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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
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NASA NTRS1986

C3H2 observations as a diagnostic probe for molecular clouds

Recently the three-membered ring molecule, cyclopropenylidene, C3H2, has been identified in the laboratory and detected in molecular clouds by Thaddeus, Vrtilek and Gottlieb (1985). This molecule is wide-spread throughout the Galaxy and has been detected in 25 separate sources including cold dust clouds, circumstellar envelopes, HII regions, and the spiral arms observed against the Cas supernova remnant. In order to evaluate the potential of C3H2 as a diagnostic probe for molecular clouds, and to attempt to identify the most useful transitions, statistical equilibrium calculations were carried out for the lowest 24 levels of the ortho species and the lowest 10 levels of the para species. Many of the sources observed by Matthews and Irvine (1985) show evidence of being optically thick in the 1(10)-1(01) line. Consequently, the effects of radiative trapping should be incorporated into the equilibrium calculations. This was done using the Large Velocity Gradient approximation for a spherical cloud of uniform density. Some results of the calculations for T(K)=10K are given. Figures are presented which show contours of the logarithm of the ratio of peak line brightness temperatures for ortho-para pairs of lines at similar frequencies. It appears that the widespread nature of C3H2, the relatively large strength of its spectral lines, and their sensitivity to density and molecular abundance combine to make this a useful molecule for probing physical conditions in molecular clouds. The 1(10)-1(01) and 2(20)-2(11) K-band lines may be especially useful in this regard because of the ease with which they are observed and their unusual density-dependent emission/absorption properties.

Avery, L. W.↗
NASA NTRS1985

Protostars and planets II

Various papers on the formation of stars and planets are presented. The general topics addressed include: molecular clouds and star formation, young stellar objects and circumstellar disks, chemistry and grains in molecular clouds and the solar nebula, formation of giant planets, and models of the solar nebula and other planetary systems. Individual papers address: molecular cloud cores, physical conditions in isolated dark globules, rotation in dark clouds, and turbulence in molecular clouds. Also discussed are: fragmentation and hierarchical structure in the interstellar medium, formation of bound stellar clusters, ambient radiation field of young solar systems, and magnetic fields.

Black, D. C.↗
NASA NTRS1972

Physics in perspective. Volume 2, part A: The core subfields of physics

Panel reports to the Survey Committee are presented to provide detailed technical background and documentation for committee findings, and to indicate the vitality and strength of the subfields of physics. Included are the core subfields of acoustics, optics, condensed matter, plasmas and fluids, atomic molecular and electron physics, nuclear physics, and elementary particle physics.

Source record↗
NASA NTRS1973

Measurement of surface stay times for physical adsorption of gases

A molecular beam time-of-flight technique is studied as a means of determining surface stay times for physical adsorption. The experimental approach consists of pulsing a molecular beam, allowing the pulse to strike an adsorbing surface and detecting the molecular pulse after it has subsequently desorbed. The technique is also found to be useful for general studies of adsorption under nonequilibrium conditions including the study of adsorbate-adsorbate interactions. The shape of the detected pulse is analyzed in detail for a first-order desorption process. For mean stay times, tau, less than the mean molecular transit times involved, the peak of the detected pulse is delayed by an amount approximately equal to tau. For tau much greater than these transit times, the detected pulse should decay as exp(-t/tau). However, for stay times of the order of the transit times, both the molecular speed distributions and the incident pulse duration time must be taken into account.

Wilmoth, R. G.↗
NASA NTRS1993

Observations of the CO J=6-5 transition in starburst galaxies

Over the past several years, short-submillimeter observations of carbon monoxide's (CO) mid-J rotational levels have revealed the presence of a large amount of excited molecular gas in luminous giant molecular clouds in our Galaxy. Submillimeter lines are specific probes of excited material: collisional excitation of the level energy of 116 K above ground, and 6-5 transition's critical density is approximately 10(exp 6) cm(exp -3) in optically thin gas. Radiative trapping effects reduce the excitation requirements to some extent, but detection of the CO J=6-5 line is nearly indisputable proof of the existence of gas that is both warm and dense. The excitation conditions also imply that cool (T less than 20 K) molecular clouds within the beam neither emit nor absorb in the short-submillimeter lines; in our Galaxy, clouds with active massive star formation emit the strongest short-submillimeter CO rotational lines. We used these properties to explore the distribution of excited molecular material and physical conditions within the star formation regions of several classical starburst nuclei: NGC253, M82, and IC342. We have used the 6-5 transition as a thermometer of warm molecular gas in starburst nuclei, unambiguously finding that the nuclear molecular gas in starburst galaxies is substantially warmer than in typical disk clouds.

