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High-Resolution and Analytical TEM Investigation of Space Radiation Processing Effects in Primitive Solar System Materials and Airless Planetary Surface Environments

Energetic ions present in the diverse plasma conditions in space play a significant role in the formation and modification of solid phases found in environments ranging from the interstellar medium (ISM) to the surfaces of airless bodies such as asteroids and the Moon. These effects are often referred to as space radiation processing, a term that encompasses changes induced in natural space-exposed materials that may be only structural, such as in radiation-induced amorphization, or may involve ion-induced nanoscale to microscale chemical changes, as occurs in preferential sputtering and ion-beam mixing. Ion sputtering in general may also be responsible for partial or complete erosion of space exposed materials, in some instances possibly bringing about the complete destruction of free-floating solid grains in the ISM or in circumstellar nebular dust clouds. We report here on two examples of the application of high-resolution and analytical transmission electron microscopy (TEM) to problems in space radiation processing. The first problem concerns the role of space radiation processing in controlling the overall fate of Fe sulfides as hosts for sulfur in the ISM. The second problem concerns the known, but as yet poorly quantified, role of space radiation processing in lunar space weathering.

Christoffersen, R.↗

From Interstellar PAHs and Ices to the Origin of Life

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to micron-sized cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In dense molecular clouds, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is very well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by earlier interstellar chemistry standards, is widespread throughout the Universe. The first part of this lecture will describe how infrared studies of interstellar space, combined with laboratory simulations, have revealed the composition of interstellar ices (the building blocks of comets) and the high abundance and nature of interstellar PAHs. The laboratory database has now enabled us to gain insight into the identities, concentrations, and physical state of many interstellar materials. Within a dense molecular cloud, and especially in the solar nebula during the star and planet formation stage, the materials frozen into interstellar/precometary ices are photoprocessed by ultraviolet light, producing more complex molecules. The remainder of the presentation will focus on the photochemical evolution of these materials and the possible role of these compounds on the early Earth. As these materials are thought to be the building blocks of comets and related to the carbonaceous components of micrometeorites, they are likely to have been important sources of complex organic materials on the early Earth and their composition may be related to the origin of life.

Allamandola, Louis J.↗

Debris Disk Structure and Morphology as Revealed by Aggressive STIS Multi-Roll Coronagraphy: A New Look at Some Old Friends

We present new imaging results from a well-selected sample of II circumstellar debris disks, all with HST pedigree, using STIS visible-light 6-roll PSF-template subtracted coronagraphy (PSFTSC). These new observations, pushing HST to its highest levels of coronagraphic performance, simultaneously probe both the interior regions of these debris systems, with inner working distances < app 8 AU for half the stars in this sample (corresponding to the giant planet and Kuiper belt regions within our own solar system), and the exterior regions far beyond. These new images enable direct inter-comparison of the architectures of these exoplanetary debris systems in the context of our own Solar System: These observations also permit us, for the first time, to characterize material in these regions at high spatial resolution and identify disk sub-structures that are signposts of planet formation and evolution; in particular, asymmetries and non-uniform debris structures that signal the presence of co-orbiting perturbing planets, and dynamical interactions (e.g., resulting in posited small grain stripping and disk "pollution") with the ISM. We focus here on recently acquired and reduced images of he circumstellar debris systems about: AU Mic (edge-on, and @ 10 pc the closest star in our sample), HD 61005, HD 32297 and HD 15115 (all with morphologies strongly suggestive of ISM wind interactions), HD 181327 & HDI07146 (close to face-on with respectively narrow and broad debris rings), and MP Mus (a "mature" proto-planetary disk hosted by a cTTS). All of our objects were previously observed in the near-IR with inferior spatial resolution and imaging efficacy, but with NICMOS r = 0.3" inner working angle (IWA) comparable to STIS multi-roll coronagraphy. The combination of new optical and existing near-IR imaging can strongly constrain the dust properties, thus enabling an assessment of grain processing and planetesimal populations. These results will directly inform upon the posited planet formation mechanisms that occur after the approximately 10 My epoch of gas depletion, a time in our solar system when giant planets were migrating and terrestrial planets were forming, and directly test theoretical models of these processes. These observations lmiquely probe both into the interior regions of these systems and are sensitive to and spatially resolve low surface-brightness (SB) material at large stellocentric distances with spatial resolution comparable to ACS and with augmenting NICMOS near-IR disk photometry in hand.

