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Part 2: Sedimentary geology of the Valles, Marineris, Mars and Antarctic dry valley lakes

Detailed mapping of the layered deposits in the Valles Marineris, Mars from high-resolution Viking orbiter images revealed that they from plateaus of rhythmically layered material whose bases are in the lowest elevations of the canyon floors, and whose tops are within a few hundred meters in elevation of the surrounding plateaus. Four hypotheses for the origin of the layered deposits were considered: that they are eolian deposits; that they are remnants of the same material as the canyon walls; that they are explosive volcanic deposits; or that they were deposited in standing bodies of water. There are serious morphologic objections to each of the first three. The deposition of the layered deposits in standing bodies of water best explains their lateral continuity, horizontality, great thickness, rhythmic nature, and stratigraphic relationships with other units within the canyons. The Martian climatic history indicated that any ancient lakes were ice covered. Two methods for transporting sediment through a cover of ice on a martian lake appear to be feasible. Based on the presently available data, along with the theoretical calculations presented, it appears most likely that the layered deposits in the Valles Marineris were laid down in standing bodies of water.

Nedell, Susan S.↗

Technology Development for the Modification of High Aspect Ratio Geometries for Thermal and Environmental Control

A key technology development driver in environmental control systems and next generation optics are discussed utilizing thin film development borrowed from the semiconductor industry. The optical and physical properties of spacecraft radiator coatings are dictated by orbital environmental conditions. For example, coatings must adequately dissipate charge buildup when orbital conditions, such as polar, geostationary or gravity neutral, result in surface charging. Current dissipation techniques include depositing a layer of ITO (indium tin oxide) on the radiator surface in a high temperature process. The application of these enhanced coatings must be such that the properties in question are tailored to mission-specific requirements. The multi-billion-dollar semiconductor industry has adopted Atomic Layer Deposition (ALD) for self-assembly and atomic-scale placement. ALD is a cost-effective nanoadditive-manufacturing technique that allows for the conformal coating of substrates with atomic control in a benign temperature and pressure environment. By using ALD, modification of these coatings can be accomplished during coating application preprocessing. The preprocessing is rendered directly on the coating dry pigment before binding. Through the introduction of paired precursor gases, thin films can be deposited on a myriad of substrates ranging from glass, polymers, aerogels, metals, powders, and other high aspect-ratio micro- and nano- structures. By providing atomic-level control, where single layers of atoms can be deposited, the fabrication of metal transparent films, precise nano-laminates, and coatings of nano-channels and pores is achievable. A method has been demonstrated for the ALD of In2O3 and films on a variety of substrates from Si(100) wafers, glass slides, and on Z93P pigments resulting in a direct spaceflight application. Results will be presented that verify the chemical composition of ALD pigments and charge dissipation properties when the pigment goes through its binding and coating process and we present early results of ALD for carbon nanotube formation and encapsulation.

Dwivedi, Vivek H.↗

Stereo Topography of the South Polar of Mar: Volatile Inventory and Mars Polar Landing Landing Site

Viking stereo images and topographic maps reveal that the south polar layered deposits of Mars are topographically complex and morphologically distinct from the north polar layered deposits. The dominant feature is a 500-km-wide topographic dome that rises 3 km above the surrounding plains. This dome underlies the residual ice cap but is at least 50% larger in area. Erosional scarps and terraces indicate that this dome was once more extensive and has undergone erosional retreat. Adjacent to the dome, layered deposits form a vast plateau 1-1.5 km high extending approximately 1000 km beyond and to one side of the residual south polar cap. This plateau is relatively flat at kilometer scales, although it is cut in places by troughs and depressions, which have locally steep scarps up to 2 km high and sloping up to roughly 10 deg. Contiguously flat kilometer-scale regions the size of the Mars Polar Lander (MPL) landing ellipse are present. These are in the form of plateaus 100-300 km wide and 1-2 km high. One of the largest of these plateaus has been proposed as a landing site for the Mars Polar Lander (MPL). The volume associated with the south polar layered deposits may be comparable to those of the layered deposits at the north pole. Although this doubles the current probable inventory of surface ice on Mars, it still falls far short of accounting for the inferred volume of water on Mars in the past.

