Voltammetry of iodine
Electrochemistry of iodine oxidation states from voltammetry of iodine chloride, iodine and iodate at rotated platinum disk and ring disk electrodes
Beran, P.↗
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Dynamics of the molecular and atomic mechanisms for the hydrogen-iodine exchange reaction.
The molecular and atomic mechanisms for the hydrogen-iodine exchange reaction are treated theoretically by means of extensive classical trajectories calculated on a reasonable potential energy surface on which the single adjustable parameter is the iodine-core effective charge. The analysis shows the molecular mechanism to be dynamically forbidden, but gives an over-all rate constant for the atomic mechanism that is in agreement with the experimental values. It is indicated that the formation of a weak H2I complex plays an important dynamical role if the atomic mechanism is limited to reactions with collision complexes involving no more than two hydrogen atoms and two iodine atoms. Excellent agreement with experiment is obtained for the rate constant for the recombination I+I+H2 yields I2+H2 and its negative temperature coefficient.
Raff, L. M.↗
Development of an iodine generator for reclaimed water purification in manned spacecraft applications
A successful 30-day test is described of a prototype Iodine Generating and Dispensing System (IGDS). The IGDS was sized to iodinate the drinking water nominally consumed by six men, 4.5 to 13.6 kg (10 to 30 lb) water per man-day with a + or - 10 to 20% variation with iodine (I2) levels of 0.5 to 20 parts per million (ppm). The I2 treats reclaimed water to prevent or eliminate microorganism contamination. Treatment is maintained with a residual of I2 within the manned spacecraft water supply. A simplified version of the chlorogen water disinfection concept, developed by life systems for on-site generation of chlorine (Cl2), was used as a basis for IGDS development. Potable water contaminated with abundant E. Coliform Group organisms was treated by electrolytically generated I2 at levels of 5 to 10 ppm. In all instances, the E. coli were eliminated.
Wynveen, R. A.↗
Automated Iodine Monitoring System Development (AIMS)
The operating principle of the automated iodine monitoring/controller system (AIMS) is described along with several design modifications. The iodine addition system is also discussed along with test setups and calibration; a facsimile of the optical/mechanical portion of the iodine monitor was fabricated and tested. The appendices include information on shuttle prototype AIMS, preliminary prime item development specifications, preliminary failure modes and effects analysis, and preliminary operating and maintenance instructions.
Source record↗
Disposal of radioactive iodine in space
The possibility of space disposal of iodine waste from nuclear power reactors is investigated. The space transportation system utilized relies upon the space shuttle, a liquid hydrogen/liquid oxygen orbit transfer vehicle, and a solid propellant final stage. The iodine is assumed to be in the form of either an iodide or an iodate, and calculations assume that the final destination is either solar orbit or solar system escape. It is concluded that space disposal of iodine is feasible.
Burns, R. E.↗
Simultaneous multiple-point velocity measurements using laser-induced iodine fluorescence
A technique is demonstrated for measuring velocity at multiple locations in a plane of a gaseous flowfield using Doppler-shifted absorption with fluorescence detection from iodine molecules, excited by a sheet of tunable single-axial-mode argon-ion laser radiation at 514.5 nm. Measurements were made simultaneously at 10,000 points in an iodine-seeded supersonic flow field with a 100 x 100 element photodiode array camera and were found to agree well with a numerical solution for the velocity field. The accuracy with which a component of velocity can be measured is limited, in the current approach, by the iodine linewidth to about 5 m/sec.
Mcdaniel, J. C.↗
Flowfield measurements in a model scramjet combustion using laser-induced iodine fluorescence
Preliminary designs were completed for an iodine mixing chamber and the optical setup to be used with a modified wind tunnel in obtaining accurate, spatially resolved measurements of variables in the flowfield of a model nonreacting scramjet combustor. Schematics of the iodine-seeded wind tunnel and a sketch of the charcoal filter for removing the iodine are included along with a cutaway section of the laboratory.
Mcdaniel, J. C., Jr.↗
Direct solar-pumped iodine laser amplifier
The improvement on the collection system of the Tarmarack Solar Simulator beam was attemped. The basic study of evaluating the solid state laser materials for the solar pumping and also the work to construct a kinetic model algorithm for the flashlamp pumped iodine lasers were carried out. It was observed that the collector cone worked better than the lens assembly in order to collect the solar simulator beam and to focus it down to a strong power density. The study on the various laser materials and their lasing characteristics shows that the neodymium and chromium co-doped gadolinium scandium gallium garnet (Nr:Cr:GSGG) may be a strong candidate for the high power solar pumped solid state laser crystal. On the other hand the improved kinetic modeling for the flashlamp pumped iodine laser provides a good agreement between the theoretical model and the experimental data on the laser power output, and predicts the output parameters of a solar pumped iodine laser.
