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At least 91 records · Page 5

Advanced methods for preparation and characterization of infrared detector materials

Crystals were prepared by the Bridgman-Stockbarger method with a wide range of crystal growth rates and temperature gradients adequate to prevent constitutional supercooling under diffusion-limited, steady-state, growth conditions. The longitudinal compositional gradients for different growth conditions and alloy compositions were calculated and compared with experimental data to develop a quantitative model of solute redistribution during the crystal growth of the alloys. Measurements were performed to ascertain the effect of growth conditions on radial compositional gradients. The pseudobinary HgTe-CdTe constitutional phase diagram was determined by precision differential-thermal-analysis measurements and used to calculate the segregation coefficient of Cd as a function of x and interface temperature. Experiments were conducted to determine the ternary phase equilibria in selected regions of the Hg-Cd-Te constitutional phase diagram. Electron and hole mobilities as functions of temperature were analyzed to establish charge-carrier scattering probabilities. Computer algorithms specific to Hg(1-x)CdxTe were developed for calculations of the charge-carrier concentration, charge-carrier mobilities, Hall coefficient, and Dermi Fermi energy as functions of x, temperature, ionized donor and acceptor concentrations, and neutral defect concentrations.

Broerman, J. G.

Microwave Signatures of Snow on Sea Ice: Observations

Part of the Earth Observing System Aqua Advanced Microwave Scanning Radiometer (AMSR-E) Arctic sea ice validation campaign in March 2003 was dedicated to the validation of snow depth on sea ice and ice temperature products. The difficulty with validating these two variables is that neither can currently be measured other than in situ. For this reason, two aircraft flights on March 13 and 19,2003, were dedicated to these products, and flight lines were coordinated with in situ measurements of snow and sea ice physical properties. One flight was in the vicinity of Barrow, AK, covering Elson Lagoon and the adjacent Chukchi and Beaufort Seas. The other flight was farther north in the Beaufort Sea (about 73 N, 147.5 W) and was coordinated with a Navy ice camp. The results confirm the AMSR-E snow depth algorithm and its coefficients for first-year ice when it is relatively smooth. For rough first-year ice and for multiyear ice, there is still a relationship between the spectral gradient ratio of 19 and 37 GHz, but a different set of algorithm coefficients is necessary. Comparisons using other AMSR-E channels did not provide a clear signature of sea ice characteristics and, hence, could not provide guidance for the choice of algorithm coefficients. The limited comparison of in situ snow-ice interface and surface temperatures with 6-GHz brightness temperatures, which are used for the retrieval of ice temperature, shows that the 6-GHz temperature is correlated with the snow-ice interface temperature to only a limited extent. For strong temperature gradients within the snow layer, it is clear that the 6-GHz temperature is a weighted average of the entire snow layer.

Markus, Thorsten

A dual dynamic shutter system for accelerating ion irradiation sample throughput via lateral gas implantation gradients

Ion irradiation for material performance testing is limited due to its serial nature, which allows for only one value of the implantation (appm) versus dose (dpa) parameter space to be explored for each ion and experiment at a time. While ion irradiation can accelerate the process by up to three orders of magnitude compared to neutron irradiation experiments, the sample throughput for ion irradiation remains relatively low. To address these limitations, a novel capability has been developed at the Michigan Ion Beam Laboratory (MIBL), enabling for the creation of single- and two-dimensional lateral ion implantation gradients using recently installed motorized-controlled ion-beam shutters. This advancement can generate a wide scope of the two-dimensional (H+, He2+) implantation parameter space within a single sample. Integration of this new capability now allows for dual- and triple-ion beam experiments to be performed with full user control over not only the ion implantation depth, but also laterally across the sample by imposing ion implantation concentration gradients, thus providing researchers with a high-throughput means for material testing under various irradiation conditions. Furthermore, recent improvements in MIBL's microbeam ion-beam analysis (IBA) target station now allow for probing these concentration gradients in irradiated alloys with exceptional spatial resolution, down to 10 µm. These two approaches promise to significantly improve ion irradiation capabilities and increase the sample throughput by several orders of magnitude. The application of the shutter technique plus the subsequent microbeam characterization of the imposed implantation gradients are showcased by two proof-of-principle ion-irradiated experiments, one performed on single-crystal Si and the other on the fusion-candidate alloy F82H-IEA. These advancements mark a substantial leap in ion-beam technology, offering researchers a robust, high-throughput method to efficiently investigate candidate alloys with high technological readiness for both advanced fission and fusion reactor applications, in a time- and cost-effective manner.

