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Low Latency Flux and Concentration Datasets in Support of Greenhouse Gas Monitoring Based on NASA's GEOS Modeling and Data Assimilation System

We present efforts to develop space-based greenhouse gas monitoring systems that can provide low latency information and traceability to independent observations. Through support from its Carbon Monitoring System program, NASA has developed the capability to assimilate XCO2 retrievals from the Orbiting Carbon Observatory, 2 (OCO-2) into the Goddard Earth Observing System (GEOS) Constituent Data Assimilation System (CoDAS) to create gap-filled, three-dimensional (3D) estimates of CO2 mixing ratio. When OCO-2 data are not available, concentration fields are further informed by a bottom-up flux package based on remotely sensed fire radiative power, nighttime lights, and vegetation reflectance combined with estimates of atmospheric growth rate based on surface in situ data. The 3D nature of this dataset supports evaluation with independent aircraft data, helping to ensure transparency of remotely sensed data products. These quasi-operational data are currently produced 2-3 months behind real time and are distributed via NASA and international dashboard services to a variety of end users. In this presentation, we provide an overview of the system as well as remaining data gaps and modeling challenges. We also highlight the application of this dataset for detecting emissions anomalies associated with COVID-19 and comparing against independent emissions estimates. Finally, we highlight a new NASA initiative called the Earth Information System (EIS), which aims to support open science and applications by leveraging emerging cloud computing capabilities to increase access to NASA’s greenhouse gas datasets, opportunities for co-development, and transparency in methods for analysis and flux attribution.

Lesley Ott↗
DOE OSTI2026

Machine learning pipeline for denoising low signal-to-noise ratio and out-of-distribution transmission electron microscopy datasets

High-resolution transmission electron microscopy (HRTEM) is crucial for observing material’s structural and morphological evolution at Angstrom scales, but the electron beam can alter these processes. Devices such as CMOS-based direct-electron detectors operating in electron-counting mode can be utilized to substantially reduce the electron dosage. However, the resulting images often lead to a low signal-to-noise ratio, which requires frame integration that sacrifices temporal resolution. Several machine learning (ML) models have been recently developed to successfully denoise HRTEM images. Yet, these models are often computationally expensive, and their inference speeds on GPUs are outpaced by the imaging speed of advanced detectors, precluding in situ analysis. Furthermore, the performance of these denoising models on datasets with imaging conditions that deviate from the training datasets has not been evaluated. To mitigate these gaps, we propose a new self-supervised ML denoising pipeline specifically designed for time-series HRTEM images. This pipeline integrates a blind-spot convolution neural network with pre-processing and post-processing steps, including drift correction and low-pass filtering. Results demonstrate that our model outperforms various other ML and non-ML denoising methods in noise reduction and contrast enhancement, leading to improved visual clarity of atomic features. Additionally, the model is drastically faster than U-Net-based ML models and demonstrates excellent out-of-distribution generalization. The model’s computational inference speed is in the order of milliseconds per image, rendering it suitable for application in in-situ HRTEM experiments.

36 MATERIALS SCIENCE↗
NASA NTRS1997

Real-Time X-Ray Transmission Microscopy of Solidifying Al-In Alloys

Real-time observations of transparent analog materials have provided insight, yet the results of these observations are not necessarily representative of opaque metallic systems. In order to study the detailed dynamics of the solidification process, we develop the technologies needed for real-time X ray microscopy of solidifying metallic systems, which has not previously been feasible with the necessary resolution, speed, and contrast. In initial studies of Al-In monotectic alloys unidirectionally solidified in an X-ray transparent furnace, in situ records of the evolution of interface morphologies, interfacial solute accumulation, and formation of the monotectic droplets were obtained for the first time: A radiomicrograph of Al-30In grown during aircraft parabolic maneuvers is presented, showing the volumetric phase distribution in this specimen. The benefits of using X-ray microscopy for postsolidification metallography include ease of specimen preparation, increased sensitivity, and three-dimensional analysis of phase distribution. Imaging of the solute boundary layer revealed that the isoconcentration lines are not parallel (as is often assumed) to the growth interface. Striations in the solidified crystal did not accurately decorate the interface position and shape. The monotectic composition alloy under some conditions grew in an uncoupled manner.

