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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Infrared and X-Ray Spectroscopy of the Kes 75 Supernova Remnant Shell: Characterizing the Dust and Gas Properties

We present deep Chandra observations and Spitzer Space Telescope infrared (IR) spectroscopy of the shell in the composite supernova remnant (SNR) Kes 75 (G29.7-0.3). The remnant is composed of a central pulsar wind nebula and a bright partial shell in the south that is visible at radio, IR, and X-ray wavelengths. The X-ray emission can be modeled by either a single thermal component with a temperature of approximately 1.5 keY, or with two thermal components with temperatures of 1.5 and 0.2 keY. Previous studies suggest that the hot component may originate from reverse-shocked supernova (SN) ejecta. However, our new analysis shows no definitive evidence for enhanced abundances of Si, S, Ar, Mg, and Fe, as expected from SN ejecta, or for the IR spectral signatures characteristic of confirmed SN condensed dust, thus favoring a circumstellar or interstellar origin for the X-ray and IR emission. The X-ray and IR emission in the shell are spatially correlated, suggesting that the dust particles are collisionally heated by the X-ray emitting gas. The IR spectrum of the shell is dominated by continuum emission from dust with little, or no line emission. Modeling the IR spectrum shows that the dust is heated to a temperature of approximately 140 K by a relatively dense, hot plasma that also gives rise to the hot X-my emission component. The density inferred from the IR emission is significantly higher than the density inferred from the X-ray models, suggesting a low filling factor for this X-my emitting gas. The total mass of the warm dust component is at least 1.3 x 10(exp -2) x solar mass, assuming no significant dust destruction has occurred in the shell. The IR data also reveal the presence of an additional plasma component with a cooler temperature, consistent with the 0.2 keV gas component. Our IR analysis therefore provides an independent verification of the cooler component of the X-ray emission. The complementary analyses of the X-ray and IR emission provide quantitative estimates of density and filling factors of the clumpy medium swept up by the SNR.

Temim, Tea↗
NASA NTRS2009

Infrared and X-Ray Spectroscopy of the KES 75 Supernova Remnant Shell: Characterizing the Dust and Gas Properties

We present deep Chandra observations and Spitzer Space Telescope infrared (IR) spectroscopy of the shell in the composite supernova remnant (SNR) Kes 75 (G29.7-0.3). The remnant is composed of a central pulsar wind nebula and a bright partial shell in the south that is visible at radio, IR, and X-ray wavelengths. The X-ray emission can be modeled by either a single thermal component with a temperature of ~ 1.5 keV, or with two thermal components with temperatures of 1.5 and 0.2 keV. Previous studies suggest that the hot component may originate from reverse-shocked SN ejecta. However, our new analysis shows no definitive evidence for enhanced abundances of Si, S, Ar, Mg, and Fe, as expected from supernova (SN) ejecta, or for the IR spectral signatures characteristic of confirmed SN condensed dust, thus favoring a circumstellar or interstellar origin for the X-ray and IR emission. The X-ray and ill emission in the shell are spatially correlated, suggesting that the dust particles are collisionally heated by the X-ray emitting gas. The IR spectrum of the shell is dominated by continuum emission from dust with little, or no line emission. Modeling the IR spectrum shows that the dust is heated to a temperature of ~ 140 K by a relatively dense, hot plasma, that also gives rise to the hot X-ray emission component. The density inferred from the IR emission is significantly higher than the density inferred from the X-ray models, suggesting a low filling factor for this X-ray emitting gas. The total mass of the warm dust component is at least 1.3 x 10(exp -2) solar mass, assuming no significant dust destruction has occurred in the shell. The IR data also reveal the presence of an additional plasma component with a cooler temperature, consistent with the 0.2 keV gas component. Our IR analysis therefore provides an independent verification of the cooler component of the X-ray emission. The complementary analyses of the X-ray and IR emission provide quantitative estimates of density and filling factors of the clumpy medium swept up by the SNR.

