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Basic Considerations in the Combustion of Hydrocarbon Fuels with Air

Basic combustion research is collected, collated, and interpreted as it applies to flight propulsion. The following fundamental processes are treated in separate chapters: atomization and evaporation of liquid fuels, flow and mixing processes in combustion chambers, ignition and flammability of hydrocarbon fuels, laminar flame propagation, turbulent flames, flame stabilization, diffusion flames, oscillations in combustors, and smoke and coke formation in the combustion of hydrocarbon-air mixtures. Theoretical background, basic experimental data, and practical significance to flight propulsion are presented.

Barnett, Henry C↗

Aerodynamic features of turbulent flames

The paper provides an interpretation for a variety of turbulent flame phenomena relating them to the aerodynamic properties of the flow field. This includes the classical notion of the breakdown of laminar flames propagation in ducts, the characteristic features of turbulent flame-fronts recorded by schlieren photography, as well as flame instabilities leading to flashback occurring in a combustion chamber behind a bluff-body flame holder. The rudimentary nature of turbulent flame propagation is shown to be associated with (1) vortex motion of a large-scale turbulent eddy, combined with (2) self-advancement of the flame at the appropriate normal burning speed and (3) the concomitant action of distributed sources of specific volume. The results furnish an insight into the macroscopic properties of the mechanism of turbulent flame propagation, rationalizing in particular its capability to sustain high flow velocities at relatively low normal burning speeds.

Oppenheim, A. K.↗

A Study of Aircraft Fire Hazards Related to Natural Electrical Phenomena

The problems of natural electrical phenomena as a fire hazard to aircraft are evaluated. Assessment of the hazard is made over the range of low level electrical discharges, such as static sparks, to high level discharges, such as lightning strikes to aircraft. In addition, some fundamental work is presented on the problem of flame propagation in aircraft fuel vent systems. This study consists of a laboratory investigation in five parts: (1) a study of the ignition energies and flame propagation rates of kerosene-air and JP-6-air foams, (2) a study of the rate of flame propagation of n-heptane, n-octane, n-nonane, and n-decane in aircraft vent ducts, (3) a study of the damage to aluminum, titanium, and stainless steel aircraft skin materials by lightning strikes, (4) a study of fuel ignition by lightning strikes to aircraft skins, and (5) a study of lightning induced flame propagation in an aircraft vent system.

Kester, Frank L.↗

Combustion modeling for experimentation in a space environment

The merits of combustion experimentation in a space environment are assessed, and the impact of such experimentation on current theoretical models is considered. It is noted that combustion theory and experimentation for less than normal gravitational conditions are incomplete, inadequate, or nonexistent. Extensive and systematic experimentation in a space environment is viewed as essential for more adequate and complete theoretical models of such processes as premixed flame propagation and extinction limits, premixed flame propagation in droplet and particle clouds, ignition and autoignition in premixed combustible media, and gas jet combustion of unpremixed reactants. Current theories and models in these areas are described, and some combustion studies that can be undertaken in the Space Shuttle Program are proposed, including crossed molecular beam, turbulence, and upper pressure limit (of gases) studies.

Berlad, A. L.↗

Flame-Vortex Studies to Quantify Markstein Numbers Needed to Model Flame Extinction Limits

This has quantified a database of Markstein numbers for unsteady flames; future work will quantify a database of flame extinction limits for unsteady conditions. Unsteady extinction limits have not been documented previously; both a stretch rate and a residence time must be measured, since extinction requires that the stretch rate be sufficiently large for a sufficiently long residence time. Ma was measured for an inwardly-propagating flame (IPF) that is negatively-stretched under microgravity conditions. Computations also were performed using RUN-1DL to explain the measurements. The Markstein number of an inwardly-propagating flame, for both the microgravity experiment and the computations, is significantly larger than that of an outwardy-propagating flame. The computed profiles of the various species within the flame suggest reasons. Computed hydrogen concentrations build up ahead of the IPF but not the OPF. Understanding was gained by running the computations for both simplified and full-chemistry conditions. Numerical Simulations. To explain the experimental findings, numerical simulations of both inwardly and outwardly propagating spherical flames (with complex chemistry) were generated using the RUN-1DL code, which includes 16 species and 46 reactions.

