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Volatile Analysis by Pyrolysis of Regolith (Vapor) on the Moon using Mass Spectrometry

The identification of lunar resources such as water is a fundamental component of the the NASA Vision for Space Exploration. The Lunar Prospector mission detected high concentrations of hydrogen at the lunar poles that may indicate the presence of water or other volatiles in the lunar regolith [1]. One explanation for the presence of enhanced hydrogen in permanently shadowed crater regions is long term trapping of water-ice delivered by comets, asteroids, and other meteoritic material that have bombarded the Moon over the last 4 billion years [2]. It is also possible that the hydrogen signal at the lunar poles is due to hydrogen implanted by the solar wind which is delayed from diffusing out of the regolith by the cold temperatures [3]. Previous measurements of the lunar atmosphere by the LACE experiment on Apollo 17, suggested the presence of cold trapped vola'tiles that were expelled by solar heating [4]. In situ composition and isotopic analyses of the lunar regolith will be required to establish the abundance, origin, and distribution of water-ice and other volatiles at the lunar poles. Volatile Analysis by Pyrolysis of Regolith (VAPoR) on the Moon using mass spectrometry is one technique that should be considered. The VAPoR pyrolysis-mass spectrometer (pyr-MS) instrument concept study was selected for funding in 2007 by the NASA Lunar Sortie Science Opportunities (LSSO) Program. VAPoR is a miniature version of the Sample Analysis at Mars (SAM) instrument suite currently being developed at NASA Goddard for the 2009 Mars Science Laboratory mission (Fig. 1).

Glavin, D. P.↗

The Lunar Potential Determination Using Apollo-Era Data and Modern Measurements and Models

Since the Apollo era the electric potential of the Moon has been a subject of interest and debate. Deployed by three Apollo missions, Apollo 12, Apollo 14 and Apollo 15, the Suprathermal Ion Detector Experiment (SIDE) determined the sunlit lunar surface potential to be about +10 Volts using the energy spectra of lunar ionospheric thermal ions accelerated toward the Moon. More recently, the Lunar Prospector (LP) Electron Reflectometer used electron distributions to infer negative lunar surface potentials, primarily in shadow. We will present initial results from a study to combine lunar surface potential measurements from both SIDE and the LP/Electron Reflectometer to calibrate an advanced model of lunar surface charging which includes effects from the plasma environment, photoemission, secondaries ejected by ion impact onto the lunar surface, and the lunar wake created downstream by the solar wind-lunar interaction.

Collier, Michael R.↗

Preliminary Crater Retention Ages for an Expanded Inventory of Large Lunar Basins

Based on LOLA topography and a new crustal thickness model, the number of candidate lunar basins greater than 300 km in diameter is at least a factor 2 larger than the traditional number based on photogeology alone, and may be as high as 95. Preliminary N(50) crater retention ages for this population of candidate basins shows two distinct peaks. Frey [1] suggested, based on Clementine-era topography (ULCN2005) and a crustal thickness model based on Lunar Prospector data [2], that there could be as many as 98 lunar basins greater than 300 km diameter. Many of the weaker cases have not stood up to recent testing [3,4,5] using LOLA data and a newer crustal thickness model based on Kaguya gravity data and LOLA topography data [6]. As described in companion abstracts [4,5], we have deleted from the earlier inventory 1 more named feature (Sikorsky- Rittenhouse; LOLA data show that its diameter is actually less than 300 km), 11 Quasi-Circular Depressions (QCDs) identified in the ULCN topography, and 11 Circular Thin Areas (CTAs) found in the earlier crustal thickness model [2]. We did this by repeating the scoring exercise originally done in [1] but with the new data [4,5]. Topographic Expression (TE) and Crustal Thickness Expression (CTE) scores were determined for each candidate on a scale of 0 to 5 (5 being a strong, circular signature, 0 for those with no discernible circular topographic or crustal thickness signature). These scores are added together to produce a Summary Score which has a range of 0 to 10. We eliminated all candidates with a Summary Score less than 3, as well as other cases where, for example, the TE went to zero because what looked like a single large circular QCD in the lower resolution ULCN data was in fact a cluster of smaller deep impacts readily apparent in the newer higher resolution LOLA data. This process reduced the original inventory from 98 to 75 candidates.