Temim, Tea↗
NASA NTRS2012

SGAS 143845.1 + 145407: A Big, Cool Starburst at Redshift 0.816

We present the discovery and a detailed multi-wavelength study of a strongly-lensed luminous infrared galaxy at z=0.816. Unlike most known lensed galaxies discovered at optical or near-infrared wavelengths, this lensed source is red, which the data presented here demonstrate is due to ongoing dusty star formation. The overall lensing magnification (a factor of 17) facilitates observations from the blue optical through to 500 micrometers, fully capturing both the stellar photospheric emission as well as the reprocessed thermal dust emission. We also present optical and near-IR spectroscopy. These extensive data show that this lensed galaxy is in many ways typical of IR-detected sources at z approximates 1, with both a total luminosity and size in accordance with other (albeit much less detailed) measurements in samples of galaxies observed in deep fields with the Spitzer telescope. Its far-infrared spectral energy distribution is well-fit by local templates that are an order of magnitude less luminous than the lensed galaxy; local templates of comparable luminosity are too hot to fit. Its size (D approximately 7 kpc) is much larger than local luminous infrared galaxies, but in line with sizes observed for such galaxies at z approximates 1. The star formation appears uniform across this spatial scale. Thus, this lensed galaxy, which appears representative of vigorously star-forming z approximates 1 galaxies, is forming stars in a fundamentally different mode than is seen at z approximates 0.

Gladders, Michael D.↗
NASA NTRS1985

Shock effects on hydrous minerals and implications for carbonaceous meteorites

The effect of shock loading over the pressure range of 29-59 GPa on the shock-recovered specimens of antigorite serpentine, Mg3Si2O5(OH)4, were investigated employing infrared (IR) spectroscopy, thermogravimetric analysis, and optical and scanning electron microscopy. With increasing shock pressure, there was an increase in H2O IR absorption peaks at the expense of OH peaks, while the changes in SiO bond vibration modes were identical to those seen for other, nonhydrous minerals. Thermogravimetric results on vented assembly samples showed linear relationships between the shock pressure and both the length of dehydration interval and the effective activation energy for releasing post-shock structural water. Optical and scanning electron microscopy revealed gas bubbles, which appeared to be injected into zones of partial melting, and vesicular dark veins distributed throughout the shocked samples. It is suggested that shock loading of hydrous minerals would release and redistribute free water in the regoliths of carbonaceous chondrite parent bodies, giving rise to observed hydrous alterations.

Lange, M. A.↗
NASA NTRS1999

Gas Sensor Evaluations in Polymer Combustion Product Atmospheres

Toxic gases produced by the combustion or thermo-oxidative degradation of materials such as wire insulation, foam, plastics, or electronic circuit boards in space shuttle or space station crew cabins may pose a significant hazard to the flight crew. Toxic gas sensors are routinely evaluated in pure gas standard mixtures, but the possible interferences from polymer combustion products are not routinely evaluated. The NASA White Sands Test Facility (WSTF) has developed a test system that provides atmospheres containing predetermined quantities of target gases combined with the coincidental combustion products of common spacecraft materials. The target gases are quantitated in real time by infrared (IR) spectroscopy and verified by grab samples. The sensor responses are recorded in real time and are compared to the IR and validation analyses. Target gases such as carbon monoxide, hydrogen cyanide, hydrogen chloride, and hydrogen fluoride can be generated by the combustion of poly(vinyl chloride), polyimide-fluoropolymer wire insulation, polyurethane foam, or electronic circuit board materials. The kinetics and product identifications for the combustion of the various materials were determined by thermogravimetric-IR spectroscopic studies. These data were then scaled to provide the required levels of target gases in the sensor evaluation system. Multisensor toxic gas monitors from two manufacturers were evaluated using this system. In general, the sensor responses satisfactorily tracked the real-time concentrations of toxic gases in a dynamic mixture. Interferences from a number of organic combustion products including acetaldehyde and bisphenol-A were minimal. Hydrogen bromide in the products of circuit board combustion registered as hydrogen chloride. The use of actual polymer combustion atmospheres for the evaluation of sensors can provide additional confidence in the reliability of the sensor response.

Delgado, Rafael H.↗
NASA NTRS2006

Vibrational Spectroscopy after OSU - From C2- to Interstellar Polycyclic Aromatic Hydrocarbons

The composition of interstellar ice and dust provides insight into the chemical history of the interstellar medium and early solar system. It is now possible to probe this unique and unusual chemistry and determine the composition of these microscopic interstellar particles which are hundreds to many thousands of light years away thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of chemical composition, and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with giant, dark molecular clouds -the birthplace of stars and planets- and others in more tenuous, UV radiation rich regions are now available. The fundamentals of IR spectroscopy and what comparisons of astronomical IR spectra with laboratory spectra of materials prepared under realistic simulated interstellar conditions tell us about the components of these materials is the subject of this talk. These observations have shown that mixed molecular ices comprised of H2O, CH3OH, CO, NH3 and H2CO contain most of the molecular material in molecular clouds and that gas phase, ionized polycyclic aromatic hydrocarbons (PAHs) are widespread and surprisingly abundant throughout most of the interstellar medium.

