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NASA NTRS2006

Polarization of Light from Leaves Measured from 0.5 - 1.6 mm

The light scattered by plant canopies depends in part on the light scattering/absorbing properties of the leaves. Insights into these properties gained at the leaf scale are necessary ultimately to accomplish the region and global scale environmental goals of the EOS era. While this scattered light may be described by the four components of the Stokes vector, (intensity, magnitude of line= polarization, angle of plane of linear polarization, and magnitude of circular polarization), significant progress has been achieved toward understanding only the first component, the intensity of the scattered light. Recent research shows that the magnitude of the linearly polarized light may be a significant part of the light scattered by some canopies. Thus, consideration of the second component may be necessary to obtain an unambiguous understanding of the canopy processes. We measured the intensity and the linear polarization of the light scattered by single leaves, testing the hypothesis that the polarization of the light scattered by each leaf was attributable to properties of the surfaces of the leaf and specifically did not depend upon the properties of the interior of the leaf. This research extends previous investigations limited to the single leaves of approximately 20 species typically found in the area of Lafayette, Indiana, to the leaves of 30 species representing monocots, dicots and ferns from six continents.

Vanderbilt, V. C.↗

NASA NTRS1974

A study of birefringence in the interstellar medium in the direction of the Crab Nebula

The interstellar medium may be regarded as a weak wave plate, the linear birefringence arising from the aligned grains which produce interstellar linear polarization. Using the Crab Nebula as a background source of linearly polarized light we have investigated this birefringence by measurements of circular polarization. The circular component is found to vary with the intrinsic linear polarization in a sinusoidal fashion characteristic of a wave plate with the orientation expected from independent measurements of the interstellar linear polarization in the same direction. Measurements of the wavelength dependence, together with the sense and magnitude of the circular polarization are interpreted as evidence for the dielectric nature of the interstellar grain materials. These observations provide a firm basis for a similar interpretation of the circular polarization of reddened stars. The observations of the stars can then be used to study the grain composition and the structure of the magnetic field in many directions in the Galaxy.

Martin, P. G.↗

NASA NTRS1989

Interstellar circular polarization and the dielectric nature of dust grains

The implications of the observed relationship between the wavelength dependence of interstellar circular and linear polarization were reexamined. Mie theory calculations for grains with various optical constants demonstrate that any population of grains which matches the observed wavelength dependence of linear polarization also yields the correct cross-over wavelength of circular polarization. The coincidence of the peak wavelength of linear polarization and the cross-over of circular polarization is therefore independent of the optical constants of the grains and cannot be used as a critical constraint on grain properties. The observed relationship instead reflects a more fundamental connection between linear and circular polarization which was derived from the Kramers-Kronig relations by Shapiro (1975). Numerical results fully support Shapiro's conclusions and demonstrate that the apparent upper limit on the visual absorptivity of polarizing grains deduced from earlier Mie theory calculations (Martin, 1972) was spurious and resulted from a violation of the Kramers-Kronig relations in the assumed optical constants of the particles. The Kramers-Kronig interpretation of circular polarization can be used to place constraints on linear polarization outside the wavelength range in which it was observed. This approach was used to show that the peak observed in the visual is likely to be the only significant feature in the linear polarization curve, which therefore appears to be well approximated at all wavelengths by the Serkowski formula. A synthesis of available laboratory data was used to analyze the properties of dielectric core-mantel grains as the source of visual extinction and polarization.

Chlewicki, Grzegorz↗

NASA NTRS1993

Polarized and specular reflectance variation with leaf surface features

The linearly polarized reflectance from a leaf depends on the characteristics of the leaf surface. In the present study the leaf reflectance of a number of plant species with varying surface characteristics was measured at the Brewster angle with a polarization photometer having 5 visible and near-infrared wavelength bands. We found that all leaf surfaces polarized incident light. Differences among species could be explained by variation in surface features. The results support our hypothesis that the polarized light is reflected by the leaf surface, not by its interior. Two mechanisms appeared responsible for the linearly polarized reflectance: (1) specular reflectance and (2) surface particle scattering. In most cases, large values of linearly polarized reflectance could be attributed to specular reflectance from the leaf surface. Attribution required knowledge of the optical dimensions of features on the leaf surface.

