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NASA NTRS2003

Optimizing IV and V for Mature Organizations

NASA is intending for its future software development agencies to have at least a Level 3 rating in the Carnegie Mellon University Capability Maturity Model (CMM). The CMM has built-in Verification and Validation (V&V) processes that support higher software quality. Independent Verification and Validation (IV&V) of software developed by mature agencies can be therefore more effective than for software developed by less mature organizations. How is Independent V&V different with respect to the maturity of an organization? Knowing a priori the maturity of an organization's processes, how can IV&V planners better identify areas of need choose IV&V activities, etc? The objective of this research is to provide a complementary set of guidelines and criteria to assist the planning of IV&V activities on a project using a priori knowledge of the measurable levels of maturity of the organization developing the software.

Fuhman, Christopher↗

NASA NTRS2008

The First Detection of [O IV] from an Ultraluminous X-ray Source with Spitzer: Evidence of High Unbeamed Luminosity in Holmberg II ULX

We present the first Spitzer Infrared Spectrograph (IRS) observations of the [O IV] 25.89 micron emission line detected from the ultraluminous X-ray source (ULX) in Holmberg II. This line is a well established signature of high excitation, usually associated with AGN. Its detection suggests that the ULX has a strong impact on the surrounding gas. A Spitzer high resolution spectral map shows that the [O IV] is coincident with the X-ray position of the Holmberg II ULX. We find that the luminosity and the morphology of the line emission is consistent with photoionization by the soft X-ray and far ultraviolet (FUV) radiation from the accretion disk of the binary system and inconsistent with narrow beaming. We show that the emission nebula is radiation bounded both in the line of sight direction and to the west, and probably matter bounded to the east. Evidence for a massive black hole (BH) in this ULX is mounting. Detailed photoionization models favor an intermediate mass black hole of at least 85 Solar Mass as the ionization source for the [OIV] emission. We find that the spectral type of the companion star strongly affects the expected strength of the [O IV] emission. This finding could explain the origin of [O IV] in some starburst galaxies containing black hole binaries.

Berghea, C. T.↗

NASA NTRS2009

The First Detection of [O IV] from an Ultraluminous X-ray Source with Spitzer: Evidence for High Luminosity in Holmberg II ULX - 2

This is the second of two papers examining Spitzer Infrared Spectrograph (IRS) observations of the ultraluminous X-ray source (ULX) in Holmberg II. Here we perform detailed photoionization modeling of the infrared lines. Our analysis suggests that the luminosity and morphology of the [O IV] 25.89 micron emission line is consistent with photoionization by the soft X-ray and far ultraviolet (FUV) radiation from the accretion disk of the binary system and inconsistent with narrow beaming. We show that the emission nebula is matter-bounded both in the line of sight direction and to the east, and probably radiation-bounded to the west. A bolometric luminosity in excess of 10(exp 40) erg/s would be needed to produce the measured [O IV] flux. We use modeling and previously published studies to conclude that shocks likely contribute very little, if at all, to the high-excitation line fluxes observed in the Holmberg II ULX. Additionally, we find that the spectral type of the companion star has a surprisingly strong effect on the predicted strength of the [O IV] emission. This finding could explain the origin of [O IV] in some starburst systems containing black hole binaries.

Berghea, C. T.↗

NASA NTRS2009

The First Detection of [O IV] from an Ultraluminous X-ray Source with Spitzer. II. Evidence for High Luminosity in Holmberg II ULX

This is the second of two papers examining Spitzer Infrared Spectrograph (IRS) observations of the ultraluminous X-ray source (ULX) in Holmberg II. Here we perform detailed photoionization modeling of they infrared lines. Our analysis suggests that the luminosity and morphology of the [O IV] 25.89 micron emission line is consistent with photoionization by the soft X-ray and far ultraviolet (FUV) radiation from the accretion disk of the binary system and inconsistent with narrow beaming. We show that the emission nebula is matter-bounded both in the line of sight direction and to the east, and probably radiation-bounded to the west. A bolometric luminosity in excess of 1040 erg per second would be needed to produce the measured [O IV] flux. We use modeling and previously published studies to conclude that shacks likely contribute very little, if at all, to the high excitation line fluxes observed in the Holmberg II ULX. Additionally, we find that the spectral type of the companion star has a surprisingly strong effect on they predicted strength of the [O IV] emission. This finding could explain the origin of [O IV] hi some starburst systems containing black hole binaries.

