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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
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NASA NTRS1995

Radiative and Nonradiative Transitions of the Rare-Earth Ions Tm(3+) and Ho(3+) in Y3AI5O12 and LiYF4

The optical spectra of rare earth ions in solids arise primarily from electric and magnetic dipole transitions between stark split multiplets of the 4f(sup N) electronic configuration. Electric dipole transitions are parity forbidden between levels of the 4f(sup N) configuration, while those of magnetic dipole origin are allowed. It is known from experiment, however, that the significant contributions to the intensities of most transitions are electric dipole in nature. Judd and Ofelt developed the theory of forced electric dipole transitions of rare-earth ions. This study is devoted to determining electric dipole transition probabilities and branching ratios for Tm(3+) and Ho(3+) ions in Yttrium Aluminum Garnet (YAG) and Yttrium Lithium Fluoride (YLF) using the theory of Judd and Ofelt. The radiative rates determined from the Judd-Ofelt analysis are used with measured lifetimes to find nonradiative rates of relaxation.

Walsh, Brian M.↗
NASA NTRS1987

Remote sensing of atomic oxygen - Some observational difficulties in the use of the forbidden O I 1173-A and O I 1641-A transitions

Recent sounding rocket and satellite studies suggest that simultaneous measurements of the O I 989-A and 1304-A resonance lines and of the forbidden 1172.6-A and 1641.3-A transitions would form the basis of a useful remote sensing technique for measuring the O I density and optical opacity of a planetary or stellar atmosphere. Because the 1172.6-A and 1641.3-A emissions are weak lines and are emitted in a wavelength region rich in spectral features, it is important to determine whether typical flight instruments can make measurements with sufficient spectral purity so that the remote sensing observations will yield accurate results. A detailed, high-resolution study of the far UV emission features in the regions surrounding the atomic oxygen transitions at 1172.6 and 1641.3 A was made. These spectra, which were excited by electron impact on O2 and N2, are presented in an attempt to display some potential sources of interference in aeronomical measurements of these O I lines. Both atomic and molecular emissions are found, and the spectral resolution necessary to make unambiguous measurements is discussed.

Erdman, P. W.↗
NASA NTRS2009

Multispectrum Analysis of 12CH4 in the v4 Band: I. Air-Broadened Half Widths, Pressure-Induced Shifts, Temperature Dependences and Line Mixing

Lorentz air-broadened half widths, pressure-induced shifts and their temperature dependences have been measured for over 430 transitions (allowed and forbidden) in the v4 band of (CH4)-12 over the temperature range 210 to 314 K. A multispectrum non linear least squares fitting technique was used to simultaneously fit a large number of high-resolution (0.006 to 0.01/cm) absorption spectra of pure methane and mixtures of methane diluted with dry air. Line mixing was detected for pairs of A-, E-, and F-species transitions in the P- and R-branch manifolds and quantified using the off-diagonal relaxation matrix elements formalism. The measured parameters are compared to air- and N2-broadened values reported in the literature for the v4 and other bands. The dependence of the various spectral line parameters upon the tetrahedral symmetry species and rotational quantum numbers of the transitions is discussed. All data used in the present work were recorded using the McMath-Pierce Fourier transform spectrometer located at the National Solar Observatory on Kitt Peak.

Smith, MaryAnn H.↗
NASA NTRS1977

Observed departures from LTE ionization equilibrium in late-type giants

Photoelectric scans of the Ca I line at 6572 A and the forbidden Ca II transition at 7323 A are studied in the K giant alpha Tau, the M supergiant alpha Ori, and the M giants beta And, alpha Cet, mu Gem, and beta Peg. The relative strengths of these lines are shown to be indicative of the ratio of the relative number densities of the neutral and ionized species in the photosphere. The analysis indicates an overionization relative to LTE in qualitative agreement with the theoretical calculations of Auman and Woodrow for the K and M giants. The M supergiant alpha Ori exhibits a large overionization relative to LTE.