Curreri, Peter A.↗
DOE OSTI2025

Comparison of the Distribution of the In Situ Ring Current Density Based on Magnetic Field Observations From THEMIS, MMS and Cluster

Abstract We review and extend previous work on the ring current density distribution by applying the curlometer technique to multi‐spacecraft magnetic field data on different spatial scales, directly comparing the results of three space missions: Time History of Events and Macroscale Interactions during Substorms (THEMIS), The Magnetospheric Multiscale (MMS) and Cluster, that have so far accrued decades of data on a range of spatial separation scales. We suggest that the statistical results of Cluster data over two decades can illustrate well the overall form of the ring current (in the ring plane), but can underestimate the current density, while THEMIS (partially) and MMS are able to observe the detailed structure of the ring current and indeed show different behavior on some (smaller) spatial scales. These results suggest that, in addition to the local time and radial form, reported previously, the morphology of the ring current may also depend on magnetic latitude, as influenced by the tilt angle between the inner and outer magnetic fields.

Tan, X. [School of Space and Earth Sciences Beihan↗
DOE OSTI2025

Real-Time Measurements of Gas-Phase Medium-Chain Chlorinated Paraffins Reveal Daily Changes in Gas-Particle Partitioning Controlled by Ambient Temperature

Chlorinated paraffins (CPs) are synthetic polychlorinated n-alkanes produced as mixtures of a range of C x Cl y H 2x–y+2 formulas. CPs have numerous industrial applications but are toxic, long-lived, and environmentally ubiquitous with environmental releases occurring throughout their production, use, and disposal. Short-chain chlorinated paraffins (SCCPs, C 10–13 ) have been regulated by the United States Environmental Protection Agency since 2009 and by the Stockholm Convention since 2017. SCCP regulation is expected to cause increased production of medium-chain chlorinated paraffins (MCCPs; C 14–17 ), which are currently under consideration for Stockholm Convention regulations. Thus, there is a need to improve the understanding of MCCP environmental transport, distribution, and fate. Existing measurements are limited in their spatial and temporal coverage. Measurements of CP atmospheric loading are particularly scarce. Historically, these measurements have required long sampling times, obscuring the temporal behavior of atmospheric CPs. We report real-time in situ measurements of 18 gas-phase MCCPs. These measurements were made in the United States Southern Great Plains with nitrate ion chemical ionization mass spectrometry (NO 3 –CIMS). Here, the estimated average lower-limit concentration of MCCPs is on the order of single-digit ng/m 3 . MCCP diel behavior is partially explained by gas-particle partitioning with implications for MCCP transport and lifetimes.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1975

Winter bulge and diurnal variations in hydrogen inferred from AE-C composition measurements

In situ mass spectrometric measurements of ion and neutral particle thermospheric compositions have been used to infer the latitudinal and diurnal variations of thermospheric atomic hydrogen for solstice conditions. Local time-dependent and local time-independent components of the observed hydrogen distribution were separated on the basis of a model generated by expanding the log of neutral hydrogen concentration in terms of spherical harmonics. Results are compared with analogous data on N2 concentration; the comparison reveals an anticorrelation between gas temperature and hydrogen concentration. The slope of this anticorrelation line represents the 'zero flux condition' from the exosphere theory of Hodges (1973), thus further bearing out the conclusion that exospheric flow is the dominant process governing the global distribution of hydrogen.