Berghea, C. T.↗

NASA NTRS2011

Ares I-X Range Safety Simulation and Analysis IV and V

NASA s Ares I-X vehicle launched on a suborbital test flight from the Eastern Range in Florida on October 28, 2009. NASA generated a Range Safety (RS) product data package to meet the RS trajectory data requirements defined in the Air Force Space Command Manual (AFSPCMAN) 91-710. Some products included were a nominal ascent trajectory, ascent flight envelopes, and malfunction turn data. These products are used by the Air Force s 45th Space Wing (45SW) to ensure public safety and to make flight termination decisions on launch day. Due to the criticality of the RS data, an independent validation and verification (IV&V) effort was undertaken to accompany the data generation analyses to ensure utmost data quality and correct adherence to requirements. As a result of the IV&V efforts, the RS product package was delivered with confidence that two independent organizations using separate simulation software generated data to meet the range requirements and yielded similar results. This document captures the Ares I-X RS product IV&V analysis, including the methodology used to verify inputs, simulation, and output data for certain RS products. Additionally a discussion of lessons learned is presented to capture advantages and disadvantages to the IV&V processes used.

Merry, Carl M.↗

NASA NTRS2012

IV&V Project Assessment Process Validation

The Space Launch System (SLS) will launch NASA's Multi-Purpose Crew Vehicle (MPCV). This launch vehicle will provide American launch capability for human exploration and travelling beyond Earth orbit. SLS is designed to be flexible for crew or cargo missions. The first test flight is scheduled for December 2017. The SLS SRR/SDR provided insight into the project development life cycle. NASA IV&V ran the standard Risk Based Assessment and Portfolio Based Risk Assessment to identify analysis tasking for the SLS program. This presentation examines the SLS System Requirements Review/System Definition Review (SRR/SDR), IV&V findings for IV&V process validation correlation to/from the selected IV&V tasking and capabilities. It also provides a reusable IEEE 1012 scorecard for programmatic completeness across the software development life cycle.

Driskell, Stephen↗

NASA NTRS2013

Report for 2012 from the Bordeaux IVS Analysis Center

This report summarizes the activities of the Bordeaux IVS Analysis Center during the year 2012. The work focused on (i) regular analysis of the IVS-R1 and IVS-R4 sessions with the GINS software package; (ii) systematic VLBI imaging of the RDV sessions and calculation of the corresponding source structure index and compactness values; (iii) investigation of the correlation between astrometric position instabilities and source structure variations; and (iv) continuation of our VLBI observational program to identify optically-bright radio sources suitable for the link with the future Gaia frame. Also of importance is the 11th European VLBI Network Symposium, which we organized last October in Bordeaux and which drew much attention from the European and International VLBI communities.

Charlot, Patrick↗

NASA NTRS2018

IV&V Planning & Execution Initiative

Independent verification and validation (IV&V) is a systems engineering discipline which seeks to provide confidence that mission-critical software-dependent systems will operate safely and achieve all mission objectives. In order to optimize application of IV&V resources, it is necessary to identify specific assurance objectives that are most likely to reveal difficulty and therefore to increase confidence. Software assurance literature deals predominantly with the code itself. However, our experience is that the most significant software-related issues are discovered via analysis of other system artifacts such as operations concepts, requirements and design. Consequently, it is desirable to, when assessing risk and defining assurance objectives, consider all facets of the software system architecture. We describe in this presentation progress and lessons learned from an IV&V capability development initiative to enhance the IV&V project planning process using all available architecture information.

Risk↗

NASA NTRS2022

Adaptive IV&V for Increasingly Complex Software Systems

As NASA software systems continue to innovate, becoming more complex and nondeterministic, the need for the NASA IV&V Program to become systemically adaptive to ensure mission success is paramount. To ensure adaptability within resource constraints, IV&V has developed an agile, risk-based approach to identify, characterize, scope, focus, and prioritize mission assurance activities. This risk based adaptive framework has been applied to trends such as increased reliance on data driven algorithms for safety and mission critical software behavior, use of MBSE in system design, and application of agile principles to embedded software development. The framework is enabled by continuous innovation of new approaches such as software only test beds, assurance design tools, and initiatives that augment IV&V assurance methods with artificial intelligence and machine learning techniques. This presentation will highlight the trends the NASA IV&V Program is seeing, the innovative steps it is taking to address those challenges, and how it is postured to address evolving risk and constantly changing and new technologies.

Wesley W Deadrick↗

NASA NTRS2023

X-57 Mod IV Avionics Power Analysis

The X-57 Mod IV Avionics Power Analysis was developed to provide the design requirements for the X-57 Mod IV Avionics Power System. In the Mod IV configuration, twelve 13kW high lift motors and motor controllers are distributed along the leading edge of the Mod III carbon fiber wing to assist with lift during takeoff and landing. These motors are turned off during the cruise phase of the flight. A high voltage traction battery (460 VDC nominal) supplies power for the high lift motors. The Mod IV avionics power design uses the Mod II and Mod III power architecture as a baseline. Please see the Mod II Avionics Power Analysis (ANLYS-CEPT-020) for a description of the Mod II and Mod III avionics power design.

