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At least 91 records · Page 5

Microbial Community Shifts Reflect Losses of Native Soil Carbon with Pyrogenic and Fresh Organic Matter Additions and Are Greatest in Low-Carbon Soils

ABSTRACT Soil organic carbon (SOC) plays an important role in regulating global climate change, carbon and nutrient cycling in soils, and soil moisture. Organic matter (OM) additions to soils can affect the rate at which SOC is mineralized by microbes, with potentially important effects on SOC stocks. Understanding how pyrogenic organic matter (PyOM) affects the cycling of native SOC (nSOC) and the soil microbes responsible for these effects is important for fire-affected ecosystems as well as for biochar-amended systems. We used an incubation trial with five different soils from National Ecological Observatory Network sites across the United States and 13 C-labeled 350°C corn stover PyOM and fresh corn stover OM to trace nSOC-derived CO 2 emissions with and without PyOM and OM amendments. We used high-throughput sequencing of rRNA genes to characterize bacterial, archaeal, and fungal communities and their responses to PyOM and OM in soils that were previously stored at −80°C. We found that the effects of amendments on nSOC-derived CO 2 reflected the unamended soil C status, where relative increases in C mineralization were greatest in low-C soils. OM additions produced much greater effects on nSOC-CO 2 emissions than PyOM additions. Furthermore, the magnitude of the microbial community composition change mirrored the magnitude of increases in nSOC-CO 2 , indicating that a specific subset of microbes was likely responsible for the observed changes in nSOC mineralization. However, PyOM responders differed across soils and did not necessarily reflect a common “charosphere.” Overall, this study suggests that soils that already have low SOC may be particularly vulnerable to short-term increases in SOC loss with OM or PyOM additions. IMPORTANCE Soil organic matter (SOM) has an important role in global climate change, carbon and nutrient cycling in soils, and soil moisture dynamics. Understanding the processes that affect SOM stocks is important for managing these functions. Recently, understanding how fire-affected organic matter (or “pyrogenic” organic matter [PyOM]) affects existing SOM stocks has become increasingly important, due to both changing fire regimes and interest in “biochar,” pyrogenic organic matter that is produced intentionally for carbon management or as an agricultural soil amendment. We found that soils with less SOM were more prone to increased losses with PyOM (and fresh organic matter) additions and that soil microbial communities changed more in soils that also had greater SOM losses with PyOM additions. This suggests that soils that already have low SOM content may be particularly vulnerable to short-term increases in SOM loss and that a subset of the soil microbial community is likely responsible for these effects.

54 ENVIRONMENTAL SCIENCES↗

Success Path Method: Conformance with Safety Management Systems

All industrial facilities deal with safety hazards such as equipment failures, chemical and toxic releases, and fires and explosions just to name a few. A disciplined framework for managing the integrity of operating systems and processes that handle hazardous substances by applying good design principles, engineering, and operating practices is called process safety. The goal of such framewoks is to prevent the release of energy or material that could cause harm to people or damage to equipment and/or environment. Process safety covers all aspects of facility operation also including design, maintenance, and human and organizational factors that could possibly have effect on process safety. As it will be seen from the discussion below, process safety is just one of the pieces of the much bigger matter, a safety culture. Many industries have long recognized the importance of safety culture in their day-to-day operation. Although the definition of safety culture can slightly differ from organization to organization, in general, a safety culture is how things are done to demonstrate a commitment to safety by everyone involved. An organization acquires safety culture over time as the product of individual and group values, actions, and behaviors toward overall safety. It is important to note that safety culture should not be viewed as some static state that an organization wants to reach. It is more like a constantly evolving level of “how things are done when nobody is watching.” Safety culture is an inherent characteristic of an organization, it is always present, but the level can range on a continuum from undesirable to desirable or more commonly used, from negative to positive. An example for an undesirable, negative safety culture would be a company in which accidents resulting in harm (physical and/or emotional) of its employees, equipment or surrounding environment and community occur frequently. At the other end of the spectrum would be a company in which such accidents are rare or do not occur at all (desired or positive safety culture). Every company/industry exists somewhere within this spectrum.