Allamandola, Louis J.↗
NASA NTRS1988

Prediction of leaf chemistry by the use of visible and near infrared reflectance spectroscopy

The chemical content of dry, ground leaf material sampled from deciduous and conifer tree species from sites in Alaska, Wisconsin, and California was estimated using visible and shortwave IR spectroscopy. Seven chemical components - sugar, starch, protein, cellulose, total chlorophyll, lignin, and total nitrogen - were analyzed by wet chemical methods and their concentrations regressed against log 1/rho and first and second differences of log 1/rho (where rho is measured reflectance) at wavelengths selected by stepwise regression. Predictions of chemical concentrations based on cross validation suggest that this technique may be useful for extracting vegetation canopy biochemical information by remote sensing.

Card, Don H.↗
NASA NTRS2005

TEM and NanoSIMS Study of Hydrated/Anhydrous Phase Mixed IDPs: Cometary or Asteroidal Origin?

Chondritic interplanetary dust particles (IDPs) are subdivided into (1) particles that form highly porous aggregates (chondritic porous "CP" IDPs), and (2) smooth particles ("CS" IDPs). Infrared (IR) spectroscopy has been a valuable tool for non-destructively determining the bulk mineralogy of IDPs. Most IDPs fall within three distinct IR groups: (1) olivine-rich particles, (2) pyroxene-rich particles, and (3) phyllosilicate-rich particles. From the IR studies, IDPs dominated by anhydrous minerals tend to be fine grained (CP), while phyllosilicate-rich IDPs are mostly CS. CP IDPs have been linked to cometary sources based on their compositions, spectral properties, and atmospheric entry velocities. Since no spectral signatures of hydrated minerals have been detected in comets, CS IDPs are thought to derive from primitive asteroids. Transmission electron microscopy (TEM) studies have revealed that the mineralogical distinctions between CP and CS IDPs are not always clear. Previous investigators have reported trace amounts of hydrous minerals in dominantly anhydrous particles. A better understanding of these particles will help to elucidate whether there is a genetic relationship between anhydrous and hydrated IDPs, provide insight into the earliest stages of aqueous alteration of primitive materials, and may help to determine whether comets have experienced any aqueous processing. Here we report a combined TEM and isotopic imaging study of an unusual anhydrous IDP with hydrated phases. Additional information is included in the original extended abstract.

Nakamura, K.↗
NASA NTRS2004

Background-Limited Infrared-Submillimeter Spectroscopy (BLISS)

The bulk of the cosmic far-infrared background light will soon be resolved into its individual sources with Spitzer, Astro-F, Herschel, and submm/mm ground-based cameras. The sources will be dusty galaxies at z approximately equal to 1-4. Their physical conditions and processes in these galaxies are directly probed with moderate-resolution spectroscopy from 20 micrometers to 1 mm. Currently large cold telescopes are being combined with sensitive direct detectors, offering the potential for mid-far-IR spectroscopy at the background limit (BLISS). The capability will allow routine observations of even modest high-redshift galaxies in a variety of lines. The BLISS instrument's capabilities are described in this presentation.

spectrometers↗
NASA NTRS2006

Comet Mineralogy as Inferred from Infrared Spectra of Comets

For most comets, infrared (IR) spectroscopy (remote sensing) is the method through which we diagnose the mineralogy and size distribution of dust in their comae. The shape and contrast of the IR spectral features depend on the particle size: optically active minerals (absorbing of visible and near-IR solar photons) and submicron solid grains or highly porous (> 90% vacuum) grains primarily contribute to the shapes of the observed resonances. Comet mineralogies typically are determined by fitting thermal emission models of ensembles of discrete mineral grains to observed IR spectral energy distributions. The absorptivities (Q-abs) and scattering efficiencies (Q-scat) of the discrete mineral grains are computed using Mie scattering, Maxwell-Garnet mixing, Discrete Dipole Approximation, and Multi-Layered Sphere codes. These techniques when applied to crystalline minerals, specifically olivine (Mg_x, Fe_1-x)2 Si04, x>0.9, require the use of ellipsoidal shaped particles with elongated axial ratios or hollow spheres to produce the shapes of the resonances observed both from comet comae and laboratory samples. The wavelength positions of the distinct resonances from submicron-radii crystalline silicates, as well as their thermal equilibrium temperatures, constrain the crystalline olivine to have a relatively high Mg-content (x>0.9, or Fo>90). Only resonances computed for submicron Mg-rich crystalline olivine and crystalline orthopyroxene match the observed IR spectral features. However, this has led to the interpretation that micron-radii and larger crystals are absent from comet comae. Furthermore, the mass fraction of silicate crystals is dependent upon whether just the submicron portion of the size distribution is being compared or the submicron crystals compare to the aggregates of porous amorphous silicates that are computationally tractable as porous spheres. We will discuss the Deep Impact results as examples of these challenges to interpreting mid-IR spectra of short-period comets.

