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The Cosmic Evolution of C IV Absorbers at 1.4 < z < 4.5: Insights from 100,000 Systems in DESI Quasars

We present the largest catalog to date of triply ionized carbon (C IV ) absorbers detected in quasar spectra from the Dark Energy Spectroscopic Instrument. Using an automated matched-kernel convolution method with adaptive signal-to-noise thresholds, we identify 101,487 C IV systems in the redshift range 1.4 < z < 4.5 from 300,637 quasar spectra. Completeness is estimated via Monte Carlo simulations, and the catalog is 50% complete at EW C IV ≥ 0.4 Å. The differential equivalent width frequency distribution declines exponentially and shows weak redshift evolution. The absorber incidence per unit comoving path increases by a factor of 2–5 from z ≈ 4.5 to z ≈ 1.4, with stronger redshift evolution for strong systems. Using column densities derived from the apparent optical depth method, we constrain the cosmic mass density of C IV , Ω C IV , which increases by a factor of ∼3.8 from (0.82 ± 0.05) × 10 −8 at z ≈ 4.5 to (3.16 ± 0.2) × 10 −8 at z ≈ 1.4. From Ω C IV , we estimate a lower limit on intergalactic medium metallicity ${\mathrm{log}}({Z}_{{\rm{IGM}}}/{Z}_{\odot })\gtrsim -3.25$ at z ∼ 2.3, with a smooth decline at higher redshifts. These trends trace the cosmic star formation history and He II photoheating rate, suggesting a link between C IV enrichment, star formation, and UV background over ∼3 Gyr. The catalog also provides a critical resource for future studies connecting circumgalactic metals to galaxy evolution, especially near cosmic noon.

79 ASTRONOMY AND ASTROPHYSICS

Onset of Cosmic Reionization: Evidence of an Ionized Bubble Merely 680 Myr After the Big Bang

While most of the intergalactic medium (IGM) today is permeated by ionized hydrogen, it was largely filled with neutral hydrogen for the first 700 million years after the big bang. The process that ionized the IGM (cosmic reionization) is expected to be spatially inhomogeneous, with fainter galaxies likely playing a significant role. However, we still have only a few direct constraints on the reionization process. Here we report spectroscopic confirmation of two galaxies and very likely a third galaxy in a group (hereafter EGS77) at redshift z = 7.7, merely 680 Myr after the big bang. The physical separation among the three members is <0.7 Mpc. We estimate the radius of ionized bubble of the brightest galaxy to be about 1.02 Mpc, and show that the individual ionized bubbles formed by all three galaxies likely overlap significantly, forming a large yet localized ionized region, indicative of inhomogeneity in the reionization process. It is striking that two of three galaxies in EGS77 are quite faint in the continuum, thanks to our selection using their Lyα line emission in the narrowband filter. Indeed, one is the faintest spectroscopically confirmed galaxy yet discovered at such high redshifts. Our observations provide direct constraints on the process of cosmic reionization, and allow us to investigate the properties of sources responsible for reionizing the universe.

Reionization

The 21-cm Signal From the Cosmic Dawn: Metallicity Dependence of High Mass X-Ray Binaries

X-rays from high-mass X-ray binaries (HMXBs) are likely the main source of heating of the intergalactic medium (IGM) during Cosmic Dawn (CD), before the completion of reionization. This Epoch of Heating (EoH; z ∼10–15) should soon be detected via the redshifted 21-cm line from neutral hydrogen, allowing us to indirectly study the properties of HMXBs in the unseen, first galaxies. Low-redshift observations, as well as theoretical models, imply that the integrated X-ray luminosity to star formation rate of HMXBs (L_X/SFR) should increase in metal-poor environments, typical of early galaxies. Here, we study the impact of the metallicity (Z) dependence of L_X/SFR during the EoH. For our fiducial models, galaxies with star formation rates of order 10^(−3)–10^(−1)M_⊙ yr^(−1) and metallicities of order 10^(−3) –10^(−2) Z_⊙ are the dominant contributors to the X-ray background (XRB) during this period. Different L_X/SFR–Z relations result in factors of ∼ 3 differences in these ranges, as well as in the mean IGM temperature and the large-scale 21-cm power, at a given redshift. We compute mock 21-cm observations adopting as a baseline a 1000 h integration with the upcoming Square Kilometer Array (SKA) for two different L_X/SFR–Z relations. We perform inference on these mock observations using the common simplification of a constant L_X/SFR, finding that constant L_X/SFR models can recover the IGM evolution of the more complicated L_X/SFR–Z simulations only during the EoH. At z < 10, where the typical galaxies are more polluted, constant L_X/SFR models overpredict the XRB and its relative contribution to the early stages of the reionization.