Schenk, Paul M.↗

The evolution of dust deposits in the Martian north polar region

The origin and evolution of two major eolian deposits of the Martian north polar region, the layered deposits and the debris mantle, are examined. Both apparently result from deposition of dust along with the seasonal CO2 frost cap. Dust deposited onto the perennial ice is incorporated into the layered deposits, while dust deposited directly onto the surface becomes part of the debris mantle. Climatically induced fluctuation of the perennial ice margin has influenced the evolution of both units. Periodic exposure to the atmosphere has allowed erosion of curvilinear troughs in the surface of the layered deposits. Intervening periods of deposition may have resulted in gradual poleward migration of the trough forms, leaving behind sets of low-amplitude surface undulations in former trough locations. Advance and retreat of the perennial ice margin has also probably resulted in a fine interfingering of the layered deposits-debris mantle contract. Limited post-depositional stripping of the debris mantle has been accomplished by intense winds blowing outward from the pole.

Squyres, S. W.↗

Exploring Mars for Evidence of Habitable Environments and Life

The climate of Mars has been more similar to that of Earth than has the climate of any other planet in our Solar System. But Mars still provides a valuable alternative example of how planetary processes and environments can affect the potential presence of life elsewhere. For example, although Mars also differentiated very early into a core, mantle and crust, it then evolved mostly if not completely without plate tectonics and has lost most of its early atmosphere. The Martian crust has been more stable than that of Earth, thus it has probably preserved a more complete record of its earliest history. Orbital observations determined that near-surface water was once pervasive. Orbiters have identified the following diverse aqueous sedimentary deposits: layered phyllosilicates, phyllosilicates in intracrater fans, plains sediments potentially harboring evaporitic minerals, deep phyllosilicates, carbonate-bearing deposits, intracrater clay-sulfate deposits, Meridiani-type layered deposits, valles-type layered deposits, hydrated silica-bearing deposits, and gypsum plains. These features, together with evidence of more vigorous past geologic activity, indicate that early climates were wetter and perhaps also somewhat warmer. The denser atmosphere that was required for liquid water to be stable on the surface also provided more substantial protection from radiation. Whereas ancient climates might have favored habitable environments at least in some localities, clearly much of the Martian surface for most of its history has been markedly less favorable for life. The combination of dry conditions, oxidizing surface environments and typically low rates of sedimentation are not conducive to the preservation of evidence of ancient environments and any biota. Thus a strategy is required whereby candidate sites are first identified and then characterized for their potential to preserve evidence of past habitable environments. Rovers are then sent to explore the most promising candidates. The Mars Exploration Rover (MER) Opportunity revealed that water once flowed to the surface across the vast Meridiani plains, creating saline lakes whose waters were roiled by ancient winds that also sculptured their salt deposits into sand dunes. Opportunity then drove more than 30 km to explore even older deposits on a crater rim. MER Spirit found evidence that thermal waters (heated by volcanism or by impacts?) altered rocks to create sulfate salts, and siliceous sinters. These discoveries indicate that an early hydrological cycle apparently sustained precipitation, streams and lakes. Liquid water participated in rock weathering reactions, such as iron and sulfur oxidation, that created distinctive weathering regimes. Volcanism, impacts, groundwater and ice interacted at least locally. Redox chemical energy from volcanism, hydrothermal activity and weathering of crustal materials would have been available for any life. Thus conditions might have supported life in the past, at least locally. The main objective of the Mars Science Laboratory (MSL) Curiosity rover is to determine the extent to which Gale crater hosted environments capable of supporting microbial life. The rover has already found stream gravels as well as sediments that might have been deposited in an ancient lake. The rover is now traversing to Mt. Sharp, a 5 km-high mound that is located on the crater floor and that exhibits layered sedimentary rocks having diverse minerals (sulfates and clays) that apparently formed in the presence of liquid water. This rock sequence was deposited over an extended time period in diverse potentially habitable watery environments. Curiosity is poised to characterize a a well-preserved rock record of hundreds of millions of years of diverse environments and profound climate change.

layered phyllosilicates↗

Topography of Valles Marineris: Implications for erosional and structural history

