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At least 91 records · Page 5

Sensitive, Selective Test For Hydrazines

Derivatives of hydrazines formed, then subjected to gas chromatography and detected via chemiluminescence. In method of detecting and quantifying hydrazine vapors, vapors reacted with dinitro compound to enhance sensitivity and selectivity. Hydrazine (HZ), monomethyl hydrazine, (MMH), and unsymmetrical dimethylhydrazine (UDMH) analyzed quantitatively and qualitatively, either alone or in mixtures. Vapors collected and reacted with 2,4-dinitrobenzaldehyde, (DNB), making it possible to concentrate hydrazine in derivative form, thereby increasing sensitivity to low initial concentrations. Increases selectivity because only those constituents of sample reacting with DNB concentrated for analysis.

Roundbehler, David↗

The DSI small satellite launcher

A new launcher has been developed by DSI, that is compatible with the GAS canisters. It has the proven capability to deploy a satellite from an orbiting Shuttle that is 18 inches in diameter, 31 inches long, and weighing 190 pounds. These DSI Launchers were used aboard the Discovery (STS-39) in May 1991 as part of the Infrared Background Signature Survey (IBSS) to deploy three small satellites known as Chemical Release Observation (CRO) satellites A, B, and C. Because the satellites contained hazardous liquids (MMH, UDMH, and MON-10) and were launched from GAS Cylinders without motorized doors, the launchers were required to pass NASA Shuttle Payload safety and verification requirements. Some of the more interesting components of the design were the V-band retention and separation mechanism, the separation springs, and the launcher electronics which provided a properly inhibited release sequence operated through the Small Payload Accommodations Switch Panel (SPASP) on board the Orbiter. The original plan for this launcher was to use a motorized door. The launcher electronics, therefore has the capability to be modified to accommodate the door, if desired.

Nichols, S.↗

Computational analysis of Variable Thrust Engine (VTE) performance

The Variable Thrust Engine (VTE) of the Orbital Maneuvering Vehicle (OMV) uses a hypergolic propellant combination of Monomethyl Hydrazine (MMH) and Nitrogen Tetroxide (NTO) as fuel and oxidizer, respectively. The performance of the VTE depends on a number of complex interacting phenomena such as atomization, spray dynamics, vaporization, turbulent mixing, convective/radiative heat transfer, and hypergolic combustion. This study involved the development of a comprehensive numerical methodology to facilitate detailed analysis of the VTE. An existing Computational Fluid Dynamics (CFD) code was extensively modified to include the following models: a two-liquid, two-phase Eulerian-Lagrangian spray model; a chemical equilibrium model; and a discrete ordinate radiation heat transfer model. The modified code was used to conduct a series of simulations to assess the effects of various physical phenomena and boundary conditions on the VTE performance. The details of the models and the results of the simulations are presented.

Giridharan, M. G.↗

Small rocket research and technology

Small chemical rockets are used on nearly all space missions. The small rocket program provides propulsion technology for civil and government space systems. Small rocket concepts are developed for systems which encompass reaction control for launch and orbit transfer systems, as well as on-board propulsion for large space systems and earth orbit and planetary spacecraft. Major roles for on-board propulsion include apogee kick, delta-V, de-orbit, drag makeup, final insertions, north-south stationkeeping, orbit change/trim, perigee kick, and reboost. The program encompasses efforts on earth-storable, space storable, and cryogenic propellants. The earth-storable propellants include nitrogen tetroxide (NTO) as an oxidizer with monomethylhydrazine (MMH) or anhydrous hydrazine (AH) as fuels. The space storable propellants include liquid oxygen (LOX) as an oxidizer with hydrazine or hydrocarbons such as liquid methane, ethane, and ethanol as fuels. Cryogenic propellants are LOX or gaseous oxygen (GOX) as oxidizers and liquid or gaseous hydrogen as fuels. Improved performance and lifetime for small chemical rockets are sought through the development of new predictive tools to understand the combustion and flow physics, the introduction of high temperature materials to eliminate fuel film cooling and its associated combustion inefficiency, and improved component designs to optimize performance. Improved predictive technology is sought through the comparison of both local and global predictions with experimental data. Results indicate that modeling of the injector and combustion process in small rockets needs improvement. High temperature materials require the development of fabrication processes, a durability data base in both laboratory and rocket environments, and basic engineering property data such as strength, creep, fatigue, and work hardening properties at both room and elevated temperature. Promising materials under development include iridium-coated rhenium and a ceramic composite of mixed hafnium carbide and tantalum carbide reinforced with graphite fibers.