Wooden, Diane H.↗
NASA NTRS1985

Analysis of TQCM surface contamination adsorbed during the Spacelab I Mission

The Temperature-Controlled Quartz Crystal Microbalance (TQCM) system was flown on the Spacelab I Mission as part of the Induced Environment Contamination Monitor to monitor surface contamination (SC) in the payload bay. SC on the five sensors of the TQCM was analyzed by means of IR spectroscopy, scanning electron spectroscopy, and energy dispersive X-ray fluorescence. The amount of SC ranged from 1.4 micrograms/sq cm for the -Z sensor to 39.9 micrograms/sq cm for the +X sensor. The IR analysis showed strong CH2, CH3, and carbonyl absorption bands, indicative of ester and polyester compounds found in adhesives, plasticizers, and tape. The particulates (mostly ranging from 1 micron to 20 microns in size) were mainly composed of Mg, Al, Al2O3, and Si, and probably originated in the solid rocket firings.

Mckeown, D.↗
NASA NTRS2017

Ground-Based Detection of Deuterated Water in Comet C/2014 Q2 (Lovejoy) at IR Wavelengths

We conducted a deep search for deuterated water (HDO) in the Oort Cloud comet C/2014 Q2 (Lovejoy), through infrared (IR) spectroscopy with NIRSPEC at the Keck Observatory. In this Letter, we present our detections of HDO and water (H2O) in comet Lovejoy on 2015 February 4 (post-perihelion) after 1 hr integration on source. The IR observations allowed simultaneous detection of H2O and HDO, yielding production rates of 5.9 +/- 0.13 × 10(exp 29) and 3.6 +/- 1.0 × 10(exp 26) molecules/sec, respectively. The simultaneous detection permitted accurate determination of the isotopic ratio (D/H) in water of 3.02 +/- 0.87 × 10(exp −4), i.e., larger than the value for water in terrestrial oceans (or Vienna Standard Mean Ocean Water, VSMOW) by a factor of 1.94 +/- 0.56. This D/H ratio in water exceeds the value obtained independently at millimeter wavelengths (0.89 +/- 0.25 VSMOW; pre-perihelion). We discuss these parameters in the context of origins and emphasize the need for contemporaneous measurements of HDO and H2O.

Paganini, L.↗
NASA NTRS1987

Vertical temperature gradients on Uranus - Implications for layered convection

Analyses of Voyager IR spectroscopy and radio occultation measurements confirm ground-based observations that the deep lapse rate of Uranus exceeds that for an adiabat of H2 in thermodynamic equilibrium. However, in approximately the same region of the atmosphere, Voyager IR and ground-based observations also indicate that the ratio of ortho to para hydrogen is near the equilibrium value. These two sets of observations can be reconciled by postulating the existence of rapid convective overturning within layers which are thin in comparison to a pressure scale height. Two forms of layered convection are examined. In one case, deposition of kinetic energy results in thin, rapidly overturning layers. Possible kinetic energy sources include braking waves and local instabilities. In the second case considered, molecular-weight discontinuities due to CH4 stratification stabilize the interfaces of thin layers. It is argued that both forms may be important in the convective portion of the Uranus atmosphere.

Gierasch, Peter J.↗
NASA NTRS2019

Molecular Identifications in Experiments with Astronomical Ice Analogues: New Data, Old Strategies, and the N2 + Acetone System

A recent publication on the radiation chemistry and IR spectroscopy of N2 plus acetone ices is used to illustrate some of the difficulties encountered in the study of astronomical ice analogues. Concerns and problems are identified and suggestions for their solution are presented, including new infrared (IR) spectra of amorphous ices. The hazards of using peak positions alone for assignments of the IR spectra of irradiated ices are illustrated, and the importance of considering the underlying reaction chemistry is shown. Several experiments are proposed as a way to investigate the behaviour of acetone in cold, extraterrestrial environments. Electronic versions of IR spectra are provided and several new refractive indices of ices are reported.

Hudson, Reggie L.↗
NASA NTRS1978

The role of earth-based observations of asteroids during the next decade

Present reconnaissance studies of asteroids shift ground based programs to more specialized, intensive studies of selected individual bodies and special classes. Two powerful techniques--radar and mid-IR spectroscopy--have yet to be widely applied to asteroids; high priority should be given to: (1) search programs with a large Schmidt telescope (especially for Mars- and Earth-approaching bodies); (2) a moderate resolution visible and near-IR spectrophotometric survey of at least half the asteroids; (3) high resolution spectrophotometry and radiometry of unusual objects; (4) radar studies of representative main belt asteroids; and (5) application of the full complement of astrophysical techniques to objects of high scientific interest and to potential space mission targets. The infrared astronomical satellite also has high potential for contributing to asteroid science.

