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At least 91 records · Page 5

Large-Strain Transparent Magnetoactive Polymer Nanocomposites

A document discusses polymer nano - composite superparamagnetic actuators that were prepared by the addition of organically modified superparamagnetic nanoparticles to the polymer matrix. The nanocomposite films exhibited large deformations under a magnetostatic field with a low loading level of 0.1 wt% in a thermoplastic polyurethane elastomer (TPU) matrix. The maximum actuation deformation of the nanocomposite films increased exponentially with increasing nanoparticle concentration. The cyclic deformation actuation of a high-loading magnetic nanocomposite film was examined in a low magnetic field, and it exhibited excellent reproducibility and controllability. Low-loading TPU nanocomposite films (0.1-2 wt%) were transparent to semitransparent in the visible wavelength range, owing to good dispersion of the magnetic nanoparticles. Magnetoactuation phenomena were also demonstrated in a high-modulus, high-temperature polyimide resin with less mechanical deformation.

Meador, Michael A.↗

Neuromuscular Adaptations to Reduced Use

This viewgraph presentation reviews the studies done to reduce neuromuscular strength loss during unilateral lower limb suspension (ULLS). Since there are animals that undergo fairly long periods of muscular disuse without any or minimal muscular atrophy, there is an answer to that might be applicable to human in situations that require no muscular use to diminish the effects of muscular atrophy. Three sets of ULLS studies were reviewed indicated that muscle strength decreased more than the muscle mass. The study reviewed exercise countermeasures to combat the atrophy, including: ischemia maintained during Compound muscle action potential (CMAP), ischemia and low load exercise, Japanese kaatsu, and the potential for rehabilitation or situations where heavy loading is undesirable. Two forms of countermeasures to unloading have been successful, (1) high-load resistance training has maintained muscle mass and strength, and low load resistance training with blood flow restriction (LL(sub BFR)). The LL(sub BFR) has been shown to increase muscle mass and strength. There has been significant interest in Tourniquet training. An increase in Growth Hormone(GH) has been noted for LL(sub BFR) exercise. An experimental study with 16 subjects 8 of whom performed ULLS, and 8 of whom performed ULLS and LL(sub BFR) exercise three times per week during the ULLS. Charts show the results of the two groups, showing that performing LL(sub BFR) exercise during 30 days of ULLS can maintain muscle size and strength and even improve muscular endurance.

Ploutz-Snyder, Lori↗

Calculation of Hub Loads at Low Airspeeds with Active Control

The effect of individual blade control (IBC) on the full-scale, low airspeed, level flight UH-60A oscillatory fixed system 4P hub loads and the rotating system blade bending moments is studied. The effect of a single 3P IBC input has been considered in this analytical study. At the low speed under consideration, it has been found that convergence of the comprehensive analysis is important for obtaining good predictions. Good correlation has been obtained with the measured full-scale wind tunnel data for the shapes of the fixed system 4P hub loads variations with the 3P IBC input phase, and also for the "best" phase of the 3P input (for minimum hub loads). The blade bending moment comparison shows mixed results. The 3P lead lag and the 4P flap bending moment trends with the 3P IBC input phase are reasonably predicted, whereas the 5P lead lag bending moment trend is not predicted well. Finally, the prediction of the baseline (no IBC) bending moments needs further study.

Kottapalli, Sesi↗

Low Catalyst Loading Enhances Charge Accumulation for Photoelectrochemical Water Splitting

Abstract Solar water oxidation is a critical step in artificial photosynthesis. Successful completion of the process requires four holes and releases four protons. It depends on the consecutive accumulation of charges at the active site. While recent research has shown an obvious dependence of the reaction kinetics on the hole concentrations on the surface of heterogeneous (photo)electrodes, little is known about how the catalyst density impacts the reaction rate. Using atomically dispersed Ir catalysts on hematite, we report a study on how the interplay between the catalyst density and the surface hole concentration influences the reaction kinetics. At low photon flux, where surface hole concentrations are low, faster charge transfer was observed on photoelectrodes with low catalyst density compared to high catalyst density; at high photon flux and high applied potentials, where surface hole concentrations are moderate or high, slower surface charge recombination was afforded by low‐density catalysts. The results support that charge transfer between the light absorber and the catalyst is reversible; they reveal the unexpected benefits of low‐density catalyst loading in facilitating forward charge transfer for desired chemical reactions. It is implied that for practical solar water splitting devices, a suitable catalyst loading is important for maximized performance.

