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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Near Surface Vapor Bubble Layers in Buoyant Low Stretch Burning of Polymethylmethacrylate

Large-scale buoyant low stretch stagnation point diffusion flames over solid fuel (polymethylmethacrylate) were studied for a range of aerodynamic stretch rates of 2-12/ sec which are of the same order as spacecraft ventilation-induced stretch in a microgravity environment. An extensive layer of polymer material above the glass transition temperature is observed. Unique phenomena associated with this extensive glass layer included substantial swelling of the burning surface, in-depth bubble formation, and migration and/or elongation of the bubbles normal to the hot surface. The bubble layer acted to insulate the polymer surface by reducing the effective conductivity of the solid. The reduced in-depth conduction stabilized the flame for longer than expected from theory neglecting the bubble layer. While buoyancy acts to move the bubbles deeper into the molten polymer, thermocapillary forces and surface regression both act to bring the bubbles to the burning surface. Bubble layers may thus be very important in low gravity (low stretch) burning of materials. As bubbles reached the burning surface, monomer fuel vapors jetted from the surface, enhancing burning by entraining ambient air flow. Popping of these bubbles at the surface can expel burning droplets of the molten material, which may increase the fire propagation hazards at low stretch rates.

Olson, Sandra L.↗
DOE OSTI2024

DM1200 Tests with C-104/AY-101 HLW Simulants (Final Report)

This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of simulated HLW C-104/AY-101 feed. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW C-104/AY-101 feed; determine the effect of bubbling rate on production rate; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and to perform pre- and post test inspections of system components.

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DOE OSTI2020

Vitrification of High-Cr Glass in Research-Scale Melter

This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory to demonstrate processing of a high-Cr simulated feed stream, designated HLW-HCr-16. The RSM is a small, joule-heated melter capable of processing melter feed continuously. The melter is equipped with Inconel ® 693 electrodes, Monofrax ® K-3 refractory, and an Inconel 690 pour spout. An electric kiln surrounds the melter body and minimizes heat loss from the melter body during operation. The RSM is equipped with an offgas treatment system that employs quenching, wet scrubbing, and high-efficiency mist elimination. The glass-discharge section is heated to facilitate pouring of the glass. The melter is fitted with a melt cavity that is ~25 cm (10 in.) in diameter with a nominal glass depth of 8.9 cm (3.5 in.). The melter was operated with a target glass temperature of 1150°C and target plenum temperature between 550°C and 700°C for this test. The air bubbling rate was 4.2 L/min. Overall, during the continuous operation of the melter for ~ 103 hours, ~ 141 kg of glass was produced. At the conclusion of the test, the melter and exhaust lines were visually inspected for particulate deposition and corrosion. Entrained material had adhered to the underside of the melter lid and to the exhaust piping. Enrichments in elements such as Cl, F, B, K, Li, P, Na, and S were measured in these deposits through inductively coupled plasma–optical emission spectroscopy and X-ray fluorescence analysis. When the melter electrodes and air bubbler tube were removed from the glass in the RSM, the electrodes appeared discolored, but no significant loss of metal was observed. The processing of a high-Cr simulant, HLW-HCr-16, in the RSM produced glass at an average rate of 1.36 kg/h, equaling a melter-surface-area normalized glass generation rate of 654 kg/day/m 2 . The resulting glass met the toxicity characteristic leaching procedure requirement. Test results of crystallinity, electrical conductivity, and viscosity showed good processing properties of this high-Cr high-level waste glass. RSM offgas was also sampled and analyzed at periodic intervals during steady-state operating conditions. The total decontamination factor averaged by four sampling periods was 134. The concentrations of CO and NO x in emissions were 237 to 422 and 69 to 94 parts per million by volume, respectively.

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DOE OSTI2023

Effect of feed composition on the production of off-gases during vitrification of simulated low-activity nuclear waste