Driscoll, James F.↗

Combustion experiments in space

Pivotal areas for needed combustion observations (available through space shuttle experimentation) include: (1) single- and two-phase premixed flame propagation and extinction limits; (2) noncoherent flame propagation and extinction; (3) autoignition of premixed single-phase and two-phase combustible reactants; (4) upper pressure limit combustion phenomena and ignition, propagation, and extinction processes in the neighborhood of such limits; (5) oscillatory combustion associated with the hydrocarbon-oxygen and with the carbon monoxide-oxygen systems; (6) two-phase flame spread and extinction involving lage liquid-gas or solid-gas interfaces; (7) radiative ignition of solids and liquids; (8) pool burning; (9) smoldering of solid combustibles and the associated transition to flaming or extinction; (10) laminar gas jet combustion; and (11) transient responses of combustible systems to time variation in gravitational field strengths. A number of these may be impacted by undesirably high g-jitter effects.

Berlad, A. L.↗

Aerodynamic properties of turbulent combustion fields

Flow fields involving turbulent flames in premixed gases under a variety of conditions are modeled by the use of a numerical technique based on the random vortex method to solve the Navier-Stokes equations and a flame propagation algorithm to trace the motion of the front and implement the Huygens principle, both due to Chorin. A successive over-relaxation hybrid method is applied to solve the Euler equation for flows in an arbitrarily shaped domain. The method of images, conformal transformation, and the integral-equation technique are also used to treat flows in special cases, according to their particular requirements. Salient features of turbulent flame propagation in premixed gases are interpreted by relating them to the aerodynamic properties of the flow field. Included among them is the well-known cellular structure of flames stabilized by bluff bodies, as well as the formation of the characteristic tulip shape of flames propagating in ducts. In its rudimentary form, the mechanism of propagation of a turbulent flame is shown to consist of: (1) rotary motion of eddies at the flame front, (2) self-advancement of the front at an appropriate normal burning speed, and (3) dynamic effects of expansion due to exothermicity of the combustion reaction. An idealized model is used to illustrate these fundamental mechanisms and to investigate basic aerodynamic features of flames in premixed gases. The case of a confined flame stabilized behind a rearward-facing step is given particular care and attention. Solutions are shown to be in satisfactory agreement with experimental results, especially with respect to global properties such as the average velocity profiles and reattachment length.

Hsiao, C. C.↗

Flammability testing conducted in support of Apollo 13

In support of the Apollo 13 investigation of the oxygen tank failure, flame propagation rates were determined for Teflon insulation in cryogenic and ambient temperature oxygen for upward, downward, and zero g burns. The propagation rates depended heavily on configuration and varied from 4.8 to 10.9 cm/sec for upward one g burns to 0.48 cm/sec for zero g burns. In addition to the flame propagation rates, tests were conducted to determine if Teflon burning in cryogenic oxygen could ignite metals (promoted ignition) with which it came in contact. Tests conducted on various metal alloys used in the oxygen tank indicated that most of the alloys could be ignited by burning Teflon in certain configurations. After the propagation rates and promoted metal ignitions had been evaluated, a test was conducted on a quantity gauge and wire harness used in the oxygen tank to determine if flame propagation to the tank wall was possible. Propagation of the wire bundle after ignition resulted in a catastrophic failure of the test vessel in the area of the quantity gauge.