Brinton, H. C.↗
NASA NTRS2020

Evaluation and Validation of a High Spatial Resolution Satellite Soil Moisture Product over the Continental United States

The soil moisture (SM) data retrieved from the Soil Moisture Active and Passive (SMAP) satellite are available at a 9 km grid spacing since April 2015. This product can provide valuable information for research and applications in hydrology and other related fields. However, the resolution may be too coarse for applications at catchment or field scale. In this study, an established downscaling methodology, which had a major modification regarding its application on the SMAP 33 km domain, was implemented to develop a 1 km soil moisture product based on the SMAP 9 km data. The algorithm proposed here is based on the thermal inertia principle and developed by modeling the relationship between surface temperature difference and SM for different Normalized Difference Vegetation Index (NDVI) classes. The model functions were established and tuned using data from the NASA’s Land Information System (LIS) North America Land Data Assimilation System (NLDAS) and remotely sensed VISible/InfRared (VIS/IR) reflectance data from Long Term Data Record (LTDR) AVHRR (Advanced Very High Resolution Radiometer) for the growing season months of April-September 1981–2018. These were then implemented using the MODIS (Moderate Resolution Imaging Spectroradiometer) data over the Continental United States (CONUS) domain. Validation activities were carried out using in situ measurements distributed through the International Soil Moisture Network (ISMN). The validation results computed using the 1 km SM data showed that the R2, unbiased RMSE (root mean square error) and bias were improved relative to the 9 km SMAP product by 0.045, 0.018m3/m3 and 0.001m3/m3, respectively. The 1 km SM also exhibited a strong time-series autocorrelation. Further accuracy assessment analyses indicated that precipitation might contribute to the uncertainties in both the 9 km SMAP and 1 km downscaled SMAP SM products.

SMAP↗
NASA NTRS2023

Spatial distributions of Tribrachidium, Rugoconites, and Obamus from the Ediacara Member (Rawnsley Quartzite), South Australia

The spatial distribution of in situ sessile organisms, including those from the fossil record, provides information about life histories, such as possible dispersal and/or settlement mechanisms, and how taxa interact with one another and their local environments. At Nilpena Ediacara National Park (NENP), South Australia, the exquisite preservation and excavation of 33 fossiliferous bedding planes from the Ediacara Member of the Rawnsley Quartzite reveals in situ communities of the Ediacara Biota. Here, the spatial distributions of three relatively common taxa, Tribrachidium, Rugoconites, and Obamus, occurring on excavated surfaces were analyzed using spatial point pattern analysis. Tribrachidium have a variable spatial distribution, implying that settlement or post-settlement conditions/preferences had an effect on populations. Rugoconites display aggregation, possibly related to their reproductive methods in combination with settlement location availability at the time of dispersal and/or settlement. Additionally, post-settlement environmental controls could have affected Rugoconites on other surfaces, resulting in lower populations and densities. Both Tribrachidium and Rugoconites also commonly occur as individuals or in low numbers on a number of beds, thus constraining possible reproductive strategies and environmental/substrate preferences. The distribution of Obamus is consistent with selective settlement, aggregating near conspecifics and on substrates of mature microbial mat. This dispersal process is the first example of substrate-selective dispersal among the Ediacara Biota, thus making Obamus similar to numerous modern sessile invertebrates with similar dispersal and settlement strategies. Resumen La distribución espacial de los organismos sésiles in situ, incluyendo los del registro fósil, brinda información sobre las historias de vida, tal como los posibles mecanismos de dispersión y/o asentamiento, y sobre cómo los taxones interactúan entre sí y entre sus entornos locales. En el Parque Nacional Nilpena Ediacara (NENP), Australia Meridional, la excelente preservación y excavación de 33 planos de lecho fosilífero del Miembro Ediacara de la Cuarcita Rawnsley revela comunidades in situ de la biota ediacárica. En este estudio analizamos las distribuciones espaciales de tres taxones relativamente comunes, Tribrachidium, Rugoconites y Obamus, que se encuentran en superficies excavadas mediante el análisis de patrones de puntos espaciales. Tribrachidium tiene una distribución espacial variable, lo que implica que las condiciones/preferencias durante o después del asentamiento tuvieron un efecto en las poblaciones. Rugoconites muestran agregación, posiblemente relacionado con sus métodos reproductivos en combinación con la disponibilidad de lugares de asentamiento en el momento de la dispersión y/o asentamiento. Además, los controles ambientales posteriormente al asentamiento podrían estar afectando a Rugoconites en otras superficies, lo que resultaría en poblaciones y densidades más bajas. Tanto Tribrachidium como Rugoconites ocurren como individuos en varios lechos, restringiendo las posibles estrategias reproductivas y las preferencias ambientales/de sustrato. La distribución de Obamus es consistente con un asentamiento selectivo, agregando cerca de sus congéneres y sobre sustratos de tapete microbiano maduro. Este proceso de dispersión es el primer ejemplo de dispersión selectiva de sustrato entre la biota ediacárica, lo que hace que Obamus sea similar a numerosos invertebrados sésiles modernos con estrategias similares de dispersión y asentamiento.