Ramsey, L. W.↗
NASA NTRS1977

Detection of forbidden Fe XIV emission in HD 153919 /3U 1700-37/

Spectra of HD 153919 show a previously unreported broad emission line near 5293 A that is present at phases 0.2 and 0.8 and is absent or weaker at other phases, including the time of eclipse of the X-ray source. Approximate calculations suggest identification of this feature with the forbidden Fe XIV transition at 5303 A. This line may arise in the extended atmosphere of the primary ionized by the compact X-ray source or may occur in a high-temperature corona. Further monitoring is needed.

Dupree, A. K.↗
NASA NTRS1982

Spectral characteristics of the iron oxides with application to the Martian bright region mineralogy

Reflectance spectra of eight polymorphs of FeOOH and Fe2O3 are determined in order to clarify the nature and significance of the iron oxide mineralogy on Mars. The effect of other components that might interfere with iron oxide absorption features is qualitatively constrained through the use of the Kebulka-Munk theory. It is found that the effect of temperature complicates the identification of a given Fe(3+) phase based on the position of the 6A1-4T1 absorption feature. While the Fe(3+) crystal field transitions are spin forbidden, most of the iron oxide polymorphs exhibit anomalously intense crystal field absorption features due to magnetic coupling between adjacent FeO6 octahedra. It is suggested that the resulting deviations from observed remotely sensed reflectance spectra of Mars may provide a basis for the exclusion of many iron oxide phases as significant components of the Martian Fe(3+) mineralogy. A comparison of these results with the visible region spectra of Martian bright regions indicates that the predominant Fe(3+)-bearing phase may be a magnetically disordered material, such as amorphous gels, some ferric sulphates, and other minerals in which Fe(3+) ions in the crystal structure are not magnetically coupled.

Sherman, D. M.↗
NASA NTRS1975

Ultraviolet emission line profiles of flares and active regions

A preliminary description of ultraviolet spectra of active regions and flares, photographed from Skylab by the Naval Research Laboratory's UV spectrograph, is given. The findings can be summarized as follows: (1) Line profiles of medium-ionized lines (transition-zone lines) show the most pronounced broadenings and shifts in flares and flare-like events; (2) typical full widths at half maximum of these lines correspond to Doppler velocities of 70 km/s; (3) shifts of the same magnitude can be observed; (4) intersystem lines are not broadened or shifted; (5) forbidden coronal lines and intersystem lines become enhanced in the flare spectrum at the moment when the turbulence seen in the allowed transitions disappears; and (6) a very broad line at 1354.2 A, which appears only in flare spectra, seems to be the forbidden transition 3P(1)-3P(0) of Fe XXI.

Brueckner, G. E.↗
NASA NTRS2017

Si III OV Bright Line of Scattering Polarized Light That Has Been Observed in the CLASP and Its Center-to-Limb Variation

The CLASP (Chromospheric Lyman-Alpha Spectro- Polarimeter) rocket experiment, in addition to the ultraviolet region of the Ly alpha emission line (121.57 nm), emission lines of Si III (120.65 nm) and OV (121.83 nm) is can be observed. These are optically thin line compared to a Ly alpha line, if Rarere captured its polarization, there is a possibility that dripping even a new physical diagnosis chromosphere-transition layer. In particular, OV bright light is a release from the transition layer, further, three P one to one S(sub 0) is a forbidden line (cross-triplet transition between lines), it was not quite know whether to polarization.

spectropolarimeter↗
NASA NTRS1971

Analysis of parallel systems.

A formal analysis procedure for hardware and software computer systems is described. A system is described by a flow table model. The concept of an output hazard is introduced to account for effects of unbounded line delays. Necessary and sufficient conditions for the absence of output hazards are given. A system that contains no output hazards is said to operate correctly if the system state graph that describes all system states and state transitions is free from forbidden states and forbidden state sequences. A flow table solution for the two-component mutual exclusion problem is analyzed and shown to be correct.

Bredt, T. H.↗
NASA NTRS1975

Glauber exchange amplitudes

The extrapolation method of Ochkur, valid for intermediate energies (about 50 eV), is applied to the exchange form of the Glauber amplitudes. In the case of elastic scattering of electrons from hydrogen atoms at 54.4 Ev the 'post' and 'prior' forms of the exchange amplitude are equivalent, whereas for the case of inelastic scattering there is a minute discrepancy between the two forms of the amplitude. The results are compared with the close-coupling calculation. The investigation is expected to be useful for optically forbidden exchange-allowed transitions due to electron impact at intermediate energies.