Liu, Tianying↗

Low Catalyst Loading Enhances Charge Accumulation for Photoelectrochemical Water Splitting

Abstract Solar water oxidation is a critical step in artificial photosynthesis. Successful completion of the process requires four holes and releases four protons. It depends on the consecutive accumulation of charges at the active site. While recent research has shown an obvious dependence of the reaction kinetics on the hole concentrations on the surface of heterogeneous (photo)electrodes, little is known about how the catalyst density impacts the reaction rate. Using atomically dispersed Ir catalysts on hematite, we report a study on how the interplay between the catalyst density and the surface hole concentration influences the reaction kinetics. At low photon flux, where surface hole concentrations are low, faster charge transfer was observed on photoelectrodes with low catalyst density compared to high catalyst density; at high photon flux and high applied potentials, where surface hole concentrations are moderate or high, slower surface charge recombination was afforded by low‐density catalysts. The results support that charge transfer between the light absorber and the catalyst is reversible; they reveal the unexpected benefits of low‐density catalyst loading in facilitating forward charge transfer for desired chemical reactions. It is implied that for practical solar water splitting devices, a suitable catalyst loading is important for maximized performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Persistent Elevated Soot Emissions Induced by Clustered Stochastic Preignition Events

Stochastic Preignition (SPI) is an abnormal combustion phenomenon that can occur in spark-ignition engines particularly under high-load operation. SPI is characterized by uncontrolled initiation of combustion prior to spark discharge, an abnormal combustion process that can lead to severe knock events and significant engine damage. SPI has been associated with fuel properties, lubricant composition, and engine design and operation. Here, in this work, a single-cylinder test engine with a dry-sump oil system was utilized to study the SPI response of E10 and E25 fuels with a range of Reid Vapor Pressure (RVP). An automated test procedure was employed, consisting of ten square-waved load profile segments, with each segment composed of 5 min of low-load operation followed by 25 min of sustained high-load operation. These tests were replicated across multiple days of testing including a lubricant triple flush between tests, and an online Fuel in Oil diagnostic measurement. Exhaust particulate emissions were continuously measured by an AVL microsoot sensor (MSS). Elevated particulate matter emissions were observed to occur concurrently with SPI events as blooms of soot. Particularly after clustered events (i.e., multiple SPI cycles occurring within 10 consecutive engine cycles), high soot emissions were observed to persist over several days of sequential operation despite daily lubricant changes, a complete warm-up procedure, and sustained low-load operation between test segments. This result implies that the particulate emissions trends may be dominated by deposit-based effects, where higher load operation is needed to alter deposition and formation processes. The observed soot blooms were also found to correspond to a reduction in the engine fueling and the fuel engine oil dilution rate despite the engine exhaust remaining at stoichiometric exhaust operation. These observations suggest that post-SPI events, pathways for lubricant migration and consumption into the combustion chamber may occur until these pathways are closed from deposit formation or ring dynamics during extended operation. These observed sooting propensity persisted with all fuels tests, but a linear correlation was observed between the summation of soot and particulate matter index (PMI) value for each fuel as well as SPI events, proving that PMI is a crucial fuel property for reducing SPI.