Grady, Carol A↗

Evolution of interstellar dust

The composition, origins, and evolution of interstellar dust (ISD) are examined, reviewing the results of recent observational and theoretical investigations. Topics discussed include amorphous and polycrystalline structures; the relationship between amorphous C, graphite, and polycyclic aromatic hydrocarbons; observational techniques for determining ISD structure and composition; ISD formation in outflows from late-type giants, planetary nebulae, and novae; destruction of ISD by shocks; the formation of ISD in the ISM; and the relationship between ISD and interplanetary dust. IR spectroscopy of molecular ices and icy grain mantles is considered in detail, and it is shown that typical grain mantles consist of a 1/0.6/0.05/0.05 mixture of H2O, CH3OH, CO, and NH3.

Tielens, A. G. G. M.↗

Vibrational Spectroscopy and Astrobiology

Role of vibrational spectroscopy in solving problems related to astrobiology will be discussed. Vibrational (infrared) spectroscopy is a very sensitive tool for identifying molecules. Theoretical approach used in this work is based on direct computation of anharmonic vibrational frequencies and intensities from electronic structure codes. One of the applications of this computational technique is possible identification of biological building blocks (amino acids, small peptides, DNA bases) in the interstellar medium (ISM). Identifying small biological molecules in the ISM is very important from the point of view of origin of life. Hybrid (quantum mechanics/molecular mechanics) theoretical techniques will be discussed that may allow to obtain accurate vibrational spectra of biomolecular building blocks and to create a database of spectroscopic signatures that can assist observations of these molecules in space. Another application of the direct computational spectroscopy technique is to help to design and analyze experimental observations of ice surfaces of one of the Jupiter's moons, Europa, that possibly contains hydrated salts. The presence of hydrated salts on the surface can be an indication of a subsurface ocean and the possible existence of life forms inhabiting such an ocean.

Chaban, Galina M.↗

Anisotropic ionizing radiation in Seyfert galaxies. I - The extended narrow-line region in Markarian 573

The morphology, kinematics, and ionization state of the nuclear extended narrow-line region (ENLR) of the Seyfert 2 galaxy Mrk 573 are studied using narrow-band images of a grid of long-slit spectra. The entire ENLR is mapped spectroscopically, and velocity structure is studied. The velocity field map shows a typical galactic rotation picture with some important deviations. A simple geometric model, in accordance with the 'unified schemes', is employed to study the effects of various parameters of the observed picture. The best match is achieved when a biconical radiation field illuminates the ISM of the host galaxy that takes part in a normal galaxy rotation but also has radial motions close to the nucleus. The emission-line images reveal an ENLR elongated along the radio axis in the northwest-southeast direction, but a map of the flux ratio forbidden O III 5007/(H-alpha + forbidden N II) shows a different structure, with the highest excitation peak offset by about 4 arcsec along the radio axis to the southeast.

Tsvetanov, Zlatan↗

CCD soft X-ray observations of the Puppis a supernova remnant

We present the first images and spectra of an astronomical object, other than the Sun, acquired with a charge coupled device (CCD) imaging X-ray spectrometer. During a 230 s sounding rocket observation, we have acquired moderate-resolution spectra and moderate-resolution images of a portion of the Pup A supernova remnant (SNR). Based on these data, we conclude that the X-ray spectrum of Pup A is inconsistent with any single-temperature equilibrium or nonequilibrium plasma model. We find evidence for variations in the emitting plasma on scales as small as 5.0 min and as large as 30.0 min. The spatial structure of the spectral variations in the remnant is found to be inconsistent with the standard Sedov model for the evolution of a SRN into a homogeneous interstellar medium (ISM). We suggest that the remnant is expanding into a region of the ISM having a density of approximately 1 cm(exp -3) with inhomogeneities on the order of 50%. We have found evidence for the presence of a knot of plasma enriched in neon, but require more data to be conclusive.