36 - MATERIALS SCIENCE

Analysis of Slope Limiters on Irregular Grids

This paper examines the behavior of flux and slope limiters on non-uniform grids in multiple dimensions. Many slope limiters in standard use do not preserve linear solutions on irregular grids impacting both accuracy and convergence. We rewrite some well-known limiters to highlight their underlying symmetry, and use this form to examine the proper - ties of both traditional and novel limiter formulations on non-uniform meshes. A consistent method of handling stretched meshes is developed which is both linearity preserving for arbitrary mesh stretchings and reduces to common limiters on uniform meshes. In multiple dimensions we analyze the monotonicity region of the gradient vector and show that the multidimensional limiting problem may be cast as the solution of a linear programming problem. For some special cases we present a new directional limiting formulation that preserves linear solutions in multiple dimensions on irregular grids. Computational results using model problems and complex three-dimensional examples are presented, demonstrating accuracy, monotonicity and robustness.

Berger, Marsha

Scalar flux transport models for self-similar turbulent mixing

A common approach to closing turbulent species flux in multicomponent Reynolds-averaged Navier-Stokes models is to use the standard gradient diffusion approximation. While such an approach has been shown to work well when applied to many canonical turbulent mixing configurations, a gradient diffusion approach is fundamentally limited in its ability to capture complex phenomena such as countergradient transport. For this reason, complicated mixing applications may benefit by treating the turbulent diffusivity with a model transport equation in a manner analogous to second-moment momentum closure in Reynolds-stress transport models. Here, the present work explores the development and application of two different scalar flux transport (SFT) models. Self-similarity constraints are derived for these models, and they are evaluated against gradient-diffusion-based models in several one- and two-dimensional problems of turbulent mixing. It is found that the new SFT models out-perform gradient diffusion models in problems involving rapid acceleration reversal and in problems involving anisotropic transport of materials. In addition, it is found that even a hybrid-SFT approach, in which an SFT equation is utilized along with a gradient diffusion closure, provides some measure of improvement over models that transport the mass flux rather than the scalar flux.

Reynolds-averaged Navier Stokes

Comparison of solution approaches for minimum-fuel, low-thrust, power-limited orbital transfers

An initial assessment of the feasibility of a function space gradient method for computing solutions to minimum-fuel power-limited transfers encompassing a wide range of thrust to weight ratios is conducted. Three transfers between coplanar ellipses are used as test cases. The gradient method performs best at the high end of the thrust to weight ratio range. At the lower end, there is reduced sensitivity of the fuel consumption to the control profiles. The minimum fuel consumption and the trajectory are computed quite accurately but the control profiles are in error. An approximate analytical solution, obtained by Edelbaum using the method of averaging, is discussed.

Mease, Kenneth D.

Decoupling the capacity fade contributions in polymer electrolyte-based high-voltage solid-state batteries

Polymer electrolyte (PE)-based solid-state batteries (PE-SSBs) made with high-voltage cathodes are known to suffer from severe capacity fade, stemming primarily from the poor oxidative stability of most PEs under high-voltage cycling conditions. PEs also suffer from greater ion-transport limitations compared to liquid or solid electrolytes. However, often, these limitations are collectively stated to be responsible for the observed capacity fade, and it is challenging to decouple the contributions of different factors. Herein, a tunable cell fabrication platform was developed to systematically investigate and decouple the two primary capacity fade drivers (cell impedance growth and kinetic limitations), while keeping the other cell parameters constant. Three PE types with distinct transport characteristics were compared. By utilizing a voltage profile analysis method, the contribution of the cell's internal impedance growth was quantitatively decoupled from the kinetic limitations stemming from the high concentration gradient in the polymer catholyte and slow charge transfer reactions. We demonstrate that the high interfacial impedance did not necessarily correlate with the high capacity fade rate. Kinetic limitations that are not reflected by impedance measurements can play a dominant role in causing cumulative capacity decay.