Splitter, Derek [Oak Ridge National Laboratory (OR↗

Predictive modeling of a subcritical pulverized-coal power plant for optimization: Parameter estimation, validation, and application

As renewable power generation deployment increases, fossil fuel plants are increasingly required to operate more flexibly. Many coal-fired power plants were originally designed to operate at base load and do not operate optimally at partial load. Predictive first-principles plant-wide models can be employed to identify opportunities for flexibility improvements and diagnose low-load operating issues. This paper describes the application of the Institute for the Design of Advanced Energy Systems Integrated Platform (IDAES) to model and optimize flexible power plant operations. The key benefits of using IDAES are that it provides an open-source, fully equation-oriented modeling framework for efficient modular model construction, reuse, and customization, together with a mathematical optimization framework leveraging powerful, state-of-the-art solvers. The process systems engineering workflow from predictive process simulation to parameter estimation, model validation, and plant optimization is applicable to a variety of existing and next-generation energy systems as well as other chemical and environmental processes. Here, to demonstrate this capability, a physics-based, steady-state model was developed to improve full- and part-load performance of the Escalante Generating Station, a 245 MWe (net) subcritical pulverized coal-fired power plant owned and operated by Tri-State Generation and Transmission Association. Specifically, sixty-nine model parameters were simultaneously estimated from several months of operating data enabling prediction of flow rates, temperatures, pressures, and steam quality throughout the plant. The validated model was leveraged by Escalante to reduce the minimum operating load from 90 MW to 50 MW by diagnosing a low-load water-hammer issue, enabling coal usage and emissions reductions during periods of low power demand. Additionally, opportunities for heat rate reduction (i.e., efficiency improvement) through a steeper sliding-pressure approach to load-following and optimization of other boiler operating variables were also identified and quantified. For example, a potential efficiency improvement of 0.7 percentage points was observed at half-load operation.

01 COAL, LIGNITE, AND PEAT↗

Design of various fixed-geometry water-lubricated hydrodynamic journal bearings for maximum stability

This publication is the result of over 260 fractional-frequency-whirl stability tests on a variety of fixed-geometry journal bearings. It is intended principally as a guide in the selection and design of antiwhirl bearings that must operate at high speeds and low loads in low-viscosity fluids such as water or liquid metals. However, the various fixed-geometry configurations can be employed as well in applications where other lubricants, such as oil, are used and fractional-frequency whirl is a problem. The important parameters that effect stability are discussed for each bearing type, and design curves to facilitate the design of optimum-geometry bearings are included. A comparison of the stability of the different bearing configurations tested is also given.

Schuller, F. T.↗

Dynamic Characterization and Performance Evaluation of a 10-kw Power Take-Off with Mechanical Motion Rectifier for Wave Energy Conversion

The power take-off (PTO) is a key component for wave energy converters (WECs). The dynamic properties of the PTO influence the response of the WEC and should be considered when designing the WEC and not oversimplified. In addition, the efficiency as well as the reliability can play an important role on whether the PTO can be suitable for real-world applications. In this paper, a novel compact PTO rated at 10 kW is designed and prototyped, and a comprehensive nonlinear dynamic model is established for the PTO. Through bench testing, the unknown parameters of the dynamic model are characterized and determined. Further verification shows that the model can predict the dynamic performance of the PTO well. In addition, the test results show that the mechanical motion rectifier PTO can achieve good energy transfer efficiency, especially for low-load and low-speed conditions.

bench test↗

Impact of Porous Transport Layer Morphology on the Performance of Proton Exchange Membrane Water Electrolyzers with Ultra-Low Iridium Loadings