Harris, A. I.↗
NASA NTRS1978

Design theory and performance of cryogenic molecular adsorption refrigeration systems

Closed-cycle operation of molecular adsorption refrigeration systems (MARS) has been demonstrated by using thermally cycled zeolites to adsorb and desorb various gases under pressures of 20-60 atm. This paper develops three aspects of the design theory: the physical theory of molecular adsorption of small molecules such as A, N2, N2O and NH3, the design relations for closed-cycle flow for three or more compressors, and the coefficient of performance. This work is intended to demonstrate nonmechanical gas compression for various cryogenic gases than can compete with mechanical systems with a different mix of advantages and disadvantages.

Hartwig, W. H.↗
NASA NTRS1995

Physical structure of the IRC+10216 wind: Molecular sidereoarcheology

We present KAO observations of the CO J=9-8 and 12-11 lines in the C-star IRC+10216; these are the highest rotational transitions so far observed in any AGB star. A model is developed for the CO emission by IRC+10216 in all the observed CO rotational transitions.

Skinner, C. J.↗
NASA NTRS1977

The energetics of molecular clouds. I - Methods of analysis and application to the S255 molecular cloud

Observations of the S255 molecular cloud in the radio lines of CO, (C-13)O, and H2O as well as in the IR region from 12 to 20 microns are presented. These results show that an extended molecular cloud is associated with the optically visible H II regions S255 - S257, both the kinetic temperature and molecular density are enhanced in an area centered on a compact near-IR source, this source is also coincident with an OH and an H2O maser (within the errors), and the IR source exhibits the silicon absorption feature. First-order techniques which allow physical properties of molecular clouds to be estimated and the energetics of the gas and dust in the clouds to be analyzed are developed and applied to S255. It is concluded that: (1) the gas cooling rate is much less than the dust cooling rate; (2) the primary energy flow is in the IR through dust emission over a range of temperatures; (3) the near-IR source is apparently responsible for the local peak in gas kinetic temperature; and (4) the exciting stars of nearby H II regions appear to be the primary heat sources for the overall molecular cloud.

Evans, N. J., II↗
NASA NTRS1979

Magnetic diffusion and ionization fractions in dense molecular clouds - The role of charged grains

The physics of magnetic diffusion in dense molecular clouds is examined, with particular attention given to the role of charged grains in controlling the process. The ionization fraction of dense molecular clouds in the presence of grains is determined from considerations of charge exchange, dissociative recombination, radiative recombination and collisions between grains and charged species, and it is found that the inclusion of grains tends to lower the ionization fraction for a given cosmic-ray ionization rate and metal depletion. The kinematics of grain motion is discussed and it is shown that at temperatures less than 30 K, each grain alternates rapidly in charge between -1 and 0 and thus executes periodic motion in a self-gravitating cloud containing a magnetic field. The full kinematics of magnetic diffusion including the motions of ions and electrons are then examined, taking into account the additional viscous force from charged grains, and numerical calculations of the diffusion time scales of uniform, magnetically supported clouds or cloud cores are presented.

Elmegreen, B. G.↗
NASA NTRS1990

Molecular clouds associated with luminous far-infrared sources in the outer Galaxy

The stellar content and physical properties of the molecular clouds associated with 21 bright far-IR sources in the outer Galaxy have been determined through C-12O, C-13O, 6-cm radio continuum, and IRAS observations. The molecular cloud masses range from 200 to about 10,000 solar masses. The far-IR luminosity-to-mass ratio for these clouds has a mean value of 6.8 solar luminosity/solar masses and shows no correlation with the cloud mass, a result similar to that found for more massive clouds in the inner Galaxy. The radio continuum survey of the 21 bright far-IR sources indicates that most of these regions probably have a single, massive star providing most of the ionization. The cloud masses derived from virial and LTE analyses are in agreement, supporting the assumptions commonly made in their calculations, and a tight, near-linear correlation is found between the C-12O luminosity and the cloud mass. The H2 column density and integrated C-12O intensity are also correlated on a point-by-point basis, although the scatter is larger than the C-12O luminosity-cloud mass relation.

Carpenter, John M.↗
NASA NTRS1961

THEORETICAL STUDY OF ATOMIC AND MOLECULAR GASES AND THEIR REACTIONS IN THE UPPER ATMOSPHERE. SUMMARY OF WORK DONE IN THE PERIOD NOV. 1, 1960 TO APR. 30, 1961

In the previous report it was stated that the major mathematical problems of computations were nearly solved and an attempt is being made to start application of "Tables of Integrals" to the computation of the different states of atoms and molecules. In this respect I like to report that the computation of a number of states of atoms and molecules has been carried out. The results are so far confined only to the equilibrium distance of molecules. We are extending the calculation to other distances so as to compute potential energy curves of different states of molecules. We are also developing Thomas Fermi Statistical model of the atom to verify our results of more accurate calculation. The results so far have been very encouraging and I hope to report some of these results in the next paper.

