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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Numerical modeling of the SNS H{sup −} ion source

Ion source rf antennas that produce H- ions can fail when plasma heating causes ablation of the insulating coating due to small structural defects such as cracks. Reducing antenna failures that reduce the operating capabilities of the Spallation Neutron Source (SNS) accelerator is one of the top priorities of the SNS H- Source Program at ORNL. Numerical modeling of ion sources can provide techniques for optimizing design in order to reduce antenna failures. There are a number of difficulties in developing accurate models of rf inductive plasmas. First, a large range of spatial and temporal scales must be resolved in order to accurately capture the physics of plasma motion, including the Debye length, rf frequencies on the order of tens of MHz, simulation time scales of many hundreds of rf periods, large device sizes on tens of cm, and ion motions that are thousands of times slower than electrons. This results in large simulation domains with many computational cells for solving plasma and electromagnetic equations, short time steps, and long-duration simulations. In order to reduce the computational requirements, one can develop implicit models for both fields and particle motions (e.g. divergence-preserving ADI methods), various electrostatic models, or magnetohydrodynamic models. We have performed simulations using all three of these methods and have found that fluid models have the greatest potential for giving accurate solutions while still being fast enough to perform long timescale simulations in a reasonable amount of time. We have implemented a number of fluid models with electromagnetics using the simulation tool USim and applied them to modeling the SNS H- ion source. We found that a reduced, single-fluid MHD model with an imposed magnetic field due to the rf antenna current and the confining multi-cusp field generated increased bulk plasma velocities of > 200 m/s in the region of the antenna where ablation is often observed in the SNS source. We report here on comparisons of simulated plasma parameters and code performance using more accurate physical models, such as two-temperature extended MHD models, for both a related benchmark system describing a inductively coupled plasma reactor, and for the SNS ion source. We also present results from scaling studies for mesh generation and solvers in the USim simulation code.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2022

Dinitrogen Binding and Functionalization

This chapter presents fundamental aspects of the coordination chemistry of N 2 , including structure, spectroscopy, reactivity, and catalysis. We start by comparing and contrasting the binding of N 2 with the isoelectronic CO ligand that is familiar to organometallic chemists, and show that though they are isolobal, there are significant differences. We also describe the numerous practical considerations to bear in mind when preparing, studying, and interpreting the properties and reactions of N 2 complexes, and include pitfalls from the perspective of practitioners. The different binding modes and reactions of N 2 complexes are tabulated, giving representative examples of various complexes and reactions. Formation of new bonds between N 2 and H sources such as protons and H 2 , as well as multiatomic groups containing Si, C, and B, give insight into the status of the field and opportunities for the future.

ammonia↗
DOE OSTI2013

The effect of the H{sub 2} density on the electron energy distribution in H{sup −} ion sources

The electron energy distribution in H{sup −} ion sources is studied. By three-dimensional Monte Carlo simulations (3D-MCC) and cross sections of collisions, the crucial collisions in the JAEA 10A are chosen to develop theoretical models for the low electron temperature and the high electron temperature, respectively. The effects of the H{sub 2} density on the low electron temperature and the high electron temperature in H{sup −} ion sources are predicted with analytic expressions and verified by 3D-MCC. The results show that both the low and high electron temperatures become lower while n{sub H2} increases.

43 PARTICLE ACCELERATORS↗
DOE OSTI2014

Dependence of beam emittance on plasma electrode temperature and rf-power, and filter-field tuning with center-gapped rod-filter magnets in J-PARC rf-driven H{sup −} ion source

The prototype rf-driven H{sup −} ion-source with a nickel plated oxygen-free-copper (OFC) plasma chamber, which satisfies the Japan Proton Accelerator Research Complex (J-PARC) 2nd stage requirements of a H{sup −} ion beam current of 60 mA within normalized emittances of 1.5 π mm mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500 μs × 25 Hz) and a life-time of more than 50 days, was reported at the 3rd international symposium on negative ions, beams, and sources (NIBS2012). The experimental results of the J-PARC ion source with a plasma chamber made of stainless-steel, instead of nickel plated OFC used in the prototype source, are presented in this paper. By comparing these two sources, the following two important results were acquired. One was that the about 20% lower emittance was produced by the rather low plasma electrode (PE) temperature (T{sub PE}) of about 120 °C compared with the typically used T{sub PE} of about 200 °C to maximize the beam current for the plasma with the abundant cesium (Cs). The other was that by using the rod-filter magnets with a gap at each center and tuning the gap-lengths, the filter-field was optimized and the rf-power necessary to produce the J-PARC required H{sup −} ion beam current was reduced typically 18%. The lower rf-power also decreases the emittances.