galaxies: high-redshift

Line Emission Mapper Probing Physics of Cosmic Ecosystems

The Line Emission Mapper (LEM) is an X-ray Probe for the 2030s that will answer the outstanding questions of the Universe’s structure formation. It will also provide transformative new observing capabilities for every area of astrophysics, and to heliophysics and planetary physics as well. LEM’s main goal is a comprehensive look at the physics of galaxy formation, including stellar and black-hole feedback and flows of baryonic matter into and out of galaxies. These processes are best studied in X-rays; as emphasized by the 2020 Decadal Survey, emission-line mapping is the pressing need in this area. LEM will use a large microcalorimeter array/IFU (that builds on Athena XIFU technology developments), covering a 30 × 300 field with 1000 angular resolution, to map the soft Xray line emission from objects that constitute galactic ecosystems. These include supernova remnants, star-forming regions, superbubbles, galactic outflows (such as the Fermi/eROSITA bubbles in the Milky Way and their analogs in other galaxies), the Circumgalactic Medium in the Milky Way and other galaxies, and the Intergalactic Medium at the outskirts and beyond the confines of galaxies and clusters. LEM’s 1–2 eV spectral resolution in the 0.2–2 keV band will make it possible to disentangle the faintest emission lines in those objects from the bright Milky Way foreground, providing groundbreaking measurements of the physics of these plasmas, from temperatures, densities, chemical composition to gas dynamics. While the mission is optimized to provide critical observations that will push our understanding of galaxy formation, LEM will provide transformative capability for all classes of astrophysical objects, from the Earth’s magnetosphere, planets and comets to the interstellar medium and X-ray binaries in nearby galaxies, AGN, and cooling gas in galaxy clusters. In addition to pointed observations, LEM will perform a shallow all-sky survey that will dramatically expand the discovery space.

Ralph Kraft

The Interaction of Hot and Cold Gas in the Disk and Halo of Galaxies

Most of the thermal energy in the Galaxy and perhaps most of the baryons in the Universe are found in hot (log T approximately 5.5 - 7) gas. Hot gas is detected in the local interstellar medium, in supernova remnants (SNR), the Galactic halo, galaxy clusters and the intergalactic medium (IGM). In our own Galaxy, hot gas exists in large superbubbles up to several hundred pc in diameter that locally dominate the interstellar medium (ISM) and determine its thermal and dynamic evolution. While X-ray observations using ROSAT, Chandra and XMM have allowed us to make dramatic progress in mapping out the morphology of the hot gas and in understanding some of its spectral characteristics, there remain fundamental questions that are unanswered. Chief among these questions is the way that hot gas interacts with cooler phase gas and the effects these interactions have on hot gas energetics. The theoretical investigations we proposed in this grant aim to explore these interactions and to develop observational diagnostics that will allow us to gain much improved information on the evolution of hot gas in the disk and halo of galaxies. The first of the series of investigations that we proposed was a thorough exploration of turbulent mixing layers and cloud evaporation. We proposed to employ a multi-dimensional hydrodynamical code that includes non-equilibrium ionization (NEI), radiative cooling and thermal conduction. These models are to be applied to high velocity clouds in our galactic halo that are seen to have O VI by FUSE (Sembach et ai. 2000) and other clouds for which sufficient constraining observations exist.

Slavin, Jonathan

Populations of High-Luminosity Density-Bounded HII Regions in Spiral Galaxies? Evidence and Implications