Gas↗
NASA NTRS1972

Optical interferometry study of film formation in lubrication of sliding and/or rolling contacts

Seventeen fluids of widely varying physical properties and molecular structure were chosen for study. Film thickness and traction were measured simultaneously in point contacts by interferometry, from which a new theory of traction was proposed. Film thickness was measured in line contacts by interferometry and electrical capacitance to establish correlation between these two methods. An interferometric method for the absolute determination of refractive index in the contact zone was developed and applied to point contact fluid entrapments. Electrical capacitance was used to study the thickness and properties of the soft surface film which sometimes forms near a metal-fluid interface.

Stejskal, E. O.↗
NASA NTRS1973

Leak testing

Leak-testing methods for gas and liquid systems are described. The physical principles of molecular, liquid, and gas flow; relations of leak-testing methods and instrumentation; and tracer gases used in testing vacuum systems are discussed.

Engelhardt, R. E.↗
NASA NTRS1972

Some surface characteristics and gas interactions of Apollo 14 fines and rock fragments.

Comprehensive survey of the physical surface characteristics of Apollo 14 fines, two fragments of a breccia (14321), and a crystalline rock (14310). The survey was carried out with optical and both scanning and transmission electron microscopy and by studying the adsorption of a variety of gases including nitrogen, hydrogen, and water vapor. Our objective in the optical microscope study was to relate the visible geological and petrological features to the surface properties. Electron microscopy particularly helped relate surface roughness and particle fusion to gas adsorption and pore structure. The fine sample (14163,111) had a surface area of 0.210 sq m/g and a helium density of 2.9 g/cc. Similar values have been observed with breccia fragments. Other observations include physical adsorption of molecular hydrogen at low temperatures and of water vapor at ambient temperatures. It is concluded that these particular lunar materials, while capable of adsorbing water vapor, do not retain it for any significant time at low pressures, nor, under lunar conditions, is there any indication of absorption or penetration.

Cadenhead, D. A.↗
NASA NTRS1981

Rayleigh scattering

The physical phenomena of molecular scattering are examined with the objective of redefining the confusing terminology currently used. The following definitions are proposed: molecular scattering consists of Rayleigh and vibrational Raman scattering; the Rayleigh scattering consists of rotational Raman lines and the central Cabannes line; the Cabannes line is composed of the Brillouin doublet and the central Gross or Landau-Placzek line. The term 'Rayleigh line' should never be used.

Young, A. T.↗
NASA NTRS1982

Characterization and degradation studies on synthetic polymers for aerospace application

The anti-misting additive for jet fuels known as FM-9 (proprietary polymer) was characterized by elemental analysis, solubility studies and molecular weight determination. Physical properties of surface tension, viscosity, specific gravity and other physical parameters were determined. These results are compared with properties of polyisobutylene and fuels modified with the same; the misting characteristics of polyisobutylene and FM-9 in Jet A fuel are included. Characterization and degradation of phthalocyanine and its derivatives were accomplished by use of a mass spectrometer and a pyroprobe solid pyrolyzer. Metal phthalocyanine tetracarboxylic acids and phthalocyanine-tetraamine cured epoxies were studied. Epoxy/graphite composite panels were exposed to a NASA-Ames radiant panel fire simulator in the flaming and non-flaming modes; toxic gases of HCN and HZS were measured along with oxygen, Co2, Co, and organic gases.

Hsu, M. T. S.↗
NASA NTRS1985

Condensation onto grains in the outflows from mass-losing red giants

In the outflows from red giants, grains are formed which are driven by radiation pressure. For the development of a model of the outflows, a detailed understanding of the interaction between the gas and dust is critical. The present investigation is concerned with condensation processes which occur after the grains nucleate near the stars. A physical process considered results from the cooling of the grains as they flow away from the star. Molecules which initially do not condense onto the grains can do so far from the star. It is shown that for some species this effect can be quite important in determining their gas-phase abundances in the outer circumstellar envelope. One of the major motivations of this investigation was provided by the desire to understand the physical conditions and molecular abundances in the outflows from the considered stars.

Jura, M.↗
NASA NTRS1993

Molecular processes in comets

Classical trajectory calculations of the cross sections for vibrational and rotational energy exchange in direct and reactive collisions of hydrogen atoms and hydrogen molecules have been carried out. To test the sensitivity, three potential energy surfaces have been used. For the exchange transitions which occur at small internuclear distances, the rate coefficients for the three surfaces agree quite well. For the direct transitions, there are significant differences for the pure rotational transitions from j=0 to 2 and from j=1 to j=3 in which there is no change in vibration. For higher j the differences tend to disappear, suggesting that the rotational angular momentum can couple to the orbital angular momentum to overcome the centrifugal barrier. Complete numerically exact quantum mechanical calculations for the process in which vJ changes have been performed. Dr. M. A'Hearn has provided data on the fluorescent population of the NH rotational and fine-structure levels from which we should be able to predict accurate photodissociation lifetimes. The distribution rate of C2 is being investigated. A review of H3(+) in terrestrial and extraterrestrial environments was prepared for a volume of Advances in Atomic, Molecular and Optical Physics.

Dalgarno, A.↗