Compilation of a simplified geologic/geomorphic map onto digital terrain models of the Valles Marineris permitted an evaluation of elevations in the vicinity of the troughs and the calculation of depth of troughs below surrounding plateaus, thickness of deposits inside the troughs, volumes of void spaces above geologic/geomorphic units, and volumes of deposits. The central troughs north Ophir, north and central Candor, and north Melas Chasmata lie as much as 11 km below the adjacent plateaus. In Ophir and Candor chasmata, interior layered deposits reach 8 km in elevation. If the deposits are lacustrine and if all troughs were interconnected, lake waters standing 8 km high would have spilled out of Coprates Chasma onto the surrounding plateaus having surface elevations of only 4-5 km. On the other hand, the troughs may not have been interconnected at the time of interior-deposit emplacement; they may have formed isolated ancestral basins. The existence of such basins is supported by independent structural and stratigraphic evidence. The ancestral basins may have eventually merged, perhaps through renewed faulting, to form northern subsidiary troughs in Ophir and Candor Chasmata and the Coprates/north Melas/Ius graben system. The peripheral troughs are only 2-5 km deep, shallower than the central troughs. Chaotic terrain is seen in the peripheral troughs near a common contour level of about 4 km on the adjacent plateaus, which supports the idea of release of water under artesian pressure from confined aquifers. The layered deposits in the peripheral troughs may have formed in isolated depressions that harbored lakes and predated the formation of the deep outflow channels. (If these layered deposits are of volcanic origin, they may have been emplaced beneath ice in the manner of table mountains.) Areal and volumetric computations show that erosion widened the troughs by about one-third and that deposits occupy one-sixth of the interior space. Even though the volume eroded is larger than the volume deposited, topographic and geologic considerations imply that material eroded from trough walls was probably part of the interior layered deposits but not their sole source. Additional material may have come from subterranean piping, from reworking of local disintegration products on the floors, such as chaotic materials, or from eolian influx. But overall it is likely that the additional material is volcanic and that it forms mostly the upper, more diversely bedded layers of the interior deposits.

Lucchitta, B. K.↗

Thermal inertia and radar reflectivity of the Martian north polar ERG: Low-density aggregates

The north polar layered deposits on Mars appear to be the source of the dark material that comprises the north polar erg. The physical properties and chemical composition of the erg material therefore have important implications for the origin and evolution of the Martian layered deposits. Viking bistatic radar and infrared thermal mapping (IRTM) data indicate that the bulk density of the erg material is lower than that of the average Martian surface. These data are consistent with hypotheses involving formation of filamentary sublimation residue (FSR) particles from erosion of the layered deposits. The color and albedo of the erg and of the layered deposits, and the presence of magnetic material on Mars, suggest that the dark material is composed of low-density aggregates of magnetic dust grains, perhaps similar to FSR particles created in laboratory experiments.

Herkenhoff, K. E.↗

Reflective Coating for Lightweight X-Ray Optics

X-ray reflective coating for next generation's lightweight, high resolution, optics for astronomy requires thin-film deposition that is precisely fine-tuned so that it will not distort the thin sub-mm substrates. Film of very low stress is required. Alternatively, mirror distortion can be cancelled by precisely balancing the deformation from multiple films. We will present results on metallic film deposition for the lightweight optics under development. These efforts include: low-stress deposition by magnetron sputtering and atomic layer deposition of the metals, balancing of gross deformation with two-layer depositions of opposite stresses and with depositions on both sides of the thin mirrors.

Chan, Kai-Wing↗

Martian glaciation and the flow of solid CO2

Results are discussed for a series of laboratory deformation experiments that were conducted to determine a flow law for solid CO2 so that a physical basis could be established for considering the possibility of CO2 glaciation in the Martian polar regions. The experimentally determined flow law indicates that (1) the concept of CO2 glacial flow at the Martian poles is not physically unrealistic, (2) the strength of CO2 near its sublimation point is considerably less than the strength of water ice near its melting point, and (3) CO2 is likely to flow over a broad range of temperatures below its melting point. A glacial model for the Martian polar caps is suggested in which CO2-rich layers deposited near the poles flowed outward laterally to relieve high internal shear stresses. It is shown that this model can explain the topography of the polar caps, the uniform layering of the layered deposits, and the general extent of the polar 'sediments'. Some problematic assumptions of the model are noted, including the large amounts of CO2 necessary to move the layered deposits and the need to increase vapor pressure and temperature with depth in the deposits.

Clark, B. R.↗

North polar region of Mars - Imaging results from Viking 2

During October 1976, the Viking 2 orbiter acquired approximately 700 high-resolution images of the north polar region of Mars. These images confirm the existence at the north pole of extensive layered deposits largely covered over with deposits of perennial ice. An unconformity within the layered deposits suggests a complex history of climate change during their time of deposition. A pole-girdling accumulation of dunes composed of very dark materials is revealed by the Viking cameras. The entire region is devoid of fresh impact craters. Rapid rates of erosion or deposition are implied. A scenario for polar geological evolution, involving two types of climate change, is proposed.