During the vitrification of nuclear waste, hazardous and radioactive emissions are generated from the feed-to-glass conversion reactions, in addition to discharges from forced air bubbling and air inleakage. Although the major gaseous emissions are water vapor, nitrogen, and carbon dioxide, various monitored environmental pollutants are also released, such as nitrogen oxides or sulfur dioxide. In addition, reactions between organics and nitrates in the feed may also form products of incomplete combustion such as carbon monoxide and acetonitrile. Although off-gas emissions are commonly measured during both laboratory- and pilot-scale melter testing, no predictive tool is currently available to a priori estimate the composition of gaseous emissions during nuclear waste vitrification. This work forms a basis for the development of such predictive tool by measuring gas evolution from a broad range of simulated low-activity waste melter feeds using evolved gas analysis data and developing correlations between the feed and off-gas compositions. Using reaction stoichiometry and regression analysis, we demonstrate that next to the content of nitrogen and organic carbon in the feed, the gaseous emissions are affected by the feed reduction-oxidation conditions – the more the feed is reduced, the less nitrogen monoxide, and more carbon monoxide and acetonitrile evolves. In conclusion, the results presented in this work provide a first step towards reducing the amount of expensive physical melter testing and the regression analysis provides a simple tool for rapid optimization of feed composition with respect to off-gas composition.

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NASA NTRS1982

Inertial Confinement fusion targets

Inertial confinement fusion (ICF) targets are made as simple flat discs, as hollow shells or as complicated multilayer structures. Many techniques were devised for producing the targets. Glass and metal shells are made by using drop and bubble techniques. Solid hydrogen shells are also produced by adapting old methods to the solution of modern problems. Some of these techniques, problems, and solutions are discussed. In addition, the applications of many of the techniques to fabrication of ICF targets is presented.

Hendricks, C. D.↗
NASA NTRS2014

Vesicles in Apollo 15 Green Glasses: The Nature of Ancient Lunar Gases

Detailed studies of Apollo 15 green glass and related beads have shown they were formed in gas-rich fire fountains.. As the magmatic fluid became super-saturated in volatile gas, bubbles or vesicles formed within the magma. These exsolved gases became trapped within vesicles as the glasses were ejected from the fire-fountain and subsequently quenched. One of the keys to understanding formation processes on the ancient moon includes determining the composition of volatile species and elements, including metals, dissolved in magmatic gases. Here we report the nature of mineral phases spatially associated with vesicles in a green glass bead from Apollo sample 15411,42. The phases reflect the composition of the cooling/degassing magmatic vapors and fluids present at the time of bead formation approx, 3 Ga ago

Thomas-Keprta, K. L.↗
DOE OSTI2021

Heat transfer from glass melt to cold cap: Computational fluid dynamics study of cavities beneath cold cap

Efficient glass production depends on the continuous supply of heat from the glass melt to the floating layer of batch, or cold cap. Computational fluid dynamics (CFD) are employed to investigate the formation and behavior of gas cavities that form beneath the batch by gases released from the collapsing primary foam bubbles, ascending secondary bubbles, and in the case of forced bubbling, from the rising bubbling gas. The gas phase fraction, temperature, and velocity distributions below the cold cap are used to calculate local and average heat transfer rates as a function of the bubbling rate. It is shown that the thickness of the cavities is nearly independent of the cold cap shape and the amount of foam evolved during batch conversion. Furthermore, it is ~7 mm and up to ~15 mm for the cases without and with forced bubbling used to promote circulation within the melt, respectively. Using computed velocity and temperature profiles, the melting rate of the simulated high-level nuclear waste glass batch was estimated to increase with the bubbling rate to the power of ~0.3 to 0.9, depending on the flow pattern. The simulation results are in good agreement with experimental data from laboratory- and pilot-scale melter tests.