Frey, H. V.↗

Polar Volatiles Exploration in Peary Crater Enabled by NASA's Kilopower Project

For more than 50 years, scientists have discussed the possibility of the existence of water ice and other frozen volatiles at the lunar poles [1]. However, it was not until the 1990s when the polar orbiting spacecraft Clementine and Lunar Prospector collected data supporting these hypotheses [2]. Subsequent missions, including the Lunar Reconnaissance Orbiter (LRO) mission [3], and the Lunar Crater Observation and Sensing Satellite (LCROSS) mission [4], provided further evidence that supports the existence of water ice deposits at the lunar poles. During NASA's Constellation Program, several areas at both lunar poles polar were included in 50 Regions of Interest (ROI) for intensive study by the Lunar Reconnaissance Orbiter Camera (LROC) [5]. These polar ROI focused on peaks and craters rims that received high amounts of solar illumination, assuming initial missions back to the lunar surface would utilize solar arrays to generate electricity. Recently, the successful demonstration of NASA's Kilopower Project at the National Nuclear Security Administration (NNSA) Nevada National Security Site makes it possible to consider lunar polar missions at locations other than highly illuminated regions. The Kilopower Project was initiated in 2015 to demonstrate subsystem-level technology readiness of a small space fission power system [6]. This abstract describes the science objectives and operations for a mission concept developed at NASA Glenn Research Center's COMPASS Concurrent Engineering Team for a 1-year exploration of Peary Crater focused on prospecting for lunar polar volatiles.

Gruener, J. E.↗

RESOLVE's Field Demonstration on Mauna Kea, Hawaii 2010

In cooperation with the Canadian Space Agency, and the Northern Centre for Advanced Technology, Inc., NASA has undertaken the In-Situ Resource Utilization (ISRU) project called RESOLVE (Regolith and Environment Science & Oxygen and Lunar Volatile Extraction). This project is an Earth-based lunar precursor demonstration of a system that could be sent to explore permanently shadowed polar lunar craters, where it would drill into regolith, quantify the volatiles that are present, and extract oxygen by hydrogen reduction of iron oxides. The resulting water could be electrolyzed into oxygen to support exploration and hydrogen, which would be recycled through the process. The RESOLVE chemical processing system was mounted on a Canadian Space Agency mobility chasis and successfully demonstrated on Hawaii's Mauna Kea volcano in February 2010. The RESOLVE unit is the initial prototype of a robotic prospecting mission to the Moon. RESOLVE is designed to go to the poles of the Moon to "ground truth" the form and concentration of the hydrogen/water/hydroxyl that has been seen from orbit (M3, Lunar Prospector and LRO) and to test technologies to extract oxygen from the lunar regolith. RESOLVE has the ability to capture a one-meter core sample of lunar regolith and heat it to determine the volatiles that may be released and then demonstrate the production of oxygen from minerals found in the regolith. The RESOLVE project, which is led by KSC, is a multi-center and multi-organizational effort that includes representatives from KSC, JSC, GRC, the Canadian Space Agency, and the Northern Center for Advanced Technology (NORCAT). This paper details the results obtained from four days of lunar analog testing that included gas chromatograph analysis for volatile components, remote control of chemistry and drilling operations via satalite communications, and real-time water quantification using a novel capacitance measurement technique.

Captain, Janine↗

RESOLVE for Lunar Polar Ice/Volatile Characterization Mission

Ever since data from the neutron spectrometer instrument on the Lunar Prospector mission indicated the possibility of significant concentrations of hydrogen at the lunar poles, speculation on the form and concentration of the hydrogen has been debated. The recent impact of the Lunar Crater Observation and Sensing Satellite (LCROSS) along with thermal, topographic, neutron spectrometry, and radar frequency data obtained from the Lunar Reconnaissance Orbiter (LRO) have provided more information suggesting significant amounts of water/ice and other volatiles may be available in the top 1 to 2 meters of regolith at the lunar poles. The next step in understanding what resources are available at the lunar poles is to perform a mission to obtain ground truth. data. To meet this need, the US National Aeronautics and Space Administration (NASA) along with the Canadian Space Agency (CSA) have been working on a prototype payload known as the Regolith & Environment Science and Oxygen & Lunar Volatile Extraction experiment, or RESOLVE.