Han, Kwang S.↗
Direct solar-pumped iodine laser amplifier
This semiannual progress report covers the period from March 1, 1987 to September 30, 1987 under NASA grant NAG1-441 entitled 'Direct solar-pumped iodine laser amplifier'. During this period Nd:YAG and Nd:Cr:GSGG crystals have been tested for the solar-simulator pumped cw laser, and loss mechanisms of the laser output power in a flashlamp-pumped iodine laser also have been identified theoretically. It was observed that the threshold pump-beam intensities for both Nd:YAG and Nd:Cr:GSGG crystals were about 1000 solar constants, and the cw laser operation of the Nd:Cr:GSGG crystal was more difficult than that of the Nd:YAG crystal under the solar-simulator pumping. The possibility of the Nd:Cr:GSGG laser operation with a fast continuously chopped pumping was also observed. In addition, good agreement between the theoretical calculations and the experimental data on the loss mechanisms of a flashlamp-pumped iodine laser at various fill pressures and various lasants was achieved.
Han, Kwang S.↗
XeCl laser pumped iodine laser using t-C4F9I
An iodine photodissociation laser using t-C4F9I as the active material was pumped by a XeCl laser. An iodine laser output energy of 3 mJ with pulse duration of 25 ns was obtained when the pumping pulse energy was 80 mJ, the iodine pressure was 70 torr, and the reflectance of the output mirror was 85 percent. The high pumping efficiency and low threshold pump power achieved in this experiment are attributable to the high absorption cross section at the pump laser wavelength (308 nm) of the iodide used.
Hwang, In Heon↗
Injectant mole-fraction imaging in compressible mixing flows using planar laser-induced iodine fluorescence
A technique is described for imaging the injectant mole-fraction distribution in nonreacting compressible mixing flow fields. Planar fluorescence from iodine, seeded into air, is induced by a broadband argon-ion laser and collected using an intensified charge-injection-device array camera. The technique eliminates the thermodynamic dependence of the iodine fluorescence in the compressible flow field by taking the ratio of two images collected with identical thermodynamic flow conditions but different iodine seeding conditions.
Hartfield, Roy J., Jr.↗
Electrochemical control of iodine disinfectant for space transportation system and space station potable water
An electrochemical microbial check valve method (EC-MCV) for controlling the iodine disinfectant in potable water (PW) for NASA's space operations was proposed. The factors affecting the design and performance of the unit were analyzed. This showed that it would be feasible to construct a recyclable unit in a small volume that will operate in either an iodine removal or addition mode. The EC-MCV should remove active iodine species rapidly from PW, but the rapid delivery rates at end-use may make complete removal of excess I(-) difficult under some conditions. Its performace change with AgI buildup needs to be investigated, as this controls the time for recycling the unit. The EC-MCV has advantages over the passive microbial check valve (MCV) method currently in use, as it would allow precise control of the I2 level and would not introduce excess I(-) to the water. The presence of oxygen in the EC-MCV needs to be investigated as it could affect the efficiency of I2 addition and excess I(-) removal.
Geer, Richard D.↗
Graphite intercalation compound with iodine as the major intercalant
Halogenated CBr(sub x)I(sub y) (1 less than y/x less than 10) was made by exposing graphite materials with interplanar spacing in the 3.35 to 3.41 A range to either pure Br2 or an I2-Br2 mixture, and then to iodine vapor containing a small amount of Br2. The electrical resistivity of this product is from 3 to 6.5 times the pristine value. The presence of a small amount of isoprene rubber in the reaction significantly increased the iodine to bromine ratio in the product. In this reaction, rubber is known to generate HBr and to slowly remove bromine from the vapor. The halogenation generally caused a 22 to 25 percent weight increase. The halogens were found uniformly distributed in the product interior. However, although the surface contains very little iodine, it has high concentrations of bromine and oxygen. It is believed that the high concentrations of bromine and oxygen in this surface cause the halogenated fiber to be more resistant to fluorine attack during subsequent fluorination to fabricate graphite fluoride fibers.