Leger, L. J.↗

Japan's research on particle clouds and sprays

Most of energy used by us is generated by combustion of liquid and solid fuels. These fuels are burned in combustors mainly as liquid sprays and pulverized solids, respectively. A knowledge of the combustion processes in combustors is needed to achieve proper designs that have stable operation, high efficiency, and low emission levels. However, current understanding of liquid and solid particle cloud combustion is far from complete. If combustion experiments for these fuels are performed under a normal gravity field, some experimental difficulties are encountered. These difficulties encountered include, that since the particles fall by the force of gravity it is impossible to stop the particles in the air, the falling speeds of particles are different from each other, and are depend on the particle size, the flame is lifted up and deformed by the buoyancy force, and natural convection makes the flow field more complex. Since these experimental difficulties are attributable to the gravity force, a microgravity field can eliminate the above problems. This means that the flame propagation experiments in static homogeneous liquid and solid particle clouds can be carried out under a microgravity field. This will provide much information for the basic questions related to combustion processes of particle clouds and sprays. In Japan, flame propagation processes in the combustible liquid and solid particle clouds have been studied experimentally by using a microgravity field generated by a 4.5 s dropshaft, a 10 s dropshaft, and by parabolic flight. Described in this presentation are the recent results of flame propagations studies in a homogeneous liquid particle cloud, in a mixture of liquid particles/gas fuel/air, in a PMMA particle cloud, and in a pulverized coal particle cloud.

Sato, Jun'ichi↗

Combustion rate limits of hydrogen plus hydrocarbon fuel: Air diffusion flames from an opposed jet burner technique

Combustion of H2/hydrocarbon (HC) fuel mixtures may be considered in certain volume-limited supersonic airbreathing propulsion applications. Effects of HC addition to H2 were evaluated, using a recent argon-bathed, coaxial, tubular opposed jet burner (OJB) technique to measure the extinction limits of counterflow diffusion flames. The OJB flames were formed by a laminar jet of (N2 and/or HC)-diluted H2 mixture opposed by a similar jet of air at ambient conditions. The OJB data, derived from respective binary mixtures of H2 and methane, ethylene, or propane HCs, were used to characterize BLOWOFF and RESTORE. BLOWOFF is a sudden breaking of the dish-shaped OJB flame to a stable torus or ring shape, and RESTORE marks sudden restoration of the central flame by radial inward flame propagation. BLOWOFF is a measure of kinetically-limited flame reactivity/speed under highly stretched, but relatively ideal impingement flow conditions. RESTORE measures inward radial flame propagation rate, which is sensitive to ignition processes in the cool central core. It is concluded that relatively small molar amounts of added HC greatly reduce the reactivity characteristics of counterflow hydrogen-air diffusion flames, for ambient initial conditions.

Pellett, Gerald L.↗

Effects of Buoyancy on the Flowfields of Lean Premixed Turbulent V-Flames

Open laboratory turbulent flames used for investigating fundament flame turbulence interactions are greatly affected by buoyancy. Though much of our current knowledge is based on observations made in these open flames, the effects of buoyancy are usually not included in data interpretation, numerical analysis or theories. This inconsistency remains an obstacle to merging experimental observations and theoretical predictions. To better understanding the effects of buoyancy, our research focuses on steady lean premixed flames propagating in fully developed turbulence. We hypothesize that the most significant role of buoyancy forces on these flames is to influence their flowfields through a coupling with mean and fluctuating pressure fields. Changes in flow pattern alter the mean aerodynamic stretch and in turn affect turbulence fluctuation intensities both upstream and downstream of the flame zone. Consequently, flame stabilization, reaction rates, and turbulent flame processes are all affected. This coupling relates to the elliptical problem that emphasizes the importance of the upstream, wall and downstream boundary conditions in determining all aspects of flame propagation. Therefore, buoyancy has the same significance as other parameters such as flow configuration, flame geometry, means of flame stabilization, flame shape, enclosure size, mixture conditions, and flow conditions.

Cheng, R. K.↗

Effects of Buoyancy on the Flowfields of Lean Premixed Turbulent V-Flames

Open laboratory turbulent flames used for investigating fundamental flame turbulence interactions are greatly affected by buoyancy. Though much of our current knowledge is based on observations made in open flames, buoyancy effects are usually not considered in data interpretation, numerical analysis or theories. This inconsistency remains an obstacle to merging experimental observations and theoretical predictions. To better understanding the effects of buoyancy, our research focuses on steady lean premixed flames propagating in fully developed turbulence. We hypothesize that the most significant role of buoyancy forces on these flames is to influence their flowfields through a coupling with the mean and the fluctuating pressure fields. This coupling relates to the elliptical problem that emphasizes the importance of the upstream, wall and downstream boundary conditions in determining all aspects of flame propagation. Therefore, buoyancy has the same significance as other parameters such as flow configuration, and flame geometry.