Grant, Lois↗

NASA NTRSDate not supplied

Polarization Measurement of the OV 121.83 nm Intercombination Line with CLASP

The Chromospheric Lyman-Alpha SpectroPolarimeter (CLASP) sounding rocket experiment provided precise polarimetric measurements of far ultraviolet (FUV) emission lines emanating from the solar chromosphere and transition region. The CLASP observation covered linear polarization not only at the optically thick H I Lyman-alpha 121.57 nm line but also at the weaker Si III 120.65 nm line as well as at the even weaker O V 121.83 nm line adjacent to H I Lyman-alpha. The Lyman-alpha wings and THE Si III line exhibit clear center-to-limb variation (CLV) of the fractional linear polarization Q/I, showing a negative increase toward the limb, with a fractional polarization signal of around 4% near the limb (Kano et al. 2017, Ishikawa et al. 2017). The negative Q/I corresponds to polarization perpendicular to the limb, which is consistent with the theoretical prediction where multiple scattering events create the linear polarization when the radiation propagates through the upper chromosphere and the transition region. The O V 121.83 nm line is weak because the line results from an intercombination transition. The CLASP observation indicates the possible existence of linear polarization perpendicular to the limb at the O V line. The fractional linear polarization Q/I is larger than the estimated noise only near the limb and is about 2% when we subtract the influence of the nearby continuum coming from the Lyman-alpha wing. If confirmed, polarization measurements of the OV line might provide a new tool to constrain the density as well as the magnetic field configuration in the upper chromosphere and the transition region.

Yukio Katsukawa↗

NASA NTRS2002

Improved performance and safety of lithium ion cells with the use of fluorinated carbonate-based electrolytes

There has been increasing interest in developing lithium-ion electrolytes that possess enhanced safety characteristics, while still able to provide the desired stability and performance. Toward this end, our efforts have been focused on the development of lithium-ion electrolytes which contain partially and fully fluorinated carbonate solvents. The advantage of using such solvents is that they possess the requisite stability demonstrated by the hydrocarbon-based carbonates, while also possessing more desirable physical properties imparted by the presence of the fluorine substituents, such as lower melting points, increased stability toward oxidation, and favorable SEI film forming Characteristics on carbon. Specifically, we have demonstrated the beneficial effect of electrolytes which contain the following fluorinated carbonate-based solvents: methyl 2,2,2-trifluoroethyl carbonate (MTFEC), ethyl-2,2,2 trifluoroethyl carbonate (ETFEC), propyl 2,2,2-trifluoroethyl carbonate (PTFEC), methyl-2,2,2,2',2',2' -hexafluoro-i-propyl carbonate (MHFPC), ethyl- 2,2,2,2',2',2' -hexafluoro-i-propyl carbonate (EHFPC), and di-2,2,2-trifluoroethyl carbonate (DTFEC). These solvents have been incorporated into multi-component ternary and quaternary carbonate-based electrolytes and evaluated in lithium-carbon and carbon-LiNio.8Coo.202 cells (equipped with lithium reference electrodes). In addition to determining the charge/discharge behavior of these cells, a number of electrochemical techniques were employed (i.e., Tafel polarization measurements, linear polarization measurements, and electrochemical impedance spectroscopy (EIS)) to further characterize the performance of these electrolytes, including the SEI formation characteristics and lithium intercalatiodde-intercalation kinetics. In addition to their evaluation in experimental cells, cyclic voltammetry (CV) and conductivity measurements were performed on select electrolyte formulations to further our understanding of the trends in stability and ionic mobility imparted by different alkyl substituents in linear carbonates.

li-ion batteries fluorinated carbonate electrolyte↗

NASA NTRS1976

A correlation polarimeter for noise-like signals

Optimum estimation (tracking) of the polarization plane of a linearly polarized electromagnetic wave is determined when the signal is a narrow-band Gaussian random process with a polarization plane angle which is also a Gaussian random process. This model is compared to previous work and is applicable to space communication. The estimator performs a correlation operation similar to an amplitude-comparison monopulse angle tracker, giving the name correlation polarimeter. Under large signal-to-noise ratio (SNR), the estimator is causal. Performance of the causal correlation polarimeter is evaluated for arbitrary SNR. Optimum precorrelation filtering is determined. With low SNR, the performance of this system is far better than that of previously developed systems. Practical implementation is discussed. A scheme is given to reduce the effect of linearly polarized noise.