Phillip C. Boan↗
DOE OSTI2025

Collaborative: in situ visual analytics technologies for extreme scale combustion simulations

This project aims to drastically enhance the usability of in situ analysis and visualization for extreme-scale scientific simulations. Current exascale computing capabilities promise to offer greater predictive ability of simulations and to further push the frontiers of science and technology. However, to validate the simulation output at extreme scale, examine the modeled phenomena, and discover previously unknowns from the output data, the output must be reduced or transformed in situ as it is being generated during the simulation such that the amount of data to examine and store is kept to a minimum. Such in situ approaches allow us to process and analyze the data and any embedded geometry to an extent that would be prohibitively expensive, if not impossible, to perform as a post hoc task. While in situ processing has been demonstrated to be a feasible and promising approach, its full potential has not yet been leveraged. In this project, we have developed comprehensive enhancements to in situ technology based on probability distributions in data. Our research focuses on jointly developing new ways of interacting with massive statistical samples while creatively utilizing new state-of-the-art computational resources to push the boundaries of in situ exploration. Moreover, we have developed new time-dependent techniques to enable previously unattainable capabilities in areas such as intelligent simulation steering and precise feature identification. We have experimentally studied our design and implementation at NERSC and OLCF, and are able to leverage existing in situ infrastructures whenever possible. While the exemplar in this project is combustion, many other fields for which turbulent transport is important, e.g., fusion, climate, astrophysics among others, encounter similar issues as simulations scale up to the exascale. This project shows its potential to generate high impact on DOE missions since the resulting technology promises to improve scientists’ ability to rapidly and correctly interpret and tune extreme-scale simulations, leading to new scientific understanding and advancements.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1981

Energetic electrons and plasma waves associated with a solar type III radio burst

Detailed in situ observations from the ISEE 3 spacecraft of energetic electrons, plasma waves, and radio emission for the type II solar radio burst of February 17, 1979, are presented. The reduced, one-dimensional electron distribution function is constructed as a function of time. Since the faster electrons arrive before the slower ones, a bump on tail distribution forms which is unstable to the growth of Langmuir waves. The plasma wave growth computed from the distribution function agrees well with the observed onset of the Langmuir waves, and there is qualitative agreement between variations in the plasma wave levels and in the development of regions of positive slope in the function. The evolution of the function, however, predicts far higher plasma wave levels than those observed. The maximum levels observed are approximately equal to the threshold for nonlinear wave processes, such as oscillation two-stream instability and soliton collapse.