43 PARTICLE ACCELERATORS↗
DOE OSTI2015

Progress in the development of an H{sup −} ion source for cyclotrons

A multi-cusp DC H{sup −} ion source has been developed for cyclotrons in medical use. Beam optics of the H{sup −} ion beam is studied using a 2D beam trajectory code. The simulation results are compared with the experimental results obtained in the Mark I source, which has produced up to 16 mA H{sup −} ion beams. The optimum extraction voltages show good agreement between the calculation and the experimental results. A new ion source, Mark II source, is designed to achieve the next goal of producing an H{sup −} beam of 20 mA. The magnetic field configurations and the plasma electrode design are optimized for Cs-seeded operation. Primary electron trajectory simulation shows that primary electrons are confined well and the magnetic filter prevents the primary electrons from entering into the extraction region.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2011

The FNAL injector upgrade

The present FNAL H{sup -} injector has been operational since the 1970s and consists of two magnetron H{sup -} sources and two 750 keV Cockcroft-Walton Accelerators. In the upgrade, both slit-type magnetron sources will be replaced with circular aperture sources, and the Cockcroft-Waltons with a 200 MHz RFQ (radio frequency quadrupole). Operational experience at BNL (Brookhaven National Laboratory) has shown that the upgraded source and RFQ will be more reliable, improve beam quality and require less manpower than the present system. The present FNAL (Fermi National Accelerator Laboratory) injector has been operational since 1978 and has been a reliable source of H{sup -} beams for the Fermilab program. At present there are two Cockcroft-Walton injectors, each with a magnetron H{sup -} source with a slit aperture. With these two sources in operation, the injector has a reliability of better than 97%. However, issues with maintenance, equipment obsolescence, increased beam quality demands and retirement of critical personnel, have made it more difficult for the continued reliable running of the H{sup -} injector. The recent past has also seen an increase in both downtime and source output issues. With these problems coming to the forefront, a new 750 keV injector is being built to replace the present system. The new system will be similar to the one at BNL (Brookhaven National Laboratory) that has a similar magnetron source with a round aperture and a 200MHz RFQ. This combination has been shown to operate extremely reliably.

43 PARTICLE ACCELERATORS↗
DOE OSTI2016

Power efficiency improvements with the radio frequency H{sup −} ion source

CW 13.56 MHz radio frequency-driven H{sup −} ion source is under development at the University of Jyväskylä for replacing an existing filament-driven ion source at the MCC30/15 cyclotron. Previously, production of 1 mA H{sup −} beam, which is the target intensity of the ion source, has been reported at 3 kW of RF power. The original ion source front plate with an adjustable electromagnet based filter field has been replaced with a new front plate with permanent magnet filter field. The new structure is more open and enables a higher flux of ro-vibrationally excited molecules towards the plasma electrode and provides a better control of the potential near the extraction due to a stronger separation of the main plasma from the plasma electrode. While the original system provided better control over the e{sup −}/H{sup −} ratio, the new configuration has led to a higher production efficiency of 1 mA H{sup −} at 1.75 kW RF power. The latest results and upgrade plans are presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1997

Determination of ammonia in ethylene using ion mobility spectrometry

A simple procedure to analyze ammonia in ethylene by ion mobility spectrometry is described. The spectrometer is operated with a silane polymer membrane., 63Ni ion source, H+ (H2O)n reactant ion, and nitrogen drift and source gas. Ethylene containing parts per billion (ppb) (v/v) concentrations of ammonia is pulled across the membrane and diffuses into the spectrometer. Preconcentration or preseparation is unnecessary, because the ethylene in the spectrometer has no noticeable effect on the analytical results. Ethylene does not polymerize in the radioactive source. Ethylene's flammability is negated by the nitrogen inside the spectrometer. Response to ammonia concentrations between 200 ppb and 1.5 ppm is near linear, and a detection limit of 25 ppb is calculated.