Ohlson, J. E.↗

NASA NTRS1984

A review of ionospheric effects on Earth-space propagation

A short description is given of each ionospheric total electron content (TEC) effect upon radio waves, along with a representative value of the magnitude of each of these effects under normal ionospheric conditions. A discussion is given of the important characteristics of average ionospheric TEC behavior and the temporal and spatial variability of TEC. Radio waves undergo several effects when they pass through the Earth's ionosphere. One of the most important of these effects is a retardation, or group delay, on the modulation or information carried on the radio wave that is due to its encounter with the free, thermal electrons in the Earth's ionosphere. Other effects the ionosphere has on radio waves include: radio frequency (RF) carrier phase advance; Doppler shift of the RF carrier of the radio wave; Faraday rotation of the plane of polarization of linearly polarized waves; angular refraction or bending of the radio wave path as it travels through the ionosphere; and amplitude and phase scintillations.

Klobuchar, J. A.↗

NASA NTRS2003

Concentration and Velocity Gradients in Fluidized Beds

In this work we focus on the height dependence of particle concentration, average velocity components, fluctuations in these velocities and, with the flow turned off, the sedimentation velocity. The latter quantities are measured using Particle Imaging Velocimetry (PIV). The PIV technique uses a 1-megapixel camera to capture two time-displaced images of particles in the bed. The depth of field of the imaging system is approximately 0.5 cm. The camera images a region with characteristic length of 2.6 cm for the small particles and 4.7 cm. for the large particles. The local direction of particle flow is determined by calculating the correlation function for sub-regions of 32 x 32 pixels. The velocity vector map is created from this correlation function using the time between images (we use 15 to 30 ms). The software is sensitive variations of 1/64th of a pixel. We produce velocity maps at various heights, each consisting of 3844 velocities. We break this map into three vertical zones for increased height information. The concentration profile is measured using an expanded (1 cm diameter) linearly polarized HeNe Laser incident on the fluidized bed. A COHU camera (gamma=1, AGC off) with a lens and a polarizer images the transmitted linearly polarized light to minimize the effects of multiply scattered light. The intensity profile (640 X 480 pixels) is well described by a Gaussian fit and the height of the Gaussian is used to characterize the concentration. This value is compared to the heights found for known concentrations. The sedimentation velocity is estimated using by imaging a region near the bottom of the bed and using PIV to measure the velocity as a function of time. With a nearly uniform concentration profile, the time can be converted to height information. The stable fluidized beds are made from large pseudo-monodisperse particles (silica spheres with radii (250-300) microns and (425-500) microns) dispersed in a glycerin/water mix. The Peclet number is sufficiently large that Brownian motion of the particles can be ignored and the Reynolds number sufficiently small that particle inertia is negligible. A packed particle bed is used to randomize and disperse the flowing fluid introduced by a peristaltic pump. The bed itself is a rectangular glass cell 8 cm wide (x), 0.8 cm deep and a height of 30.5 cm (z). The depth of field of the camera is approximately 0.5 cm so depth information is averaged. Over flow fluid is returned to the reservoir making a closed loop system. In these experiments the particles form a sediment approximately 5.7 cm high with the pump off and expand to 22 cm with the pump on. For the smaller particles the pump velocity is .5 millimeters per second and 1.1 millimeters per second for the large particles. At this concentration the bed has a very well defined top where particle concentration rapidly drops to zero.

McClymer, James P.↗

NASA NTRS2005

Microelectromechanical Systems Actuator Based Reconfigurable Printed Antenna

A polarization reconfigurable patch antenna is disclosed. The antenna includes a feed element, a patch antenna element electrically connected to the feed element, and at least one microelectromechanical systems (MEMS) actuator, with a partial connection to the patch antenna element along an edge of the patch antenna element. The polarization of the antenna can be switched between circular polarization and linear polarization through action of the at least one MEMS actuator.