Franklin Harris↗

NASA NTRSDate not supplied

Classical Flutter Analysis of X-57 Aircraft Mod II, III, and IV Configurations

To support airworthiness assessment of the X-57 electric propulsion demonstrator aircraft, the National Aeronautics and Space Administration (NASA) completed classical flutter analysis of the Mod II, Mod III, and Mod IV aircraft configurations. Aeroelastic analysis was primarily performed using the ZAERO analysis code developed by Zona Technology. Supplemental computational fluid dynamics (CFD) flutter analysis for the Mod III and Mod IV configurations was performed using NASA’s FUN3D software to verify the aeroelastic behavior at deployed flaps conditions. The NASTRAN finite element models (FEMs) used for aeroelastic analysis were developed by NASA. The final Mod II FEM utilized shell elements for the wing and fuselage, and beam elements for the tail and wing control surfaces. For Mod III and Mod IV aircraft models, shell element wing FEMs developed throughout the Mod III/IV wing design cycle were utilized. The fuselage and empennage FEM components were shared between the Mod II, III, and IV aircraft models. ZAERO analyses predicted flutter boundaries were >60% beyond the X-57 flight-test envelope never exceed airspeed (V NE ) for all configurations. Aeroelastic Reynolds-averaged Navier–Stokes (RANS) CFD simulations using FUN3D of the Mod III/IV configurations predicted flap mode instability did not occur until at least speeds of 60% higher than the Mod III/IV maximum flap deployment airspeed (V FE ).

Keerti K. Bhamidipati↗

NASA NTRS2023

Performance of the IVS R1 and R4 Sessions

The International VLBI Service for Geodesy and Astrometry (IVS) has observed the weekly IVS-R1 (R1) and IVS-R4 (R4) series of sessions since 2002. These regular series are generally stable in the sense that the networks were designed to be similar from week to week. The uniformity of these series has allowed researchers to conduct many scientific investigations. The IVS also observes with other networks that allow continued sampling of data from all VLBI stations, but the R1 and R4 observing sessions are a dominant part of overall VLBI observing accounting for 1841 sessions out of a total of 3129 24-hour sessions from 2002.0 to 2020.0 (where the last R1 and R4 in 2019 was on December 30 and December 26, respectively). In this paper, we investigate the evolution of these series in terms of their observing networks. We also discuss the construction of the R1 and R4 networks and the scheduling of these sessions. The performance of these networks in terms of the formal precision of polar motion have improved by factors of 2–3 over the period from 2002.0 to 2018.0. UT1 precision improved by a factor of about 1.2–1.5. The main reason for this improvement is the increased size of the networks. We also discuss the effect on this improvement arising from changes in the data rate and the number of observed sources. There is some degradation in performance after 2018 that is most likely due to a decline in the number of available network stations.

Cynthia C. Thomas↗

NASA NTRS1963

Tiros IV Radiation Data Catalog and Users' Manual

The TIROS IV Meteorological Satellite contains a medium resolution scanning radiometer. Two of the channels of this instrument are sensitive to reflected solar radiation and the remaining two respond to emitted thermal radiation from the earth and its atmosphere. The two thermal channels are calibrated in terms of equivalent blackbody temperatures, and the reflected solar radiation channels in terms of effective radiant emittances. The calibration data, along with orbital and attitude data and the radiation data from the satellite, were incorporated in a computer program for an IBM 7090 which was used to produce, in binary form, the "Final Meteorological Radiation Tape" which is the basic repository of all radiation data. After launch, the radiometer displaye d the same degradation of response characteristics as did its predecessors in TIROS II and TIROS III. The onset of degradation results in a departure of the data from the prelaunch laboratory calibration. The cause of degradation has not been determined, and the matter is still being studied at the Goddard Space Flight Center. Before work with the TIROS IV radiation data is attempted, an understanding of the radiometer, its calibration, and the problems encountered in the experiment, especially from response degradation, is essential. The instrumentation design, development work, and the calibrations herein described were performed by the Goddard Space Flight Center Staff, whereas the computer and programming efforts were carried out jointly by the staffs of the National Weather Satellite Center, U. S. Weather Bureau, and the Goddard Space Flight Center. In this Catalog-Manual, the radiometer an d its calibration, data processing, the "Final Meteorological Radiation Tape", the observed degradation patterns, and possible corrections for degradation are discussed. The Catalog-Manual also includes, in two forms, documentation of each orbit of successfully reduced radiation data acquired by TIROS IV. One method of presentation is the Index of Final Meteorological Radiation Tapes and the other is a Subpoint Track, Summary of Available Radiation Data in diagrammatic form.