NASA Discipline Environmental Health↗
DOE OSTI2011

A general solution-chemistry route to the synthesis LiMPO{sub 4} (M=Mn, Fe, and Co) nanocrystals with [010] orientation for lithium ion batteries

A general and efficient solvothermal strategy has been developed for the preparation of lithium transition metal phosphate microstructures (LiMnPO{sub 4}, LiFePO{sub 4}, and LiCoPO{sub 4}), employing ethanol as the solvent, LiI as the Li source, metal salts as the M sources, H{sub 3}PO{sub 4} as the phosphorus source, and poly(vinyl pyrrolidone) (PVP) as the carbon source and template. This route features low cost, environmental benign, and one-step process for the cathode material production of Li-ion batteries without any complicated experimental setups and sophisticated operations. The as-synthesized LiMPO{sub 4} microstructures exhibit unique, well-shaped and favorable structures, which are self-assembled from microplates or microrods. The b axis is the preferred crystal growth orientation of the products, resulting in a shorter lithium ion diffusion path. The LiFePO{sub 4} microstructures show an excellent cycling stability without capacity fading up to 50 cycles when they are used as a cathode material in lithium-ion batteries. - Graphical abstract: A general and efficient solvothermal strategy has been developed for the preparation of lithium transition metal phosphate microstructures under solvothermal conditions in the presence of PVP. Highlights: > A general and efficient solvothermal strategy has been developed for the preparation of LiMPO{sub 4} microstructures. > This route features low cost, environmental benign, and one-step process. > The LiMPO{sub 4} microstructures exhibit unique, well-shaped, and favorable structures. > The LiFePO{sub 4} microstructures show an excellent cycling stability up to 50 cycles as a cathode material of lithium-ion batteries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1986

Molecular clouds and star formation in the inner galaxy - A comparison of CO, H II, and far-infrared surveys

Surveys of the galactic plane over galactic latitudes from -1 degree to +1 degree and galactic longitudes from 12 degrees to 60 degrees are compared in the CO line at 2.6 mm, in the far-infrared (FIR) continuum at 150 micrometers and 250 micrometers, and in the radio continuum and H 110-alpha recombination line at 6 cm. The main purposes are to determine the degree of association between FIR sources, H II regions, and molecular clouds in the first quadrant and to describe and analyze the stellar content of these molecular clouds. Among the conclusions it is noted that most FIR sources coincide with HII regions, and nearly all H II regions coincide with molecular clouds, and that clouds in the inner galaxy are probably several tens of millions of years old and may have been producing O stars for only about the most recent 20 percent of their lives.

Myers, P. C.↗
DOE OSTI2012

Research and development of H{sup -} ion source and low energy beam transport for a kaon-neutrino factory

A baseline H{sup -} ion source and low energy beam transport (LEBT) system have been identified for Project X. The filament-discharge H{sup -} ion source has been fabricated by D-Pace, Inc. and is now in operation at LBNL. The source is capable of delivering over 10 mA of H{sup -} beam in cw operation with normalized 4 rms emittances less than 0.7 {pi} mm mrad. A two-solenoid magnetic lens LEBT system has been design. The design has been validated with simulations of beam transport for 5 mA 30 keV H{sup -} beams using various simulation codes.

43 PARTICLE ACCELERATORS↗
DOE OSTI2012

Wave frequency dependence of H{sup -} ion production and extraction in a transformer coupled plasma H{sup -} ion source at SNU

The effect of rf wave frequencies on the production of H{sup -} ion is investigated in a transformer coupled plasma H{sup -} ion source at Seoul National University. A Langmuir probe is installed to measure the plasma density and temperature, and these plasma parameters are correlated to the extracted H{sup -} beam currents at various frequencies. The Langmuir probe is also used to measure the density of H{sup -} ions at the ion source by generating photodetachment with an Nd:YAG laser. The extracted H{sup -} currents decrease to a minimum value until 13 MHz and then, increase as the driving frequency increases from 13 MHz while the relative H{sup -} population measured by photodetachment monotonically decreases as the driving rf frequency increases from 11 MHz to 15 MHz. A potential well formed at the extraction region at high frequencies of more than 13 MHz is considered responsible for the increased H{sup -} beam extraction even with a lower photodetachment signal. The variation in the driving rf frequency not only affects the density and temperature of the plasma but also modifies the plasma potential with the existence of a filtering magnetic field and consequently, influences the extracted H{sup -} current through the extraction as well as formation of H{sup -} ions.