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NASA NTRS2000

The Investigation of the Effects of Gravity on Single Bubble Sonoluminescence

In single bubble following it's rapid collapse each cycle of oscillation of an ultrasonic field. Since widely varying length and time scales affect the bubble dynamics and optical emission processes, it is difficult to anticipate the importance of the effects of gravity present for observations on earth. Our bubble is driven in an acoustically resonating cavity at it's first harmonic mode. The acoustical radiation pressure (Bjerknes force) will then keep it suspended in the center near the pressure antinode. When driven in a region where the diffusive processes balance the bubble it acts in a nonlinear but regular way, emitting a short (approx. 200ps) burst of light each acoustic cycle. Balancing the Bjerknes force with buoyancy, as in, we can see that the bubble should be displaced from the velocity node approximately 20m at normal gravity. Therefore, water flows past the bubble at the time of collapse. Gravitation also changes the ambient pressure at the bubble's location, as Delta.P = rho.g.h this gives a change of approximately -0.5% in our experiment when going from 1.8g to 0g. Studies of ambient pressure changes were also done in order to assess these effects. Inside a pressure sealed chamber a spherical glass cell is filled with distilled water which has been degassed to 120mmHg. A bubble is then trapped in the center and driven by a piezoelectric transducer at 32.2kHz attached to the side of the cell. An optical system is then set up to take strobbed video images along and light emission data simultaneously. Temperature, pressure, drive voltage, and listener voltage are also monitored. PMT output in Volts The radii of the bubbles for both experiment s are fit using the Rayleigh-Plesset equation and the acoustic drive amplitude and the ambient bubble radius are found. There is little change in the acoustic drive amplitude as we expect, since we are not varying the drive voltage. However. the ambient bubble radius goes up considerably. These changes (increased light output, increased maximum bubble radius, and increased ambient bubble radius) are also observed when the ambient pressure is varied in the laboratory by an amount similar to that due to gravitation. The changes in the ambient bubble radius and light output with a change in ambient pressure are predicted by the "dissociation hypothesis" and have been observed by other groups in the laboratory. It seems clear that buoyancy's effect on light output and bubble radius, are at best on the same order as the effects of ambient pressure.

Dzikowicz, Ben↗
DOE OSTI2021

Melting rate correlation with batch properties and melter operating conditions during conversion of nuclear waste melter feeds to glasses

The rate of conversion of nuclear waste melter feed to glass is affected by the selection of melter feed materials and by melter design and operation. The melting rate correlation (MRC) is an equation that relates the glass production rate with two types of variables: (1) feed and melt properties: conversion heat, cold-cap bottom temperature, and glass melt viscosity; and (2) melter design and operation parameters: melter geometry, melter operating temperature, and gas bubbling rate. The MRC shows good agreement for an extended melting-rate data set of high-level waste (HLW) melter feeds and a data set generated for low-activity waste (LAW) melter feeds. Laboratory observation of heated melter feed samples is often used to assess the cold-cap bottom temperature of HLW melter feeds (moderately foaming feeds), but this technique appears inadequate for LAW melter feeds (vigorously foaming feeds). For LAW feeds, an adequate assessment of the cold-cap bottom temperature was achieved using evolved gas analysis, which allows identification of the collapse of primary foam for oxidized feeds. This assessment shows that the cold-cap bottom temperature for vigorously foaming LAW feeds is higher than that for moderately foaming HLW feeds. When the results of MRC are compared, LAW feeds are generally less sensitive to the bubbling rate and melt viscosity, and more sensitive to the cold-cap bottom temperature than HLW feeds. The MRC qualifies as a promising tool to support the selection of melter feed materials and melter operating conditions, which is determined from expensive independent scaled melter experiments, and sophisticated mathematical models.

Lee, Seung Min↗
NASA NTRS2002

Fluid Dynamics of Bubbly Liquids

Experiments have been performed to study the average flow properties of inertially dominated bubbly liquids which may be described by a novel analysis. Bubbles with high Reynolds number and low Weber number may produce a fluid velocity disturbance that can be approximated by a potential flow. We studied the behavior of suspensions of bubbles of about 1.5 mm diameter in vertical and inclined channels. The suspension was produced using a bank of 900 glass capillaries with inner diameter of about 100 microns in a quasi-steady fashion. In addition, salt was added to the suspension to prevent bubble-bubble coalescence. As a result, a nearly monodisperse suspension of bubble was produced. By increasing the inclination angle, we were able to explore an increasing amount of shear to buoyancy motion. A pipe flow experiment with the liquid being recirculated is under construction. This will provide an even larger range of shear to buoyancy motion. We are planning a microgravity experiment in which a bubble suspension is subjected to shearing in a couette cell in the absence of a buoyancy-driven relative motion of the two phases. By employing a single-wire, hot film anemometer, we were able to obtain the liquid velocity fluctuations. The shear stress at the wall was measured using a hot film probe flush mounted on the wall. The gas volume fraction, bubble velocity, and bubble velocity fluctuations were measured using a homemade, dual impedance probe. In addition, we also employed a high-speed camera to obtain the bubble size distribution and bubble shape in a dilute suspension. A rapid decrease in bubble velocity for a dilute bubble suspension is attributed to the effects of bubble-wall collisions. The more gradual decrease of bubble velocity as gas volume fraction increases, due to subsequent hindering of bubble motion, is in qualitative agreement with the predictions of Spelt and Sangani for the effects of potential-flow bubble-bubble interactions on the mean velocity. The ratio of the bubble velocity variance to the square of the mean is 0(0.1). For these conditions Spelt and Sangani predicted that the homogeneous suspension would be unstable and clustering into horizontal rafts will take place. Evidence for bubble clustering is obtained by analysis of video images. The liquid velocity variance is larger than would be expected for a homogeneous suspension and the liquid velocity frequency spectrum indicates the presence of velocity fluctuations that are slow compared with the time for the passage of an individual bubble. These observations provide further evidence for bubble clustering.