42 ENGINEERING↗

Estimating the influence of field inventory sampling intensity on forest landscape model performance for determining high-severity wildfire risk

Abstract Historically, fire has been essential in Southwestern US forests. However, a century of fire-exclusion and changing climate created forests which are more susceptible to uncharacteristically severe wildfires. Forest managers use a combination of thinning and prescribed burning to reduce forest density to help mitigate the risk of high-severity fires. These treatments are laborious and expensive, therefore optimizing their impact is crucial. Landscape simulation models can be useful in identifying high risk areas and assessing treatment effects, but uncertainties in these models can limit their utility in decision making. In this study we examined underlying uncertainties in the initial vegetation layer by leveraging a previous study from the Santa Fe fireshed and using new inventory plots from 111 stands to interpolate the initial forest conditions. We found that more inventory plots resulted in a different geographic distribution and wider range of the modelled biomass. This changed the location of areas with high probability of high-severity fires, shifting the optimal location for management. The increased range of biomass variability from using a larger number of plots to interpolate the initial vegetation layer also influenced ecosystem carbon dynamics, resulting in simulated forest conditions that had higher rates of carbon uptake. We conclude that the initial forest layer significantly affects fire and carbon dynamics and is dependent on both number of plots, and sufficient representation of the range of forest types and biomass density.

Science & Technology - Other Topics↗

AI/ML-Enhanced Wind Forecasts for Reducing Uncertainty in Prescribed Fire Planning

Prescribed fire is a vital tool for ecosystem management and wildfire risk reduction but its escalation is constrained by overly conservative burn windows because of uncertainties, for instance, in wind forecasts. This review describes the state of the art in weather product use by fire/smoke models and identifies three priority research gaps that artificial intelligence/machine learning (AI/ML) is well positioned to address: (1) spatial and temporal downscaling to meter-scale, sub-hourly wind fields; (2) bias correction for systematic model errors in complex terrain; and (3) robust uncertainty quantification to inform ensemble-based simulations. Emerging AI/ML techniques offer promising frameworks to address all three challenges. By providing high-resolution, bias-corrected, and probabilistic wind fields, AI/ML-enhanced forecasts will allow for expanded burn windows, improved ignition strategy design and a reduced reliance on expert intuition, especially when a prescribed fire is introduced into new areas.

54 ENVIRONMENTAL SCIENCES↗

Conclusions from 3 years of continuous capture plant operation without exchange of the AMP/PZ-based solvent at Niederaussem – insights into solvent degradation management

A many times heard mantra of solvent degradation management in amine-based post combustion capture is “keep the solvent clean” to minimize solvent consumption. It is assumed that the amine losses would decrease by the removal of metals, degradation products, and reactive trace components which are captured from the flue gas, like NO 2 (as potentially driving components of the amine degradation besides dissolved O 2 ). However, this theoretical hypothesis – based on results from laboratory experiments typically generated with fresh amines – disregards the complexity of the solvent matrix, interaction of potential metal catalysts with degradation products and oxidizing agents, and specific chemical requirements which must be fulfilled before a degradation mechanism can proceed. Degradation of the solvent CESAR1 (aqueous solution of 3.0 molar 2-amino-2-methylpropan-1-ol (AMP) and 1.5 molar piperazine (PZ)) is investigated in a unique long-time test campaign (testing time up to now 40 months; 24/7 operation) without replacement of the solvent inventory at the capture pilot plant at the lignite-fired power plant in Niederaussem. Three solvent management strategies with different effect mechanisms are investigated and evaluated: (a) removal of only anionic compounds and trace elements (within 75 days solvent inventory treated two times) and anionic as well as cationic compounds and trace elements (114 days, inventory treated four times) from the solvent by ion exchange, (b) adsorptive removal of trace elements from the solvent by active carbon in 35% of the operating time, and (c) removal of >80% NO 2 by flue gas pretreatment with thiosulfate/sulfite solution (dosing for 2,000 h). The results of the testing program clearly show that “solvent cleanliness” is not a well-defined parameter and that results from laboratory tests, tests without fully representative industrial flue gasses, and short-term testing of monoethanolamine cannot be generalized for other solvents and industrial application. Furthermore, these results showcase that specific degradation management considering solvent, capture plant and flue gas quality is reasonable. Overshooting efforts for solvent management are contra-productive and produce unnecessary waste streams, efficiency losses and costs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Invasive Plant Species Management Plan for Los Alamos National Laboratory (Rev.3)