Sanders, G. B.↗

Improved Calibration of Reflectance Data from the LRO Lunar Orbiter Laser Altimeter (LOLA) and Implications for Space Weathering

The Lunar Orbiter Laser Altimeter (LOLA) experiment on Lunar Reconnaissance Orbiter (LRO) is a laser altimeter that also measures the strength of the return pulse from the lunar surface. These data have been used to estimate the reflectance of the lunar surface, including regions lacking direct solar illumination. A new calibration of these data is presented that features lower uncertainties overall and more consistent results in the polar regions. We use these data, along with newly available maps of the distribution of lunar maria, also derived from LRO instrument data, to investigate a newly discovered dependence of the albedo of the lunar maria on latitude (Hemingway et al., [2015]). We confirm that there is an increase in albedo with latitude in the lunar maria, and confirm that this variation is not an artifact arising from the distribution of compositions within the lunar maria, using data from the Lunar Prospector Neutron Spectrometer. Radiative transfer modeling of the albedo dependence within the lunar maria is consistent with the very weak to absent dependence of albedo on latitude in the lunar highlands; the lower abundance of the iron source for space weathering products in the lunar highlands weakens the latitude dependence to the extent that it is only weakly detectable in current data. In addition, photometric mod- els and normalization may take into account the fact that the lunar albedo is latitude dependent, but this dependence can cause errors in normalized reflectance of at most 2% for the majority of near-nadir geometries. We also investigate whether the latitude dependent albedo may have obscured detection of small mare deposits at high latitudes. We find that small regions at high latitudes with low roughness similar to the lunar maria are not mare deposits that may have been misclassified owing to high albedos imposed by the latitude dependence. Finally, we suggest that the only modest correlations among space weathering indicators defined for the lunar samples may be due to mixing of soils from distinct latitudes.

Lemelin, M.↗

Neutron Measurements at the Lunar Surface (NMLS)

The Neutron Measurement System (NMS-Lunar) is an instrument payload manifested on Astrobotic’s Peregrine Mission One (M1). Astrobotic Mission One will land at Lacus Mortis (~44oN, 254oE). Astrobotic will fly up to fourteen NASA payloads to the lunar surface in addition to other payload customers on M1. NMS-Lunar is a re-design of the MSFC Fast Neutron Spectrometer (FNS) currently operating on the ISS. The design of NMS-Lunar enables operation on the lunar surface, integration onto the Peregrine lander, and measurement of thermal neutron count rates on the lunar surface. The primary science objectives for NMS-Lunar is to provide ground truth of mapped neutron data from the Lunar Reconnaissance Orbiter and Lunar Prospector missions. Neutrons are created when galactic cosmic rays interact with the lunar regolith, and can provide valuable elemental composition information.

Haviland, H. Fuqua↗

Using Microwaves for Extracting Water from the Moon

Twenty years ago, the Lunar Prospector remote sensing satellite provided evidence of relatively large hydrogen concentrations at the lunar poles and in particular concentrated in permanently shadowed craters. The scientific hypothesis is that the hydrogen is in the form of cryo-trapped water just under the surface of the soil. If true this would mean that an average of about 2% water ice is mixed with the lunar soil existing in the form of ice at cryogenic temperatures. For 5 years we have been investigating the use of microwaves for the processing of lunar soil. One of the early uses could be to use microwave energy to extract volatiles and in particular water from the lunar permafrost. Prototype experiments have shown that microwave energy at 2.45 GHz, as in consumer microwave ovens, will couple with and heat cryogenically cooled lunar soil permafrost simulant, resulting in the rapid sublimation of water vapor into the vacuum chamber. The water vapor has been collected on a cryogenic cold trap with high efficiency. The primary advantage of microwave processing is that the volatiles can be extracted in situ. Excavation would not be required. Microwave frequency dielectric property measurements are being made of different lunar soil simulants and plans are to measure Apollo lunar soil at different frequencies and over a range of temperatures. The materials properties are being used to evaluate the heating of lunar soil and develop COMSOL models that can be used to evaluate different microwave extraction scenarios. With COMSOL the heating from cryogenic temperatures can be calculated and COMSOL will permit temperature dependent materials properties to be used during the heating process. Calculations at different microwave frequencies will allow the evaluation of the type of hardware that would be needed to most efficiently extract the water and other volatiles.