In this paper we present evidence that the H II regions of high luminosity in disk galaxies may be density bounded, so that a significant fraction of the ionizing photons emitted by their exciting OB stars escape from the regions. The key piece of evidence is the presence, in the Ha luminosity functions (LFs) of the populations of H iI regions, of glitches, local sharp peaks at an apparently invariant luminosity, defined as the Stromgren luminosity Lstr), LH(sub alpha) = Lstr = 10(sup 38.6) (+/- 10(sup 0.1)) erg/ s (no other peaks are found in any of the LFs) accompanying a steepening of slope for LH(sub alpha) greater than Lstr This behavior is readily explicable via a physical model whose basic premises are: (a) the transition at LH(sub alpha) = Lstr marks a change from essentially ionization bounding at low luminosities to density bounding at higher values, (b) for this to occur the law relating stellar mass in massive star-forming clouds to the mass of the placental cloud must be such that the ionizing photon flux produced within the cloud is a function which rises more steeply than the mass of the cloud. Supporting evidence for the hypothesis of this transition is also presented: measurements of the central surface brightnesses of H II regions for LH(sub alpha) less than Lstr are proportional to L(sup 1/3, sub H(sub alpha)), expected for ionization bounding, but show a sharp trend to a steeper dependence for LH(sub alpha) greater than Lstr, and the observed relation between the internal turbulence velocity parameter, sigma, and the luminosity, L, at high luminosities, can be well explained if these regions are density bounded. If confirmed, the density-bounding hypothesis would have a number of interesting implications. It would imply that the density-bounded regions were the main sources of the photons which ionize the diffuse gas in disk galaxies. Our estimates, based on the hypothesis, indicate that these regions emit sufficient Lyman continuum not only to ionize the diffuse medium, but to cause a typical spiral to emit significant ionizing flux into the intergalactic medium. The low scatter observed in Lstr, less than 0.1 mag rms in the still quite small sample measured to date, is an invitation to widen the data base, and to calibrate against primary standards, with the aim of obtaining a precise, approx. 10(exp 5) solar luminosity widely distributed standard candle.

Beckman, J. E.

On the X-Ray Spectral Energy Distributions of Star-Forming Galaxies: The 0.3-30 keV Spectrum of the Low-Metallicity Starburst Galaxy VV 114

Binary population synthesis combined with cosmological models suggests that X-ray emission from star-forming galaxies, consisting primarily of emission from X-ray binaries(XRBs)and the hot interstellar medium(ISM),could be an important, and perhaps dominant, source of heating of the intergalactic medium prior to the epoch of reionization. However, such models rely on empirical constraints for the X-ray spectral energy distributions(SEDs)of star-forming galaxies, which are currently lacking for low-metallicity galaxies. Using a combination of Chandra, XMM-Newton, and NuSTAR observations, we present new constraints on the 0.3–30 keV SED of the low-metallicity starburst galaxy VV 114, which is known to host several ultraluminous X-ray sources(ULXs)with luminosities above 1040erg s−1. We use an archival Chandra observation of VV 114 to constrain the contributions to the X-ray SED from the major X-ray-emitting components of the galaxy and newly acquired, nearly simultaneous XMM-Newton and NuSTAR observations to extend the spectral model derived from Chandra to cover the 0.3–30 keV range. Using our best-fit galaxy-wide spectral model, we derive the 0.3–30 keV SED ofVV114, which we find is dominated by emission from the XRB population, and in particular ULXs, at energies>1.5 keV, and which we find to have an elevated galaxy-integrated X-ray luminosity per unit star formation rate relative to higher-metallicity star-forming galaxies. We discuss our results in terms of the effect of metallicity on XRB populations and the hot ISM, as well as the importance of X-ray emission from star-forming galaxies in the high-redshift universe.

Kristen Garofali

Enrichment of intergalactic matter.

The primordial gas out of which the Galaxy condensed may have been significantly enriched in heavy elements. A specific mechanism of enrichment is described, in which quasi-stellar sources eject enriched matter into the intergalactic medium. This matter is recycled through successive generations of these sources, and is progressively enriched. The enriched intergalactic matter is accreted by the protogalaxy and we find, for rates of mass ejection by quasi-stellar sources equal to about one solar mass per year in heavy elements, that this mechanism can account for the heavy-element abundances in the oldest Population II stars. Expressions are given for the degree of enrichment of the intergalactic gas as a function of redshift, and we show that our hypothesis implies that the present density of intergalactic gas must be at least a factor 3 larger than the mean density in galaxies at the present epoch.

Silk, J.

