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Phase 1 Space Fission Propulsion System Design Considerations

Fission technology can enable rapid, affordable access to any point in the solar system. If fission propulsion systems are to be developed to their full potential; however, near-term customers must be identified and initial fission systems successfully developed, launched, and operated. Studies conducted in fiscal year 2001 (IISTP, 2001) show that fission electric propulsion (FEP) systems operating at 80 kWe or above could enhance or enable numerous robotic outer solar system missions of interest. At these power levels it is possible to develop safe, affordable systems that meet mission performance requirements. In selecting the system design to pursue, seven evaluation criteria were identified: safety, reliability, testability, specific mass, cost, schedule, and programmatic risk. A top-level comparison of three potential concepts was performed: an SP-100 based pumped liquid lithium system, a direct gas cooled system, and a heatpipe cooled system. For power levels up to at least 500 kWt (enabling electric power levels of 125-175 kWe, given 25-35% power conversion efficiency) the heatpipe system has advantages related to several criteria and is competitive with respect to all. Hardware-based research and development has further increased confidence in the heatpipe approach. Successful development and utilization of a "Phase 1" fission electric propulsion system will enable advanced Phase 2 and Phase 3 systems capable of providing rapid, affordable access to any point in the solar system.

Houts, Mike

Phase 1 Space Fission Propulsion System Testing and Development Progress

Successful development of space fission systems requires an extensive program of affordable and realistic testing. In addition to tests related to design/development of the fission system, realistic testing of the actual flight unit must also be performed. If the system is designed to operate within established radiation damage and fuel burn up limits while simultaneously being designed to allow close simulation of heat from fission using resistance heaters, high confidence in fission system performance and lifetime can be attained through a series of non-nuclear tests. The Safe Affordable Fission Engine (SAFE) test series, whose ultimate goal is the demonstration of a 300 kW flight configuration system, has demonstrated that realistic testing can be performed using non-nuclear methods. This test series, carried out in collaboration with other NASA centers, other government agencies, industry, and universities, successfully completed a testing program with a 30 kWt core, Stirling engine, and ion engine configuration. Additionally, a 100 kWt core is in fabrication and appropriate test facilities are being reconfigured. This paper describes the current SAFE non-nuclear tests, which includes test article descriptions, test results and conclusions, and future test plans.

VanDyke, Melissa

Phase 1 Space Fission Propulsion Energy Source Design

Fission technology can enable rapid, affordable access to any point in the solar system. If fission propulsion systems are to be developed to their full potential; however, near-term customers must be identified and initial fission systems successfully developed, launched, and operated. Studies conducted in fiscal year 2001 (IISTP, 2001) show that fission electric propulsion (FEP) systems with a specific mass at or below 50 kg/kWjet could enhance or enable numerous robotic outer solar system missions of interest. At the required specific mass, it is possible to develop safe, affordable systems that meet mission requirements. To help select the system design to pursue, eight evaluation criteria were identified: system integration, safety, reliability, testability, specific mass, cost, schedule, and programmatic risk. A top-level comparison of four potential concepts was performed: a Testable, Passive, Redundant Reactor (TPRR), a Testable Multi-Cell In-Core Thermionic Reactor (TMCT), a Direct Gas Cooled Reactor (DGCR), and a Pumped Liquid Metal Reactor.(PLMR). Development of any of the four systems appears feasible. However, for power levels up to at least 500 kWt (enabling electric power levels of 125-175 kWe, given 25-35% power conversion efficiency) the TPRR has advantages related to several criteria and is competitive with respect to all. Hardware-based research and development has further increased confidence in the TPRR approach. Successful development and utilization of a "Phase I" fission electric propulsion system will enable advanced Phase 2 and Phase 3 systems capable of providing rapid, affordable access to any point in the solar system.

Houts, Mike

Fission Surface Power Technology Development Status

Power is a critical consideration in planning exploration of the surfaces of the Moon, Mars, and beyond. Nuclear power is an important option, especially for locations in the solar system where sunlight is limited in availability or intensity. NASA is maintaining the option for fission surface power for the Moon and Mars by developing and demonstrating technology for an affordable fission surface power system. Because affordability drove the determination of the system concept that this technology will make possible, low development and recurring costs result, while required safety standards are maintained. However, an affordable approach to fission surface power also provides the benefits of simplicity, robustness, and conservatism in design. This paper will illuminate the multiplicity of benefits to an affordable approach to fission surface power, and will describe how the foundation for these benefits is being developed and demonstrated in the Exploration Technology Development Program s Fission Surface Power Project.