Native species are plants and animals that continually occupy a natural range without direct or indirect introduction and/or care by humans. They are adapted to the environmental conditions and processes of the ecosystem in which they reside. A species introduced into a novel ecosystem can either exploit that ecosystem and thrive or be unable to survive in that ecosystem (Hobbs et al. 2006). Alien or non-native species are species that are intentionally or accidentally introduced into a novel ecosystem and are capable of living and propagating within the physical parameters of that ecosystem. Invasive species is a species that is non-native (or alien) to the ecosystem under consideration and a noxious species are those whose introduction causes or is likely to cause economic or environmental harm. The term invasive species is applicable to plants and animals alike; however, this invasive species management plan currently focuses on invasive vegetation. Invasive plant species are usually capable of rapid colonization of disturbed ground, such as after a change in wildfire regime intensity and frequency (Reilly et al. 2020) or anthropogenic ground disturbance (Burke and Grime 1996; Hobbs and Huenneke 1992). Climate change facilitates the spread and establishment of many alien species and creates new opportunities for them to become invasive (Turbelin and Catford 2021). As climate change impacts increase in the coming decades, we may see in an increase in invasive species establishment. See a list of definitions of terms pertinent to this document in Appendix A: Definitions. Los Alamos National Laboratory (LANL) hosts populations of non-native and invasive species all typical of the northern New Mexico region (Martin 2004; NMDA 2020). By implementing an invasive species management plan, LANL will have readily accessible management strategies for invasive species that are found on-site. The benefits of managing invasive species include a decrease in wildland fire risks, an increase in soil productivity, an increase in (productive or beneficial) wildlife habitat, an increase in water quantity and quality, and the restoration of impacted areas (Burke and Grime 1996; Hobbs and Huenneke 1992; D’Antonio and Hobbie 2005; MacDougall et al. 2013; Reilly et al. 2020). The aforementioned benefits from invasive species management directly enable the LANL mission by ensuring compliance requirements are met and site-wide programs, such as the Vulnerability Assessment and Resilience Plan, are supported for a mutually beneficial outcome. An example for the LANL site specifically, controlling non-native annual plant species, for example, could reduce the costs associated with stabilizing soils during the stormwater pollution prevention compliance process. Roadway and utility right-of-way areas are another place where an integrated vegetation management strategy would promote low growing perennial plants in a way that is mutually beneficial to habitat and the institution through lowered maintenance costs. There is also an economic benefit to managing invasive species. In one nationwide study, invasive plants had an estimated impact cost of $190.45 billion (Fantel-Lepczyk et al. 2022). Investing in preventative measures and surveillance could help to offset future control and management costs of invasive species that have the potential to become established. The State of New Mexico has developed plant species lists and recommendations through the New Mexico Department of Agriculture’s Noxious Weeds Management Act, Article 7D (NM Statute § 76-7D-4 2021); however, effective invasive species management must rely on local knowledge of the site and region. Los Alamos County (LAC) has already compiled a target invasive plant species list and species-specific management objectives (Martin 2004). Therefore, the New Mexico Noxious Weed List and the LAC invasive plant species list, as well as management objectives from those documents, are integrated into LANL’s invasive plant species management plan.

