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NASA NTRS1998

Exploring the Unknown: Selected Documents in the History of the US Civilian Space Program: Using Space - Volume 3

One of the most important developments of the twentieth century has been the movement of humanity into space with machines and people. The underpinnings of that movement -why it took the shape it did; which individuals and organizations were involved; what factors drove a particular choice of scientific objectives and technologies to be used; and the political, economic, managerial, and international contexts in which the events of the space age unfolded- are all important ingredients of this epoch transition from an earthbound to spacefaring people. This desire to understand the development of spaceflight in the United States sparked this documentary history series. 'Exploring the Unknown' is a multi-volume series containing a selection of key documents in history of the U.S. civil space program. This current volume, Volume III, focusing on the use of space for practical applications, prints 112 key documents on the history of satellite communications, remote sensing of earth, and space as an investment in economic growth, edited for ease of use. Each is introduced by a headnote providing context, bibliographical information, and background information necessary to understanding the document.

Logsdon, John M.↗

NASA NTRS1998

The History of Allan Hills 84001 Revised: Multiple Shock Events

The geologic history of Martian meteorite Allan Hills (ALH) 84001 is more complex than previously recognized, with evidence for four or five crater-forming impacts onto Mars. This history of repeated deformation and shock metamorphism appears to weaken some arguments that have been offered for and against the hypothesis of ancient Martian life in ALH 84001. Allan Hills 84001 formed originally from basaltic magma. Its first impact event (I1) is inferred from the deformation (D1) that produced the granular-textured bands ("crush zones") that transect the original igneous fabric. Deformation D1 is characterized by intense shear and may represent excavation or rebound flow of rock beneath a large impact crater. An intense thermal metamorphism followed D1 and may be related to it. The next impact (I2) produced fractures, (Fr2) in which carbonate "pancakes" were deposited and produced feldspathic glass from some of the igneous feldspars and silica. After I2, carbonate pancakes and globules were deposited in Fr2 fractures and replaced feldspathic glass and possibly crystalline silicates. Next, feldspars, feldspathic glass, and possibly some carbonates were mobilized and melted in the third impact (I3). Microfaulting, intense fracturing, and shear are also associated with 13. In the fourth impact (I4), the rock was fractured and deformed without significant heating, which permitted remnant magnetization directions to vary across fracture surfaces. Finally, ALH 84001 was ejected from Mars in event I5, which could be identical to I4. This history of multiple impacts is consistent with the photogeology of the Martian highlands and may help resolve some apparent contradictions among recent results on ALH 84001. For example, the submicron rounded magnetite grains in the carbonate globules could be contemporaneous with carbonate deposition, whereas the elongate magnetite grains, epitaxial on carbonates, could be ascribed to vapor-phase deposition during I3.

Treiman, Allan H.↗

NASA NTRS1999

Ellington Field: A Short History, 1917-1963

My 1998 NASA/ASEE Summer Faculty Fellowship comprised two separate assignments: one to study the history of Ellington Field, the other to evaluate the Johnson Space Center Oral History Project (JSCOHP). This final report gives a summary of my article-length history of Ellington Field, from it inception as a U.S. Army training base to its present commercial/private status. This final report also presents my assessment of the methodology, administration, and continuing value of the JSCOHP, which is a series of recorded interviews with former and long-time JSC employees begun in 1997 to capture the experience of key participants in the human space program.

Carlson, Erik D.↗

NASA NTRS1994

Quantification of Cyclic Ground Reaction Force Histories During Daily Activity in Humans

Theoretical models and experimental studies of bone remodeling suggest that bone density and structure are influenced by local cyclic skeletal tissue stress and strain histories. Estimation of long-term loading histories in humans is usually achieved by assessment of physical activity level by questionnaires, logbooks, and pedometers, since the majority of lower limb cyclic loading occurs during walking and running. These methods provide some indication of the mechanical loading history, but fail to consider the true magnitude of the lower limb skeletal forces generated by various daily activities. These techniques cannot account for individual gait characteristics, gait speed, and unpredictable high loading events that may influence bone mass significantly. We have developed portable instrumentation to measure and record the vertical component of the ground reaction force (GRFz) during normal daily activity. This equipment allows long-term quantitative monitoring of musculoskeletal loads, which in conjunction with bone mineral density assessments, promises to elucidate the relationship between skeletal stresses and bone remodeling.