The Evolution of Galaxies and Clusters at High Spatial Resolution with Advanced X-ray Imaging Satellite (AXIS)

Stellar and black hole feedback heat and disperse surrounding cold gas clouds, launching gas flows off circumnuclear and galactic disks, producing a dynamic interstellar medium. On large scales bordering the cosmic web, feedback drives enriched gas out of galaxies and groups, seeding the intergalactic medium with heavy elements. In this way, feedback shapes galaxy evolution by shutting down star formation and ultimately curtailing the growth of structure after the peak at redshift 2–3. To understand the complex interplay between gravity and feedback, we must resolve both the key physics within galaxies and map the impact of these processes over large scales, out into the cosmic web. The Advanced X-ray Imaging Satellite (AXIS) is a proposed X-ray probe mission for the 2030s with arcsecond spatial resolution, large effective area, and low background. AXIS will untangle the interactions of winds, radiation, jets, and supernovae with the surrounding interstellar medium across the wide range of mass scales and large volumes driving galaxy evolution and trace the establishment of feedback back to the main event at cosmic noon. This white paper is part of a series commissioned for the AXIS Probe mission concept; additional AXIS white papers can be found at the AXIS website.

47 OTHER INSTRUMENTATION

The dynamic interstellar medium in NGC 4438

We present multiwavelength observations of the interstellar medium in the disturbed galaxy NGC 4438. We find extended emission-line filaments, which are kinematically unrelated to the galaxy disk. For one of these features, an extended loop, we propose a scheme in which the 'bubble' seen at radio wavelengths has swept a clear path for outflowing material from the nucleus to ionize more distant material. Another radial emission-line feature might represent shocks in the disk along a gravitationally-defined caustic produced during a tidal encounter, or a 'searchlight beam' escaping the inner dusty regions of the galaxy. Energy-balance arguments favor the shock picture, but further study will be important in understanding this feature. Emission-line ratios indicate that shocks may be important in the energetics of the interstellar medium (ISM) through much of the disk of NGC 4438; the alternative is star formation in a uniformly very dense ISM. We use K-band data to locate the stellar peak of the galaxy, which is just outside the prominent radio-continuum loop or shell feature. The nucleus itself is at most a very weak radio source. However, the more extended radio structure shows that energetic events have taken place in the innermost few hundred parsees of NGC 4438. The interstellar medium of NGC 4438 may show at once the impact of nuclear energy input (from an AGN or cocooned starburst), perturbation by the companion NGC 4435, and interaction with the dense intergalactic medium in the Virgo core.

Keel, William C.

The ionization of the diffuse ionized gas

The diffuse ionized gas (DIG), responsible for producing the faint but pervasive H(sub alpha), requires 15% of the power of all Galactic O stars for its ionization. No other source of ionization seems practical. The spectrum is strong in low stages of ionization (N II, SII), weak in (O III), and very weak in (O I) lambda 6300, at least in one well-observed direction, all significantly different from denser H II regions. We give low-density, low-excitation photoionization models that explain the observed spectrum. The lambda 6300 observation eliminates the simplest models for the DIG (Mathis 1986), in which neutral H extends beyond the edge of the very dilute stellar radiation field. Our present models include two components. One, representing the edges of interstellar H I clouds, extends to the point where H becomes neutral. In the second, the fraction of H(sup o) is not allowed to exceed 0.05 to 0.1. Both have very low values of the ionization parameter, or ratio of the number densities of ionizing photons to electrons. The ionization parameter required by our models is shown to be compatible with observed values of photon and electron densities in the diffuse interstellar medium. Interstellar dust is not important in either model. Predictions of the model are that the Galaxy is leaking about 4% of the ionizing radiation of at least the local O stars into the intergalactic medium, that (O II) lambda 3727 approximately equals 1.1 H(sub alpha), and that He(sup +)/H (sup +)) approximately equals 0.6 He/H. A major difficul ty of this picture is having ionizing radiation propagate from the ionizing stars in the plane of the Galaxy to the DIG. We suggest, as do Miller & Cox (1993), that the ionizing radiation from O stars produces holes or tunnels in the distribution of neutral H as seen from their positions, while we see a sky covered with H I sheets or filaments because we are not near a source of ionizing radiation. With our models, several interfaces between ionized and neutral gas are allowed before the observational limit on lambda 6300 is exceeded. Another difficulty is the gas-phase N(S(sup +))/N(H(sup o)) ratio toward the high-latitude star HD 93521 (Spitzer & Fitzpatrick 1993). We require (S/H) to be somewhat lower than solar, either because of depletion onto grains or a Galactic abundance gradient, so that the S(sup +) can be produced in each of separate H(sup o) and H(sup +) regions.

Domgorgen, H.