Lin, R. P.↗
NASA NTRS1996

DC-8 scanning lidar characterization of aircraft contrails and cirrus clouds

A Subsonic Assessment (SASS) element of the overall Atmospheric Effects of Aviation Project (AEAP) was initiated by NASA to assess the atmospheric impact of subsonic aircraft. SRI was awarded a project to develop and test a scanning backscatter lidar for installation on the NASA DC-8 (year 1), participate in the Subsonic Aircraft: Contrail and Cloud Effects Special Study (SUCCESS) field program (year 2), and conduct a comprehensive analysis of field data (year 3). A scanning mirror pod attached to the DC-8 aircraft provides for scanning lidar observations ahead of the DC-8 and fixed-angle upward or downward observations. The lidar system installed within the DC-8 transmits 275 MJ at 1.06 gm wavelength or about 130 mJ at 1.06 and 0.53 gm simultaneously. Range-resolved aerosol backscatter is displayed in real time in terms of cloud/contrail spatial distributions. The objectives of the project are to map contrail/cloud vertical distributions ahead of DC-8; provide DC-8 guidance into enhanced scattering layers; document DC-8 flight path intersection of contrail and cloud geometries (in-situ measurement positions relative to cloud/contrail shape and an extension of in-situ measurements into the vertical -- integrated contrail/cloud properties); analyze contrail/cloud radiative properties with LIRAD (combined lidar and radiometry) technique; evaluate mean particle sizes of aircraft emissions from two-wavelength observations; study contrail/cloud interactions, diffusion, and mass decay/growth; and make observations in the near-field of aircraft engine emissions. The scanning mirror pod may also provide a scanning capability for other remote sensing instruments.

Nielsen, Norman B.↗
NASA NTRS2002

Science Prospects from the STEREO Mission

The solar magnetic field is constantly generated beneath the surface of the Sun by the solar dynamo. To balance this flux generation, there is constant dissipation of magnetic flux at and above the solar surface. The largest phenomenon associated with this dissipation is the Coronal Mass Ejection (CME). The Solar and Heliospheric Observatory (SOHO) has provided remarkable views of the corona and CMEs, and served to highlight how these large interplanetary disturbances can have terrestrial consequences. STEREO is the next logical step to study the physics of CME origin, propagation, and terrestrial effects. Two spacecraft with identical instrument complements will be launched on a single launch vehicle in November 2007. One spacecraft will drift ahead and the second behind the Earth at a separation rate of 22 degrees per year. Observation from these two vantage points will for the first time allow the observation of the three-dimensional structure of CMEs and the coronal structures where they originate. Each STEREO spacecraft carries a complement of 10 instruments, which include (for the first time) an extensive set of BOTH remote sensing and in-situ instruments. The remote sensing suite is capable of imaging CMEs from the solar surface out to beyond Earth's orbit (1 AU), and in-situ instruments are able to measure distribution functions for electrons, protons, and ions over a broad energy range, from the normal thermal solar in wind plasma to the most energetic solar particles. It is anticipated that these studies will ultimately lead to an increased understanding, of the CME process and eventually to the ability to predict CME occurrence and thereby 'forecast' the condition of the near-Earth environment.

Davila, Joseph M.↗
NASA NTRS2003

Solar Terrestrial Relations Observatory (STEREO)

The solar magnetic field is constantly generated beneath the surface of the Sun by the solar dynamo. To balance this flux generation, there is constant dissipation of magnetic flux at and above the solar surface. The largest phenomenon associated with this dissipation is the Coronal Mass Ejection (CME). The Solar and Heliospheric Observatory (SOHO) has provided remarkable views of the corona and CMEs, and served to highlight how these large interplanetary disturbances can have terrestrial consequences. STEREO is the next logical step to study the physics of CME origin, propagation, and terrestrial effects. Two spacecraft with identical instrument complements will be launched on a single launch vehicle in November 2007. One spacecraft will drift ahead and the second behind the Earth at a separation rate of 22 degrees per year. Observation from these two vantage points will for the first time allow the observation of the three-dimensional structure of CMEs and the coronal structures where they originate. Each STEREO spacecraft carries a complement of 10 instruments, which include (for the first time) an extensive set of both remote sensing and in-situ instruments. The remote sensing suite is capable of imaging CMEs from the solar surface out to beyond Earth's orbit (1 AU), and in-situ instruments are able to measure distribution functions for electrons, protons, and ions over a broad energy range, from the normal thermal solar wind plasma to the most energetic solar particles. It is anticipated that these studies will ultimately lead to an increased understanding of the CME process and provide unique observations of the flow of energy from the corona to the near-Earth environment. An international research program, the International Heliophysical Year (IHY) will provide a framework for interpreting STEREO data in the context of global processes in the Sun-Earth system.