Cheng, R. K.↗

Turbulent Jet Flames Into a Vitiated Coflow

Examined is the vitiated coflow flame, an experimental condition that decouples the combustion processes of flows found in practical combustors from the associated recirculating fluid mechanics. The configuration consists of a 4.57 mm diameter fuel jet into a coaxial flow of hot combustion products from a lean premixed flame. The 210 mm diameter coflow isolates the jet flame from the cool ambient, providing a hot environment similar to the operating conditions of advanced combustors; this important high temperature element is lacking in the traditional laboratory experiments of jet flames into cool (room) air. A family of flows of increasing complexity is presented: 1) nonreacting flow, 2) all hydrogen flame (fuel jet and premixed coflow), and 3) set of methane flames. This sequence of experiments provides a convenient ordering of validation data for combustion models. Laser Raman-Rayleigh-LIF diagnostics at the Turbulent Diffusion Flame laboratory of Sandia National Laboratories produced instantaneous multiscalar point measurements. These results attest to the attractive features of the vitiated coflow burner and the well-defined boundary conditions provided by the coflow. The coflow is uniform and steady, isolating the jet flame from the laboratory air for a downstream distance ranging from z/d = 50-70. The statistical results show that differential diffusion effects in this highly turbulent flow are negligible. Complementing the comprehensive set of multiscalar measurements is a parametric study of lifted methane flames that was conducted to analyze flame sensitivity to jet and coflow velocity, as well as coflow temperature. The linear relationship found between the lift-off height and the jet velocity is consistent with previous experiments. New linear sensitivities were found correlating the lift-off height to coflow velocity and temperature. A blow-off study revealed that the methane flame blows off at a common coflow temperature (1260 K), regardless of coflow or jet velocity. An explanation for this phenomenon is that entrainment of ambient air at the high lift-off heights prevents autoignition. Analysis of the results suggests that flame stabilization occurs through a combination of flame propagation, autoignition, and localized extinction processes. Proposed is an expanded view of distributed reaction combustion based on analysis of the distributions of probe volume conditions at the stabilization region of the lifted hydrogen and methane flames. Turbulent eddies the size of the flame thickness mix fuel and hot coflow across the flame front, thereby enhancing the reaction zone with autoignition of reactants at elevated temperatures; this is the reverse effect of turbulent flames in ambient air, where intense turbulence in cool mixtures result in localized extinction. Each of the three processes (i.e., flame propagation, autoignition and localized extinction) contributes to flame stabilization in varying degrees, depending on flow conditions.

Holdeman, James D.↗

Effects of confinement on partially premixed flames

Partially premixed combustion is an intermediate regime between the limiting cases of premixed and nonpremixed combustion. Although combustion problems are generally approached from one of these two limiting cases, there are many practical situations where flames cannot be considered as purely premixed or nonpremixed, and thus the partially premixed approach must be used. In partially premixed combustion, mechanisms from the premixed and nonpremixed regimes can coexist, and as a result some interesting new phenomena can arise. One such phenomenon is the flame stabilization in laminar mixing layers by triple flames. One of the first observations of triple flames was made by Phillips (1965), who investigated a triple flame propagating in a methane mixing layer. Kioni et al. (1993) also examined triple flames both experimentally and numerically. There have also been numerous analytical studies on the shape and propagation of triple flames under various assumptions by Dold (1989), Dold et al. (1991), and Hartley and Dold (1991). In terms of modeling, Muller et al. (1994) have combined the flamelet formulations for premixed and nonpremixed combustion in order to treat lifted diffusion flames. One common feature in the analytical and numerical studies mentioned above is the assumption of zero heat release, which is necessary to make the problem tractable. The effect of heat release on triple flames was investigated by Ruetsch et al. (1995), where for the unconfined case, flame speeds larger than their premixed counterparts were found. One of the most important practical situations in which these conditions arise is in lifted turbulent jet diffusion flames. At a critical velocity the burning zone of a fuel jet lifts off from the nozzle, moves to increasing distances as the jet velocity increases, and finally blows off. The mechanisms that control these phenomena, i.e. that determine the stability of these flames, are still not understood. In addition to regions where diffusion flame stabilization takes place, partially premixed conditions also exist during the ignition process in nonpremixed systems. Numerical simulations by Reveillon et al. (1994) of the ignition process in a weakly stirred mixture of fuel and oxidizer show that triple flames propagate along lines of stoichiometric mixture fraction throughout the fluid. In addition, Peters (1994) notes that NO(x) emissions are likely to be large in such transient cases, and therefore an understanding of triple flames can provide information concerning pollutant formation. This study extends the work previously done and examines the effects of lateral confinement on partially premixed flames. Once again, we study both the flame structure and propagation.