Ethridge, Edwin C.↗

Using Microwaves for Extracting Water from the Moon

This disk contains a video that accompanies the talk. Twenty years ago, the Lunar Prospector remote sensing satellite provided evidence of relatively large hydrogen concentrations at the lunar poles and in particular concentrated in permanently shadowed craters. The scientific hypothesis is that the hydrogen is in the form of cryo-trapped water just under the surface of the soil. If true this would mean that an average of about 2% water ice is mixed with the lunar soil existing in the form of ice at cryogenic temperatures. For 5 years we have been investigating the use of microwaves for the processing of lunar soil. One of the early uses could be to use microwave energy to extract volatiles and in particular water from the lunar permafrost. Prototype experiments have shown that microwave energy at 2.45 GHz, as in consumer microwave ovens, will couple with and heat cryogenically cooled lunar soil permafrost simulant, resulting in the rapid sublimation of water vapor into the vacuum chamber. The water vapor has been collected on a cryogenic cold trap with high efficiency. The primary advantage of microwave processing is that the volatiles can be extracted in situ. Excavation would not be required. Microwave frequency dielectric property measurements are being made of different lunar soil simulants and plans are to measure Apollo lunar soil at different frequencies and over a range of temperatures. The materials properties are being used to evaluate the heating of lunar soil and develop COMSOL models that can be used to evaluate different microwave extraction scenarios. With COMSOL the heating from cryogenic temperatures can be calculated and COMSOL will permit temperature dependent materials properties to be used during the heating process. Calculations at different microwave frequencies will allow the evaluation of the type of hardware that would be needed to most efficiently extract the water and other volatiles. The video shows the partial results of the COMSOL modeling.

Ethridge, Edwin C.↗

Using Microwaves for Extracting Water from the Moon

This disk contains 2 videos that accompanies the talk. Twenty years ago, the Lunar Prospector remote sensing satellite provided evidence of relatively large hydrogen concentrations at the lunar poles and in particular concentrated in permanently shadowed craters. The scientific hypothesis is that the hydrogen is in the form of cryo-trapped water just under the surface of the soil. If true this would mean that an average of about 2% water ice is mixed with the lunar soil existing in the form of ice at cryogenic temperatures. For 5 years we have been investigating the use of microwaves for the processing of lunar soil. One of the early uses could be to use microwave energy to extract volatiles and in particular water from the lunar permafrost. Prototype experiments have shown that microwave energy at 2.45 GHz, as in consumer microwave ovens, will couple with and heat cryogenically cooled lunar soil permafrost simulant, resulting in the rapid sublimation of water vapor into the vacuum chamber. The water vapor has been collected on a cryogenic cold trap with high efficiency. The primary advantage of microwave processing is that the volatiles can be extracted in situ. Excavation would not be required. Microwave frequency dielectric property measurements are being made of different lunar soil simulants and plans are to measure Apollo lunar soil at different frequencies and over a range of temperatures. The materials properties are being used to evaluate the heating of lunar soil and develop COMSOL models that can be used to evaluate different microwave extraction scenarios. With COMSOL the heating from cryogenic temperatures can be calculated and COMSOL will permit temperature dependent materials properties to be used during the heating process. Calculations at different microwave frequencies will allow the evaluation of the type of hardware that would be needed to most efficiently extract the water and other volatiles. The 1st video shows the results of the COMSOL models. The second video shows brief views of the lunar surface.

Ethridge, Edwin C.↗

Is There Water on the Moon? NASA's LCROSS Mission

NASA is preparing for its return to the moon with the Lunar CRater Observation and Sensing Satellite (LCROSS) mission. This secondary payload spacecraft will travel with the Lunar Reconnaissance Orbiter (LRO) satellite to the Moon on the same Atlas-V 401 Centaur rocket launched from Cape Canaveral Air Force Station, Florida. The LCROSS mission will robotically seek to determine the presence of water ice at the Moon's South Pole. The 1000kg Secondary Payload budget is efficiently used to provide a highly modular and reconfigurable LCROSS Spacecraft with extensive heritage to accurately guide the expended Centaur into the crater. Upon separation, LCROSS flies through the impact plume, telemetering real-time images and characterizing water ice in the plume with infrared cameras and spectrometers. LCROSS then becomes a 700kg impactor itself, to provide a second opportunity to study the nature of the Lunar Regolith. LCROSS provides a critical ground-truth for Lunar Prospector and LRO neutron and radar maps, making it possible to assess the total lunar water inventory. This presentation contains a reference to video animation of the LCROSS mission that will be covered separately.