54 ENVIRONMENTAL SCIENCES↗

Scalable, Dual-Mode Occupancy Sensing for Commercial Venues

The ability to establish accurate occupancy is a key enabler for improved energy efficiency in human-occupied indoor spaces. The accurate counts can be used to adjust, in real-time, air exchange, heating, and cooling, to closely match the environmental needs of the occupants rather than to use a single setting based on maximum room occupancy. This project focuses on the use of overhead fisheye cameras and artificial intelligence (AI) algorithms as the technology to realize accurate people counting in large commercial spaces. We developed Computational Occupancy Sensing SYstem ("COSSY''), which supports large-scale deployment (thousands of square feet) and straightforward installation (using conventional power over ethernet), while providing high accuracy and low cost. COSSY has been validated at Boston University and by a third party, demonstrating people-counting accuracy of at least 89.5% in large spaces (2,000 sqft). A cost/benefit analysis performed for Boston commercial market indicates that a full payback of COSSY deployment costs due to energy savings would occur within 3-6 months from installation. Applications of COSSY reach far beyond saving energy. The precise people counting in real time could also be useful for emergency response (e.g., fire), in spatial analytics (e.g., office space management) and in some health applications (e.g., social distance assessment during pandemics).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Evaluation of Cease Fire CFP 640 for Use in Gloveboxes (Final Report)

A Los Alamos National Laboratory (LANL) task group was established to discuss and evaluate a candidate fire suppression system (FSS) for gloveboxes (GB) and dropboxes (DB, for brevity, this report will simply refer to gloveboxes). Suitability criteria include compliance, compatibility, and capability. LANL contracted with New Mexico Tech (NMT) to quantitatively evaluate the perfor mance of one of those systems including its ability to extinguish GB fires, limit over-pressurization of the GB, etc. Additionally, the results of these experiments provide data points that could be used when fire hazard evaluations (FHEs) are conducted for determining when to require a fire suppres sion system installation within a GB (as required by NFPA 801, Standard for Facilities Handling Radioactive Materials, DOE Standard 1066-2012 Fire Protection, and AGS-G010-2011 Standard of Practice for Glovebox Fire Protection).

42 ENGINEERING↗

Amplified drought trends in Nepal increase the potential for Himalayan wildfires

Here we report in the spring 2021, Nepal underwent a record wildfire season in which active fires were detected at a rate 10 times greater than the 2002–2020 average. Prior to these major wildfire events, the country experienced a prolonged precipitation deficit and extreme drought during the post-monsoon period (starting in October 2020). An analysis using observational, reanalysis, and climate model ensemble data indicates that both climate variability and climate change-induced severe drought conditions were at play. Further analysis of climate model outputs suggests the likely reoccurrence of drought conditions, thus favoring active wildfire seasons in Nepal throughout the twenty-first century. While the inter-model uncertainty is large and direct modeling of wildfire spread and suppression has not been completed, the demonstrated relationship between a drought index (the standardized precipitation and evapotranspiration index) and subsequent fire activity may offer actionable opportunities for forest managers to employ the monitoring and projection of climate anomalies at sub-seasonal to decadal timescales to inform their management strategies for Nepal’s wildlands.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of Glovebox Fires Involving Flammable Liquids and Standard Glovebox Tools (Final Report)

This research effort was commissioned to examine factors related to loss of containment due to fire within a glovebox (GB). Tests consisted of multiple trials with varying initial conditions. Com bustible levels and types were chosen to reflect realistic operation conditions (including worst-case scenarios), involving flammable liquids, GB tools, and other combustible items commonly found in GBs at Los Alamos National Labs (LANL).