Reducing Ir loadings in proton exchange membrane water electrolyzer anodes is critical for lowering capital expenses. Loading reduction could be achieved by improving the Ir activity via doping/alloying and/or the development of advanced microstructures. However, the anode porous transport layer (PTL) is a comparatively simple component whose properties also impact Ir utilization. Therefore, well-designed PTLs may also enable reduced Ir loadings. In this work, we survey eight PTLs from various manufacturers to observe their impact on cell performance at low (0.4 mg Ir cm -2 ) and ultralow (0.1 mg Ir cm -2 ) Ir loadings. The PTLs were characterized by their microstructural properties, including porosity, particle size distribution, and pore size distribution. Electrochemical cell performance was correlated to PTL morphology, and it was found that PTLs with lower porosities and smaller particle and pore radii enabled good performance even at ultralow Ir loadings. 1000-h durability testing indicated that using lower porosity PTLs can significantly improve durability behavior. A runaway voltage phenomenon was observed during durability testing of cells with ultralow Ir loadings, which was caused by increases in both anode and cathode overpotentials. Furthermore, we observed that the beginning of test performance of 0.1 mg Ir cm -2 cells correlates to the 1000-h degradation rates of 0.4 mg Ir cm -2 cells, suggesting that for the Ir catalyst used in this work, short-term testing at ultralow loadings can be used as an indicator of long-term degradation at higher loadings.

08 HYDROGEN↗

Adventures in Low Disc Loading VTOL Design

This memoir covers the first eight years of my 37 year career in VTOL aircraft design. It starts with family and how I came to be an engineer with a passion for aviation and a desire to make a difference. At MIT I acquired a solid understanding of basic physics, learned the basics of the various engineering disciplines and gained design experience. After over a decade on the East Coast I was homesick for Northern California. I decided to take a chance on working for the government instead of industry in order to return home. I was hired by Dr. Richard M. Carlson in March 1975 and joined a wonderful Army/NASA technical environment. The Interservice Helicopter Commonality Study was an important introduction to Joint Service aircraft design. The Advanced Attack Helicopter Source Selection Evaluation Board was an opportunity to learn acquisition system fundamentals and to lead a small team in a major technical evaluation. The Advanced Scout Helicopter Concept Formulation was an opportunity to learn how an aircraft development program is created and it formed a partnership between Dr. Carlson's Labs and Charlie Crawford's Development and Qualification directorate. The Army was Executive Service for the first year (1982) of the Joint Services Advanced Vertical Lift Aircraft (JVX) program. The JVX Joint Technology Assessment concluded that there was at least one design configuration, the tilt rotor, which could satisfy all JVX mission requirements with a high degree of inter-service commonality. The Navy became Executive Service at the end of the year and promptly released a JVX RFP to industry. This RFP resulted in the V-22 Osprey tilt rotor as the third type of VTOL aircraft to enter production and service. I was very lucky to have a useful role early in this program.

VTOL Design↗

Additive-Mixing Fuel Injection (AMFI): A device for robust control and improved performance of high-efficiency LTGC engines

Low-temperature gasoline combustion (LTGC) engines can provide high efficiencies with very low NOx and particulate emissions. Despite these major advantages, methods for controlling LTGC combustion timing, achieving robust autoignition, and good low-load performance have challenged the development of practical LTGC engines. A key reason is that the ideal reactivity of the fuel varies with operating conditions, with low-reactivity fuels working well at high loads and higher-reactivity fuels working better at low loads. This article introduces a new technique called Additive Mixing Fuel Injection (AMFI) that adjusts the reactivity of the gasoline to obtain good performance over the operating map. Moreover, AMFI can provide robust combustion-timing control because it precisely meters very small amounts (0.01–0.6 mm 3 ) of an ignition-enhancing additive into the fuel each engine cycle. The additive used was 2-ethylhexyl nitrate (EHN), a common, inexpensive diesel-fuel ignition improver, but other additives could be used. Because additive amounts are so small, a 2-gal reservoir would be sufficient for medium-duty applications with refilling only at service intervals of about 8000 mi. The AMFI system has been installed on a single-cylinder LTGC research engine and demonstrated to provide robust combustion-timing control over wide ranges of combustion phasing, fueling rate, intake boost, engine speed, and intake temperature. AMFI also increases the fuel’s reactivity sufficiently to greatly reduce or eliminate the need for charge heating, simplifying engine design and significantly increasing thermal efficiency and the maximum load at low-boost conditions. The nitrogen in the EHN produced a modest increase in NOx, but it was mitigated by lower intake temperatures, and NOx emissions remained very low. Finally, the additive increases the sensitivity of autoignition reactions to variations in the local fuel/air mixture within the charge. This allows the use of controlled fuel stratification for improved LTGC-engine performance, and its potential to improve low-load operation was demonstrated.