Chapman, C. R.↗
NASA NTRS2001

Evolution of the Earth and Origin of Life: The Role of Gas/Fluid Interactions with Rocks

The work under the Cooperative Agreement will be centered on questions of the evolution of Life on the early Earth and possibly on Mars. It is still hotly debated whether the essential organic molecules were delivered to the early Earth from space (by comets, meteorites or interplanetary dust particles) or were generated in situ on Earth. Prior work that has shown that the matrix of igneous minerals is a medium in which progenitors of organic molecules assemble from H2O, C02 and N2 incorporated as minority "impurities" in minerals of igneous rocks during crystallization from H2O/CO2/N2-laden magmas. The underlying processes involve a redox. conversion whereby C, H, and N become chemically reduced, while 0 becomes oxidized to the peroxy state. During Year 02 the work will be divided into three tasks. Task 1: After carboxylic (fatty) acids and N-bearing compounds have been identified, other extractable organic molecules including lipids, oily substances and amino acids will be studied. Dedicated lipid analysis will be combined with gas chromatographic-mass spectroscopic (GCMS) analysis of organic compounds extracted from minerals and rocks. Task 2: Using infrared (IR) spectroscopy, C-H entities that are indicators for the organic progenitors in mineral matrices will be studied. A preliminary heating experiment with MgO single crystals has shown that the C-H entities can be pyrolyzed, causing the IR bands to disappear, but at room temperature the IR bands reappear in a matter of days to weeks. This work will be expanded, both by studying synthetic MgO crystals and olivine crystals from the Earth's upper mantle. The C-H bands will be compared to the published "organic" IR feature of dust in the interstellar medium (ISM) and interplanetary dust particles (IDP). Task 3: A paradox marks the evolution of early Life: Oxygen is highly toxic to primitive life, yet early organisms "learned" to detoxify reactive oxygen species, to utilize oxygen, and even produce it. Why would organisms on the early anaerobic Earth be under evolutionary pressure to evolve defenses against reactive oxygen species? Minerals in igneous rocks are now known to contain peroxy. When such minerals weather, the peroxy hydrolyzes to H2O2. The hypothesis will be tested whether organisms living in intimate contact with rock surfaces are subjected to a constant trickle of H202 and thus under stress to develop strategies to either detoxify the reactive oxygen species or repair the molecular damage that they cause. Understanding these processes is central to the Astrobiology mission. It opens new avenues toward understanding the evolution of early life on Earth, and the potential for aerobic life elsewhere. This Cooperative Agreement also has a strong educational and public outreach component involving high school, undergraduate students, and high school teachers.

Freund, Friedemann↗
NASA NTRS2010

Thermal Infrared Emission Spectroscopy of Synthetic Allophane and its Potential Formation on Mars

Allophane is a poorly-crystalline, hydrous aluminosilicate with variable Si/Al ratios approx.0.5-1 and a metastable precursor of clay minerals. On Earth, it forms rapidly by aqueous alteration of volcanic glass under neutral to slightly acidic conditions [1]. Based on in situ chemical measurements and the identification of alteration phases [2-4], the Martian surface is interpreted to have been chemically weathered on local to regional scales. Chemical models of altered surfaces detected by the Mars Exploration Rover Spirit in Gusev crater suggest the presence of an allophane-like alteration product [3]. Thermal infrared (TIR) spectroscopy and spectral deconvolution models are primary tools for determining the mineralogy of the Martian surface [5]. Spectral models of data from the Thermal Emission Spectrometer (TES) indicate a global compositional dichotomy, where high latitudes tend to be enriched in a high-silica material [6,7], interpreted as high-silica, K-rich volcanic glass [6,8]. However, later interpretations proposed that the high-silica material may be an alteration product (such as amorphous silica, clay minerals, or allophane) and that high latitude surfaces are chemically weathered [9-11]. A TIR spectral library of pure minerals is available for the public [12], but it does not contain allophane spectra. The identification of allophane on the Martian surface would indicate high water activity at the time of its formation and would help constrain the aqueous alteration environment [13,14]. The addition of allophane to the spectral library is necessary to address the global compositional dichotomy. In this study, we characterize a synthetic allophane by IR spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) to create an IR emission spectrum of pure allophane for the Mars science community to use in Martian spectral models.

Rampe, E. B.↗