Davila, Joseph M.↗
NASA NTRS2016

Extraction and Capture of Water from Martian Regolith Experimental Proof-of-Concept

Mars Design Reference Architecture 5.0:Lists in-situ resource utilization (ISRU) as enabling for robust human Mars missionsLO2LCH4 ascent propulsion 25,000 kg oxygen from atmosphere for ascent and life support Atmospheric based ISRU processes less operationally complex than surface based limited concept evaluation to date and Mars surface water property and distribution uncertainty would not allow [Mars soil water processing] to be base lined at this time Limited Concept Evaluation to Date Lunar regolith O2 extraction processing experience Lunar regolith is fluidized and heated to high temperatures with H2 to produce H2O from iron-bearing minerals Mars similarity concept: Soil placed in fluidized bed reactor Heated to moderate temperatures Inert gas flow used to fluidize the bed and help with water desorption Challenges: High-temperature dusty seals Working gas requires downstream separation and recycling to reduce consumables loss Batch process heating thermally inefficient.

in situ resource utilization↗
NASA NTRS2019

Sea Surface Salinity Distribution in the Southern Ocean as Observed from Space

Large-scale spatial and temporal variabilities of sea surface salinity (SSS) in the Southern Ocean from 2011 to 2017 were studied using products derived from microwave sensors on board Aquarius, Soil Moisture and Ocean Salinity (SMOS), and Soil Moisture Active and Passive (SMAP) satellites. Four products, three from Aquarius and one from SMOS, were evaluated and shown to be generally consistent within 0.3 to 0.6 psu and agree favorably with in situ measurements. However, although the Aquarius products show consistent seasonality of SSS with high values of 34.45 psu in October and low values of 33.40 psu in May, theSMOS and SMAP products lack such seasonal variations. This may be caused by larger uncertainties in the SMOS and SMAP data due in part to the lack of concurrent scatterometer measurements that is used to correct for roughness effects. The four products provide similar spatial distributions of SSS with root mean square difference from 0.25 to 0.58 psu. Differences among Aquarius products are mainly due to varying salinity retrieval algorithms, smoothing, and masking of sea ice, while the SMOS product showed the highest SSS deviation that is likely due to the bias adjustment done on the data set. Our analyses show that SSS in the Southern Ocean region has significant meridional variations with the lowest SSS near the ice edge and highest at lower latitudes. The SSS is also lowest in summer indicating the predominant influence of sea ice and glacial melt, but it stays low near ice edges even during the growth season. Salinity together with temperature is the key parameters that control the state and circulation of the World's oceans. The large‐scale distribution of the sea surface salinity of the Southern Ocean is quantified for the first time using Aquarius, Soil Moisture and Ocean Salinity, and Soil Moisture Active and Passive satellite microwave data. Seasonal and interannual changes in the distribution as affected by the sea ice cover, surface temperature, and precipitation are evaluated. Comparative studies were done, using four different products that are publicly available, in conjunction with in situ observations to gain insights into the true nature of the distribution and how consistently the sea surface salinity is depicted by the different products. There are general consistencies in the products, and discrepancies are attributed to different algorithms, smoothing techniques, and sea ice masking. Aquarius data are shown to have higher accuracy than Soil Moisture and Ocean Salinity and Soil Moisture Active and Passive products in part because of having concurrent scatterometer that provides accurate correction to roughness effects.