Breit, G. A.↗

NASA NTRS2001

Shuttle-Mir: The United States and Russia Share History's Highest Stage

This book is an example of what may become the norm for history texts-an illustrated narrative accompanied by a CD-ROM. The text tells the story from the human side. It is based on reflections and quotes from the astronauts, cosmonauts, and team members who participated in the historic partnership. The main chapters give the perspectives of the seven U.S. astronauts living on Mir. The "STS boxes" share the Space Shuttle crews' experiences from the 11 Shuttle-Mir missions. The "Meanwhile on Earth" sections provide details of what was happening on Earth while the attention of the Program focused on the situations in space. The text reflects conventional usage; that is, temperature is given in degrees Fahrenheit, and metrics are used as appropriate. While this publication provides an accurate overview of the Shuttle-Mir Program, the reader is encouraged to explore the companion CD-ROM. It contains a complete, searchable text of the book itself plus source publications, mission data, status reports, drawings and illustrations, videos and hundreds of images, and even a virtual Shuttle-Mir children's book. Of particular interest are the Shuttle-Mir oral history transcripts and the letters written by American astronauts while they were in residence on the Russian space station. Many of the quotes in "Shuttle-Mir: The U.S. and Russia Share History's Highest Stage" came from sources located on the CD-ROM. The reader is invited to explore the Shuttle-Mir story through the words, images, and insights of those who took part in it.

Morgan, Clay↗

NASA NTRS2002

Effects of Thermomechanical History on the Tensile Behavior of Nitinol Ribbon

Shape memory alloys (SMAs) have enormous potential for a wide variety of applications. A large body of work exists on the characterization of the microstructure and stress-strain behavior of these alloys, Nitinol (NiTi) in particular. However, many attributes of these materials are yet to be fully understood. Previous work at NASA Langley Research Center (LaRC) has included fabrication of hybrid composite specimens with embedded Nitinol actuators and modeling of their thermomechanical behavior. An intensive characterization effort has been undertaken to facilitate fundamental understanding of this alloy and to promote implementation of Nitinol in aerospace applications. Previous work revealed attributes of the Nitinol ribbon that were not easily rationalized with existing data in the literature. In particular, tensile behavior at ambient temperature showed significant dependence on the thermomechanical history prior to testing. The present work is focused on characterizing differences in the microstructure of Nitinol ribbons exposed to four different thermomechanical histories and correlation of the microstructure with tensile properties. Differential scanning calorimetry (DSC) and x-ray diffraction (XRD) analysis were employed to rationalize the microstructures present after exposure to various thermomechanical histories. Three of the Nitinol ribbon conditions were reversible upon heating (in the DSC) through the reverse transformation temperature (A(sub f) to transform the microstructure to austenite. However, the prior thermomechanical conditioning for the Nitinol ribbon that reflected the entire fabrication procedure (4% thermal cycle condition) was found to have an irreversible effect on the microstructure, as it remained unchanged after repeated complete thermal cycles. Tensile tests were conducted to determine the effect of prior thermomechancal conditioning on both the tensile behavior of the Nitinol ribbons and the stress state of the microstructure. The stress-strain behavior of the Nitinol actuators appears to be governed by the interplay between two major variables: namely, microstructural constituents such as the R-phase and the martensite; and the stress state of these constituents (whether twinned with low residual stresses, or detwinned with high residual stresses). The most significant difference in the stress-strain behavior of the four conditions, the critical stress required to achieve an initial stress plateau, was found to depend on both the amount and stress state (twinned or detwinned) of R-phase present in the initial microstructure. Thus, the effect of prior thermomechanical processing is critical to the resulting tensile behavior of the Nitinol actuator. For numerical modeling inputs one must take into account the entire fabrication process on the Nitinol actuator.