Berthiaume, G. D.↗

Laboratory Studies of Extraterrestrial Ices and PAHs: Making an Astrobiological Silk Purse Out of An Interstellar Sow's Ear

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Today, the composition of dust in the ISM is reasonably well constrained to cold, micron-sized particles of various refractory materials. Shrouded within the protective confines of cold, opaque molecular clouds--the birthplace of stars and planets--these particles secrete mantles of mixed molecular lees whose major components are also well constrained. Finally, amidst the molecular inventory of these ice mantles are likely to be found polycyclic aromatic hydrocarbons (PAHs), whose telltale infrared signature I is now recognized throughout the Universe. However, of what significance is this scenario to the origin of life in our solar system--or any other? The major components of the icy materials observed in interstellar clouds and in our own solar system are uniformly quite simple. In addition, despite the fact that PAHs likely represent the single largest molecular reservoir of organic carbon in evolving planetary systems, they are not what would be considered "biogenic" molecules. Although interesting from a chemical and astrophysical standpoint, in the absence of a mechanism by which these materials can be transformed into more biochemically significant structures, they are of little Astrobiological significance. In this talk, we will begin with a brief review of the nature and abundance of the "raw" population of PAHs and PAH-related materials in the ISM. From there, we will move on to explore our laboratory simulations of the photochemical evolution of realistic mixed molecular ices under conditions which simulate those encountered in the ISM and in evolving planetary systems. Particular attention will be paid to the surprisingly complex array of organic species that are produced in these ices from such a deceptively simple inventory of starting materials. In addition, we will explore the chemistry of PAHs under these conditions and consider its potential for transforming that rich repository of pre-biotic organic "ore" into materials of greater importance to Astrobiology.

Hudgins, Douglas M.↗

High-resolution sodium absorption-line observations of the local interstellar medium

High-resolution observations of the sodium D1 and D2 interstellar absorption lines have been made toward 19 stars in the local ISM at distances ranging from 20 to 220 pc. A least-squares absorption line-fitting analysis is carried out on 10 of the stars that show detectable sodium. The velocity structure, velocity dispersions, and column densities of the various interstellar cloud components are derived. For the majority of stars, the best-fit dispersion parameter is about 2 km/s, corresponding to an upper limit for the kinetic temperature of the interstellar gas of about 5500 K. No sodium is detected toward stars with distances less than 42 pc, placing an upper limit 2.5 x 10 to the 18th/sq cm to the hydrogen column density in these lines of sight.

Welsh, Barry Y.↗

The life cycle of the Interstellar Medium in other galaxies

Gas in spiral galaxies cycles between the diffuse and dense phases as clouds collapse, form stars and are dispersed back into the ISM. Far infrared observations of continuum emission from interstellar dust and line emission from interstellar gas have revealed a wealth of information on the state of the ISM in galaxies of different morphological types. The analysis of these observations gives us information about the processes of star formation and about the evolution of the ISM. Star formation rates vary widely from galaxy to galaxy, with the rates in starburst galaxies being 10 - 100 times those in quiescent spiral galaxies. Far infrared spectroscopy of star-forming galaxies shows that the interstellar pressure increases with star formation rate. The structure of the interstellar medium in starburst galaxies is quite different from that of quiescent galaxies - much of the mass and volume are in HII regions and photodissociation regions. The size distribution of dust grains seems to depend on environment; small grains are abundant in the diffuse interstellar medium but not in dense molecular star forming regions. Quiescent spiral and elliptical galaxies contain a significant population of small grains, but starburst galaxies do not. Dwarf irregular galaxies also seem to contain few small grains; this may be the result of the higher UV flux in these galaxies. The star forming regions in dwarf irregulars also have a higher ratio of atomic to molecular gas than do those in the Galaxy. These results show that the ISM in galaxies of different morphological types reaches different equilibria, resulting in different modes of star formation and global galaxy evolution.