Schneider, Steven↗

Development of an Automated Reader for Analysis and Storage of Personnel Dosimeter Badge Data

The collection and archiving of data from personnel dosimeters has become increasingly important in light of the lowered Threshold Limit Values (TLV) for HydraZine (HZ), MonoMethylHydrazine (MMH), and Unsymmetrical DiMethylHydrazine (UDMH). The American Conference of Government Industrial Hygienists (ACGIH) lowered the TLV from 100 parts per billion (ppb) to IO ppb and has caused increased concern over long term exposures of personnel to trace levels of these hypergols and other potentially harmful chemicals. An automated system of reading the exposure levels of personnel dosimeters and storing exposure data for subsequent evaluation has been developed. The reading of personnel dosimeter badges for exposure to potentially harmful vapor concentrations of hydrazines or other chemicals is performed visually by comparing the color developed by the badge with a calibrated color comparator. The result obtained using visual comparisons of the developed badge color with the comparator may vary widely from user to user. The automated badge reader takes the variability out of the dosimeter reading by accurately comparing the reflectance obtained from a colored spot on the badge with a reading on the same spot prior to any exposure to chemical vapors. The observed difference between the reflectance values is used as part of a calculation of the dose value for the badge based on a stored calibration curve. The badge reader also stores bar-code data unique to each badge, as well as bar-code information on the user, as part of the permanent badge record. The start and stop exposure times for each badge are recorded and can be used as part of the calculated concentration, in ppm, for each badge logged during a recording period. The badge reader is equipped with a number of badge holders, each of which is unique to a specific type of personnel dosimeter badge. This gives the reader maximum flexibility to allow for the reading of several different types of badges. Test results of the badge reader for several different types of personnel dosimeter badges are presented within the body of this paper.

Meneghelli, B. J.↗

Development of an Automated Reader for Analysis and Storage of Personnel Dosimeter Badge Data

The collection and archiving of data from personnel dosimeters has become increasingly important in light of the lowered threshold limit values (TLV) for hydrazine (HZ), monomethylhydrazine (MMH), and unsymmetrical dimethylhydrazine (UDMH). The American Conference of Government Industrial Hygienists (ACGIH) lowered the TLV from 100 parts per billion (ppb) to 10 ppb and has caused increased concern over long term exposures of personnel to trace levels of these hypergols and other potentially harmful chemicals. An automated system of reading the exposure levels of personnel dosimeters and storing exposure data for subsequent evaluation has been developed. The reading of personnel dosimeter badges for exposure lo potentially harmful vapor concentrations of hydrazines or other chemicals is performed visually by comparing the color developed by the badge with a calibrated color comparator. The result obtained using visual comparisons of the developed badge color with the comparator may vary widely from user to user. The automated badge reader takes the variability out of the dosimeter reading by accurately comparing the reflectance obtained from a colored spot on the badge with a reading on the same spot prior to any exposure to chemical vapors. The observed difference between the reflectance values is used as part of a calculation of the dose value for the badge based on a stored calibration curve. The badge reader also stores bar-code data unique to each badge, as well as bar-code information on the user, as part of the permanent badge record. The start and stop exposure times for each badge are recorded and can be used as part of the calculated concentration, in ppm, for each badge logged during a recording period. The badge reader is equipped with a number of badge holders, each of which is unique to a specific type of personnel dosimeter badge. This gives the reader maximum flexibility to allow for the reading of several different types of badges. Test results of the badge reader for several different types of personnel dosimeter badges are presented within the body of this paper.