Cutts, J. A.↗

Evidence for Possible Exposed Water Ice Deposits in Martian Low Latitude Chasms and Chaos

A light-toned interior layer deposit (ILD) on the floor of the deep martian depression Juventae Chasma is found to have a relatively high thermal inertia approx. 500 J m(exp -2) s(exp -1/2) K(exp -1). This could imply rock, but is also similar to the average value of thermal inertia found for north polar layered deposits. Furthermore, ILD-B is found to exhibit a bluff and terrace structure . A terrace structure arises naturally in model simulations of the sublimation of large ice deposits. Such a staircase terrain, of course, is a further characteristic of north polar layered terrain. Morphological similarity, thermal inertia in the range of thermal inertias of the north polar cap layered terrain, and relatively high albedo lead us to propose that the ILD-B may consist of residual water ice partially covered by, and perhaps mixed with, varying amounts of dust or sand. Other ILDs (A-C) are also found in Juventae Chasma. While these ILDs lack the close morphological resemblance to the north polar cap, they share many other common features and appear to be part of the same formation. Similar ILDs are found in chaotic terrain elsewhere in the martian tropics. This leads us to propose that water ice may exist in the martian tropics today and may be implicit in the formation of chaotic terrain.

Leovy, C.↗

Lunar and Planetary Science XXXV: Mars Polar Processes: Land and Sky

The titles in this section include: 1) Morphological Evidence for the Large-scale Evolution of Martian North Polar Troughs? 2) New Views of the Martian Polar Regions: The Latest Results from the Mars Odyssey THEMIS Investigation; 3) Observations at the Chasma Australe Re-Entrant, South Polar Region, Mars; 4) Stratigraphic Details of Uppermost Units within South Polar Layered Deposits on Mars; 5) Detailed Geologic Analysis of Part of the South Polar Layered Deposits, Planum Australe, Mars: Part II; 6) SHARAD: Radar Volume Scattering and the Polar Layered Terrains on Mars; 7) Arabia and Memnonia Equatorial Regions with High Content of Water: Data from HEND/Odyssey; 8) Alaskan Permafrost Analogs of Martian Small Valley Networks, Thermokarst, Terrain Softening, Terraces, and Volcanic Craters; 9) Periglacial Processes in the Southern Hemisphere of Mars; 10) Thermal Modeling of Possible Surface Water Ice Deposits in Juventae Chasma; 11) Modeling Depth to Ground Ice on Mars; 12) Ground Ice at the Phoenix Landing Site: A Preflight Assessment; 13) Possible Temperature-related Differences in Slope Angle between the North and South Walls of Coprates Chasma, Mars; 14) Seasonal Variations within Korolev Crater, Mars; 15) South Polar Ar Enhancement as a Tracer for Southern Winter Horizontal Meridional Mixing; 16) An Investigation of the Correlation of Water-Ice and Dust Retrievals via the MGS TES Data Set; 17) Observations of Plasma Waves near Mars and Their Implications for Atmospheric Loss.

Source record↗

Multi-Dimensional Sensors and Sensing Systems

A universal microelectromechanical (MEMS) nano-sensor platform having a substrate and conductive layer deposited in a pattern on the surface to make several devices at the same time, a patterned insulation layer, wherein the insulation layer is configured to expose one or more portions of the conductive layer, and one or more functionalization layers deposited on the exposed portions of the conductive layer to make multiple sensing capability on a single MEMS fabricated device. The functionalization layers are adapted to provide one or more transducer sensor classes selected from the group consisting of: radiant, electrochemical, electronic, mechanical, magnetic, and thermal sensors for chemical and physical variables and producing more than one type of sensor for one or more significant parameters that need to be monitored.

Stetter, Joseph R.↗

Widespread Layers in Arabia Terra: Implications for Martian Geologic History

Layered rocks in Arabia Terra have been the focus of several recent papers. Studies have focused on the layers found in crater basins located in the southwest portion of the region. However, Mars Orbiter Camera (MOC) images have identified layered deposits across the region. Terrestrial layered rocks are usually sedimentary, and often deposited in water. Thus extensive layered sequences in Arabia Terra may indicate locations of past, major depositional basins on Mars. Other mechanisms can also create layered rocks, or the appearance of layered rocks, including volcanism (both lava flows and ash falls), wind-blown deposits, and wave-cut terraces at shorelines. By identifying where in the region layers occur, and classifying the layers according to morphology and albedo, past depositional environments may be identified. Arabia Terra is characterized by heavily cratered Noachian plains, as well as a rise from -4000 m in the northwest to 4000 m in the southeast (Mars Orbital Laser Altimeter [MOLA] datum). This slope may have provided a constraint on sediment deposition and thus layer formation. While most of the region is Noachian in age, a significant percentage of the area is identified as Hesperian. Although the history of the Arabia Terra initially seems to be straightforward cratered plains with several younger units atop them analysis of high-resolution imagery may reveal a more complex history.