Madan, R. N.↗
NASA NTRS1976

Radiative cooling of a low-density plasma

The paper extends and improves the radiative cooling coefficient calculations of Cox and Tucker (1969) and Cox and Daltabuit (1971) for a low-density optically thin plasma with no molecules or dust, of cosmic abundances in the range from 10,000 to 100,000,000 K. Earlier rates applied to a plasma containing H, He, C, N, O, Ne, Mg, Si, and S; the present study added Ca, Fe, and Ni. For the elements included, many individual lines are calculated which previously has been averaged together. The cooling processes considered are permitted, forbidden, and semiforbidden line transitions, including contributions from dielectronic recombination and bremsstrahlung, radiative recombination, and two-photon continua. The ionization balance is calculated in collisional equilibrium using an approximate auto-ionization following inner-shell excitation and the low-density limit for the dielectronic recombination rate. Cooling in various observational bands in the soft X-ray region is determined.

Raymond, J. C.↗
NASA NTRS1987

Effective collision strengths for electron impact excitations in S II

Electron impact collision strengths for forbidden, semiforbidden, and allowed transitions in S II calculated using the R-matrix method are presented. Configuration interaction wave functions are used to represent the six target states included in the calculation. At low impact energies the collision strengths are dominated by resonances for several transitions. The contribution from higher partial waves is obtained in the close-coupling approximation with exchange terms omitted. Results are presented for the effective collision strengths over a wide temperature range (5000-150,000 K) of astrophysical interest. The present results for the 4S(0) yields 2P(0) transition are 20-30 percent lower than previous calculations, while for the 4S(0) yields 2D(0) transition they are in good agreement. The results are approximately 30 percent higher than those of Ho and Henry (1983) for the 4S(0) yields 2P(0) transition at 80,000 K, and the difference between the two results increases with decreasing temperatures (under 80,000 K).

Tayal, S. S.↗
NASA NTRS1973

Computer checking of rotational line intensity factors for diatomic transitions.

Previously published analytical formulae for the rotational line intensity factors of diatomic molecules have been compared with results from a comprehensive computer program, which determines numerical intensity factors for both spin-allowed and spin-forbidden electric and magnetic dipole transitions in diatomic molecules. The comparison uncovered several typographical errors and a few algebraic errors in the published formulae. The changes required in the formulae to give agreement with the results from the computer program are tabulated.

Whiting, E. E.↗
NASA NTRS2006

New Critical Compilations of Atomic Transition Probabilities for Neutral and Singly Ionized Carbon, Nitrogen, and Iron

We have undertaken new critical assessments and tabulations of the transition probabilities of important lines of these spectra. For Fe I and Fe II, we have carried out a complete re-assessment and update, and we have relied almost exclusively on the literature of the last 15 years. Our updates for C I, C II and N I, N II primarily address the persistent lower transitions as well as a greatly expanded number of forbidden lines (M1, M2, and E2). For these transitions, sophisticated multiconfiguration Hartree-Fock (MCHF) calculations have been recently carried out, which have yielded data considerably improved and often appreciably different from our 1996 NIST compilation.

Wiese, Wolfgang L.↗
NASA NTRS1984

Detection of far-infrared forbidden O I and forbidden O III emission from the galaxy M82

Observations in M82 of the lowest-lying transitions of neutral and doubly ionized oxygen, forbidden O I 63.2 microns and forbidden O III 88.4 microns, which have wavelengths at which the extinction toward M82 is negligible, are reported. For O III, the +220 km/s velocity of the line center with respect to the local standard of rest, the 300 km/s intrinsic line width, and the asymmetry of the profile are consistent with the systemic velocity and rotational broadening seen in other ionic lines in the nucleus of M82. The fraction of oxygen that is present in doubly ionized form, indicates that the ionization state is similar to that found in H II regions in the disk of the Milky Way Galaxy. The central velocity of the O I line is +130 km/s, and no broadening in excess of instrumental resolution is seen. This result appears to rule out association of this emission with the periphery of the central H II region.

Watson, D. M.↗