Suppression of pair beam instabilities in a laboratory analogue of blazar pair cascades

The generation of dense electron–positron pair beams in the laboratory can enable direct tests of theoretical models of γ-ray bursts and active galactic nuclei. We have successfully achieved this using ultrarelativistic protons accelerated by the Super Proton Synchrotron at (CERN). In the first application of this experimental platform, the stability of the pair beam is studied as it propagates through a meter-length plasma, analogous to TeV γ-ray-induced pair cascades in the intergalactic medium. It has been argued that pair beam instabilities disrupt the cascade, thus accounting for the observed lack of reprocessed GeV emission from TeV blazars. If true, this would remove the need for a moderate strength intergalactic magnetic field to explain the observations. We find that the pair beam instability is suppressed if the beam is not perfectly collimated or monochromatic, hence the lower limit to the intergalactic magnetic field inferred from γ-ray observations of blazars is robust.

blazar jets

The generation of a multiphase medium in ‘Splash’ bridge systems: towards an understanding of star formation suppression in turbulent galaxy systems

ABSTRACT Cloud–cloud collisions in splash bridges produced in gas-rich disc galaxy collisions offer a brief but interesting environment to study the effects of shocks and turbulence on star formation rates in the diffuse intergalactic medium, far from the significant feedback effects of massive star formation and active galactic nucleus. Expanding on our earlier work, we describe simulated collisions between counter-rotating disc galaxies of relatively similar mass, focusing on the thermal and kinematic effects of relative inclination and disc offset at the closest approach. This includes essential heating and cooling signatures, which go some way towards explaining the luminous power in H$_2$ and [C ii] emission in the Taffy bridge, as well as providing a partial explanation of the turbulent nature of the recently observed compact CO-emitting clouds observed in Taffy by the Atacama Large Millimeter Array (ALMA). The models show counter-rotating disc collisions result in swirling, shearing kinematics for the gas in much of the post-collision bridge. Gas with little specific angular momentum due to collisions between counter-rotating streams accumulates near the centre of mass. The disturbances and mixing in the bridge drive continuing cloud collisions, differential shock heating, and cooling throughout. A wide range of relative gas phases and line-of-sight velocity distributions are found in the bridges, depending sensitively on initial disc orientations, and the resulting variety of cloud collision histories. Most cloud collisions can occur promptly or persist for quite a long duration. Cold and hot phases can largely overlap throughout the bridge or can be separated into different parts of the bridge.

79 ASTRONOMY AND ASTROPHYSICS

X-ray studies of galactic and intergalactic gas in the Pegasus I cluster

Einstein Observatory IPC observations of Pegasus I show hot gas in a low density intergalactic medium as well as in a galactic medium within each of the dominant elliptical galaxies, NGC 7619 and NGC 7626. The short central cooling times inferred, of 100 million years or less, suggest that the galaxies contain cooling flows of about 1 solar mass/yr. The intergalactic gas, which is about 5 times less dense than in the least dense of the known Abell clusters, is incapable of stripping the hot gas from the elliptical galaxies or the neutral gas from the spirals. The gas around NGC 7619 appears to be influencing one of the radio lobes of NGC 7626.

Canizares, C. R.

Supernovae, supernova remnants, and superbubbles

Supernovae, supernova remmants, and superbubbles in the interstellar medium are reviewed, with an emphasis on infrared studies of these phenomena. Superbubbles are likely to be relevant for understanding such Galactic and extragalactic issues as the photoionization of gas in the Galactic halo, 'superwinds,' and the contribution of 'starbursts' to photoionization of the intergalactic medium.

Shull, J. Michael

Interim Report of the Astronomy Spacelab Payloads Study: Ultraviolet and Optical Astronomy - Volume 2