42 ENGINEERING↗

Response of soil nutrient pools and microbiomes to recurrent wildfire disturbance and varying burn severities in a mixed conifer forest

Wildfire is a pervasive disturbance in mixed-conifer forests, yet the relative influence of fire recurrence versus burn severity on soil biogeochemistry and microbial communities remains poorly quantified. We examined a natural gradient of fire history (0–3 prior fires) and burn severity (low–high) spanning 50 yr in a mixed-conifer ecosystem to assess how repeated fire shapes soil carbon (C) and nitrogen (N) pools, their isotopic signatures, mineral and particulate fractions, microbial community composition, carbon-use, CO₂ fluxes, and vegetation cover. Successive fires produced progressively higher bare-ground percentages and lower tree cover, which were tightly linked to declines in microbial diversity and reductions bulk %C, and %N. δ 13 C increased with fire frequency, indicating preferential loss of labile C through combustion or enhanced microbial oxidation, thereby explaining the observed net soil-C decline. Conversely, δ 15 N decreased and pH increased as tree density declined, reflecting altered N cycling and reduced acidification in post-fire soils. Fire recurrence, more than severity, corresponded with a marked shift in the bacterial community: for example, Xanthobacteraceae—key N-fixers and C-cyclers—diminished, while N-fixing Bacillaceae increased, underscoring the tightly coupled nature of soil nutrient dynamics and microbiome composition after repeated burns. Our results demonstrate that fire recurrence appears to be a stronger driver of post-fire soil ecosystem responses in this mixed-conifer forest, influencing both abiotic nutrient pools and the functional potential of the soil microbiome. These findings provide a more enhanced assessment and understanding to date of the biogeochemical consequences of repeated wildfire disturbance that can be used to inform management strategies aimed at preserving soil health in fire-prone landscapes.

54 ENVIRONMENTAL SCIENCES↗

Dynamic and Responsive Distributed Energy Resource Education Solutions for Building, Fire, and Safety Department Officials (Final Technical Report)

From April 2021 through March 2024, the Interstate Renewable Energy Council (IREC) led a collaborative project to develop a free online clearinghouse of educational resources about solar photovoltaics (PV), energy storage systems (ESS), electric vehicle supply equipment (EVSE), and grid-interactive efficient building (GEB) technologies. Two websites—the Clean Energy Clearinghouse and CleanEnergyTraining.org—housed over 70 educational resources. Over the course of the three-year project, 154,272 unique visitors accessed the learning materials. Learner feedback was overwhelmingly positive. Even through the end of the project, there was sustained demand for education and communication. A primary innovation of the project was to drive multiple complementary audiences to the same place. Building owners, designers, installation contractors and developers, authorities having jurisdiction (AHJs), and fire service personnel all benefit from a shared understanding of clean energy technologies, including safety and code-related requirements. When considering the impact on the target audience, the project team worked with partners and advisors to inform resource creation and delivery in such a way as to address key motivational factors of the target audience and compel each user to seek additional information on the topic and return to the Clean Energy Clearinghouse website as their central location for more information. Resources were intentionally developed to be concise—five to 15 minutes—and accessible, meaning not overly technical. Providing basic information demystified the technologies and invited the professional to explore additional learning opportunities. Awardee and partner collaboration was key to project success. IREC facilitated collaboration among the other Topic 2 awardees, Southface and New Buildings Institute (NBI). The three awardees shared relevant information gained through discovery and validation questionnaires that informed product development and reduced duplication of effort by coordinating the development of complementary, and not competing, educational resources. Inspired by this collaboration, IREC brought on additional partners even in the final year of the project. Five regional energy efficiency organizations were part of the project, which expanded the connection between efficiency and distributed energy resources. We also included resources on the Clearinghouse that were developed through other federally funded projects, such as the Buildings Energy Efficiency Frontiers & Innovation Technologies (BENEFIT) program. The website was developed with the learner in mind, and not solely the funding source. Feedback from stakeholders throughout the project, and especially in its final year, indicated the need for continued education and facilitated communication among stakeholders to further the safe and widespread adoption of clean energy.