Knapp, G. R.↗

Understanding Structure in Line-Driven Stellar Winds Using Ultraviolet Spectropolarimetry in the Time Domain

The most massive stars are thought to lose a significant fraction of their mass in a steady wind during the main-sequence and blue supergiant phases. This in turn sets the stage for their further evolution and eventual supernova, and preconditions the surrounding medium for all following events, with consequences for ISM energization, chemical enrichment, and dust formation. Understanding these processes requires accurate observational constraints on the mass-loss rates of the most luminous stars, which can also be used to test theories of stellar wind driving. In the past, mass-loss rates have been characterized via collisional emission processes such as optical Hα and free-free radio emission, but these so-called “density squared” diagnostics require correction in the presence of widespread clumping. Recent observational and theoretical evidence points to the likelihood of a ubiquitously high level of such clumping in hot-star winds, but quantifying its effects requires a deeper understanding of the complex dynamics of radiatively driven winds and their stochastic instabilities. Furthermore, large-scale structures initiating in surface anisotropies and propagating throughout the wind can also affect wind driving and alter mass-loss diagnostics. Time series spectroscopy of high resonance-line opacity in the UV, capable of high resolution and high signal-to-noise, are required to better understand these complex dynamics, and more accurately determine mass-loss rates. The proposed Polstar mission (Scowen et al. 2022, this volume) provides the necessary resolution at the Sobolev (∼10 km s −1 ) or sound-speed (∼20 km s −1 ) scale, for over three dozen bright galactic massive stars with signal-to noise an order of magnitude above that of the celebrated MEGA campaign (Massa et al. 1995) of the International Ultraviolet Explorer (IUE), via continuous observations that track propagating structures through the winds in real time. Supporting geometric constraints are provided by the polarimetric capabilities present in all the datasets of such a mission.

Polstar – NASA MIDEX↗

Star formation activity in spiral galaxy disks and the properties of radio halos: Observational evidence for a direct dependence

In this article we address observationally the questions: how does star formation (SF) in the disks of galaxies lead to the creation of radio halos, and what minimum energy input into the interstellar medium (ISM) is needed to facilitate this? For the investigation we use a sample of five edge-on galaxies exhibiting radio continuum emmission in their halos and enhanced SF spread over large parts of their disks. In a detailed study of the two galaxies in our sample for which we have the best data, NGC 891 and NGC 4631, we show that the radio halos cut off abruptly at galactocentric radii smaller than those of the underlying thin radio disks. Our most important result is that the halo cutoffs are spatially coincident with the radii where the SF activity in the underlying disks drops sharply. The difference in radius of the emission distributions tracing ongoing SF in the disks (IRAS 50 micrometers, H alpha) versus that of the nonthermal radio continuum thin disks (tracing the distribution of cosmic-ray (CR) electrons) is typically a few kpc. This difference in extent is caused by CR diffusion. We have measured the CR diffusion coefficients in the thin disks of both NGC 891 and NGC 4631. For radial diffusion of CR electrons within the galactic disks the values are D(sub r) = 1.1-2.5 x 10 (exp 29) sq cm/s (NGC 4631) and D(sub r) = 1.2 x 10(exp 29) sq cm/s (NGC 891). For motions in the z-direction in areas within the thin disks where no outflows occur, we derive a firm upper limit of D(sub z) less than or equal to 0.2 x 10(exp 28) sq cm/s for NGC 891. The value for NGC 4631 is D(sub z = 1.4 x 10 (exp 28) sq cm/s. The other three galaxies in our sample, NGC 3044, NGC 4666, and NGC 5775 show (at the sensitivity of our data) less extended, more filamentary radio halos. Isolates spurs or filaments of nonthermal radio continuum emission in their halos are traced only above the most actively star-forming regions in the disks. This, in conjuction with the results obtained for NGC 891 and NGC 4631, suggests a direct connection between the shapes and radial extents of radio halos of normal galaxies and the level and the spatial distribution of the current SF in their disks. The existence of filamentary structures implies that expansion and convection of CR-heated plasma plays an important role even at low z-distances above the plane. Based on radio data we derive the disk-averaged mean energy input rates into the ISM due to supernova explosions per unit surface area in nine galaxies, including the ones in our sample. We find a clear trend in the sense that the galaxies with the highest mean energy input rates in the underlying disks have the most extended and pervasisve radio halos. Below a certain threshohld, outflows are inhibited. As a lower limit for this threshhold we derive an energy input rate of approximately 10 (exp -4) erg/s sq cm. The fact that radio halo emission is found only above the most luminous giant H 2 regions in late-type 'normal' galaxies (of type Sbc or later) indicates that only these are capable of initiating disk-halo interactions by locally exceeding the threshold. The distribution of the local outflows determines the overall shapes of the CR halos and leads to the observed filamentary structures.