The Space Shuttle will comprise NASA's primary transportation system into near-earth orbit during the 1980s. The Shuttle will provide the astronomical community with a major new capability to send a wide variety of instrumentation into orbit, to utilize it there under manned or automatic control for periods from seven to thirty days, and to return it to the ground. To this end the European Space Research Organization (ESRO) is developing Spacelab, an array of interchangeable components -pressurized manned modules, unpressurized pallets and related support systems - to be mounted in the Shuttle payload bay. Spacelab will offer important opportunities to carry out astronomical research with instruments optimized for specific objectives. With a high flight frequency and with the ability to modify or interchange telescopes and instruments between flights, one will not need to make rigid long-term commitments to specific and compromised telescope/instrument/ detector combinations as is the case for automated satellites. Observational techniques demanding the physical return of data and equipment - in particular the use of photographic film, instruments requiring tight calibration controls, cryogens, high-risk detectors and degradeable optical coatings -will open research areas not readily addressed by automated satellites. Although Shuttle flight duration will be limited to periods from seven to thirty days, substantial data can be obtained with a single instrument on short missions, if targets are carefully selected and prioritized, and a large number of instruments can be accommodated on a single flight. Important astronomical data are regularly obtained on sounding rocket flights of five minutes duration. Spacelab will provide far longer observing periods for large and small telescopes, with resources greatly exceeding those of sounding rockets, while retaining much of the sounding rocket philosophy in terms of instrument flexibility, simplicity, reliability assurance and development costs. The Ultraviolet and Optical Astronomy Program on Spacelab is being planned to provide optical astronomers with relatively simple and regular access to the extended wavelength coverage, the superior image quality and the darkness of the night sky available above the earth's atmosphere. In a rapidly evolving science one cannot predict what problems will be timely in the 1980s. Extrapolating from the current epoch, however, one can envision a continuing interest in such areas as the structure, composition and phenomenology of planetary surfaces and atmospheres; the composition and physical nature of the interstellar medium; the composition, structure and life history of stars, especially those in advanced stages of evolution; the stellar population of other galaxies; such enigmatic phenomena as X-ray binary black holes, pulsars, active galactic nuclei and quasars; large scale interactions between galaxies and the nature of the intergalactic medium; precise calibration of the Hubble law for the expansion of the universe; the average density of the universe; and the existence of extraterrestrial life.

Source record

The proximity profile of intergalactic He II resonance absorption toward high-redshift QSOs

The Gunn-Peterson effect predicts that an absorption trough should be associated with any resonance line arising in the intergalactic medium (IGM), extending blueward of the line in the QSO's rest frame. We show that such an absorption trough will not generally have a sharp edge at the QSO's redshift but should develop gradually toward shorter wavelengths. This proximity profile of the Gunn-Peterson trough arises because diffuse intergalactic gas in the vicinity of the QSO is more highly ionized than the general IGM. We consider the case of a uniform IGM in approximate photoionization equilibrium with a metagalactic UV background and investigate the proximity profile of He II lambda 304, which might be observable in QSOs with Z(sub Q) approximately 3. Assuming the QSO continuum extends beyond the He II ionization edge, the proximity profile has a characteristic width of delta z(sub p) = delta lambda/304 is approximately 0.1 f is the QSO Lyman limit luminosity in units of 10(exp 31) ergs/s/Hz averaged over the past approximately 10(exp 7) yr, omega(sub I) is the IGM density near (is less than or equal to 10 Mpc) the QSO, omega(sub b) is the normalized baryon density predicted by standard big band necleosynthesis, and f is a factor of order unity which depends weakly on several other factors. Application of this result to the reported detection of the He II Gunn-Peterson effect in Q0302-003 (Jakobsen et al. 1994) suggests that omega(sub I) is approximately equal to omega(sub b), some three orders of magnitude larger than the minimum density that may be inferred from application of the ordinary Gunn-Peterson effect to this QSO. Future observations of the He II proximity profile at higher resolution and signal-to-noise ratio in serveral ASOs should provide the means to measure the IGM density accurately.

Zheng, Wei

Chemical evolution in spiral and irregular galaxies

A brief review of models of chemical evolution of the interstellar medium in our galaxy and other galaxies is presented. These models predict the time variation and radial dependence of chemical composition in the gas as function of the input parameters; initial mass function, stellar birth rate, chemical composition of mass lost by stars during their evolution (yields), and the existence of large scale mass flows, like infall from the halo, outflow to the intergalactic medium or radial flows within a galaxy. At present there is a considerable wealth of observational data on the composition of HII regions in spiral and irregular galaxies to constrain the models. Comparisons are made between theory and the observed physical conditions. In particular, studies of helium, carbon, nitrogen and oxygen abundances are reviewed. In many molecular clouds the information we have on the amount of H2 is derived from the observed CO column density, and a standard CO/H2 ratio derived for the solar neighborhood. Chemical evolution models and the observed variations in O/H and N/O values, point out the need to include these results in a CO/H2 relation that should be, at least, a function of the O/H ratio. This aspect is also discussed.

Torres-Peimbert, S.