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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Development of risk mitigation guidance for sensor placement inside mechanically ventilated enclosures – Phase 1

Guidance on Sensor Placement was identified as the top research priority for hydrogen sensors at the 2018 HySafe Research Priority Workshop on hydrogen safety in the category Mitigation, Sensors, Hazard Prevention, and Risk Reduction. This paper discusses the initial steps (Phase 1) to develop such guidance for mechanically ventilated enclosures. This work was initiated as an international collaborative effort to respond to emerging market needs related to the design and deployment equipment for hydrogen infrastructure that is often installed in individual equipment cabinets or ventilated enclosures. The ultimate objective of this effort is to develop guidance for an optimal sensor placement such that, when integrated into a facility design and operation, will allow earlier detection at lower levels of incipient leaks, leading to significant hazard reduction. Reliable and consistent early warning of hydrogen leaks will allow for the risk mitigation by reducing or even eliminating the probability of escalation of small leaks into large and uncontrolled events. To address this issue, a study of a real-world mechanically ventilated enclosure containing GH2 equipment was conducted, where CFD modeling of the hydrogen dispersion (performed by AVT and UQTR, and independently by the JRC) was validated by the NREL Sensor laboratory using a Hydrogen Wide Area Monitor (HyWAM) consisting of a 10-point gas and temperature measurement analyzer. In the release test, helium was used as a hydrogen surrogate. Expansion of indoor releases to other larger facilities (including parking structures, vehicle maintenance facilities and potentially tunnels) and incorporation into QRA tools, such as HyRAM is planned for Phase 2. It is anticipated that results of this work will be used to inform national and international standards such as NFPA 2 Hydrogen Technologies Code, Canadian Hydrogen Installation Code (CHIC) and relevant ISO/TC 197 and CEN documents.

08 HYDROGEN↗

High Pressure Hydrogen Nozzle Assembly and Dispenser for Heavy Duty Vehicles (Final Technical Report)

Electricore, Inc. along with partners Bennett Pump Company (Bennett), WEH Technologies, Inc. (WEH), National Renewable Energy Laboratory (NREL), and Quong & Associates, Inc. (QAI) have developed a high-pressure hydrogen nozzle assembly and dispenser for heavy-duty (HD) vehicles. The system was installed, tested and demonstrated at NREL’s Hydrogen Infrastructure Testing and Research Facility (HITRF). The system was designed to have a maximum operating pressure of 87.5 MPa and an approximate average flow rate of 10 kg/min over 10 minutes at fuel temperatures of -40°C. To further develop the specifications and design of the system, the team performed an industry survey to ensure the system met the needs of potential users.

08 HYDROGEN↗

A Business Case Evaluation of Gas Switching Reforming (GSR) Technology: A Promising Technology for Natural Gas Reforming with Integrated CO2 Capture

Hydrogen is essential in the transition to sustainable energy, and developing low-carbon production methods is a key research focus. Traditional steam methane reforming (SMR) dominates the hydrogen industry but contributes substantially to CO2 emissions. In response, Gas Switching Reforming (GSR) has emerged as a novel process that integrates carbon capture and utilizes process heat more efficiently. Unlike other reforming methods, GSR consolidates oxidation and reduction reactions within a single reactor, which minimizes external energy inputs and simplifies scaling. Like conventional steam methane reforming (SMR), GSR can be integrated with water-gas shift and pressure swing adsorption units for pure hydrogen production. This work presents a comprehensive business case analysis of GSR technology based on experimental results in Technology Readiness Level 3, Life Cycle Assessment (LCA) and Techno-Economic (TEA) evaluation incorporating ASPEN Plus process modeling considering different configurations and energy scenarios. The TEA incorporates data from kinetic experiments from various catalysts to evaluate the GSR process under various conditions. The goal of this work is to evaluate GSR’s potential to serve as a low-carbon alternative to SMR, focusing on global warming potential and additional impact categories to evaluate a wide spectrum of environmental impacts. Comparative assessments were conducted with SMR, chemical loop reforming (CLR), and proton exchange membrane (PEM) electrolysis to explore trade-offs across environmental metrics. The environmental impact assessment of this work encompasses the entire hydrogen production lifecycle from raw material extraction to plant decommissioning, using a cradle-to-gate boundary. Preliminary findings highlight that GSR, when integrated with low-carbon energy sources, could significantly reduce environmental impacts, making it a promising candidate for low-carbon hydrogen infrastructure. The insights from this business case evaluation aim to guide industry in scale-up and commercialization of this promising clean energy technology.