Meneghelli, B. J.↗

High Pressure Earth Storable Rocket Technology Program-Hipes Options 1/2 Report

Under the High Pressure Earth Storable Rocket Technology (HIPES) Program, TRW successfully completed testing of two 100 lbf thrust class rhenium chambers using N204-MMH. The first chamber was successfully fired for 4789 seconds of operating time with a maximum duration of 700 seconds. This chamber had been previously fired for 5230 seconds with N2O4-N2H4. The second chamber was successfully fired for 8085 seconds with a maximum firing duration of 1200 seconds. The Isp (specific impulse) for both chambers ranged from 323 lbf-sec/lbm to 330 lbf-sec/lbm.

Chazen, M. L.↗

WSTF Pyrovalve Test Program Status: 2000

Extensive propulsion and pyrotechnic testing has been in progress at NASA/JSC White Sands Test Facility (WSTF) since 1995, starting with the Mars Observer Propulsion and Pyrotechnics Corrective Action Test Program (MOCATP). The MOCATP has been concluded, but extensive pyrovalve testing plus research and development continues at WSTF. Our capability to accurately characterize pyrovalve combustion product blow-by into propellant systems, evaluate hydrazine and monomethylhydrazine (MMH) thermal decomposition initiated by blow-by, and characterize valve actuation operation, continues to be used and refined. Data from this and several low blow-by pyrovalves manufactured by Conax and other corporations continues to be evaluated as a potential corrective measure for blow-by induced propellant explosions. Additionally, new measurement techniques are being developed, advanced pyrovalve development is under-way, and nondestructive examination (NDE) methods are being developed to help ensure pyrovalve safety. Starting in 2000 these data are being formatted into a pyrovalve application and testing handbook. Near-term testing includes evaluation of 3/8-in. Conax pyrovalves and other commercially available valves; development of advanced pyrovalve subcomponent technology; investigation of NDE techniques to evaluate pyrovalve ram seals and real-time measurement of housing deformation; and investigation of pyrotechnically induced explosive hydrazine decomposition both through testing and modeling. Evaluation of 3/8-in. Conax valves is to include operational margin testing to be accomplished at the NASA Langley Research Center.

Saulsberry, Regor L.↗

Detached Solidification of InSb on Earth

Detached solidification of lightly gallium-doped indium antimonide was achieved in the laboratory only when the ampoule was coated with hexagonal boron nitride and when the material appeared to be oxide-free. A furnace was constructed with the temperature increasing with height in order to minimize bouyancy-driven convection, so as to maximize transport of segregated dissolved gases into the gap between the growing solid and the ampoule wall. There appeared to be no difference in results with freezing rates of 5 mmh and 10 mm/h. Best results were obtained when the ampoule was backfilled with 20 kPa of Ar-10%H2 prior to sealing. The detached portions were depressed by several pm from adjacent attached regions, were rough, and sometimes had microfacets and steps.

Wang, Jianbin↗

Design and Testing of Non-Toxic RCS Thrusters for Second Generation Reusable Launch Vehicle