Lach, Cynthia L.↗

NASA NTRS2003

The Wind and Beyond: A Documentary Journey into the History of Aerodynamics in America: The Ascent of the Airplane - Volume 1

This first volume, plus the succeeding five now in preparation, covers the impact of aerodynamic development on the evolution of the airplane in America. As the six-volume series will ultimately demonstrate, just as the airplane is a defining technology of the twentieth century, aerodynamics has been the defining element of the airplane. Volumes two through six will proceed in roughly chronological order, covering such developments as the biplane, the advent of commercial airliners, flying boats, rotary aircraft, supersonic flight, and hypersonic flight. This series is designed as an aeronautics companion to the Exploring the Unknown: Selected Documents in the History of the U.S. Civil Space Program (NASA SP-4407) series of books. As with Exploring the Unknown, the documents collected during this research project were assembled from a diverse number of public and private sources. A major repository of primary source materials relative to the history of the civil space program is the NASA Historical Reference Collection in the NASA Headquarters History Office. Historical materials housed at NASA field centers, academic institutions, and Presidential libraries were other sources of documents considered for inclusion, as were papers in the archives of private individuals and corporations.

Hansen, James R.↗

NASA NTRS2004

Exposure and Terrestrial Histories of New Lunar and Martian Meteorites

Cosmogenic nuclide studies of lunar and Martian meteorites have contributed significantly to our understanding of these objects. By measuring a combination of cosmogenic stable- and radionuclides, we can determine a number of important properties of those meteorites. Most lunar meteorites have complex cosmic ray exposure histories, having been exposed both at some depth on the lunar surface (2 irradiation) before their ejection and as small bodies in space (4 irradiation) during transport from the Moon to the Earth. On the other hand, we have not observed evidence of complex exposure history for any Martian meteorites, so far. These exposures were then followed by residence on Earth s surface, a time commonly referred to as the terrestrial age. In addition to their complement of galactic cosmic ray (GCR) produced nuclides some lunar and Martian meteorites contain nuclides produced by solar cosmic rays (SCR). Unraveling the complex history of these objects requires the measurement of at least four cosmogenic nuclides. The specific goals of these measurements are to constrain or set limits on the following shielding or exposure parameters: (1) the depth of the sample at the time of ejection from the Moon or Mars; (2) the transit time (4 exposure age) from ejection off the lunar or Martian surface to the time of capture by the Earth and (3) the terrestrial residence time. The sum of the transit time and residence time yield an ejection age. The ejection age, in conjunction with the sample depth on the Moon or Mars, can then be used to model impact and ejection mechanisms.

Nishiizumi, K.↗

NASA NTRS2004

Impact Constraints on Major Events in Early Mars History

MOLA data have revealed a large population of "Quasi-Circular Depressions" (QCDs) with little or no visible expression in image data. These likely buried impact basins have important implications for the age of the lowland crust, how that compares with original highland crust, and when and how the crustal dichotomy may have formed. The buried lowlands are of Early Noachian age, likely slightly younger than the buried highlands but older than the exposed (visible) highland surface. A depopulation of large visible basins at diameters 800 to 1300 km suggests some global scale event early in martian history, maybe related to the formation of the lowlands and/or the development of Tharsis. A suggested early disappearance of the global magnetic field can be placed within a temporal sequence of formation of the very largest impact basins. The global field appears to have disappeared at about the time the lowlands formed. It seems likely the topographic crustal dichotomy was produced very early in martian history by processes which operated very quickly. Thus there appears to have been a northern lowland throughout nearly all of martian history, predating the last of the really large impacts (Hellas, Argyre and Isidis) and their likely very significant environmental consequences.