Simons, Rainee N.↗

NASA NTRS2002

Improved low temperature performance of lithium ion cells with quaternary carbonate-based electrolytes

In order to enable future missions involving the exploration of the surface of Mars with Landers and Rovers, NASA desires long life, high energy density rechargeable batteries which can operate well at very low temperature (down to 40(deg)C). Lithium-ion technology has been identified as being the most promising chemistry, due to high gravimetric and volumetric energy densities, as well as, long life characteristics. However, the state-of-art (SOA) technology is not sufficient to meet the needs of many applications that require excellent low temperature capabilities. To further improve this technology, work at JF'L has been focused upon developing electrolytes that result in lithium-ion cells with wider temperature ranges of operation. These efforts have led to the identification of a number of ternary and quaternary, all carbonate-based electrolytes that have been demonstrated to result in improved low temperature performance in experimental three-electrode MCMB carbon/LiNio.sCoo.zOz cells. A number of electrochemical characterization techniques were performed on these cells (i.e., Tafel polarization measurements, linear polarization measurements, and electrochemical impedance spectroscopy (EIS)) to further enhance our understanding of the performance limitations at low temperature. The most promising electrolyte formulations, namely 1 .O M LiPF6EC+DEC+DMC+EMC (1 : 1: 1 :2 v/v) and 1 .O M LiPF6 EC+DEC+DMC+EMC (1 : 1 : 1 :3 v/v), were incorporated into SAFT prototype DD-size (9 Ahr) lithium- cells for evaluation. A number of electrical tests were performed on these cells, including rate characterization as a function of temperature, cycle life characterization at different temperatures, as well as, many mission specific characterization test to determine their viability to enable future missions to Mars. Excellent performance was observed with the prototype DD-size cells over a wide temperature range (-50 to 4OoC), with high specific energy being delivered at very low temperatures (i.e, over 95 WHrKg being delivered at 40(deg)C using a C/10 discharge rate).

Li-ion low temperature electrolytes↗

NASA NTRS2022

Near Space Demonstration of A Compact LWIR Spectro-Polarimeter for Ice Cloud Measurements

In the summer of 2021, an InfraRed Channeled Spectro-Polarimeter (IRCSP) was demonstrated in the near space environment aboard a NASA Columbia Scientific Ballooning Facility high-altitude balloon out of Fort Sumner, NM. The compact IRCSP is sensitive to linearly polarized long-wave infrared (LWIR) light between 7-12 micron and targets cloud micro-physical properties. Post landing the instrument was retrieved with no damage to the optical payload and collected over 150 minutes of flight data at altitudes above 30 km. The results collected both demonstrate the application of uncooled microbolometers in the low pressure environment and represent the first know field evidence of a polarized signal from clouds in the LWIR. During deployment, the IRCSP reported brightness temperatures between 250-285K with uncertainty of < 1.5K. In addition, multiple intervals of statistically significant polarization with degrees of linear polarization (DoLP) between 1−20% were detected. These results support the hypothesis that the LWIR polarimetry has the potential to add new sensitivity to existing remote sensing platforms.

remote sensing↗

NASA NTRS2011

The Primordial Inflation Explorer (PIXIE): A Nulling Polarimeter for Cosmic Microwave Background Observations

The Primordial Inflation Explorer (PIXIE) is a concept for an Explorer-class mission to measure the gravity-wave signature of primordial inflation through its distinctive imprint on the linear polarization of the cosmic microwave background. The instrument consists of a polarizing Michelson interferometer configured as a nulling polarimeter to measure the difference spectrum between orthogonal linear polarizations from two co-aligned beams. Either input can view the sky or a temperature-controlled absolute reference blackbody calibrator. Rhe proposed instrument can map the absolute intensity and linear polarization (Stokes I, Q, and U parameters) over the full sky in 400 spectral channels spanning 2.5 decades in frequency from 30 GHz to 6 THz (1 cm to 50 micron wavelength). Multi-moded optics provide background-limited sensitivity using only 4 detectors, while the highly symmetric design and multiple signal modulations provide robust rejection of potential systematic errors. The principal science goal is the detection and characterization of linear polarization from an inflationary epoch in the early universe, with tensor-to-scalar ratio r < 10..3 at 5 standard deviations. The rich PIXIE data set can also constrain physical processes ranging from Big Bang cosmology to the nature of the first stars to physical conditions within the interstellar medium of the Galaxy.