The current NASA Space Shuttle auxiliary propulsion system utilizes nitrogen tetroxide (NTO) and monomethylhydrazine (MMH), hypergolic propellants. This use of these propellants has resulted in high levels of maintenance and precautions that contribute to costly launch operations. By employing alternate propellant combinations, those less toxic to humans, the hazards and time required between missions can be significantly reduced. Use of alternate propellants can thereby increase the efficiency and lower the cost in launch operations. In support of NASA's Space Launch Initiative (SLI), TRW proposed a three-phase project structured to significantly increase the technology readiness of a high-performance reaction control subsystem (RCS) thruster using non-toxic propellant for an operationally efficient and reusable auxiliary propulsion system (APS). The project enables the development of an integrated primary/vernier thruster capable of providing dual-thrust levels of both 1000-lbf class thrust and 25-lbf thrust. The intent of the project is to reduce the risk associated with the development of an improved RCS flight design that meets the primary NASA objectives of improved safety and reliability while reducing systems operations and maintenance costs. TRW proposed two non-toxic auxiliary propulsion engine designs, one using liquid oxygen and liquid hydrogen and the other using liquid oxygen and liquid ethanol, as candidates to meet the goals of reliability and affordability at the RCS level. Both of these propellant combinations offer the advantage of a safe environment for maintenance, while at the same time providing adequate to excellent performance for a conventional liquid propulsion systems. The key enabling technology incorporated in both TRW thrusters is the coaxial liquid on liquid pintle injector. This paper will concentrate on only the design and testing of one of the thrusters, the liquid oxygen (LOX) and liquid hydrogen (LH2) thruster. The LOX/LH2 thruster design includes a LOX-centered pintle injector, consisting of two rows of slots that create a radial spoke spray pattern in the combustion chamber. The main fuel injector creates a continuous sheet of LH2 originating upstream of the LOX pintle injector. The two propellants impinge at the pintle slots, where the resulting momentum ratio and spray pattern determines the combustion efficiency and thermal effects on the hardware. Another enabling technology used in the design of this thruster is fuel film cooling through a duct, lining the inner wall of the combustion chamber barrel section. The duct is also acts as a secondary fuel injection point. The variation in the amount of LH2 used for the duct allows for adjustments in the cooling capacity for the thruster. The Non-Toxic LOX-LH2 RCS Workhorse Thruster was tested at the NASA Marshall Space Flight Center's Test Stand 500. Hot-fire tests were conducted between March 08, 2002 and April 05, 2002. All testing during the program base period were performed at sea-level conditions. During the test program, 7 configurations were tested, including 2 combustion chambers, 3 LOX injector pintle tips, and 4 LH2 injector stroke settings. The operating conditions that were surveyed varied thrust levels, mixture ratio and LH2 duct cooling flow. The copper heat sink chamber was used for 16 burns, each burn lasting from 0.4 to 10 seconds, totaling 51.4 seconds, followed by Haynes chamber testing ranging from 0.9 to 120 seconds, totaling 300.9 seconds. The total accumulated burn time for the test program is 352.3 seconds. C* efficiency was calculated and found to be within expectable limits for most operating conditions. The temperature on the Haynes combustion chamber remained below established material limits, with the exception of one localized hot spot. The test results demonstrate that both the coaxial liquid-on-liquid pintle injector design and fuel duct concepts are viable for the intended application. The thruster head-e design maintained cryogenic injection temperatures while firing, which validates the concept for minimal heat soak back. By injecting fuel into the duct, the throat temperatures were manageable, yet the split of fuel through the cooling duct does not compromise the overall combustion efficiency, which indicates that, provided proper design refinement, such a concept can be applied to a high-performance version of the thruster. These hot fire tests demonstrate the robustness of the duct design concept and good capability to withstand off-nominal operating conditions without adversely impacting the thermal response of the engine, a key design feature for a cryogenic thruster.

Calvignac, Jacky↗

Propellant Gauging for Exploration

This paper presents a brief overview of propellant gauging needs and requirements in the context of lunar exploration missions defined by the Exploration Systems Architecture Study (ESAS) report. A timeline for the development and testing of gauging technologies, and a few key design review dates are presented. A lunar exploration mission scenario is discussed which aids in defining the propellant gauging needs. The fleet of new exploration vehicles includes the Ares I and Ares V launch vehicles, Earth Departure Stage (EDS), Lunar Surface Access Module (LSAM) ascent and descent stages, and the Orion Crew Exploration Vehicle (CEV). The liquid propellant choices are currently oxygen - hydrogen for the launch vehicles, the EDS, and LSAM descent module; oxygen - methane for LSAM ascent module; and monomethylhydrazine nitrogen tetroxide (MMH-NTO) for the CEV. Estimated tank sizes, temperatures, pressures, and storage durations are presented. A baseline propellant gauging system is proposed that is based on high Technology Readiness Level (TRL) gauging technologies. In order to be considered for use on the new exploration vehicles, any new gauging technologies will have to show a clear benefit over the baseline methods in terms of performance and/or cost.

