Development of a spectroscopic shock tube
Gas spectroscopic tube and component equipment instrumentation for radiative transfer experiments
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Gas spectroscopic tube and component equipment instrumentation for radiative transfer experiments
Density and temperature results from peak height data obtained from rocketborne mass spectrometer
Temperature behind shock waves determined for argon containing powdered solids
Nitric oxide titration method compared with absolute nitrogen atom concentrations measured by quantitative esr spectrometry
Mean beam length with respect to band absorption laws and gas body geometries
Laboratory light source emitting forbidden Vegard-Kaplan bands of nitrogen with sufficient intensity for high resolution spectrograph
Absorption coefficient for lines with combined Doppler and Lorentz broadening calculated, using Runge-Kutta method, continued fraction expansion and Hermite-Gauss quadrature
Photochemical studies of oxygen-ozone and carbon dioxide equilibria with bromine UV lamp
High-temperature gas radiance in simulated planetary atmosphere at various entry velocities
Single continuous correlation for total band absorptance of radiating gases
Spectroscopic electron beam diagnostic technique, examining negligible effect elevated vibrational temperatures have on measured rotational temperatures of molecular nitrogen
Spectrum of three-times ionized nitrogen analyzed in wavelength region 300-8000 angstroms, using theta pinch discharge, connecting singlets and triplets
Dielectric relaxation of gases and sharp rise in microwave absorption coefficient in Cytherean atmosphere
Volatilizable C compounds in lunar fines from Mare Tranquillitatis, investigating pyrolysis and acid hydrolysis products by mass spectroscopy and gas chromatography
High temperature plasmas optical properties measurement by plasma spectroscopy, using gas driven shock tube as light source
Phthalates are very objectionable contaminants in space experiments because of their strong absorption in the UV and IR regions of the spectrum. Thus, even minute amounts of these compounds migrating to optical equipment, in test or space flight conditions, can seriously compromise the results of experiments by altering the sensitivity of the functional equipment. Volatility data of the phthalates and other plasticizers are presented in addition to UV spectra of ultrathin films of these same types of compounds. Sources of plasticizer contamination are revealed with special recognition given to di-2-ethylhexyl phthalate (DEHP), the single most ubiquitous plasticizer in use. A surprisingly large percentage of the outgassing condensates from vacuum testing of spacecraft contain DEHP as well as other plasticizers. IR and gas chromatography/mass spectroscopy methods were used to analyze samples from spacecraft. Methods for successful reduction of plasticizers and other contaminants are mentioned.
A new optical technique has been developed for ultra-sensitive attenuation measurements in gaseous media and, in particular, for determination of low levels of smoke emitted from jet engines. It is a variation on direct light transmission where the sample gas density in a cell is modulated acoustically by a speaker. The amplitude variation of the light transmission is proportional to the gas density and is insensitive to window contamination and detector instabilities. Preliminary analysis and experiments indicate that the instrument promises to measure light absorption to less than 1 percent per meter and allow measurment of smoke emissions from 1 to 100 mg/cu m. The technique has been demonstrated through the use of an absorbing gas, viz., 200 ppm of NO2 in N2 which produces 25 percent per meter absorption.
Small transition metal clusters were studied at a high level of approximation, including all the valence electrons in the calculation and extensive electron correlation, in order to understand the electronic structure of these small metal clusters. By comparison of dimers, trimers, and possibly higher clusters, the information obtained was used to provide insights into the electronic structure of bulk transition metals. Small metal clusters are currently of considerable experimental interest and some information is becomming available both from matrix electron spin resonance studies and from gas phase spectroscopy. Collaboration between theorists and experimentalists is thus expected to be especially profitable at this time since there is some experimental information which can serve to guide the theoretical work.