Palac, Donald T.

Scotty, I Need More Power - The Fission System Gateway to Abundant Power for Exploration

In planning and in crisis, electrical power has been a key consideration when humans venture into space. Since the 1950's, nuclear fission (splitting of atoms) power has been a logical alternative in both fact and fiction, due to its ability to provide abundant power with high energy density, reliability, and immunity to severe environments. Bringing space fission power to a state of readiness for exploration has depended on clearing the hurdle of technology readiness demonstration. Due to the happy coincidence of heritage from prior space fission development efforts such as the Prometheus program, foresight from NASA's Exploration Mission Systems Directorate in the mid-2000's, and relative budget stability through the late 2000's, National Aeronautics and Space Administration (NASA) and Department of Energy (DOE), with their industry partners, are poised to push through to this objective. Hardware for a 12 kWe non-nuclear Fission Power System Technology Demonstration Unit is being fabricated now on a schedule that will enable a low-cost demonstration of technology readiness in the mid-2010s, with testing beginning as early as 2012. With space fission power system technology demonstrated, exploration mission planners will have the flexibility to respond to a broad variety of missions and will be able to provide abundant power so that future explorers will, in planning or crisis, have the power they need when they most need it.

Palac, Donald T.

Fission Systems for Mars Exploration

Fission systems are used extensively on earth, and 34 such systems have flown in space. The energy density of fission is over 10 million times that of chemical reactions, giving fission the potential to eliminate energy density constraints for many space missions. Potential safety and operational concerns with fission systems are well understood, and strategies exist for affordably developing such systems. By enabling a power-rich environment and highly efficient propulsion, fission systems could enable affordable, sustainable exploration of Mars.

Houts, Michael G.

The Kilopower Space Nuclear Fission Power Reactor

Nuclear fission power offers an attractive alternative to solar electric or radioisotope power systems for certain applications on the Moon, Mars, and deep space science missions. The advantages of independence from solar irradiance, high energy density, and abundance of fuel allow fission power systems to enable novel, high power mission architectures. While NASA has had numerous fission power programs throughout its history, few have gone far beyond the design phase. The recent test campaign called the Kilopower Reactor Using Stirling Technology project (KRUSTY) focused on a low power, kilowatt-scale design for simplicity and reduced cost, with the driving motivation to perform a full nuclear hardware prototype test. Following the successful completion of the KRUSTY nuclear hardware test in March of 2018, NASA has begun the formulation process for a Technology Demonstration Mission (TDM) using the Kilopower reactor technology. In support of NASA's lunar surface initiatives, the Kilopower TDM will target a 1-3 kW fission electric power system that can survive the lunar night and operate for one year. The system will be heavily influenced by the KRUSTY reactor design, using a solid Uranium metal core with high temperature heat pipes and Stirling engine power conversion. During this formulation phase, continued engineering efforts are ongoing to improve heat transfer efficiency in the system, examine fission radiation damage effects, and begin to address the thermal and structural requirements of a Kilopower flight system.

Chaiken, Max

LENR Products: Lattice Confinement Fusion (LCF), Fission, or Both?

Lattice Confinement Fusion (LCF) or Low Energy Nuclear Reactions (LENR) generate heat from the high energy products they produce. Conventionally, d-d fusion reactions may produce either 2.45 MeV neutrons, 3 MeV protons, or high energy gammas. Generally, fission will give 5-10x the excess energy of fusion. However, aneutronic “cold fusion” would provide 24 MeV/reaction, D(d,γ) 4 He, where the gamma is suppressed. In a series of pressurized gas cycling experiments with a palladium silver (75 wt.% Pd and 25 wt.% Ag or Pd25Ag) alloy [1], samples cycled with deuterium showed excess heat via unexplained temperature rises. Post-test analysis of the Pd25Ag samples using a Scanning Electron Microscope (SEM/EDX) showed several molten features containing anomalous elements other than Pd and Ag. Researchers such as Liu et al [2] have also observed transmutations under similar conditions. These molten areas and anomalous elements suggest Pd fission. This nuclear process has been referred to as nuclear disintegration. Either nuclear fission or disintegration may result in neutron rich fragments. The fragments would rapidly beta decay to shorter lived daughters until they reach stability. We’ve observed evidence of both fusion and fission products [3]. Figure 1 shows neutron spectroscopy showing fusion and boosted neutron energies in bremsstrahlung-initiated fusion of TiD2. Figure 2 shows possible fission products from D 2 gas cycled Pd25Ag alloy. Alternatively, Oppenheimer-Phillips stripping reactions, enhanced by electron screening [4] may also occur. In this case, the 8.6 MeV binding energy per Pd or Ag minus the 2.2 MeV deuteron binding energy leaves 6.4 MeV distributed between the reaction products. The energy is shared inversely proportional to the masses of the stripped off nucleon, p or n, and the new target nucleus.