Zimmerli, Gregory A.↗

Design of a Mars Airplane Propulsion System for the Aerial Regional-Scale Environmental Survey (ARES) Mission Concept

The Aerial Regional-Scale Environmental Survey (ARES) is a Mars exploration mission concept that utilizes a rocket propelled airplane to take scientific measurements of atmospheric, surface, and subsurface phenomena. The liquid rocket propulsion system design has matured through several design cycles and trade studies since the inception of the ARES concept in 2002. This paper describes the process of selecting a bipropellant system over other propulsion system options, and provides details on the rocket system design, thrusters, propellant tank and PMD design, propellant isolation, and flow control hardware. The paper also summarizes computer model results of thruster plume interactions and simulated flight performance. The airplane has a 6.25 m wingspan with a total wet mass of 185 kg and has to ability to fly over 600 km through the atmosphere of Mars with 45 kg of MMH / MON3 propellant.

Kuhl, Christopher A.↗

Electrochemical Disposal of Hydrazines in Water

An electrochemical method of disposal of hydrazines dissolved in water has been devised. The method is applicable to hydrazine (N2H4), to monomethyl hydrazine [also denoted by MMH or by its chemical formula, (CH3)HNNH2], and to unsymmetrical dimethyl hydrazine [also denoted UDMH or by its chemical formula, (CH3)2NNH2]. The method involves a room-temperature process that converts the hydrazine to the harmless products N2, H2O, and, in some cases, CO2

Kim, Jinseong↗

Three Methods of Detection of Hydrazines

Three proposed methods for measuring trace quantities of hydrazines involve ionization and detection of hydrazine derivatives. These methods are intended to overcome the limitations of prior hydrazine- detection methods. Hydrazine (Hz), monomethylhydrazine (MMH), and unsymmetrical dimethylhydrazine (UDMH) are hypergolic fuels and are highly reactive, toxic, and corrosive. A capability to measure concentrations of hydrazines is desirable for detecting leaks and ensuring safety in aerospace settings and in some industrial settings in which these compounds are used. One of the properties (high reactivity) that make it desirable to detect trace amounts of hydrazines also makes it difficult to detect hydrazines and measure their concentrations accurately using prior methods: significant amounts are lost to thermal and catalytic decomposition prior to detection. Further complications arise from the sticky nature of hydrazines: Sample hydrazine molecules tend to become irreversibly adsorbed onto solid surfaces with which they come into contact during transport to detectors, giving rise to drift in detector responses. In each proposed method, the reactive, sticky nature of hydrazines would be turned to advantage by providing a suitably doped substrate surface with which the hydrazines would react. The resulting hydrazine derivatives would be sufficiently less sticky and sufficiently more stable so that fewer molecules would be lost to decomposition or adsorption during transport. Consequently, it would be possible to measure concentration with more sensitivity and less error than in prior techniques. The first proposed method calls for the use of a recently developed technique known as desorption electrospray ionization (DESI), in which a pneumatically assisted micro -electrospray at ambient pressure is directed at a surface of interest. In this case, the surface of interest would be that of a substrate described above.

Griffin, Timothy↗

Aerojet - Attitude Control Engines

All the engines were both qualification and acceptance tested at Marquardt s facilities. After we won the Apollo Program contract, we went off and built two vacuum test facilities, which simulated altitude continuous firing for as long as we wanted to run an engine. They would run days and days with the same capability we had on steam ejection. We did all of the testing in both for the qualification and the acceptance test. One of them was a large ball, which was an eighteen-foot diameter sphere, evacuated again with a big steam ejector system that could be used for system testing; that s where we did the Lunar Excursion Module testing. We put the whole cluster in there and tested the entire cluster at the simulated altitude conditions. The lowest altitude we tested at - typically an acceptance test - was 105,000 feet simulated altitude. The big ball - because people were interested in what they called goop formation, which is an unburned hydrazine product migrating to cold surfaces on different parts of spacecraft - was built to address those kinds of issues. We ran long-life tests in a simulated space environment with the entire inside of the test cell around the test article, liquid nitrogen cooled, so it could act as getter for any of the exhaust products. That particular facility could pull down to about 350,000 feet (atmosphere) equivalent altitude, which was pushing pretty close to the thermodynamic triple point of the MMH. It was a good test facility. Those facilities are no longer there. When the guys at Marquardt sold the company to what eventually became part of Aerojet, all those test facilities were cut off at the roots. I think they have a movie studio there at this point. That part of it is truly not recoverable, but it did some excellent high-altitude, space-equivalent testing at the time. Surprisingly, we had very few problems while testing in the San Fernando Valley. In the early 1960s, nobody had ever seen dinitrogen tetroxide (N2O4), so that wasn't too big a deal. We really did only make small, red clouds. In all the hundreds of thousands of tests and probably well over one million firings that I was around that place for, in all that thirty-something years, we had a total of one serious injury associated with rocket engine testing and propellants. Because we were trying to figure out what propellants would really be good, we tried all of the fun stuff like the carbon tetrafluoride, chlorine pentafluoride, and pure fluorine. The materials knowledge wasn't all that great at the time. On one test, the fluorine we had didn't react well with the copper they were using for tubing, and it managed to cause another unscheduled disassembly of the facility. It was very serious. It's like one of those Korean War stories. The technician happened to be walking past the test facility when it decided to blow itself up. A piece of copper tubing pierced one cheek and came out the other. That was the only serious accident in all of the engines handled in all those years. Now, we did have a problem with the EPA later because they figured out what the brown clouds were about. We built a whole bunch of exhaust mitigation scrubbers to take care of engine testing in the daytime. In general, we operated the big shuttle (RCS) engine, the 870- pounder at nominal conditions; they scrubbed the effluents pretty well. If you operated that same 870-pound force engine at a level where you get a lot of excess oxidizer, yeah, there s a brown cloud. But, you know, it doesn't show up well in the dark. They did do some of that. But, that s gone; it was addressed one way or another. RELEASED -