TIROS IV SATELLITE↗

NASA NTRSDate not supplied

International DORIS Service (IDS): The IDS at 20 and the IVS at 25; Together on a Long Journey

This is an invited presentation to the the IVS General Meeting 2024 to celebrate the 25th anniversary of the International VLBI Service (IVS). The presentation shares aspects of the common journey of the International DORIS Service (IDS), and IVS over the last 20 years, as sibling services of the International Association of Geodesy, and as space geodetic techniques that contribute to the International Terrestrial Reference Frame (ITRF).

DORIS↗

DOE OSTI2025

High Pressure Synthesis of Pr 2 O 5 – A Unique Lanthanoid(IV) Oxide Peroxide

Abstract Reacting praseodymium(IV) oxide with oxygen at 27 GPa in a diamond anvil cell yielded the oxide peroxide Pr 2 IV (O 2 )O 3 , which was characterized by single crystal X‐ray diffraction on multi‐grain samples, Raman spectroscopy and quantum theoretical calculations at various pressure points. The presence of tetravalent praseodymium ions is supported by electronic structure calculations, showing a band gap of ca. 1.2 eV, which is consistent with the anticipated chemical model of an ionic solid. Pr 2 (O 2 )O 3 thus far represents the most oxygen rich phase of any binary compound of a lanthanoid and oxygen and is the first example of a peroxide anion next to Pr 4+ . Additionally, these results demonstrate that instead of oxidizing the praseodymium ions past their +IV oxidation state, oxygen undergoes a comproportionation to form peroxide anions. Direct oxidation of the oxide anions by Pr 4+ ‐ions was ruled out by a control experiment in argon instead of oxygen, where no oxidation of oxide ions was observed.

Chemistry↗

DOE OSTI2025

Homoleptic An(IV) Dimethyl Sulfoxide Complexes of Th–Pu Enable Insight into Solution Speciation and Redox

A family of 8- and 9- coordinate homoleptic dimethyl sulfoxide An(IV) complexes is used to evaluate the solvation properties of tetravalent actinide ions in dimethyl sulfoxide (DMSO) vs aqueous media. These compounds are prepared from aqueous mixtures of DMSO and yield crystalline solids, whose solid-state electronic absorption spectra are compared to solution phase spectra, providing insight into the solution speciation. The thermodynamics of the equilibria between the 8- and 9-coordinate compounds were determined experimentally and computationally, showing a trend that correlates with ionic radius. Cyclic voltammetry data for the +IV/+III couples of Np and Pu in the DMSO electrolyte indicate that the +IV ions are significantly stabilized compared to aqueous media due to the more donating nature of DMSO compared to water. As a result, computational studies of these systems indicate that further reactivity may take place upon reduction to the +III oxidation state.

Actinides↗

DOE OSTI2024

Experimental Definition of the S = 1 π vs S = 2 σ Reactivity and S = 2 Character in the Ground State of an S = 1 Fe IV O Complex

Iron(IV)-oxo intermediates found in iron enzymes and artificial catalysts are competent for H atom abstraction in catalytic cycles. For S = 2 intermediates, both axial and equatorial approaches are well-established. The mechanism for S = 1 sites is not as well understood: an equatorial approach is more energetically favorable, and an axial approach requires crossing from the S = 1 to the S = 2 surface. Here, in this study, we use 1s2p resonant inelastic X-ray scattering (RIXS) and Fe L-edge X-ray absorption spectroscopy on the S = 1 [Fe IV O(TMC)(CH3CN)] 2+ and observe both S = 2 and S = 1 final states, which enables the experimental evaluation of the energetics of the axial and equatorial reactivity of an S = 1 Fe IV O center on its S = 2 vs S = 1 surface. The observation of S = 2 final states in the RIXS spectrum demonstrates significant S = 2 character spin–orbit mixed into the S = 1 ground state.

energy↗

DOE OSTI2024

Photoluminescence of a Uranium(IV) Alkoxide Complex

In this report, we describe the photoluminescence of a homoleptic uranium(IV) alkoxide complex. Excitation of [Li(THF)] 2 [U IV (O t Bu) 6 ] leads to the first example of photoluminescence from a well-defined actinide complex originating from an f–f excitation, supported by second order multiconfigurational electronic structure calculations including spin–orbit coupling. These calculations show strong spin–orbit coupling between the excited triplet and singlet states for the 5f-orbital manifold, which leads to a long-lived excited state lifetime of 0.85 s at low temperature. The photophysical properties of homoleptic uranium(V) and uranium(VI) tertbutoxide complexes are also presented; we find that oxidation of the uranium(IV) alkoxide results in quenching of luminescence in [Li(THF)][U V (O t Bu) 6 ] and [U VI (O t Bu) 6 ]. This is attributed to competing ligand to metal charge transfer absorption processes shifted to lower energy upon oxidation of the actinide center, which mask the relevant f–f transitions in the visible region of the electronic absorption spectrum.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