03 NATURAL GAS↗

Hydrogen charging and desorption from microstructural viewpoint: A method for deconvoluting hydrogen desorption spectra and unveiling the hydrogen-microstructure interaction

Understanding the interaction of hydrogen with microstructural features in metallic materials is crucial for designing hydrogen-resistant alloys. Although thermal desorption spectroscopy (TDS) is widely used for investigating the hydrogen binding behavior of various microstructural features, its application to face-centered cubic (fcc) metals and alloys that exhibit low hydrogen diffusivity is limited due to the lumped TDS desorption signals. This paper shows that, by coupling a Sofronis–McMeeking type hydrogen transport model with a microstructure-informed finite-element model, TDS data can be deconvoluted to reveal the underlying adsorption–diffusion–desorption processes, hydrogen diffusivity, and trap-binding energies. In conclusion, the austenitic steel SS316L in solution-annealed condition is used as a demonstration material, and we focused on investigating the interaction of deuterium (hydrogen isotope) with grain boundaries, which is difficult to investigate from experiments alone but critical for design of alloys for hydrogen infrastructure.

Finite element simulation, Polycrystalline Microst↗

A Review of Regulations, Codes, and Standards for Hydrogen Fuel Cell Electric Bus Use on Airports

This report reviews regulations, codes, and standards to be considered for FCEB operations on airports governing vehicle safety, hydrogen infrastructure, and airport operations. Overall, the review found the existing regulatory framework largely suitable for FCEB operations on airports, with only minor gaps identified pertaining to heavy-duty vehicle fueling, operation and fire safety on airport aprons, and authorization for emergency power use.

08 HYDROGEN↗

Total cost of ownership of vehicle electrification and fuel switching options for light-duty and heavy-duty vehicles

Projecting the transition from combustion engines to battery-based powertrains is complex becuase it involves numerous interdependent decisions. This study estimates total cost of ownership (TCO) to assess the economic viability of powertrain electrification, focusing exclusively on advances in vehicle and fuel technologies. Under two bounding technology-progress scenarios, we develop vehicle designs and fuel cost trajectories, which serve as inputs to TCO projections for selected classes from 2021 to 2050. We analyzed a small sport utility vehicle (SUV) to represent the light-duty vehicle (LDV) sector, and four medium- and heavy-duty vehicle (MHDV) classes: Class 6 box delivery, Class 8 drayage, Class 8 long-haul, and Class 8 transit bus. For each class, we compared the TCO of battery electric vehicles (BEVs) and fuel cell hybrid electric vehicles (FCHEVs) against conventional internal combustion engine vehicles (ICEVs). The results show that modern ICEVs generally have lower TCO; however, BEVs and FCHEVs could match or have lower TCOs than ICEVs over time, depending on technological progress. In LDVs, BEV300 is projected to deliver the lowest TCO by 2050, particularly under the high-progress scenario. In MHDVs, both BEVs and FCHEVs could become more cost-competitive than ICEVs by 2050 in the high-progress case. Beyond these results, the findings suggest further investigation is warranted for BEV charging infrastructure, FCHEV hydrogen refueling infrastructure, and MHDV charging strategies. In conclusion, these factors could reduce the fuel-cost share of TCO and enhance the competitiveness of BEVs and FCHEVs relative to ICEVs.