Hung, Ching-Cheh↗
An iodine hypersonic wind tunnel for the study of nonequilibrium reacting flows
A pilot scale hypersonic wind tunnel operating on pure iodine vapor has been designed and tested. The wind tunnel operates intermittently with a run phase lasting approximately 20 minutes. Successful recirculation of the iodine used during the run phase has been achieved but can be improved. Relevant issues regarding the full scale facility's design and operation, and the use of iodine as a working gas are discussed. Continuous wave laser induced fluorescence was used to monitor number densities within the plume flowfield, while pulsed laser induced fluorescence was used in an initial attempt to measure vibrational energy state population distributions. Preliminary nozzle flow calculations based on finite rate chemistry are presented.
Pham-Van-diep, G. C.↗
Inactivation of a model coliphage virus in water by iodine
Until now, NASA's space water reuse research program has not considered the transport of water-borne infectious enteric viruses; however, viral diseases probably are a signifficant concern in long-duration space missions. To simplify monitoring and prediction of pathogen distribution, model indicator strains historically have been used. In this research, the male specific RNA coliphage MS-2 is used as a model of enteric viruses due to their similar size and biochemical composition. Inactivation of some water-borne enteric viruses by iodine has previously been characterized. In this paper, iodine inactivation of the model coliphage MS-2 in buffered water is compared with earlier bench-scale disinfection survival data and with survival in iodinated simulated shower water used in a test water recycling system.
Brion, Gail M.↗
Iodine susceptibility of pseudomonads grown attached to stainless steel surfaces
Pseudomonads were adapted to grow in phosphate-buffered water and on stainless steel surfaces to study the iodine sensitivity of attached and planktonic cells. Cultures adapted to low nutrient growth were incubated at room temperature in a circulating reactor system with stainless steel coupons to allow biofilm formation on the metal surfaces. In some experiments, the reactor was partially emptied and refilled with buffer at each sampling time to simulate a "fill-and-draw" water system. Biofilms of attached bacteria, resuspended biofilm bacteria, and reactor suspension, were exposed to 1 mg l-1 iodine for 2 min. Attached bacterial populations which established on coupons within 3 to 5 days displayed a significant increase in resistance to iodine. Increased resistance was also observed for resuspended cells from the biofilm and planktonic bacteria in the system suspension. Generally, intact biofilms and resuspended biofilm cells were most resistant, followed by planktonic bacteria and phosphate buffer cultures. Thus, biofilm formation on stainless steel surfaces within water systems can result in significantly increased disinfection resistance of commonly-occurring water-borne bacteria that may enhance their ability to colonise water treatment and distribution systems.
NASA Program Environmental Health↗
Iodine Tagging Velocimetry in a Mach 10 Wake
A variation on molecular tagging velocimetry (MTV) [1] designated iodine tagging velocimetry (ITV) is demonstrated. Molecular iodine is tagged by two-photon absorption using an Argon Fluoride (ArF) excimer laser. A single camera measures fluid displacement using atomic iodine emission at 206 nm. Two examples ofMTVfor cold-flowmeasurements areN2OMTV [2] and Femtosecond Laser Electronic Excitation Tagging [3]. These, like most MTV methods, are designed for atmospheric pressure applications. Neither can be implemented at the low pressures (0.1- 1 Torr) in typical hypersonic wakes. Of all the single-laser/singlecamera MTV approaches, only Nitric-Oxide Planar Laser Induced Fluorescence-based MTV [4] has been successfully demonstrated in a Mach 10 wake. Oxygen quenching limits transit times to 500 ns and accuracy to typically 30%. The present note describes the photophysics of the ITV method. Off-body velocimetry along a line is demonstrated in the aerothermodynamically important and experimentally challenging region of a hypersonic low-pressure near-wake in a Mach 10 air wind tunnel. Transit times up to 10 μs are demonstrated with conservative errors of 10%.
Balla, Robert Jeffrey↗
Iodine Hall Thruster Propellant Feed System for a CubeSat
The components required for an in-space iodine vapor-fed Hall effect thruster propellant management system are described. A laboratory apparatus was assembled and used to produce iodine vapor and control the flow through the application of heating to the propellant reservoir and through the adjustment of the opening in a proportional flow control valve. Changing of the reservoir temperature altered the flowrate on the timescale of minutes while adjustment of the proportional flow control valve changed the flowrate immediately without an overshoot or undershoot in flowrate with the requisite recovery time associated with thermal control systems. The flowrates tested spanned a range from 0-1.5 mg/s of iodine, which is sufficient to feed a 200-W Hall effect thruster.
Polzin, Kurt A.↗