Tsang, Y. H.↗
NASA NTRS1976

Magnetoresistance and noise properties of chevron stretcher detectors for field access bubble domain devices

Experiments were devised to study the angular variation of the resistance and noise properties of one- and two-level chevron stretcher magnetoresistive detectors for use in field access bubble memory devices. All measurements, made with an electronic system, were performed on glass or garnet samples upon which 1 micron of SiO2 was sputter-deposited, followed by 4000 A of Permalloy for the 28-micron-period devices and 0.8 microns of SiO2, followed by 3000 A of Permalloy for the 20-micron-period devices. The geometrical and drive-state dependence of the zero-state noise were studied, as was its frequency dependence. It is found that both types of detectors operate primarily in the amplitude-shift mode for drive fields of interest and that the presence of a bubble in a detector causes a magnetoresistance change equal to that produced by increasing the in-plane drive field about 8 Oe in the absence of a bubble.

George, P. K.↗
DOE OSTI2024

Thermo-rheological snapshot of melter feed conversion to glass

Slurry feed charged into an electric melter creates a layer of reacting and melting material (termed cold cap) that floats on the surface of molten glass. The rheological behavior of heated melter feed affects the spreading of slurry at the top of the cold cap and the stability of the primary foam, affecting cold-cap coverage and melter plenum temperatures. The apparent viscosity of a high-alumina high-level waste melter feed was assessed by thermomechanical analysis, high-temperature viscometer, and the hot stage microscopy method, yielding viscosity estimates from ≈10 7.5 Pa s at 550°C to ≈10 2.5 Pa s at 1050°C. As the temperature of feed materials increased, their state changed from rigid solid to dilatant fluid, to pseudoplastic bubbly liquid with dissolving solids, to fully developed foam, and finally to Newtonian glass melt.

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DOE OSTI2022

Analysis of DWPF Sludge Batch 6 (Macrobatch 7): Pour Stream Glass Samples

The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 6 (SB6), also referred to as Macrobatch 7 (MB7), in June 2010. SB6 is a blend of the heel of Tank 40 from Sludge Batch 5 (SB5), H-Canyon Np transfers and SB6 that was transferred to Tank 40 from Tank 51.1 SB6 was processed using Frit 418. Sludge is received into the DWPF Chemical Processing Cell (CPC) and is processed through the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator Tank (SME). The treated sludge slurry is then transferred to the Melter Feed Tank (MFT) and fed to the melter. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP) and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. The DWPF requested various analyses of radioactive glass samples obtained from the melter pour stream during processing of SB6 as well as reduction/oxidation (REDOX) analysis of MFT samples to determine the impact of Argon bubbling. Sample analysis followed the Task Technical and Quality Assurance Plan (TTQAP) and an Analytical Study Plan (ASP). Four Pour Stream (PS) glass samples and two MFT slurry samples were delivered to the Savannah River National Laboratory (SRNL) from the DWPF. Table 1-1 lists the sample information for each pour stream glass sample. SB6 PS3 (S03472) was selected as the official pour stream sample for SB6 and full analysis was requested. This report details the visual observations of the as-received SB6 PS No.3 glass sample as well as results for the chemical composition, Product Consistency Test (PCT), radionuclide content, noble metals, and glass density. REDOX results will be provided for all four pour stream samples and vitrified samples of MFT-558 and MFT-568A. Where appropriate, data from other pour stream samples will be provided.