Ruetsch, G. R.↗

Effect of gravity on the stability and structure of lean hydrogen-air flames

Detailed, time-dependent, 2D numerical simulations with full hydrogen-oxygen chemistry are used to investigate the effects of gravity on the stability and structure of laminar flames in lean, premixed hydrogen-air mixtures. The calculations show that the effects of gravity becomes more important as the lean flammability limit is approached. In a 12 percent hydrogen-air mixture, gravity plays only a secondary role in determining the multidimensional structure of the flame with the stability and structure of the flame controlled primarily by the thermo-diffusive instability mechanism. However, in leaner hydrogen-air mixtures gravity becomes more important. Upward-propagating flames are highly curved and evolve into a bubble rising upwards in the tube. Downward-propagating flames are flat or even oscillate between structures with concave and convex curvatures. The zero-gravity flame shows only cellular structures. Cellular structures which are present in zero gravity can be suppressed by the effect of buoyancy for mixtures leaner than 11 percent hydrogen. These observations are explained on the basis of an interaction between the processes leading to buoyancy-induced Rayleigh-Taylor instability and the thermo-diffusive instability.

Patnaik, G.↗

Plasma assisted NH 3 /H 2 /air ignition in nanosecond discharges with non-equilibrium energy transfer

Ammonia (NH 3 ), with its high energy density and easiness to store and transport as a hydrogen carrier, has become a promising alternative green fuel. However, its adoption in power generation is hindered by challenges such as low burning velocity, slow low-temperature oxidation, high NO x emissions, and ignition difficulty. Here, this work computationally investigates the effects of non-equilibrium energy transfer by nanosecond discharges on NH 3 ignition and flame propagation in an NH 3 /H 2 /air flow at 700 K and 1 atm. The simulation results demonstrate that NH 3 /air mixtures require a large ignition energy due to their large critical ignition radius. It is shown that adding 30 % hydrogen significantly reduces the critical ignition radius and minimum ignition energy. Two-dimensional modeling further shows a non-monotonic dependence of ignition kernel volume on the applied voltage and reduced electric field. The optimum ignition enhancement occurs at 200 Td where the generation of electronically excited species and radicals including N 2 (B), O( 1 D) and OH becomes most efficient. Higher voltages divert electron energy toward ionization, which makes it less effective for NH 3 ignition. The study also identifies an optimal electrode gap size for a given pulse energy. Smaller gap sizes increase deposited energy density, raising temperature and radical concentrations. However, excessive reduction of the gap distance reduces flame propagation speed due to the flame stretch effect in rich mixtures with the effective Lewis number greater than unity. A nonlinear relationship between pulse repetition frequency and ignition kernel volume is observed in a nanosecond pulsed high frequency discharge (NPHFD). An optimal frequency range of 200 kHz to 2 MHz is found when two pulses are used. In addition, an optimal number of pulses exists for each pulse repetition frequency, with higher frequencies requiring more pulses to maximize the overlap region. These findings provide critical insights on developing controlled plasma discharge techniques for efficient NH 3 ignition in reactive flows within internal combustion engines and gas turbines.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

On Combustion in a Turbulent Flow

The characteristics introduced by the turbulence in the process of the flame propagation are considered. On the basis of geometrical and dimensional considerations an expression is obtained for the velocity of the flame propagation in a flow of large scale of turbulence.

Shelkin, K. I.↗