Frey, H. V.↗

NASA NTRS2009

Pulling Marbles from a Bag: Deducing the Regional Impact History of the SPA Basin from Impact Melt Rocks

The South Pole-Aitken (SPA) basin is an important target for absolute age-dating. Vertical and lateral impact mixing ensures that regolith within SPA will contain rock fragments from SPA itself, local impact craters, and faraway giant basins. About 20% of the regolith at any given site is foreign [1, 2], but much of this material will be cold ejecta, not impact melt. We calculated the fraction of contributed impact melt using scaling laws to estimate the amount and provenance of impact melt, demonstrating that SPA melt is the dominant impact melt rock (>70%) likely to be present. We also constructed a statistical model to illustrate how many randomly-selected impact-melt fragments would need to be dated, and with what accuracy, to confidently reproduce the impact history of a site. A detailed impact history becomes recognizable after a few hundred to a thousand randomly-selected marbles, however, it will be useful to have more information (e.g. compositional, mineralogical, remote sensing) to group fragments. These exercises show that SPA melt has a high probability of being present in a scoop sample and that dating of a few hundred to a thousand impact-melt fragments will yield the impact history of the SPA basin.

Cohen, Barbara A.↗

NASA NTRS2012

Mars Sample Return: The Next Step Required to Revolutionize Knowledge of Martian Geological and Climatological History

The capability of scientific instrumentation flown on planetary orbiters and landers has made great advances since the signature Viking mission of the seventies. At some point, however, the science return from orbital remote sensing, and even in situ measurements, becomes incremental, rather than revolutionary. This is primarily caused by the low spatial resolution of such measurements, even for landed instrumentation, the incomplete mineralogical record derived from such measurements, the inability to do the detailed textural, mineralogical and compositional characterization needed to demonstrate equilibrium or reaction paths, and the lack of chronological characterization. For the foreseeable future, flight instruments will suffer from this limitation. In order to make the next revolutionary breakthrough in understanding the early geological and climatological history of Mars, samples must be available for interrogation using the full panoply of laboratory-housed analytical instrumentation. Laboratory studies of samples allow for determination of parageneses of rocks through microscopic identification of mineral assemblages, evaluation of equilibrium through electron microbeam analyses of mineral compositions and structures, determination of formation temperatures through secondary ion or thermal ionization mass spectrometry (SIMS or TIMS) analyses of stable isotope compositions. Such details are poorly constrained by orbital data (e.g. phyllosilicate formation at Mawrth Vallis), and incompletely described by in situ measurements (e.g. genesis of Burns formation sediments at Meridiani Planum). Laboratory studies can determine formation, metamorphism and/or alteration ages of samples through SIMS or TIMS of radiogenic isotope systems; a capability well-beyond flight instrumentation. Ideally, sample return should be from a location first scouted by landers such that fairly mature hypotheses have been formulated that can be tested. However, samples from clastic sediments derived from an extensive region of Mars can provide important, detailed understanding of early martian geological and climatological history. Interrogating clastic "sediments" from the Earth, Moon and asteroids has allowed discovery of new crustal units, identification of now-vanished crust, and determination of the geological history of extensive, remote regions. Returned sample of martian fluvial and/or aeolian sediments, for example from Gale crater, could be "read like a book" in terrestrial laboratories to provide truly revolutionary new insights into early martian geological and climatological evolution.