Venechuk, Elizabeth M.↗

Moonshine Versus Earthshine: Physics Makes a Difference

Introduction: Recently released, high-resolution images from the Mars Orbiter Camera (MOC) and the Thermal Emission Imaging System (THEMIS) reveal a myriad of intriguing landforms banked along the northern edge of Terby Crater located on the northern rim of Hellas (approx.28degS, 287degW). Landforms within this crater include north-trending troughs and ridges, a remarkable 2.5 km-thick sequence of exposed layers, mantled ramps that extend across and between layered sequences, fan-like structures, sinuous channels, collapse pits, a massive landslide and viscous flow features. The suite of diverse landforms in Terby and its immediate surroundings attest to a diversity of rock types and geologic processes, making this locality ideal for studying landform-climate relationships on Mars. In order to decipher the complicated geologic history of Terby Crater and the nature of the layered deposits, a generalized geomorphic map was created and the slope of the layered deposits was examined.

Wilson, T. L.↗

Development of X-43A Mach 10 Leading Edges

The nose leading edge of the Hyper-X Mach 10 vehicle was orginally anticipated to reach temperatures near 4000 F at the leading-edge stagnation line. A SiC coated carbon/carbon (C/C) leading-edge material will not survive that extreme temperature for even a short duration single flight. To identify a suitable leading edge for the Mach 10 vehicle, arc-jet testing was performed on thirteen leading-edge segments fabricated from different material systems to evaluate their performance in a simulated flight environment. Hf, Zr, Si, and Ir based materials, in most cases as a coating on C/C, were included in the evaluation. Afterwards, MER, Tucson, AZ was selected as the supplier of the flight vehicle leading edges. The nose and the vertical and horizontal tail leading edges were fabricated out of a 3:1 biased high thermal conductivity C/C. The leading edges were coated with a three layer coating comprised of a SiC conversion of the top surface of the C/C, followed by a chemical vapor deposited layer of SiC, followed by a thin chemical vapor deposited layer of HfC. This paper will describe the fabrication of the Mach 10 C/C leading edges and the testing performed to validate performance.

Ohlhorst, Craig W.↗

Using ALD To Bond CNTs to Substrates and Matrices

Atomic-layer deposition (ALD) has been shown to be effective as a means of coating carbon nanotubes (CNTs) with layers of Al2O3 that form strong bonds between the CNTs and the substrates on which the CNTs are grown. ALD is a previously developed vaporphase thin-film-growth technique. ALD differs from conventional chemical vapor deposition, in which material is deposited continually by thermal decomposition of a precursor gas. In ALD, material is deposited one layer of atoms at a time because the deposition process is self-limiting and driven by chemical reactions between the precursor gas and the surface of the substrate or the previously deposited layer.

Wong, Eric W.↗

Preparation of Thick NI/AL Reactive Multilayer Films and Prospective Use for Self-Powered Brazing of TI-6AL-4V

In this study we demonstrate a new method for depositing thick reactive multilayer films (RMFs) (thickness > 14 µm) by using Ti interlayer integration and substrate preheating during fabrication. These two adjustments are designed to alleviate internal planar stresses that cause delamination between deposited layers and peeling off the substrate. Decreasing the distance between Ti interlayers helps to eliminate delamination between deposited layers. Through high speed camera measurements, the reaction propagation speed of an RMF sample with preheating is 42% slower than the same RMF that was not preheated, indicating a slower heat release rate. The preliminary experiments on brazing Ti-6Al-4V coated with BAlSi-4 brazing material revealed dendritic structure branching out from the RMF surface into the brazing material. The dendrite structures most likely form because of rapid melting and solidification of the brazing material. However, this rapid melting and solidification cycle does not appear to occur uniformly across the BAlSi-4RMF interface which is linked to its low bonding strength. When the Ti-6Al-4V substrate is heated to 150 °C prior to ignition, the strength increases to 0.47 MPa when the total RMF thickness is 84 µm and 15 MPa of pressure is applied.

Cheng, Jinquan↗