Ock, Ji-young [Oak Ridge National Laboratory (ORNL

The Zooplankton International Geospatial dataset: A global repository of spatiotemporal freshwater zooplankton community composition data from lakes and reservoirs to support ecological research

Zooplankton transfer substantial energy in aquatic food webs and are used as indicators of environmental change. Syntheses of zooplankton community dynamics globally require datasets that span a wide range of environmental gradients; however, these datasets are limited due to methodological differences across programs, taxonomic inconsistencies, and a lack of standardized metadata. To reconcile these challenges, we created the Zooplankton International Geospatial (ZIG) dataset, which includes original zooplankton, water physical and chemical variables, and lake morphometric data from 311 inland lakes and reservoirs. ZIG includes waterbodies ranging in size from 0.005 to 82,100 km2 and spanning broad latitudinal (−47.26 to 64.90) and longitudinal ranges (−165.04 to 176.53). Temporal coverage for individual waterbodies ranges between 1 and 60 yr with sampling frequency ranging from annually to weekly. With its extensive coverage and content, we consider ZIG to be a cornerstone for future investigations of global scale lake biodiversity change.

Figary, Stephanie [Cornell University, Ithaca, NY]

Resource assessment of ocean thermal energy conversion in Puerto Rico and U.S. Virgin Islands

Island communities often struggle to establish and maintain traditional electric grids and are therefore heavily reliant on costly imported fossil fuels. In the case of Puerto Rico, these challenges are enhanced by extreme weather and other natural hazards that threaten the local electricity generation and transmission infrastructure. Ocean thermal energy conversion (OTEC) could play an important role in establishing a more resilient electrical grid in the region. Here, in this study, a detailed analysis is conducted to characterize the ocean thermal resource and power potential of OTEC in Puerto Rico based on a 14-year dataset of modeled ocean temperature. The assessment considers seasonal and interannual variability in the region's thermal resource and examines the operational limitations associated with minimal thermal gradients required to run a typical OTEC heat engine. Notably, the local thermal resource is found to be sensitive to El Niño-Southern Oscillation (ENSO) climate patterns, with La Niña conditions linked to greater OTEC power availability. Seven areas of opportunity are identified based on their resource potential and proximity to existing electrical distribution lines, including two that could benefit the nearby U.S. Virgin Islands. The greatest OTEC power potential is observed to the south of the main island of Puerto Rico in the Caribbean Sea with an estimated capacity of 138 MW for a plant pumping cold water from a depth of 1,000 m, or the equivalent amount of electricity required to power 219,000 households.

OTEC

Anodized Aluminum Oxide Membrane Ionic Memristors

Memory effect in ion transport (IT) at the solid–solution interface is uniquely attractive in that the conductance depends on or “memorizes” the previous states. Hysteretic and rectified transport properties offer exciting potential to developing advanced iontronics and neuromorphic functions, improving the efficiency of energy conversion and electrochemical processes, and overcoming the selectivity-throughput bottleneck in the enrichment of low abundant species for environment- and energy-friendly separations, among others. Herein, memory effects are discovered in the rectified electrokinetic IT through anodized aluminum oxide (AAO) membranes containing densely packed highly ordered nanochannels (10 10 per cm 2 ). Characteristic memristor responses of pinched current–potential loops are resolved in voltammetric experiments and successfully reproduced through finite element simulation. Excitatory and inhibitory conductance states are shown to arise from the enrichment and depletion of mobile charge carriers. Structurewise, the transport symmetry is broken by the barrier oxide layer (BOL) on the one end of the cylindrical nanochannels across the AAO membranes. Charge selectivity is attributed to the gradient(s) of the space charge density across the BOL characterized by depth profiling via X-ray photoelectron spectroscopy analysis. The space charge gradient(s) overcomes the fundamental limitation of widely exploited surface charge effects to enable intense rectification and hysteresis prevailing at very high ionic concentrations up to 1–2 M. A new strategy is developed for controlling the preferential IT direction and selectivity via counterion intercalation and extraction/exchange. Mechanistic understanding is further confirmed through parameter variations such as potential scan rate and ionic strength, which also demonstrates convenient controls of the related functions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Bipolar nickel-hydrogen battery design