43 PARTICLE ACCELERATORS↗
DOE OSTI2012

STAR FORMATION ACTIVITY IN THE GALACTIC H II REGION Sh2-297

We present a multiwavelength study of the Galactic H II region Sh2-297, located in the Canis Major OB1 complex. Optical spectroscopic observations are used to constrain the spectral type of ionizing star HD 53623 as B0V. The classical nature of this H II region is affirmed by the low values of electron density and emission measure, which are calculated to be 756 cm{sup -3} and 9.15 Multiplication-Sign 10{sup 5} cm{sup -6} pc using the radio continuum observations at 610 and 1280 MHz, and Very Large Array archival data at 1420 MHz. To understand local star formation, we identified the young stellar object (YSO) candidates in a region of area {approx}7.'5 Multiplication-Sign 7.'5 centered on Sh2-297 using grism slitless spectroscopy (to identify the H{alpha} emission line stars), and near infrared (NIR) observations. NIR YSO candidates are further classified into various evolutionary stages using color-color and color-magnitude (CM) diagrams, giving 50 red sources (H - K > 0.6) and 26 Class II-like sources. The mass and age range of the YSOs are estimated to be {approx}0.1-2 M {sub Sun} and 0.5-2 Myr using optical (V/V-I) and NIR (J/J-H) CM diagrams. The mean age of the YSOs is found to be {approx}1 Myr, which is of the order of dynamical age of 1.07 Myr of the H II region. Using the estimated range of visual extinction (1.1-25 mag) from literature and NIR data for the region, spectral energy distribution models have been implemented for selected YSOs which show masses and ages to be consistent with estimated values. The spatial distribution of YSOs shows an evolutionary sequence, suggesting triggered star formation in the region. The star formation seems to have propagated from the ionizing star toward the cold dark cloud LDN1657A located west of Sh2-297.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1986

H 1504 + 65 - An extraordinarily hot compact star devoid of hydrogen and helium

The optical identification of the bright soft X-ray source H 1504 + 65, originally discovered by the HEAO I A-2 low energy detectors, is reported. The optical counterpart exhibits a steep, virtually featureless continuum from optical wavelengths through the ultraviolet. The spectrum is remarkably featureless except for a broad O VI adsorption feature at 3494.7 A and C IV absorption at 3934 A and emission at 4658 A. The soft X-ray data, which are not consistent with any published models for degenerate stars having predominantly H or He compositions, suggest that H 1504 + 65 is a metal-rich, near-degenerate object of very high temperature. Qualitative considerations indicate that it is definitely hotter than PG 1159 - 035 and similar objects. A temperature of roughly 160,000 K is suggested.

Nousek, J. A.↗
DOE OSTI2014

Plasma ignition and steady state simulations of the Linac4 H{sup −} ion source

The RF heating of the plasma in the Linac4 H{sup −} ion source has been simulated using a particle-in-cell Monte Carlo collision method. This model is applied to investigate the plasma formation starting from an initial low electron density of 10{sup 12} m{sup −3} and its stabilization at 10{sup 18} m{sup −3}. The plasma discharge at low electron density is driven by the capacitive coupling with the electric field generated by the antenna, and as the electron density increases the capacitive electric field is shielded by the plasma and induction drives the plasma heating process. Plasma properties such as e{sup −}/ion densities and energies, sheath formation, and shielding effect are presented and provide insight to the plasma properties of the hydrogen plasma.