Mittlefehldt, D. W.↗

NASA NTRS2014

The Bombardment History of 4 Vesta as Told by Sample Geochronology

The Dawn mission showed asteroid 4 Vesta to be an extensively cratered body, ancient in age, with craters in a variety of morphologies and preservation states [1-3]. Tying Vesta's relative crater ages to an absolute impact history can be accomplished through investigations of the HED (howardite, eucrite, diogenite) meteorites. Eucrites are crustal basalts and gabbros, diogenites are mostly orthopyroxenites representing lower crust or upper mantle materials, and howardites are mixed breccias containing both lithologies. Eucrite 53Mn-53Cr systematics show that the HED parent body globally differentiated by ~4.56 Ga and fully crystallized soon afterwards [4]. Much later, many eucrites were brecciated and heated by large impacts into the parent body surface. Disturbance ages in eucrites show that multiple large impacts occurred within 1 Gyr after crystallization, showing a history that largely resembles that of the Moon [5-7]. Dawn images also showed that Vesta is covered with a well-developed regolith that is spectrally similar to howardite meteorites [8]. Howardites are polymict regolith breccias made up mostly of clasts of eucrites and diogenites, but which also contain clasts formed by melting of the regolith by relatively large, energetic impact events. Impact-melt clast ages from howardites extend our knowledge of the impact history of Vesta, expanding on eucrite disturbance ages and helping give absolute age context to the observed crater-counts produced using Dawn data. The distribution of 40Ar-39Ar ages of impact-melt clasts in howardites shows that they formed within the time period 3.3-3.8 Ga [9]. These, and other impact-melted HED materials, have distinct age and compositional characteristics that suggest they formed in discrete impact events. In order to create these crystalline impact-melt products on the surface of Vesta, the impacts during this time period must have had velocities much higher than 5 km/s, the main belt average [10]. This is inconsistent with formation by a normal distribution of impact velocities and points instead to a unique period where high-velocity collisions were more frequent than currently observed. Until now, impact-reset ages in the HED meteorites have been be interpreted under the umbrella of the canonical lunar cataclysm where an increase in the absolute number of bombarding objects is responsible for creating larger absolute amounts of impact-affected and impact-melted rocks, statistically increasing their chances of being found on Earth and dated. However, the distribution of age among the howardite impact-melt clasts may not necessarily result from an increased number of impacts, but rather result from impacts of higher velocity. The changeover from a typical main belt velocity profile to this regime of increased velocity population at Vesta occurs contemporaneously with a similar transition at the Moon, indicating that howardite impact-melt clast ages reinforce the notion of a dynamically unusual episode of bombardment in the inner solar system beginning at around 4.0 Ga.

Cohen, B. A.↗

NASA NTRS2014

Investigating the Geological History of Asteroid 101955 Bennu Through Remote Sensing and Returned Sample Analyses

The NASA New Frontiers Mission OSRIS-REx will return surface regolith samples from near-Earth asteroid 101955 Bennu in September 2023. This target is classified as a B-type asteroid and is spectrally similar to CI and CM chondrite meteorites [1]. The returned samples are thus expected to contain primitive ancient Solar System materials that formed in planetary, nebular, interstellar, and circumstellar environments. Laboratory studies of primitive astromaterials have yielded detailed constraints on the origins, properties, and evolutionary histories of a wide range of Solar System bodies. Yet, the parent bodies of meteorites and cosmic dust are generally unknown, genetic and evolutionary relationships among asteroids and comets are unsettled, and links between laboratory and remote observations remain tenuous. The OSIRIS-REx mission will offer the opportunity to coordinate detailed laboratory analyses of asteroidal materials with known and well characterized geological context from which the samples originated. A primary goal of the OSIRIS-REx mission will be to provide detailed constraints on the origin and geological and dynamical history of Bennu through coordinated analytical studies of the returned samples. These microanalytical studies will be placed in geological context through an extensive orbital remote sensing campaign that will characterize the global geological features and chemical diversity of Bennu. The first views of the asteroid surface and of the returned samples will undoubtedly bring remarkable surprises. However, a wealth of laboratory studies of meteorites and spacecraft encounters with primitive bodies provides a useful framework to formulate priority scientific questions and effective analytical approaches well before the samples are returned. Here we summarize our approach to unraveling the geological history of Bennu through returned sample analyses.