The initial design for the NASA-Lewis advanced nickel-hydrogen battery is discussed. Fabrication of two 10-cell boilerplate battery stacks will soon begin. The test batteries will undergo characterization testing and low Earth orbit life cycling. The design effectively deals with waste heat generated in the cell stack. Stack temperatures and temperature gradients are maintained to acceptable limits by utilizing the bipolar conduction plate as a heat path to the active cooling fluid panel external to the edge of the cell stack. The thermal design and mechanical design of the battery stack together maintain a materials balance within the cell. An electrolyte seal on each cell frame prohibits electrolyte bridging. An oxygen recombination site and electrolyte reservoir/separator design does not allow oxygen to leave the cell in which it was generated.

Koehler, C. W.

Analyses of convective flows and spatial gradients in energetic ion observations

Based on the measured anisotropy of three-dimensional energetic ion distributions obtained from the Medium Energy Particle Instrument experiment of the ISEE 1 spacecraft, bulk flow, epsilon x B convection, and pressure gradients in magnetospheric plasmas are measured with two techniques. In the first technique, using a Compton-Getting transform into the appropriate rest frame in an iterative fashion and converging to the unique velocity that removes the first-order anisotropy from the flux angular distribution, the actual measured angular distribution, and spectrum at each angle, are employed. The second technique uses a first moment of the distribution function in which the shift in velocity space of the distribution function is obtained at two phase space density values. The convection contribution to the velocity shift is assumed to be perpendicular to the pressure gradient contribution if an MHD generator condition is assumed, rendering the two shifts separable, and a gradient scale and a lower limit to the convection electric field are derived in one calculation.

Mitchell, D. G.

Crater relaxation on Ganymede - Implications for ice rheology

Controversy has existed over whether or not viscous relaxation is an important process on the icy satellites. Previous models involved large extrapolations of Newtonian flow laws for ice, whereas ice is known to exhibit non-Newtonian behavior. Recently, the flow law parameters for ice at the appropriate temperatures and stresses have been measured. Numerical modeling of the viscous relaxation of basins on Ganymede using these parameters has given implausibly short relaxation times. However, this model treated ice as a purely viscous substance, so that no elastic lithosphere could develop near the surface. Here, ice is treated as a Maxwell visco-elastic material and numerically model the relaxation of basins on Ganymede. It is found that realistic Young's moduli lead to little relaxation occurring in basins even 4.0 Ga after their formation. Further, it is shown that within braod limits the near surface temperature gradient has little effect on this result. Finally, examination of the distribution of Maxwell times in the vicinity of the crater shows that most viscous relaxation occurs early in the basin's history when stresses are high, and thus Maxwell time is short. As stresses are relieved, the Maxwell time becomes long, and relaxation essentially ceases.

Hillgren, Valerie J.

Euler and potential computational results for selected aerodynamic configurations

A selection of CFD successes and failures is evaluated, on the basis of experimental data/CFD result correlations involving full-potential and Euler computations of the aerodynamics of four commercial transport wings and two low aspect ratio delta wings. An effort is made to ascertain optimum values for grid density and distribution, artificial dissipation, Courant-Friedrichs-Lewy number, enthalphy damping, and a multigrid scheme for each flow condition and configuration analyzed. It is demonstrated that CFD solutions can assist the experimentalist prior to a test by indicating the locations of high pressure gradients and projecting test condition limitations due to balance design limits.

