in AEGIS, Rockster-MER analyzes an image captured by the rover, and detects and automatically identifies the boundary contours of rocks and regions of outcrop present in the scene. This initial segmentation step reduces the data volume from millions of pixels into hundreds (or fewer) of rock contours. Subsequent stages of AEGIS then prioritize the best rocks according to scientist- defined preferences and take high-resolution, follow-up observations. Rockster-MER has performed robustly from the outset on the Mars surface under challenging conditions. Rockster-MER is a specially adapted, embedded version of the original Rockster algorithm ("Rock Segmentation Through Edge Regrouping," (NPO- 44417) Software Tech Briefs, September 2008, p. 25). Although the new version performs the same basic task as the original code, the software has been (1) significantly upgraded to overcome the severe onboard re source limitations (CPU, memory, power, time) and (2) "bulletproofed" through code reviews and extensive testing and profiling to avoid the occurrence of faults. Because of the limited computational power of the RAD6000 flight processor on Opportunity (roughly two orders of magnitude slower than a modern workstation), the algorithm was heavily tuned to improve its speed. Several functional elements of the original algorithm were removed as a result of an extensive cost/benefit analysis conducted on a large set of archived rover images. The algorithm was also required to operate below a stringent 4MB high-water memory ceiling; hence, numerous tricks and strategies were introduced to reduce the memory footprint. Local filtering operations were re-coded to operate on horizontal data stripes across the image. Data types were reduced to smaller sizes where possible. Binary- valued intermediate results were squeezed into a more compact, one-bit-per-pixel representation through bit packing and bit manipulation macros. An estimated 16-fold reduction in memory footprint relative to the original Rockster algorithm was achieved. The resulting memory footprint is less than four times the base image size. Also, memory allocation calls were modified to draw from a static pool and consolidated to reduce memory management overhead and fragmentation. Rockster-MER has now been run onboard Opportunity numerous times as part of AEGIS with exceptional performance. Sample results are available on the AEGIS website at http://aegis.jpl.nasa.gov.

Burl, Michael C.↗

Refinement of the Robert-Bonamy Formalism: Considering Effects from the Line Coupling

Since it was developed in 1979, the Robert-Bonamy (RB) formalism has been widely used in calculating pressure broadened half-widths and induced shifts for many molecular systems. However, this formalism contains several approximations whose applicability has not been thoroughly justified. One of them is that lines of interest are well isolated. When these authors developed the formalism, they have relied on this assumption twice. First, in calculating the spectral density F(ω), they have only considered the diagonal matrix elements of the relaxation operator. Due to this simplification, effects from the line mixing are ignored. Second, when they applied the linked cluster theorem to remove the cutoff, they have assumed the matrix elements of the operator exp(-iS(sub 1) - S(sub 2)) can be replaced by the exponential of the matrix elements of -iS(sub 1) - S(sub 2). With this replacement, effects from the line coupling are also ignored. Although both these two simplifications relied on the same approximation, their validity criteria are completely different and the latter is more stringent than the former. As a result, in many cases where the line mixing becomes negligible, significant effects from the line coupling have been completely missed. In the present study, we have developed a new method to evaluate the matrix elements of exp(-iS(sub 1) - S(sub 2)) and have refined the RB formalism such that line coupling can be taken into account. Our numerical calculations of the half-widths for Raman Q lines of the N(sub 2)-N(sub 2) pair have demonstrated that effects from the line coupling are important. In comparison with values derived from the RB formalism, new calculated values for these lines are significantly reduced. A recent study has shown that in comparison with the measurements and the most accurate close coupling calculations, the RB formalism overestimates the half-widths by a large amount. As a result, the refinement of the RB formalism goes in the right direction and these new calculated half-widths become closer to the "true" values.

spectra↗

Evaluation of an Electrostatic Dust Removal System with Potential Application in Next-Step Fusion Devices

The ability to manage inventories of carbon, tritium, and high-Z elements in fusion plasmas depends on means for effective dust removal. A dust conveyor, based on a moving electrostatic potential well, was tested with particles of tungsten, carbon, glass and sand. A digital microscope imaged a representative portion of the conveyor, and dust particle size and volume distributions were derived before and after operation. About 10 cu mm volume of carbon and tungsten particles were moved in under 5 seconds. The highest driving amplitude tested of 3 kV was the most effective. The optimal driving frequency was 210 Hz (maximum tested) for tungsten particles, decreasing to below 60 Hz for the larger sand particles. Measurements of particle size and volume distributions after 10 and 100 cycles show the breaking apart of agglomerated carbon, and the change in particle distribution over short timescales 1 s).

Friesen, F. Q. L.↗

International Space Station Bacteria Filter Element Post-Flight Testing and Service Life Prediction

The International Space Station uses high efficiency particulate air (HEPA) filters to remove particulate matter from the cabin atmosphere. Known as Bacteria Filter Elements (BFEs), there are 13 elements deployed on board the ISS's U.S. Segment. The pre-flight service life prediction of 1 year for the BFEs is based upon performance engineering analysis of data collected during developmental testing that used a synthetic dust challenge. While this challenge is considered reasonable and conservative from a design perspective, an understanding of the actual filter loading is required to best manage the critical ISS Program resources. Thus testing was conducted on BFEs returned from the ISS to refine the service life prediction. Results from this testing and implications to ISS resource management are discussed. Recommendations for realizing significant savings to the ISS Program are presented.

Perry, J. L.↗