Messenger, S.↗

NASA NTRS2017

The Effects of Vegetative Type, Edges, Fire History, Rainfall and Management in Fire-Maintained Ecosystems

The combined effects of repeated fires, climate, and landscape features (e.g., edges) need greater focus in fire ecology studies, which usually emphasize characteristics of the most recent fire and not fire history. Florida scrub-jays are an imperiled, territorial species that prefer medium (1.2-1.7 m) shrub heights. We measured short, medium, and tall habitat quality states annually within 10 ha grid cells that represented potential territories because frequent fires and vegetative recovery cause annual variation in habitat quality. We used multistate models and model selection to test competing hypotheses about how transition probabilities between states varied annually as functions of environmental covariates. Covariates included vegetative type, edges, precipitation, openings (gaps between shrubs), mechanical cutting, and fire characteristics. Fire characteristics not only included an annual presenceabsence of fire covariate, but also fire history covariates: time since the previous fire, the maximum fire-free interval, and the number of repeated fires. Statistical models with support included many covariates for each transition probability, often including fire history, interactions and nonlinear relationships. Tall territories resulted from 28 years of fire suppression and habitat fragmentation that reduced the spread of fires across landscapes. Despite 35 years of habitat restoration and prescribed fires, half the territories remained tall suggesting a regime shift to a less desirable habitat condition. Measuring territory quality states and environmental covariates each year combined with multistate modeling provided a useful empirical approach to quantify the effects of repeated fire in combinations with environmental variables on transition probabilities that drive management strategies and ecosystem change.

Breininger, David R.↗

NASA NTRS2018

The Effects of Vegetative Type, Edges, Fire History, Rainfall and Management in Fire-Maintained Habitat

The combined effects of fire history, climate, and landscape features (e.g., edges) on habitat specialists need greater focus in fire ecology studies, which usually only emphasize characteristics of the most recent fire. Florida scrub-jays are an imperiled, territorial species that prefer medium (1.2-1.7 m) shrub heights, which are dynamic because of frequent fires. We measured short, medium, and tall habitat quality states annually within 10 ha grid cells (that represented potential territories) because fires and vegetative recovery cause annual variation in habitat quality. We used multistate models and model selection to test competing hypotheses about how transition probabilities vary between states as functions of environmental covariates. Covariates included vegetative type, edges (e.g., roads, forests), precipitation, openings (gaps between shrubs), mechanical cutting, and fire characteristics. Fire characteristics not only included an annual presence/absence of fire covariate, but also fire history covariates: time since the previous fire, the longest fire-free interval, and the number of repeated fires. Statistical models with support included many covariates for each transition probability, often including fire history, interactions and nonlinear relationships. Tall territories resulted from 28 years of fire suppression and habitat fragmentation that reduced the spread of fires across landscapes. Despite 35 years of habitat restoration and prescribed fires, half the territories remained tall suggesting a regime shift to a less desirable habitat condition. Edges reduced the effectiveness of fires in setting degraded scrub and flatwoods into earlier successional states making mechanical cutting an important tool to compliment frequent prescribed fires.

Breininger, David R.↗

NASA NTRS2019

The Sedimentary History of Mars as Observed by Rovers

Mars has a sedimentary history that spans billions of years. Orbital images have allowed for the identification of vast regional sedimentary deposits that can be traced over 100s of kilometers and are 100s of meters thick including localized alluvial, deltaic, and lacustrine deposits. Detections of secondary minerals in these deposits from orbital spectroscopy suggest the aqueous history of early Mars varied as a function of space and time. Orbital observations, however, provide a simplified and incomplete picture of Mars’ sedimentary history because measurements for inferring sediment transport and deposition, such as lithology, grain size, and internal structures, and measurements for inferring sediment source and aqueous alteration, such as outcrop-scale mineralogic and geochemical composition and diagenetic features, cannot be identified from orbit. Rover observations have significantly enhanced our view of ancient and modern sedimentary environments on Mars, resulting in detailed reconstructions of paleo-environments and habitability.