14 SOLAR ENERGY↗

Informing climate adaptation strategies using ecological simulation models and spatial decision support tools

Introduction: Forest landscapes offer resources and ecosystem services that are vital to the social, economic, and cultural well-being of human communities, but managing for these provisions can require socially and ecologically relevant trade-offs. We designed a spatial decision support model to reveal trade-offs and synergies between ecosystem services in a large eastern Cascade Mountain landscape in Washington State, USA. Methods: We used process-based forest landscape (LANDIS-II) and hydrology (DHSVM) models to compare outcomes associated with 100 years of simulated forest and wildfire dynamics for two management scenarios, Wildfire only and Wildfire + Treatments. We then examined the strength and spatial distribution of potential treatment effects and trends in a set of resources and ecosystem services over the simulation period. Results: We found that wildfire area burned increased over time, but some impacts could be mitigated by adaptation treatments. Treatment benefits were not limited to treated areas. Interestingly, we observed neighborhood benefits where fire spread and severity were reduced not only in treated patches but in adjacent patches and landscapes as well, creating potential synergies among some resource benefits and services. Ordinations provided further evidence for two main kinds of outcomes. Positive ecological effects of treatments were greatest in upper elevation moist and cold forests, while positive benefits to human communities were aligned with drier, low- and mid-elevation forests closer to the wildland urban interface. Discussion: Our results contribute to improved understanding of synergies and tradeoffs linked to adaptation and restoration efforts in fire-prone forests and can be used to inform management aimed at rebuilding resilient, climate-adapted landscapes.

54 ENVIRONMENTAL SCIENCES↗

A two-stage optical fusion framework for wildfire severity mapping across the conterminous United States

Accurate wildfire severity mapping (WSM) is essential for post-fire recovery planning, erosion risk assessment, ecosystem monitoring, and disaster risk reduction. Although Landsat and Sentinel optical imagery have been widely used for burn severity assessment, the added value of fusing multiple optical sensors has not been sufficiently quantified across diverse fire events, particularly since the launch of Landsat-9. This study evaluates whether multisensor optical fusion improves wildfire severity mapping relative to single-sensor baselines using Sentinel-2, Landsat-8, and Landsat-9 imagery across 40 wildfire events in the conterminous United States. We tested a two-stage fusion framework that combines feature-level fusion with pixel-level dimensionality reduction. First, feature-level fused datasets were created through early fusion by combining standardized post-fire bands from each sensor into a single predictor stack. Both raw reflectance bands and pairwise spectral transforms were retained to capture within- and cross-sensor spectral interactions. Second, Linear Discriminant Analysis was applied to both single-sensor and fused datasets to produce comparable low-dimensional feature spaces. Six machine-learning classifiers were then used to benchmark model performance with repeated spatially buffered train–test splits. Results show that Landsat-9 was the strongest single-sensor baseline. Among the fusion strategies, Sentinel-2 + Landsat-9 produced the most consistent improvement and reduced performance variability. Landscape-condition analysis further showed that this fusion was most beneficial in shrubland-dominated and high-terrain fires, where it achieved the highest overall mean accuracy and the fewest failures. In contrast, its benefits were less reliable in evergreen forests, mixed vegetation, and low- to moderate-elevation terrain. In operational settings, the Sentinel-2 + Landsat-9 configuration offers a practical solution for post-fire recovery planning, erosion-risk assessment, watershed management, and ecological monitoring when field observations are available and timely satellite-based information is needed.

Landsat↗

AmeriFlux FLUXNET-1F US-xJE NEON Jones Ecological Research Center (JERC)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xJE NEON Jones Ecological Research Center (JERC). This is the FLUXNET version of the carbon flux data for the site US-xJE NEON Jones Ecological Research Center (JERC) produced by applying the standard ONEFlux (1F) software. Site Description - This terrestrial relocatable field site is located in the Joseph Jones Ecological Research Center is an 11,000-hectare reserve located within the Lower Coastal Plains and Flatwoods areas in southern Georgia. The Jones site has been managed with low intensity, dormant-season prescribed fires for the past 75 years at a frequency of every 3-4 years.