Battery electric vehicle↗

Multi-Functional Distributed Fiber Sensors for Pipeline Monitoring and Methane Detections. Final Report

As an abundant and cheap fossil energy source, natural gas has become a significant energy supply to support the United States’ economy. However, the large-scale extraction and utilization of natural gas also impose significant challenges on methane leakage. This problem is exacerbated by aging gas utility delivery systems, including interstate high-pressure pipelines, storage, and transmission facilities. This project aims to develop a cost-effective fiber optical sensing method that can perform multi-parameter real-time measurements of natural gas pipelines across long interrogation distances up to 100 km with 1-meter spatial resolution. This sensing tool can evaluate overall pipeline efficiency and reduce methane emissions for mid-stream methane infrastructures. To accomplish this objective, research and development efforts funded by this project have resulted in the following accomplishments: This project successfully has developed new functional sensory polymer materials using Metal-Organic Frameworks (MOFs) that can be coated on optical fiber through the reel-to-reel coating process. Functional polymer-coated optical fibers can perform sensitive methane detection through evanescence wave interaction and strain-based measurements to achieve 1% detection sensitivities. The new sensors fibers support both distributed measurements and multiplexed fiber sensors array for multi-point measurements. This project developed and optimized a new multi-core optical fiber that supports simultaneous and distributed measurements of strain and temperatures with 1-meter spatial resolutions across up to 100-km interrogation distance. This new fiber, combined with sensory polymercoated fiber, could perform both distributed temperature and methane detections. This project developed a new artificial intelligence big data algorithm approach that can effectively analyze high-resolution data harnessed by distributed fiber sensors to protect natural gas pipelines against external threats and detect internal defects induced by corrosion. Working with our industry partner, this project developed new optical fibers that support fiber sensor fabrications through polymer coating after the fibers are drawn. These new fibers eliminate the need for direct sensor fabrication when the fiber is fabricated on a fiber draw tower, which drastically expands fiber sensors' applicability. This research project has significantly advanced the distributed fiber sensing technology. It will dramatically increase the applicability and adaptability of distributed fiber sensors for a wide array of applications in energy, sustainability, and environmental science, including structural health monitoring of natural gas pipelines, oil infrastructures, hydrogen facilities, and environmental monitoring of carbon storage sites, water supply systems, and others.

03 NATURAL GAS↗

Levelized Cost of Dispensed Hydrogen for Heavy-Duty Vehicles

In this short technical report, we explore the range of levelized costs of dispensed hydrogen (H2) from hydrogen refueling (or fueling) stations (HRS) for H2 heavy-duty fuel cell electric vehicles (FCEVs) that are feasible in the 2030 timeframe. We explore different scenarios by varying hydrogen delivery distances, HRS sizes, HRS utilization rates, and economies of scale in the Hydrogen Delivery Scenario Analysis Model (HDSAM). Thus, we observe how the contribution to the levelized cost of each supply chain component changes.

30 DIRECT ENERGY CONVERSION↗

Toyota Highlander FCHV (CRADA CRD-12-00469 Final Report)

This project relates to the loan of four Toyota Mirai FCEV-adv vehicles to NLR to provide a load (vehicles to fill with hydrogen) to our fueling station research facility to study hydrogen fueling infrastructure performance using 700 bar precooled hydrogen at ESIF’s Hydrogen Infrastructure Testing and Research Facility (HITRF) facility.

33 ADVANCED PROPULSION SYSTEMS↗

Hydrogen Transportation and Distributed Energy Systems Risk and Feasibility Assessment for Airport Facilities - CRADA 555 (Abstract)