Theresa L. Benyo

LENR Products: Lattice Confinement Fusion (LCF), Fission, or Both?

Lattice Confinement Fusion (LCF) or Low Energy Nuclear Reactions (LENR) generate heat from the high energy products they produce. Conventionally, d-d fusion reactions may produce either 2.45 MeV neutrons, 3 MeV protons, or high energy gammas. Generally, fission will give 5-10x the excess energy of fusion. However, aneutronic “cold fusion” would provide 24 MeV/reaction, D(d,γ) 4 He, where the gamma is suppressed. In a series of pressurized gas cycling experiments with a palladium silver (75 wt.% Pd and 25 wt.% Ag or Pd25Ag) alloy [1], samples cycled with deuterium showed excess heat via unexplained temperature rises. Post-test analysis of the Pd25Ag samples using a Scanning Electron Microscope (SEM/EDX) showed several molten features containing anomalous elements other than Pd and Ag. Researchers such as Liu et al [2] have also observed transmutations under similar conditions. These molten areas and anomalous elements suggest Pd fission. This nuclear process has been referred to as nuclear disintegration. Either nuclear fission or disintegration may result in neutron rich fragments. The fragments would rapidly beta decay to shorter lived daughters until they reach stability. We’ve observed evidence of both fusion and fission products [3]. Figure 1 shows neutron spectroscopy showing fusion and boosted neutron energies in bremsstrahlung-initiated fusion of TiD2. Figure 2 shows possible fission products from D2 gas cycled Pd25Ag alloy. Alternatively, Oppenheimer-Phillips stripping reactions, enhanced by electron screening [4] may also occur. In this case, the 8.6 MeV binding energy per Pd or Ag minus the 2.2 MeV deuteron binding energy leaves 6.4 MeV distributed between the reaction products. The energy is shared inversely proportional to the masses of the stripped off nucleon, p or n, and the new target nucleus.

Theresa L. Benyo

Rapid separation of radiopure yttrium-91 for tracer studies from mixed fission products and uranium

A novel, single step method for isolating 91 Y from irradiated uranium and mixed fission products has been developed based on the commercially available Eichrom LN resin. The separation procedure allows for loading an LN resin column with an irradiated uranium solution, containing mixed fission products, in dilute HCl where both uranium and yttrium are retained on the resin. Eluting dilute (0.5–1 M) HCl will strip the majority of fission products. Furthermore, increasing the concentration to 3 M HCl will elute 91 Y without the presence of any other fission products. Finally, uranium can be recovered by passing concentrated HCl through the column.

Chromatography

In-situ ion irradiation of fission products in a spent UO 2 fuel

This study investigates the behavior of fission gas bubbles and five metal precipitates (5MPs) (Mo, Ru, Rh, Tc, Pd) in spent uranium dioxide (UO 2 ) fuel under various ion irradiation doses, temperatures, and flux conditions. Utilizing in-situ ion irradiation and advanced transmission electron microscopy, we analyzed the evolution of fission gas bubbles and 5MPs in UO 2 samples from the Belgium Reactor 3 (BR-3). Our findings reveal significant shrinkage of fission gas bubbles and 5MPs with increasing irradiation dose, accompanied by a decrease in pair density. We demonstrate that ion irradiation induces a homogeneous re-solution process where individual atoms are ejected from bubbles and precipitates, leading to their dissolution and subsequent re-precipitation in the matrix. In conclusion, this study provides critical insights into the dynamic behavior of fission products under irradiation, facilitating the development of predictive models and contributing to the optimization of nuclear fuel performance and safety.