Dahlem, Michael↗

A GALAH View of the Chemical Homogeneity and Ages of Stellar Strings Identified in Gaia

The advent of Gaia has led to the discovery of nearly 300 elongated stellar associations (called ‘strings’) spanning hundreds of parsecs in length and mere tens of parsecs in width. These newfound populations present an excellent laboratory for studying the assembly process of the Milky Way thin disc. In this work, we use data from GALAH DR3 to investigate the chemical distributions and ages of 18 newfound stellar populations, 10 of which are strings and 8 of which are compact in morphology. We estimate the intrinsic abundance dispersions in [X/H] of each population and compare them with those of both their local fields and the open cluster (OC) M 67. We find that all but one of these groups are more chemically homogeneous than their local fields. Furthermore, half of the strings, namely Theias 139, 169, 216, 303, and 309, have intrinsic [X/H] dispersions that range between 0.01 and 0.07 dex in most elements, equivalent to those of many OCs. These results provide important new observational constraints on star formation and the chemical homogeneity of the local interstellar medium (ISM). We investigate each population’s Li and chemical clock abundances(e.g. [Sc/Ba], [Ca/Ba], [Ti/Ba], and [Mg/Y]) and find that the ages suggested by chemistry generally support the isochronal ages in all but six structures. This work highlights the unique advantages that chemistry holds in the study of kinematically related stellar groups.

Stars: abundances↗

Spectrophotometry of the shell around AG Carinae

Spatially-resolved long-slit spectrophotometry are presented for two regions of the shell nebula around the P-Cygni variable star AG Carinae. The spectra cover the 3700-6800 A wavelength range. Emission-line diagnostics are used to derive extinction, electron temperatures, and densities for various positions in the nebula. The chemical abundances and ionization structure are calculated and compared with other types of planetary nebulae and shells around other luminous stars. It is found that the N/O and N/S ratios of Ag Car are high compared to solar neighborhood ISM values. The O/H depletion found for the AG Car shell approaches that found in the condensations of the Eta Car system.

Mitra, P. Mila↗

A Suzaku Study of Ejecta Structure and Origin of Hard X-ray Emission in the Supernova Remnant G156.2+5.7

We report an X-ray study of the evolved Galactic supernova remnant (SNR) G1S6.2+S.7 based on six pointing observations with Suzaku. The remnant's large extent (100' in diameter) allows us to investigate its radial structure in the northwestern and eastern directions from the apparent center. The X-ray spectra. were well fit with a two-component non-equilibrium ionization model representing the swept-up interstellar medium (ISM) and the metal-rich ejecta. We found prominent central concentrations of Si, S and Fe from the ejecta component; the lighter elements of O, Ne and Mg were distributed more uniformly. The temperature of the ISM component suggests a slow shock (610-960 km/s), hence the remnant's age is estimated to be 7,000-15,000 yr, assuming its distance to be approx. 1.1 kpc. G1S6.2+5.7 has also been thought to emit hard, non-thermal X-rays, despite being considerably older than any other such remnant. In response to a recent discovery of a background cluster of galaxies (2XMM J045637.2+522411), we carefully excluded its contribution, and reexamined the origin of the hard X-ray emission. We found that the residual hard X-ray emission is consistent with the expected level of the cosmic X-ray background. Thus, no robust evidence for the non-thermal emission was obtained from G156.2+5.7. These results are consistent with the picture of an evolved SNR.