This CRADA presents the strategy that Pacific Northwest National Laboratory (PNNL) and Sandia National Laboratories (SNL) will take to support PDX in performing a risk assessment for several hydrogen deployment scenarios. It is intended that the deployment of hydrogen at PDX could serve several roles, including decarbonizing its bus fleet and building out a distributed energy system which could also be used to facilitate emergency operations. PDX’s initial plans concern replacing their current fleet of 28 busses with FCEBs. To do so, PDX will need to deploy the hydrogen systems needed to support the buses. This includes hydrogen storage, production, delivery, filling, compression, and maintenance. PDX also has long range plans to build a distributed energy system to support normal and resilient operations. This study will investigate the risks of each plan individually, and a combined plan which serves both. Additionally, PDX is in an area with the potential for high seismic activity, as such this work will also include a seismic risk assessment. A detailed risk assessment using PDX as a test case is necessary to ensure the deployment of large-scale hydrogen is successful and to understand the benefits or drawbacks in contrast to electric only technologies. Many technologies have been proposed that claim to utilize hydrogen for both transportation and distributed energy systems; however, these technologies need to be analyzed as they apply to an actual site. The physical infrastructure and hydrogen use cases for PDX will be analyzed, a risk assessment will be performed on the hydrogen infrastructure and distributed energy system. These assessments will be useful for understanding how each of these technologies would perform as applied to a large public facility and public safety. The results of this CRADA, and an impact of the DOE funding, will evaluate hydrogen as a key fuel for PDX and will accelerate by several years availability of hydrogen, fuel cells, and other low-carbon technologies.

08 HYDROGEN↗

Federal Oversight of Hydrogen Systems

The application of hydrogen as an energy carrier has been expanding into industrial and transportation sectors enabling sustainable energy resources and providing a zero-emission energy infrastructure. The hydrogen supply infrastructure includes processes from production and storage, to transportation and distribution, to end use. Each portion of the hydrogen supply infrastructure is regulated by international, federal, state, and local entities. Regulations are enforced by entities which provide guidance and updates as necessary. While energy sources such as natural gas are currently regulated via the Code of Federal Regulations and United States Code, there might be some ambiguity as to which regulations are applicable to hydrogen and where regulatory gaps may exist. This report contains an overview of the regulations that apply to hydrogen, and those that may indirectly cover hydrogen as an energy carrier participating in a sustainable zero emission global energy system. As part of this effort, the infrastructure of hydrogen systems and regulation enforcement entities are defined, and a visual map and reference table are developed. This regulatory map and table can be used to identify the boundaries of federal oversight for each component of the hydrogen supply value chain which includes production, storage, distribution, and use.

08 HYDROGEN↗

Refueling Infrastructure Scoping and Feasibility Assessment for Hydrogen Rail Applications

The feasibility and component cost of hydrogen rail refueling infrastructure is examined. Example reference stations can inform future studies on components and systems specifically for hydrogen rail refueling facilities. All of the 5 designs considered assumed the bulk storage of liquid hydrogen on-site, from which either gaseous or liquid hydrogen would be dispensed. The first design was estimated to refuel 10 multiple unit trains per day, each train containing 260 kg of gaseous hydrogen at 350 bar on-board. The second base design targeted the refueling of 50 passenger locomotives, each with 400 kg of gaseous hydrogen on-board at 350 bar. Variations from this basic design were made to consider the effect of two different filling times, two different hydrogen compression methods, and two different station design approaches. For each design variation, components were sized, approximate costs were estimated for major components, and physical layouts were created. For both gaseous hydrogen-dispensing base designs, the design of direct-fill using a cryopump design was the lowest cost due to the high cost of the cascade storage system and gas compressor. The last three base designs all assumed that liquid hydrogen was dispensed into tender cars for freight locomotives that required 7,500 kg of liquid hydrogen, and the three different designs assumed that 5, 50, or 200 tender cars were refueled every day. The total component costs are very different for each design, because each design has a very different dispensing capacity. The total component cost for these three designs are driven by the cost of the liquid hydrogen tank; additionally, delivering that much liquid hydrogen to the refueling facility may not be practical. Many of the designs needed the use of multiple evaporators, compressors, and cryopumps operating in parallel to meet required flow rates. In the future, the components identified here can be improved and scaled-up to better fit the needs of heavy-duty refueling facilities. This study provides basic feasibility and first-order design guidance for hydrogen refueling facilities serving emerging rail applications.