Pfeifer, Gerald R.↗

A Summary of NASA and USAF Hypergolic Propellant Related Spills And Fires

Hypergolic fluids are toxic liquids that react spontaneously and violently when they contact each other. These fluids are used in many different rocket and aircraft systems for propulsion and hydraulic power including, orbiting satellites, manned spacecraft, military aircraft, and deep space probes. Hypergolic fuels include hydrazine (N 2H4) and its derivatives including monomethylhydrazine (MMH), unsymmetrical di-methylhydrazine (UDMH), and Aerozine 50 (A-50), which is an equal mixture of N2H4 and UDMH. The oxidizer used with these fuels is usually nitrogen tetroxide (N2O4), also known as di-nitrogen tetroxide or NTO, and various blends of N2O4 with nitric oxide (NO). Several documented, unintentional hypergolic fluid spills and fires related to the Apollo Program, the Space Shuttle Program, and several other programs from approximately 1968 through the spring of 2009 have been studied for the primary purpose of extracting the lessons learned. Spill sites include KSC, JSC, WSTF, CCAFS, EAFB, McConnell AFB, and VAFB.

Nufer, B. M.↗

LADEE Propulsion System Cold Flow Test

Lunar Atmosphere and Dust Environment Explorer (LADEE) is a NASA mission that will orbit the Moon. Its main objective is to characterize the atmosphere and lunar dust environment. The spacecraft development is being led by NASA Ames Research Center and scheduled for launch in 2013. The LADEE spacecraft will be operated with a bi-propellant hypergolic propulsion system using MMH and NTO as the fuel and oxidizer, respectively. The propulsion system utilizes flight-proven hardware on major components. The propulsion layout is composed of one 100-lbf main thruster and four 5-lbf RCS thrusters. The propellants are stored in four tanks (two parallel-connected tanks per propellant component). The propellants will be pressurized by regulated helium. A simulated propulsion system has been built for conducting cold flow test series to characterize the transient fluid flow of the propulsion system feed lines and to verify the critical operation modes, such as system priming, waterhammer, and crucial mission duty cycles. Propellant drainage differential between propellant tanks will also be assessed. Since the oxidizer feed line system has a higher flow demand than the fuel system does, the cold flow test focuses on the oxidizer system. The objective of the cold flow test is to simulate the LADEE propulsion fluid flow operation through water cold flow test and to obtain data for anchoring analytical models. The models will be used to predict the transient and steady state flow behaviors in the actual flight operations. The test activities, including the simulated propulsion test article, cold flow test, and analytical modeling, are being performed at NASA Marshall Space Flight Center. At the time of the abstract submission, the test article checkout is being performed. The test series will be completed by November, 2012

Williams, Jonathan Hunter↗