Dec, John E.↗

Initial rotation-loading and low speed flutter test results for a straight wing version of the space shuttle vehicle

For three straight semispan model space shuttle wings, the maximum total load during rapid rotation from 66 deg to 0 deg angle of attack, at Mach numbers from 0.28 to 0.60, was essentially no higher than that measured for buffet. During slow rotation over the same angle range, there was no visible flutter. For one of the wings, however, unstable aerodynamic damping was established at two fixed angles of attack.

Warner, R. W.↗

Translating Fundamental Insights into Ag-Based Bimetallic Electrocatalysts to Anion-Exchange Membrane Fuel Cells

To address challenges of high costs and scalability for fuel cells, it is essential to develop af-fordable and earth-abundant materials that are Pt-group-metal (PGM)-free. Recent advance-ments in PGM-free electrocatalysis for the oxygen reduction reaction (ORR) in alkaline media show that high catalyst loadings are needed to achieve high reaction rates; however, there are associated mass transport limitations. To address this issue, we develop low-loading ionomer-less Ag-bimetallic thin films by alloying with 3d block elements or Sn. We bridge knowledge from fundamental rotating disk electrode (RDE) studies to gas-diffusion cathodes in high-temperature anion-exchange membrane fuel cells (HT-AEMFCs), resulting in high-activity ORR catalysis and peak power densities up to 1.2 W cm-² geo for the Ag-Sn and Ag-Co alloys. Here, experimental post-characterization and theoretical calculations reveal small Co or Sn oxide nano-islands on Ag as likely active sites enhancing ORR activity, ultimately offering these low-loading PGM-free ORR materials as a viable path towards sustainable energy conversion.

Catalysts↗

AOI 5 Improved Efficiency of Medium- and Heavy-Duty Natural Gas and Propane (LPG) Engines

Spark-ignited heavy-duty (HD) natural gas engines typically experience efficiency losses at part-load operation due to throttling requirements needed to maintain stoichiometric combustion. A substantial portion of medium- and heavy-duty engine operation occurs in this low-load region, resulting in increased brake-specific carbon dioxide emissions and reduced overall efficiency. This project designed, developed and demonstrated cylinder deactivation (CDA) technology on an HD natural gas engine to mitigate these losses. CDA enables selective deactivation of cylinders, reducing pumping losses while maintaining required torque output and meeting vehicle noise, vibration, and harshness (NVH) targets. The project objectives were successfully achieved, demonstrating up to 12% improvement in fuel consumption over the next generation HD NG engine on key low loaded HD cycles and maintained compliance with 0.02 g/hp-hr NO x emissions with comparable or better vibrations to current product. These results confirm that CDA technology can substantially improve the fuel efficiency and environmental performance of heavy-duty natural gas engines, reinforcing their potential as a low-carbon bridge solution in the transition toward zero-emission transportation technologies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Molecular Dynamics Simulation and Cryo-Electron Microscopy Investigation of AOT Surfactant Structure at the Hydrated Mica Surface