Garcia-Eidell, Cynthia↗
NASA NTRS2009

Saturn's Magnetosphere and Properties of Upstream Flow at Titan: Preliminary Results

Using Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) measurements, we present the ion fluid properties and its ion composition of the upstream flow for Titan's interaction with Saturn's magnetosphere. A 3D ion moments algorithm is used which is essentially model independent with only requirement is that ion flow is within the CAPS IMS 2(pi) steradian field-of-view (FOV) and that the ion 'velocity distribution function (VDF) be gyrotropic. These results cover the period from TA flyby (2004 day 300) to T22 flyby (2006 363). Cassini's in situ measurements of Saturn's magnetic field show it is stretched out into a magnetodisc configuration for Saturn Local Times (SLT) centered about midnight local time. Under those circumstances the field is confined near the equatorial plane with Titan either above or below the magnetosphere current sheet. Similar to Jupiter's outer magnetosphere where a magnetodisc configuration applies, one expects the heavy ions within Saturn's outer magnetosphere to be confined within a few degrees of the current sheet while at higher magnetic latitudes protons should dominate. We show that when Cassini is between dusk-midnight-dawn local time and spacecraft is not within the current sheet that light ions (H, 142) tend to dominate the ion composition for the upstream flow. If true, one may expect the interaction between Saturn's magnetosphere, locally devoid of heavy ions and Titan's upper atmosphere and exosphere to be significantly different from that for Voyager 1, TA and TB when heavy ions were present in the upstream flow. We also present observational evidence for Saturn's magnetosphere interaction with Titan's extended H and H2 corona which can extend approx. 1 Rs from Titan.

Sittler, E. C., Jr.↗
NASA NTRS2014

Global Distribution and Trends of Tropospheric Ozone: An Observation-Based Review

Tropospheric ozone plays a major role in Earth's atmospheric chemistry processes and also acts as an air pollutant and greenhouse gas. Due to its short lifetime, and dependence on sunlight and precursor emissions from natural and anthropogenic sources, tropospheric ozone's abundance is highly variable in space and time on seasonal, interannual and decadal time-scales. Recent, and sometimes rapid, changes in observed ozone mixing ratios and ozone precursor emissions inspired us to produce this up-to-date overview of tropospheric ozone's global distribution and trends. Much of the text is a synthesis of in situ and remotely sensed ozone observations reported in the peer-reviewed literature, but we also include some new and extended analyses using well-known and referenced datasets to draw connections between ozone trends and distributions in different regions of the world. In addition, we provide a brief evaluation of the accuracy of rural or remote surface ozone trends calculated by three state-of-the-science chemistry-climate models, the tools used by scientists to fill the gaps in our knowledge of global tropospheric ozone distribution and trends.

Mixing ratios↗
NASA NTRS2001

Large-Scale Air Mass Characteristics Observed Over the Remote Tropical Pacific Ocean During March-April 1999: Results from PEM-Tropics B Field Experiment

Eighteen long-range flights over the Pacific Ocean between 38 S to 20 N and 166 E to 90 W were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (O3), water vapor (H2O), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in O3, carbon monoxide, hydrocarbons, and aerosols and an increase in H2O. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced O3 and aerosols and an associated decrease in H2O. Average latitudinal and longitudinal distributions of O3 and H2O were constructed from the remote and in situ O3 and H2O data, and these distributions are compared with results from PEM-Tropics A conducted in August-October 1996. During PEM-Tropics B, low O3 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced O3 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their O3, aerosols, clouds, and potential vorticity characteristics. The data from each flight were binned by altitude according to air mass type, and these results showed the relative observational frequency of the different air masses as a function of altitude in seven regions over the Pacific. The average chemical composition of the major air mass types was determined from in situ measurements in the NH and SH, and these results provided insight into the origin, lifetime, and chemistry of the air in these regions.

Browell, Edward V.↗