Kogut, Alan J.↗

NASA NTRS1993

The Brewster angle effect in SAR polarimetry

For the double bounce case, where the radar signal is reflected twice before returning to the radar antenna, some polarization effects may be observed related to the dielectric constant of the two surfaces causing the reflections. The most noticeable effect would be that the returned signal would be preferentially H polarized. In fact, it may be possible to discern the Brewster angle for both surfaces. The locations of the Brewster angle will depend on the dielectric constant and permittivity of each surface. If it is assumed that both reflections are in the same plane of incidence, and that both surfaces are smooth and flat, there is a straightforward relationship between the degree of linear polarization m and both the dielectric constants of the two reflecting surfaces and the angle of incidence of the illuminating wave: m carat = cos 2(arccot (square root of (R(sub v) / R(sub h)))) where R(sub v,h) are the V and H polarized Fresnel reflection coefficients for two surfaces perpendicular to each other. The degree of linear polarization may be calculated from AIRSAR compressed Stokes data and compared with the given equation. The degree of linear polarization may also be calculated using tree models and compared with AIRSAR data. With further work, it may be possible to use the degree of linear polarization to determine surface parameters of certain imaged areas.

Chapman, B.↗

NASA NTRS1980

A model of plant canopy polarization

A model for the amount of linearly polarized light reflected by the shiny leaves of grain crops is based on the morphological and phenological characteristics of the plant canopy and upon the Fresnel equations which describe the light reflection process at the smooth boundary separating two dielectrics. The theory used demonstrates that, potentially, measurements of the linearly polarized light from a crop canopy may be used as an additional feature to discriminate between crops such as wheat and barley, two crops which are so spectrally similar that they are misclassified with unacceptable frequency. Examination of the model suggests that, potentially, satellite polarization measurements may be used to monitor crop development stage, leaf water content, leaf area index, hail damage, and certain plant diseases. The information content of these measurements is needed to evaluate the proposed polarization sensor for the satellite-borne multispectral resource sampler.

Vanderbilt, V. C.↗

NASA NTRS1981

Intrinsic polarization of SS 433 - An electron scattering model

A model for the generation of the observed intrinsic linear polarization in the optical radiation from SS 433 due to scattering from free electrons in highly ionized material in a jet or inclined disk is examined and compared with observational data. Expressions for the Stokes parameters of the linear polarization as a function of phase are obtained for a simple jet model in which continuum light from a point source is singly scattered by free electrons located along the jets resulting in strikingly different relations between Q and U at different values of model parameters. Comparison of 30 broadband linear polarization measurements with the model indicates a mean value of rotation axis inclination to the line of sight of 63 deg, which is not inconsistent with X-ray and radio data. The measurements are also compatible with models invoking highly inclined disks or rings with emission arising in regions on opposite sides of a diameter.

Mclean, I. S.↗

NASA NTRS2014

The Primordial Inflation Explorer (PIXIE)

The Primordial Inflation Explorer is an Explorer-class mission to measure the gravity-wave signature of primordial inflation through its distinctive imprint on the linear polarization of the cosmic microwave background. PIXIE uses an innovative optical design to achieve background-limited sensitivity in 400 spectral channels spanning 2.5 decades in frequency from 30 GHz to 6 THz (1 cm to 50 micron wavelength). Multi-moded non-imaging optics feed a polarizing Fourier Transform Spectrometer to produce a set of interference fringes, proportional to the difference spectrum between orthogonal linear polarizations from the two input beams. Multiple levels of symmetry and signal modulation combine to reduce the instrumental signature and confusion from unpolarized sources to negligible levels. PIXIE will map the full sky in Stokes I, Q, and U parameters with angular resolution 2.6 deg and sensitivity 0.2 μK per 1 deg square pixel. The principal science goal is the detection and characterization of linear polarization from an inflationary epoch in the early universe, with tensor-to-scalar ratio r less than 10(exp −3) at 5 standard deviations. In addition, PIXIE will measure the absolute frequency spectrum to constrain physical processes ranging from inflation to the nature of the first stars to the physical conditions within the interstellar medium of the Galaxy. We describe the PIXIE instrument and mission architecture with an emphasis on the expected level of systematic error suppression.

Primordial Inflation Explorer is an Explorer-class↗

NASA NTRS1977

Far-infrared polarization of M42

This paper reports a search for linearly polarized radiation from M42 at 85 microns. The observed polarization is significantly less than the peak observed 11-micron polarization and is consistent with no linear polarization at all.

Dennison, B.↗