Rampe, E. B.↗

NASA NTRS2019

Constraining the Metallicities, Ages, Star Formation Histories, and Ionizing Continua of Extragalactic Massive Star Populations

We infer the properties of massive star populations using the far-ultraviolet stellar continua of 61 star-forming galaxies: 42 at low redshift observed with the Hubble Space Telescope and 19 at z ~ 2 from the MegaSaura sample. We fit each stellar continuum with a linear combination of up to 50 single-age and single-metallicity starburst99 models. From these fits, we derive light-weighted ages and metallicities, which agree with stellar wind and photospheric spectral features, and infer the spectral shapes and strengths of the ionizing continua. Inferred light-weighted stellar metallicities span 0.05–1.5 Z(sub ⊙) and are similar to the measured nebular metallicities. We quantify the ionizing continua using the ratio of the ionizing flux at 900 Å to the non-ionizing flux at 1500 Å and demonstrate the evolution of this ratio with stellar age and metallicity using theoretical single-burst models. These single-burst models only match the inferred ionizing continua of half of the sample, while the other half are described by a mixture of stellar ages. Mixed-age populations produce stronger and harder ionizing spectra than continuous star formation histories, but, contrary to previous studies that assume constant star formation, have similar stellar and nebular metallicities. Stellar population age and metallicity affect the far-UV continua in different and distinguishable ways; assuming a constant star formation history diminishes the diagnostic power. Finally, we provide simple prescriptions to determine the ionizing photon production efficiency (ξ(sub ion)) from the stellar population properties. The ξ(sub ion) inferred from the observed star-forming galaxies has a range of log(ξ(sub ion)) = 24.4–25.7 Hz erg(exp −1) that depends on the stellar population age, metallicity, star formation history, and contributions from binary star evolution. These stellar population properties must be observationally determined to accurately determine the number of ionizing photons generated by massive stars.

Chisholm, J.↗

NASA NTRSDate not supplied

Using Mineralogy to Interpret Martian Geologic History

The surface mineralogy of Mars is key to interpreting the planet’s geologic history and constraining when and where Mars may have been habitable to microbial life. Orbital mineralogical data from infrared spectrometers collected over the last two decades have demonstrated that Mars is more than a basaltic planet. Thermal infrared (TIR) emission spectrometers have identified regional variations in igneous minerals, iron oxides, and chloride salts, showing evidence for magmatic evolution and aqueous alteration. Orbital visible/shortwave infrared reflectance spectra provide detailed information about the aqueous history of Mars through the identification of clay minerals, sulfates, carbonates, zeolites, and amorphous materials in ancient ~3-4-billion-year-old terrains. Mineralogical data from rovers allow us to better characterize mineral formation mechanisms by identifying mineral assemblages and placing them in geologic context using outcrop- to grain-scale images. TIR and Mössbauer data from the Mars Exploration Rovers helped identify an ancient dune-interdune playa environment with multiple episodes of groundwater at Meridiani Planum and volcanism-induced hydrothermalism at Gusev crater. The CheMin X-ray diffractometer on the Mars Science Laboratory Curiosity rover in Gale crater is the first fully quantitative mineralogical instrument sent to another planetary surface. CheMin data allow the quantification of minerals and X-ray amorphous materials with a mineral detection limit of <1 wt.% and provide crystal chemistry of major phases from refined unit-cell parameters. CheMin has revealed local mineralogical changes in ancient sedimentary rocks not seen from orbit and helped identify habitable environments. Throughout the 600+ m of vertical stratigraphy studied so far, changes in clay mineralogy, Fe-oxides/oxyhydroxides, sulfates, and carbonates demonstrate a long history of surface and groundwater at Gale crater with variable salinity, pH, Eh, and temperature. Recent CheMin data document a decrease in clay minerals and an increase in sulfate minerals in younger strata that corresponds with a change from fluvio-lacustrine to eolian depositional environments, potentially documenting a change to a drier climate across the planet.

E. B. Rampe↗