Network), NEON (National Ecological Observatory↗

AmeriFlux US-xSB NEON Ordway-Swisher Biological Station (OSBS)

This is the AmeriFlux version of the carbon flux data for the site US-xSB NEON Ordway-Swisher Biological Station (OSBS). Site Description - The Ordway-Swisher Biological Station (OSBS) is operated by the University of Florida and comprises over 9,300 acres. It is a year-round field station established for the long-term study and conservation of unique ecosystems through management, research and education. The Station is located approximately 20 miles east of Gainesville in Melrose (Putnam County, Florida). There are two aquatic arrays at Ordway-Swisher, representing the two dominant aquatic features on the landscape: 1) Suggs lake, a shallow surface water lake that is rich in taxa and biologically active in structure and function; and 2) Barco lake, a deep lake connected to ground water. The forest is maintained by fire and has a relatively open structure: it is managed with prescribed burns at a frequency of 3-4 years.

Network), NEON (National Ecological Observatory↗

AmeriFlux FLUXNET-1F US-xSB NEON Ordway-Swisher Biological Station (OSBS)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xSB NEON Ordway-Swisher Biological Station (OSBS). This is the FLUXNET version of the carbon flux data for the site US-xSB NEON Ordway-Swisher Biological Station (OSBS) produced by applying the standard ONEFlux (1F) software. Site Description - The Ordway-Swisher Biological Station (OSBS) is operated by the University of Florida and comprises over 9,300 acres. It is a year-round field station established for the long-term study and conservation of unique ecosystems through management, research and education. The Station is located approximately 20 miles east of Gainesville in Melrose (Putnam County, Florida). There are two aquatic arrays at Ordway-Swisher, representing the two dominant aquatic features on the landscape: 1) Suggs lake, a shallow surface water lake that is rich in taxa and biologically active in structure and function; and 2) Barco lake, a deep lake connected to ground water. The forest is maintained by fire and has a relatively open structure: it is managed with prescribed burns at a frequency of 3-4 years.

Network), NEON (National Ecological Observatory↗

Evidence for multi-decadal fuel buildup in a large California wildfire from smoke radiocarbon measurements

In recent decades, there has been a significant increase in annual area burned in California's Sierra Nevada mountains. This rise in fire activity has prompted the need to understand how historical forest management practices affect fuel composition and emissions. Here we examined the total carbon (TC) concentration and radiocarbon abundance (Δ 14 C) of particulate matter (PM) emitted by the KNP Complex Fire, which occurred during California's 2021 wildfire season and affected several groves of giant sequoia trees in the southern Sierra Nevada. During a 26 h sampling period, we measured concentrations of fine airborne PM (PM 2.5 ), as well as dry air mole fractions of carbon monoxide (CO) and methane (CH 4 ), using a ground-based mobile laboratory. We also collected filter samples of PM 2.5 for analysis of TC concentration and Δ 14 C. High correlation among PM 2.5 , CO, and CH 4 time series confirmed that our PM 2.5 measurements captured variability in wildfire emissions. Using a Keeling plot approach, we determined that the mean Δ 14 C of PM 2.5 was 111.6 ± 7.7‰ (n = 12), which was considerably enriched relative to atmospheric carbon dioxide in the northern hemisphere in 2021 (-3.2 ± 1.4‰). Combining these Δ 14 C data with a steady-state one-box ecosystem model, we estimated that the mean age of fuels combusted in the KNP Complex Fire was 40 years, with a range of 29–57 years. These results provide evidence for emissions originating from woody biomass, larger-diameter fine fuels, and coarse woody debris that have accumulated over multiple decades. This is consistent with independent field observations that indicate high fire intensity contributed to widespread giant sequoia mortality. With the expanded use of prescribed fires planned over the next decade in California to mitigate wildfire impacts, our measurement approach has the potential to provide regionally-integrated estimates of the effectiveness of fuel treatment programs.

54 ENVIRONMENTAL SCIENCES↗