43 PARTICLE ACCELERATORS↗
DOE OSTI2016

Simulation of space charge compensation in a multibeamlet negative ion beam

Ion beam space charge compensation occurs by cumulating in the beam potential well charges having opposite polarity, usually generated by collisional processes. In this paper we investigate the case of a H{sup −} ion beam drift, in a bi-dimensional approximation of the NIO1 (Negative Ion Optimization phase 1) negative ion source. H{sup −} beam ion transport and plasma formation are studied via particle-in-cell simulations. Differential cross sections are sampled to determine the velocity distribution of secondary particles generated by ionization of the residual gas (electrons and slow H{sub 2}{sup +} ions) or by stripping of the beam ions (electrons, H, and H{sup +}). The simulations include three beamlets of a horizontal section, so that multibeamlet space charge and secondary particle diffusion between separate generation regions are considered, and include a repeller grid biased at various potentials. Results show that after the beam space charge is effectively screened by the secondary plasma in about 3 μs (in agreement with theoretical expectations), a plasma grows across the beamlets with a characteristic time three times longer, and a slight overcompensation of the electric potential is verified as expected in the case of negative ions.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

Rod-filter-field optimization of the J-PARC RF-driven H{sup −} ion source

In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) second-stage requirements of an H{sup −} ion beam of 60mA within normalized emittances of 1.5πmm•mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of longer than 1month, the J-PARC cesiated RF-driven H{sup −} ion source was developed by using an internal-antenna developed at the Spallation Neutron Source (SNS). Although rod-filter-field (RFF) is indispensable and one of the most beam performance dominative parameters for the RF-driven H{sup −} ion source with the internal-antenna, the procedure to optimize it is not established. In order to optimize the RFF and establish the procedure, the beam performances of the J-PARC source with various types of rod-filter-magnets (RFMs) were measured. By changing RFM’s gap length and gap number inside of the region projecting the antenna inner-diameter along the beam axis, the dependence of the H{sup −} ion beam intensity on the net 2MHz-RF power was optimized. Furthermore, the fine-tuning of RFM’s cross-section (magnetmotive force) was indispensable for easy operation with the temperature (T{sub PE}) of the plasma electrode (PE) lower than 70°C, which minimizes the transverse emittances. The 5% reduction of RFM’s cross-section decreased the time-constant to recover the cesium effects after an slightly excessive cesiation on the PE from several 10 minutes to several minutes for T{sub PE} around 60°C.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2012

FORMALDEHYDE SILHOUETTES AGAINST THE COSMIC MICROWAVE BACKGROUND: A MASS-LIMITED, DISTANCE-INDEPENDENT, EXTINCTION-FREE TRACER OF STAR FORMATION ACROSS THE EPOCH OF GALAXY EVOLUTION

We examine the absorption of cosmic microwave background (CMB) photons by formaldehyde (H{sub 2}CO) over cosmic time. The K-doublet rotational transitions of H{sub 2}CO become 'refrigerated'-their excitation temperatures are driven below the CMB temperature-via collisional pumping by molecular hydrogen (H{sub 2}). 'Anti-inverted' H{sub 2}CO line ratios thus provide an accurate measurement of the H{sub 2} density in molecular clouds. Using a radiative transfer model, we demonstrate that H{sub 2}CO centimeter wavelength line excitation and detectability are nearly independent of redshift or gas kinetic temperature. Since the H{sub 2}CO K-doublet lines absorb CMB light, and since the CMB lies behind every galaxy and provides an exceptionally uniform extended illumination source, H{sub 2}CO is a distance-independent, extinction-free molecular gas mass-limited tracer of dense gas in galaxies. A Formaldehyde Deep Field could map the history of cosmic star formation in a uniquely unbiased fashion and may be possible with large bandwidth wide-field radio interferometers whereby the silhouettes of star-forming galaxies would be detected across the epoch of galaxy evolution. We also examine the possibility that H{sub 2}CO lines may provide a standardizable galaxy ruler for cosmology similar to the Sunyaev-Zel'dovich effect in galaxy clusters but applicable to much higher redshifts and larger samples. Finally, we explore how anti-inverted meter-wave H{sub 2}CO lines in galaxies during the peak of cosmic star formation may contaminate H I 21 cm tomography of the Epoch of Reionization.

79 ASTRONOMY AND ASTROPHYSICS↗