Hicks, R. M.

Derivation of particulate directional information from analysis of elliptical impact craters on LDEF

The Long Duration Exposure Facility provided a gravity gradient stabilized platform which allowed limited directional information to be derived from particle impact experiments. The morphology of impact craters on semi-infinite materials contains information which may be used to determine the direction of impact much more accurately. We demonstrate the applicability of this technique and present preliminary results of measurements from LDEF and modelling of interplanetary dust and space debris.

Newman, P. J.

Thermocapillary Bubble Migration - An Oseen-Like Analysis of the Energy Equation

The thermocapillary migration of a bubble in a liquid possessing a temperature gradient is analyzed in the limit of large Reynolds and Marangoni numbers. Crespo and Manuel (1983) performed an analysis in this limit wherein energy conduction is completely neglected and obtained the bubble migration velocity using energy dissipation arguments. In the present analysis, performed in a coordinate system moving with the bubble, the velocity field in the convection term in the energy equation is approximated in an Oseen-like manner by replacing it with the velocity field far away from the bubble (i.e., the migration velocity of the bubble). Conduction is retained to satisfy the zero conductive heat flux boundary condition on the bubble surface. An approximate solution has been obtained for the Oseen-like energy equation. The bubble velocity obtained using energy dissipation considerations is in agreement with the result of Crespo and Manuel. The solution shows the thermal boundary layer and wake structure in the vicinity of the bubble. The Oseen-like analysis, however, has inherent limitations, as the flow penetrates the bubble surface. These issues are discussed and the result are compared to those in the literature.

Balasubramaniam, R.

Lock-up failure of a four-bar linkage deployment mechanism

A successful failure investigation of a four-bar linkage deployment mechanism has been performed. Possible failure causes such as the mismatch of material coefficient of thermal expansion (CTE), excessive hinge friction, limit switch interference, and thermal gradient induced resistive preload were investigated and are discussed. The final conclusions and corrective actions taken are described. Finally, valuable lessons learned during the investigation are discussed.

Zinn, Michael

Plains tectonism on Venus: The deformation belts of Lavinia Planitia

High-resolution radar images from the Magellan spacecraft have revealed the first details of the morphology of the Lavinia Planitia region of Venus. A number of geologic units can be distinguished, including volcanic plains units with a range of ages. Transecting these plains over much of the Lavinia region are two types of generally orthogonal features that we interpret to be compressional wrinkle ridges and extensional grooves. The dominant tectonic features of Lavinia are broad elevated belts of intense deformation that transect the plains with complex geometry. They are many tens to a few hundred kilometers wide, as much as 1000 km long, and elevated hundreds of meters above the surrounding plains. Two classes of deformation belts are seen in the Lavinia region. 'Ridge belts' are composed of parallel ridges, each a few hundred meters in elevation, that we interpret to be folds. Typical fold spacings are 5-10 km. 'Fracture belts' are dominated instead by intense faulting, with faults in some instances paired to form narrow grabens. There is also some evidence for modest amounts of horizontal shear distributed across both ridge and fracture belts. Crosscutting relationships among the belts show there to be a range in belt ages. In western Lavinia, in particular, many ridge and fracture belts appear to bear a relationship to the much smaller wrinkle ridges and grooves on the surrounding plains: ridge morphology tends to dominate belts that lie more nearly parallel to local plains wrinkle ridges, and fracture morphology tends to dominate belts that lie more nearly parallel to local plains grooves. We use simple models to explore the formation of ridge and fracture belts. We show that convective motions in the mantle can couple to the crust to cause horizontal stresses of a magnitude sufficient to induce the formation of deformation belts like those observed in Lavinia. We also use the small-scale wavelengths of deformation observed within individual ridge belts to place an approximate lower limit on the venusian thermal gradient in the Lavinia region at the time of deformation.

Squyres, Steven W.