Fission products

Swelling and Fission Gas Release of U-10Mo and U-17Mo Following Neutron Irradiation at 250 – 500°C

The performance of metallic fuel alloys, U-10Mo and U-17Mo, was examined using the MiniFuel test system in the High Flux Isotope Reactor. Approximately 0.8 mm thick disks were irradiated at target temperatures of 250°C, 350°C, 450°C, and 500°C up to three different fission densities, culminating at a maximum fission density of 6.8 × 10 20 cm −3 . Fission rates decayed from 3 – 6 × 10 13 cm −3 s −1 to 2 – 4 × 10 13 cm −3 s −1 over the course of the longest, eight cycle, irradiation as the 235 U was consumed and the 239 Pu concentration accumulated. Actual irradiation temperature on the last day of irradiation was measured via dilatometry using the SiC passive thermometry recovered from the MiniFuel subcapsules and compared favorably with the thermal calculations using as-built geometry and test conditions. Furthermore, average simulated temperatures were within 50°C of the target temperatures, except for the 500°C irradiation, for which the temperature variation was 62°C, 32°C, and 90°C in the in two, four, and eight cycle irradiations, respectively. Fission gas release (FGR) measurements showed no release above recoil for any U-17Mo fuels or for the U-10Mo fuel irradiated at 250°C. Finally, significant (40%–80%) FGR was found for the medium- to highest-burnup U-10Mo samples irradiated at target temperatures 350°C–500°C. Significant FGR correlated with sample thickness swelling, which was as high as 13%–35% for high-release samples and below 7% for all other (low–gas release) samples.

FGR

A machine learning approach to quantify degradation of nuclear fuels and the effects of fission products

Nuclear fuel performance is critically dependent on understanding the evolution of fuel properties under operational conditions, a complex challenge driven by chemical changes and substantial radiation damage during fission. Traditionally, property evolution has been determined via empirical data collected following irradiation. However, these empirical correlations are limited in their applicability beyond the specific conditions in which they were obtained. This study explores a novel approach to address this challenge by applying materials informatics to develop a machine learning random forest (ML-RF) model that captures the effects of fission products on fuel compounds. The model predicts formation enthalpy (ΔH f ) by leveraging extensive quantum materials property data and correlating it with material descriptors such as composition, atomic and site features, and crystal lattice properties. This ML-RF model enables rapid interpolation across the compositional and structural spaces covered by the training data, thus supporting high-throughput screening and energetic ranking of candidate phases. The model demonstrates the ability to predict ΔH f with a mean absolute error (MAE) of approximately 0.1 to 0.2 eV/atom across a wide range of compounds, including key nuclear fuel systems (U-O, U-N, U-C, U-Si, and U-Mo). For example, it was used to assess shifts in stoichiometry for UO 2 (O/M) and UN (N/M) fuels, revealing their distinct tendencies in chemical potential variation and enabling preliminary convex hull analyses. Furthermore, the model provides insights into how individual fission products affect fuel properties. Results indicate that larger fission products (e.g., Nd, Pu, Ce) have a more pronounced impact on UO 2 , while lighter ones (e.g., Zr) strongly influence UN. Here, the model developed in this work can be used to support the Accelerated Fuel Qualification approach by facilitating preliminary evaluations prior to extensive materials modeling and experimentation. To this end, the trained model has been made available to the fuel community to support ongoing fuel development efforts.

Accelerated fuel qualification

Interplay between Mixed and Pure Exciton States Controls Singlet Fission in Rubrene Single Crystals

Singlet fission (SF) is a multielectron process in which one singlet exciton S converts into a pair of separated triplet excitons T. SF is widely studied as it may help overcome the Shockley−Queisser efficiency limit for semiconductor photovoltaic cells. To elucidate and control the SF mechanism, great attention has been given to the identification of intermediate states in SF materials, which often appear elusive due to the complexity and fast time scales of the SF process. Here, we apply 14 fs-1 ms transient absorption techniques to high-purity rubrene single crystals to disentangle the intrinsic fission dynamics from the effects of defects and grain boundaries and to identify reliably the fission intermediates. Our data demonstrates that above-gap excitation directly generates a hybrid vibronically assisted mixture of singlet state and triplet-pair multiexciton [S/TT], which rapidly (<100 fs) and coherently branches into pure singlet or triplet excitations. The relaxation of [S/TT] to S is followed by a relatively slow and temperature-activated (48 meV activation energy) incoherent fission process. The SF competing pathways and intermediates revealed here unify the observations and models presented in previous studies of SF in rubrene and offer alternative strategies for the development of SF-enhanced photovoltaic materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Correlated fission fragment spin dynamics

Here, this study explores the role of nucleon exchange for the generation of the fission fragment angular momenta. For a number of typical fission cases, samples of 10 4 shape evolutions are generated by Langevin simulation and, subsequently, for each such evolution, the nucleon exchange transport theory previously developed for damped nuclear reactions is used to obtain the development of the fragment spin-spin distribution within the Fokker-Planck transport framework. The characteristic evolution of both parallel and perpendicular spin components is discussed. A common feature is that the rotational modes fall out of equilibrium before scission when the temperature rises rapidly while the concurrent shrinking of the neck suppresses further exchange. A number of fission observables are extracted from the event ensembles: the distribution of the magnitude of the fragment spin and its orientation relative to the fission axis, as well as the correlation between the two spins and the distribution of their opening angle. The dependence of these observables on the mass asymmetry is also examined.