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NASA NTRS2020

Reconstructing Magma Storage Depths for the 2018 Kilauean Eruption from melt inclusion CO2 Contents: The importance of Vapor Bubbles

The 2018 Lower East Rift Zone (LERZ) eruption of Kīlauea Volcano and the accompanying collapse of the summit caldera marked the most destructive phase of activity on Hawai’i in the last 200 years. The integration of petrological data extracted from lava samples collected throughout the eruption with geodetic data examining the caldera collapse event, and estimates of the co-erupted flux of SO2 from the main eruptive fissure (Fissure 8), provides an exceptional opportunity to determine the reservoir geometry and magma transport paths supplying Kīlauea’s LERZ. The forsterite contents of erupted olivines and the degree of disequilibrium with their carrier melts indicate that two distinct olivine populations were erupted from Fissure 8. Melt inclusion entrapment pressures reveal that more evolved olivines (Fo<81.5) crystallized at ~2 km depth within the shallower Halema’uma’u reservoir, while more primitive olivines (Fo>81.5)crystallized within the deeper South Caldera reservoir at ~3–5 km depth. Crucially, primitive olivines experienced extensive post-entrapment crystallization, driving the growth of a vapor bubble. Raman spectroscopy reveals that this bubble contains up to 99% of the total inclusionCO2 budget (median=93%). Measurements of CO2 in only the glass phase would have underestimated entrapment depths by up to 60× (median=11×), and the importance of the SC reservoir as a source of magma to Fissure 8 would have been overlooked. Overall, we demonstrate that Raman measurements of bubbles, along with careful choice of suitably-calibrated H2O-CO2 solubility model, is vital to place accurate constraints on the depths of magma storage regions supplying volcanic eruptions.

SIMS↗
NASA NTRS1976

Ocean foam generation and modeling

A laboratory investigation was conducted to determine the physical and microwave properties of ocean foam. Special foam generators were designed and fabricated, using porous glass sheets, known as glass frits, as the principal element. The glass frit was sealed into a water-tight vertical box, a few centimeters from the bottom. Compressed air, applied to the lower chamber, created ocean foam from sea water lying on the frit. Foam heights of 30 cm were readily achieved, with relatively low air pressures. Special photographic techniques and analytical procedures were employed to determine foam bubble size distributions. In addition, the percentage water content of ocean foam was determined with the aid of a particulate sampling procedure. A glass frit foam generator, with pore diameters in the range 70 - 100 micrometers, produced foam with bubble distributions very similar to those found on the surface of natural ocean foam patches.

Porter, R. A.↗
NASA NTRS1986

Behavior of a non-wetting melt in free fall - Experimental

To explain why nonwetting metals and semiconductors, directionally solidified in space, yield ingots which are smaller in diameter than the ampoule, the behavior of mercury during a parabolic free-fall in a KC135 aircraft was observed using transparent ampoules with attached video cameras. Triangular glass ampoules and cylindrical polycarbonate ampoules were filled to 30-95 percent capacity. In polycarbonate ampoules, mercury did not pull away from the ampoule walls. The photographs displayed either liquid columns separated by gas spaces or gas bubbles on the wall. At low levels of liquid, separated columns were favored, while only bubbles were seen when the liquid mercury almost filled the ampoule. In ampoules with triangular cross section, the liquid pulled away from the glass walls along the edges and contacted the walls along the centers, over about half of the wall width of each side.

Sen, R.↗
NASA NTRS1983

MEA/A-1 experiment 81F01 conducted on STS-7 flight, June 1983. Containerless processing of glass forming melts

The space processing of containerless, glassforming melts on board the space shuttle flight STS-7 is investigated. Objectives include; (1) obtain quantitative evidence for the supression of heterogeneous nucleation/crystallization, (2) study melt homogenization without gravity driven convection, (3) procedural development for bubble free, high purity homogeneous melts inmicro-g, (4) comparative analysis of melts on Earth and in micro g, and (5) assess the apparatus for processing multicomponent, glass forming melts in a low gravity environment.

Day, D. E.↗
NASA NTRS1984

Space processing applications rocket project. SPAR 8

The Space Processing Applications Rocket Project (SPAR) VIII Final Report contains the engineering report prepared at the Marshall Space Flight Center (MSFC) as well as the three reports from the principal investigators. These reports also describe pertinent portions of ground-based research leading to the ultimate selection of the flight sample composition, including design, fabrication, and testing, all of which are expected to contribute immeasurably to an improved comprehension of materials processing in space. This technical memorandum is directed entirely to the payload manifest flown in the eighth of a series of SPAR flights conducted at the White Sands Missile Range (WSMR) and includes the experiments entitled Glass Formation Experiment SPAR 74-42/1R, Glass Fining Experiment in Low-Gravity SPAR 77-13/1, and Dynamics of Liquid Bubbles SPAR Experiment 77-18/2.

Chassay, R. P.↗