Uchida, Hiroyuki↗

Probing for Exoplanets Hiding in Dusty Debris Disks: Disk Imaging, Characterization, and Exploration with HST-STIS Multi-roll Coronagraphy

Spatially resolved scattered-light images of circumstellar debris in exoplanetary systems constrain the physical properties and orbits of the dust particles in these systems. They also inform on co-orbiting (but unseen) planets, the systemic architectures, and forces perturbing the starlight-scattering circumstellar material. Using HST/STIS broadband optical coronagraphy, we have completed the observational phase of a program to study the spatial distribution of dust in a sample of ten circumstellar debris systems, and one "mature" protoplanetrary disk all with HST pedigree, using PSF-subtracted multi-roll coronagraphy. These observations probe stellocentric distances greater than or equal to 5 AU for the nearest systems, and simultaneously resolve disk substructures well beyond corresponding to the giant planet and Kuiper belt regions within our own Solar System. They also disclose diffuse very low-surface brightness dust at larger stellocentric distances. Herein we present new results inclusive of fainter disks such as HD92945 (F (sub disk) /F (sub star) = 5x10 (sup -5) confirming, and better revealing, the existence of a narrow inner debris ring within a larger diffuse dust disk. Other disks with ring-like sub-structures and significant asymmetries and complex morphologies include: HD181327 for which we posit a spray of ejecta from a recent massive collision in an exo-Kuiper belt; HD61005 suggested to be interacting with the local ISM; HD15115 and HD32297, discussed also in the context of putative environmental interactions. These disks, and HD15745, suggest that debris system evolution cannot be treated in isolation. For AU Mic's edge-on disk we find out-of-plane surface brightness asymmetries at greater than or equal to 5 AU that may implicate the existence of one or more planetary perturbers. Time resolved images of the MP Mus proto-planetary disk provide spatially resolved temporal variability in the disk illumination. These and other new images from our HST/STIS GO/12228 program enable direct inter-comparison of the architectures of these exoplanetary debris systems in the context of our own Solar System.

stellocentric distances↗

Polycyclic Aromatic Hydrocarbons

Carbonaceous materials play an important role in space. Polycyclic Aromatic Hydrocarbons (PAHs) are a ubiquitous component of the carbonaceous materials. PAHs are the best-known candidates to account for the IR emission bands. They are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge is to reproduce in the laboratory the physical conditions that exist in the emission and absorption interstellar zones. The harsh physical conditions of the ISM -low temperature, collisionless, strong UV radiation fields- are simulated in the laboratory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions and radicals are formed from the neutral precursors in an isolated environment at low temperature and probed with high-sensitivity cavity ringdown spectroscopy in the NUV-NIR range. Carbon nanoparticles are also formed during the short residence time of the precursors in the plasma and are characterized with time-offlight mass spectrometry. These experiments provide unique information on the spectra of large carbonaceous molecules and ions in the gas phase that can now be directly compared to interstellar and circumstellar observations (IR emission bands, DIBs, extinction curve). These findings also hold great potential for understanding the formation process of interstellar carbonaceous grains. We will review recent progress in the experimental and theoretical studies of PAHs, compare the laboratory data with astronomical observations and discuss the global implications.

Salama, Farid↗

The infrared structure of M33

IRAS spatial observations of M33 are presented and compared to UV optical, and radio wavelength data. At 12, 25, 60, and 100 microns the emission appears as two bright spiral arms superposed on a diffuse disk, with localized sources at the position of the nucleus and the brightest H II region complexes. The global IR properties of M33 are characteristic of quiescent spirals. The 8-30 micron mid-IR global emission is about 20 percent of the far-IR emission, similar to the ratio of these fluxes found for the local ISM. The local IR excess of M33 is about 2-3 times larger than the excess derived for H II regions in the Galaxy. The radial distributions of the IR colors are flat or nearly flat, implying near-constant dust temperatures across the diffuse disk. The integrated F(IR)-to-radio continuum emission of M33 follows the relation seen in other galaxies, but the radial distribution of the two emission components differ. A striking correlation is seen between the IR emission structure and the distribution of H II regions.

Rice, W.↗