Noneman, Steven↗

Is There Water on the Moon? NASA's LCROSS Mission [Supplemental Video]

Presents a supplemental video supporting the original conference presentation under the same title. The conference presentation discussed NASA's preparation for its return to the moon with the Lunar CRater Observation and Sensing Satellite (LCROSS) mission which will robotically seek to determine the presence of water ice at the Moon's South Pole. This secondary payload spacecraft will travel with the Lunar Reconnaissance Orbiter (LRO) satellite to the Moon on the same Atlas-V 401 Centaur rocket launched from Cape Canaveral Air Force Station, Florida. The 1000kg Secondary Payload budget is efficiently used to provide a highly modular and reconfigurable LCROSS Spacecraft with extensive heritage to accurately guide the expended Centaur into the crater. Upon separation, LCROSS flies through the impact plume, telemetering real-time images and characterizing water ice in the plume with infrared cameras and spectrometers. LCROSS then becomes a 700kg impactor itself, to provide a second opportunity to study the nature of the Lunar Regolith. LCROSS provides a critical ground-truth for Lunar Prospector and LRO neutron and radar maps, making it possible to assess the total lunar water inventory. The video contains an animated simulation of the Centaur launch, LRO separation, LRO high resolution lunar survey, LCROSS mission elements and LCROSS impactor separation and impact observations.

Source record↗

Bounding Extreme Spacecraft Charging in the Lunar Environment

Robotic and manned spacecraft from the Apollo era demonstrated that the lunar surface in daylight will charge to positive potentials of a few tens of volts because the photoelectron current dominates the charging process. In contrast, potentials of the lunar surface in darkness which were predicted to be on the order of a hundred volts negative in the Apollo era have been shown more recently to reach values of a few hundred volts negative with extremes on the order of a few kilovolts. The recent measurements of night time lunar surface potentials are based on electron beams in the Lunar Prospector Electron Reflectometer data sets interpreted as evidence for secondary electrons generated on the lunar surface accelerated through a plasma sheath from a negatively charged lunar surface. The spacecraft potential was not evaluated in these observations and therefore represents a lower limit to the magnitude of the lunar negative surface potential. This paper will describe a method for obtaining bounds on the magnitude of lunar surface potentials from spacecraft measurements in low lunar orbit based on estimates of the spacecraft potential. We first use Nascap-2k surface charging analyses to evaluate potentials of spacecraft in low lunar orbit and then include the potential drops between the ambient space environment and the spacecraft to the potential drop between the lunar surface and the ambient space environment to estimate the lunar surface potential from the satellite measurements.

Minow, Joseph I.↗

Overview of the Resource Prospector (RP) Mission

This presentation describes the motivation, development, and key elements of the Resource Prospector lunar rover mission concept. This presentation is a modified version of Introducing the Resource Prospector (RP) Mission, which was presented by Dan Andrews at AIAA Space 2014.

Moon↗

Surface-Correlated Nanophase Iron Metal in Lunar Soils: Petrography and Space Weathering Effects

Space weathering is a term used to include all of the processes that act on material exposed at the surface of a planetary or small body. In the case of the Moon, it includes a variety of processes that formed the lunar regolith, caused the maturation of lunar soils, and formed patina on rock surfaces. The processes include micrometeorite impact and reworking, implantation of solar wind and flare particles, radiation damage and chemical effects from solar particles and cosmic rays, interactions with the lunar atmosphere, and sputtering erosion and deposition. Space weathering effects collectively result in a reddened continuum slope, lowered albedo, and attenuated absorption features in reflectance spectra of lunar soils as compared to finely comminuted rocks from the same Apollo sites. Understanding these effects is critical in order to fully integrate the lunar sample collection with remotely sensed data from recent robotic missions (e.g., Lunar Prospector, Clementine, Galileo). Our objective is to determine the origin of space weathering effects in lunar soils through combined electron microscopy and microspectrophotometry techniques applied to individual soil particles from <20 pm size factions (dry-sieved) of mature lunar soils. It has been demonstrated that it is the finest size fraction (<25 pm) of lunar soils that dominates the optical properties of the bulk soils.

Keller, Lindsay P.↗