08 HYDROGEN↗

Microstructural Engineering and Accelerated Test Method Development to Achieve Low Cost, High Performance Solutions for Hydrogen Storage and Delivery

This project made advancements in developing lower cost steel alloys with novel microstructural design for use in hydrogen refueling infrastructure such as storage, compressors, and dispensing components, and utilizing accelerated test methods to efficiently evaluate variations in alloy and microstructure design. The project specifically sought to design alloys with lower nickel contents to reduce alloy cost, which was accomplished through substituting manganese for nickel along with other alloy additions to control deformation characteristics known to be important for hydrogen embrittlement resistance. Through Mn substitutions for nickel, austenitic and duplex austenite-ferrite steels were successfully developed with lower cost than currently available commercial stainless steel products that are employed for hydrogen refueling infrastructure. The steels were processed to achieve comparable strength and toughness in hydrogen environments as the commercially available steels containing high Ni contents. To evaluate mechanical performance in hydrogen, a testing methodology was employed to compare ubiquitous laboratory testing using electrochemical hydrogen charging in a liquid electrolyte to less accessible high pressure gaseous testing. While the application of these steels is in high pressure gaseous environments, the electrochemical hydrogen charging tests produced comparable results. Additionally, the Los Alamos Neutron Scatting Center enabled characterization of deformation mechanisms of the steel alloys in the presence of hydrogen, which has been associated with steel alloy characteristics associated with hydrogen embrittlement. Finally, a fracture mechanics based test bed model was developed to predict the influence of hydrogen gas pressure and fatigue conditions on fatigue lifetimes of pressure vessel steels. Together, these developments can be employed to enable lower cost hydrogen fueling infrastructure and more reliable prediction of steel alloy components in hydrogen service conditions. In particular, the newly alloys have the potential to replace stainless steels, having demonstrated comparable performance at substantially reduced cost.

08 HYDROGEN↗

Sustainable hydrogen manufacturing via renewable-integrated intensified process for refueling stations

The widescale consumer adoption of hydrogen fuel cell electric vehicles (HFCEVs) is currently hindered by the high cost of small-scale hydrogen generation and the lack of extensive hydrogen refueling infrastructure. Natural gas-based hydrogen is cheaper when produced in large volumes but is also associated with high CO 2 emissions. To counter these challenges, we propose a hybrid approach where both natural gas and renewables are integrated in a synergistic manner using a dynamic process intensification technology that can be deployed on-site for meeting local demands of refueling stations. The technology is based on sorption enhanced steam methane reforming (SE-SMR) that utilizes a combination of reaction with in-situ CO 2 adsorption for enhancing process modularity, productivity and efficiency thereby outperforming conventional SMR at small scale. We develop a mixed integer linear programming (MILP)-based optimization framework for simultaneous design and scheduling of the SE-SMR process. The simultaneous optimization provides a synergistic combination whereby the renewables allow sustainable hydrogen manufacturing and the dynamic SE-SMR allows optimal use of the intermittency of the renewables. The U.S. nationwide analysis indicates that for futuristic renewable prices and a hydrogen production capacity of 2 ton/day, hydrogen can be produced at 50% less cost compared to the current cost of small-scale hydrogen generation. Finally, the city-wise analysis with varying hydrogen demand shows that even with just 5% HFCEV market penetration level, hydrogen production cost less than $3/kg can be obtained at small scales across the United States with even cheaper hydrogen for large cities.

08 HYDROGEN↗

Hydrogen Production, Grid Integration, and Scaling for the Future

The Hydrogen Production, Grid Integration, and Scaling for the Future project will inform clean hydrogen production deployment across the planning, procurement, and operation stages of hydrogen production on the grid. Hydrogen production from renewables is a clean source of fuel which is near zero for greenhouse gas emissions and criteria pollutants. The results from this project will inform entities looking to build clean energy projects that produce good paying jobs in manufacturing, installation, maintenance and operation of these facilities. This project provides system characterization examples, multiple configurations, optimizations, and suggested metering and custody transfer points through multiple scenarios and hardware testing of NREL's state-of-the-art 1.25 MW polymer electrolyte membrane (PEM) electrolyzer system to characterize system performance in relevant scenarios. This work also creates a digital twin for emulation in the Advanced Research on Integrated Systems (ARIES) virtual environment and performs hardware-in-the-loop (HIL) testing of pilot-scale, decentralized, and centralized hydrogen systems.

centralized hydrogen production↗