Structural properties of the anionic surfactant dioctyl sodium sulfosuccinate (AOT or Aerosol-OT) adsorbed on the mica surface were investigated by molecular dynamics simulation, including the effect of surface loading in the presence of monovalent and divalent cations. The simulations confirmed recent neutron reflectivity experiments that revealed the binding of anionic surfactant to the negatively charged surface via adsorbed cations. At low loading, cylindrical micelles formed on the surface, with sulfate head groups bound to the surface by water molecules or adsorbed cations. Cation bridging was observed in the presence of weakly hydrating monovalent cations, while sulfate groups interacted with strongly hydrating divalent cations through water bridges. The adsorbed micelle structure was confirmed experimentally with cryogenic electronic microscopy, which revealed micelles approximately 2 nm in diameter at the basal surface. At higher AOT loading, the simulations reveal adsorbed bilayers with similar surface binding mechanisms. Adsorbed micelles were slightly thicker (2.2–3.0 nm) than the corresponding bilayers (2.0–2.4 nm). Upon heating the low loading systems from 300 K to 350 K, the adsorbed micelles transformed to a more planar configuration resembling bilayers. The driving force for this transition is an increase in the number of sulfate head groups interacting directly with adsorbed cations.

58 GEOSCIENCES↗

Full-scale S-76 rotor performance and loads at low speeds in the NASA Ames 80- by 120-Foot Wind Tunnel

A full-scale helicopter rotor test was conducted in the NASA Ames 80- by 120-Foot Wind Tunnel with a four-bladed S-76 rotor system. Rotor performance and loads data were obtained over a wide range of rotor shaft angles-of-attack and thrust conditions at tunnel speeds ranging from 0 to 100 kt. The primary objectives of this test were (1) to acquire forward flight rotor performance and loads data for comparison with analytical results; (2) to acquire S-76 forward flight rotor performance data in the 80- by 120-Foot Wind Tunnel to compare with existing full-scale 40- by 80-Foot Wind Tunnel test data that were acquired in 1977; (3) to evaluate the acoustic capability of the 80- by 120- Foot Wind Tunnel for acquiring blade vortex interaction (BVI) noise in the low speed range and compare BVI noise with in-flight test data; and (4) to evaluate the capability of the 80- by 120-Foot Wind Tunnel test section as a hover facility. The secondary objectives were (1) to evaluate rotor inflow and wake effects (variations in tunnel speed, shaft angle, and thrust condition) on wind tunnel test section wall and floor pressures; (2) to establish the criteria for the definition of flow breakdown (condition where wall corrections are no longer valid) for this size rotor and wind tunnel cross-sectional area; and (3) to evaluate the wide-field shadowgraph technique for visualizing full-scale rotor wakes. This data base of rotor performance and loads can be used for analytical and experimental comparison studies for full-scale, four-bladed, fully articulated rotor systems. Rotor performance and structural loads data are presented in this report.

Shinoda, Patrick M.↗

Simulations of Multi-Mode Combustion Regimes Realizable In a Gasoline Direct Injection Engine

Lean and dilute gasoline compression ignition (GCI) operation in spark ignition (SI) engines are an attractive strategy to attain high fuel efficiency and low NOx levels. However, this combustion mode is often limited to low-load engine conditions due to the challenges associated with autoignition controllability. In order to overcome this constrain, multi-mode (MM) operating strategies, consisting of advanced compression ignition (ACI) at low load and conventional SI at high load, have been proposed. In this three-dimensional computational fluid dynamics study, the concept of multi-mode combustion using two RON98 gasoline fuel blends (Co-Optima Alkylate and E30) in a gasoline direct injection (GDI) engine were explored. To this end, a new reduced mechanism for simulating the kinetics of E30 fuel blend is introduced in this study. To cover the varying engine load demands for multi-mode engines, primary combustion dynamics observed in ACI and SI combustion modes was characterized and validated against experimental measurements. In order to implement part-load conditions, a strategy of mode transition between SI and ACI combustion (i.e., mixed-mode combustion) was then explored numerically by creating a virtual test condition. The results obtained from the mixed-mode simulations highlight an important feature that deflagrative flame propagation regime coexists with ignition-assisted end-gas autoignition. This study also identifies a role of turbulent flow property adjacent to premixed flame front in characterizing the mixed-mode combustion. The employed hybrid combustion model was verified to perform simulations aiming at suitable range of multi-mode engine operations.

Kim, Sayop↗