fission

AGR-5/6/7 Irradiation Experiment Fission Product Mass Balance

This report presents the fission product mass balance for the AGR-5/6/7 TRISO fuel irradiation experiment. The fission product inventories deposited on capsule components outside of the fuel (e.g., stainless-steel shells, graphite holders, Grafoil disks, and associated hardware) were quantified as part of the post-irradiation examination (PIE) to assess the performance of this fuel. Comparisons were made between these inventories and depletion calculations, non-destructive measurements of fuel fission product inventories in the intact fuel compacts, prior AGR experiments, and results from among each of the five distinct AGR-5/6/7 capsules. The data served as estimates of the condensable fission products released from the fuel during irradiation. Excluding Capsule 1 (which experienced accidental damage during irradiation) and Capsule 3 (which was tested at very high irradiation temperatures of >1300°C), the results indicate that the AGR-5/6/7 fuel performed comparably to fuel from earlier AGR experiments. The mass balance results were also used to estimate the number of particles with in-pile SiC failures. Subject to the assumptions made in these estimates, and excluding Capsules 1 and 3, the in-pile SiC failure rates for AGR-5/6/7 are comparable to those observed in AGR-2.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS

Pulsed Fission-Fusion (PuFF)

In September 2013 the NASA Innovative Advanced Concept (NIAC) organization awarded a phase I contract to the PuFF team. Our phase 1 proposal discussed a pulsed fission-fusion propulsion system that injected gaseous deuterium (D) and tritium (T) as a mixture in a column, surrounded concentrically by gaseous uranium fluoride (UF6) and then an outer shell of liquid lithium. A high power current would flow down the liquid lithium and the resulting Lorentz force would compress the column by roughly a factor of 10. The compressed column would reach criticality and a combination of fission and fusion reactions would occur. The fission reactions would further energize the fusion center, and the fusion reactions would generate neutrons that promote more complete burnup of the fission fuel. The lithium liner provides some help as a neutron reflector but also acts as a propulsive medium, being converted to plasma which is then expanded against a magnetic nozzle for thrust. The expansion of the (primarily) lithium plasma against the nozzle's magnetic field inducts a current that is used to charge the system for the next pulse. Our concept also included secondary injection of a Field Reversed Configuration (FRC) plasmoid that would provide a secondary compression direction, axially against the column, and push the column away from the injection manifold, increasing the manifold's survivability.Our phase 1 proposal included modeling the above process first under steady state assumptions and second under a time variant integration. We proposed including these results into a Mars concept vehicle and finally proposing promising conditions to be evaluated experimentally in Phase II. In phase I we quickly realized that we needed to modify our approach. Our steady state work was completed as proposed, and the results indicated that one, a two stage compression system was not needed and two, that we wanted to move away from UF6. The steady state model shows much more margin than expected, to the point that we may well reach breakeven with the Charger – 1 facility, a 572 kJ Marx bank currently under refurbishment at UAH. Additionally we found that using gaseous D-T and UF6, provided a relatively simple prospect of using a pulsed injector, made reaching criticality more difficult. The introduction of large amounts of fluorine meant a radiative sink, sapping power from the fusion plasma and was harder to handle. Therefore we moved to a solid uranium target that held D-T under pressure. In so doing we could move our target closer to criticality and remove any material that did not sustain the reaction.

Fusion

Lattice Confinement Fusion and Fusion-Fast-Fission Energy Source Development

NASA and the US Navy have demonstrated Lattice Confinement Fusion (LCF) and the Fusion-Fast-Fission of natural uranium and thorium. Both methods build upon decades of research, and the latter benefits from conventional nuclear fission and fusion results. However, this nascent technology doesn’t require fissile isotopes and avoids nuclear weapons proliferation concerns from uranium 235U isotopic enrichment or plutonium 239Pu separation. Of particular note, LCF doesn’t need power hungry magnets, lasers, or particle beams. Potentially, it could provide watts to hundreds of kilowatts of electrical power and process heat suitable for space power and high Isp nuclear electric propulsion (NEP) as well as distributed terrestrial power. Finally, there are indications that LCF fast-fission products are more benign than those of conventional fission reactors. Our goal is to scale the reactions and increase the power output through higher temperature operation and increased material masses.

lattice confinement fusion