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Y-12 Groundwater Protection Program Monitoring Well Inspection and Maintenance Plan

This plan describes the systematic approach for: inspecting the physical condition of monitoring wells at Y-12, determining maintenance needs that extend the life of a well, and identifying those wells that no longer meet acceptable monitoring well design or well construction standards and require plugging and abandonment. The inspection and maintenance of groundwater monitoring wells is one of the primary management strategies of the Y-12 Groundwater Protection Program (GWPP) Management Plan, that is, the “proactive stewardship of the extensive monitoring well network at Y-12" (Consolidated Nuclear Security, L.L.C. [CNS], 2018). Effective stewardship, and a program of routine inspections of the physical condition of each monitoring well, ensures that representative water-quality samples and hydrologic data are obtained from the well network and protects the subsurface environment. In accordance with the Y-12 GWPP Monitoring Optimization Plan (MOP) for Groundwater Monitoring Wells at the Y-12 National Security Complex, Oak Ridge, Tennessee (CNS, 2017), the status designation (active or inactive) for each well determines the scope and extent of well inspections and maintenance activities. This plan, in conjunction with the above document, formalizes the GWPP approach to focus available resources on monitoring wells which provide the most useful data, and for that reason the GWPP inspects and performs maintenance on the wells sampled by the GWPP. This plan applies to groundwater monitoring wells installed at Y-12 and the related waste management facilities located within the three hydrogeologic regimes: (1) the Bear Creek Hydrogeologic Regime (Bear Creek Regime), (2) the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and (3) the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek Regime encompasses the section of Bear Creek Valley (BCV) immediately west of Y-12. The East Fork Regime encompasses most of the Y-12 process, operations, and support facilities in BCV west of Scarboro Road. The Chestnut Ridge Regime is directly south of Y-12 and encompasses a section of Chestnut Ridge that is bounded to the west by a surface drainage feature (Dunaway Branch, located immediately west of Industrial Landfill II) and by Scarboro Road to the east. The GWPP maintains an extensive database of geographic and construction details and related information for the monitoring wells in each hydrogeologic regime in the Updated Subsurface Database for Bear Creek Valley, Chestnut Ridge, and Parts of Bethel Valley on the U.S. DOE Oak Ridge Reservation (CNS, 2019). A detailed description of the hydrogeologic framework at Y-12 can be found in the GWPP Management Plan (CNS, 2018).

54 ENVIRONMENTAL SCIENCES↗

Distributed Wind Monitoring Best Practices

Accessible performance and operational data have been identified as a key enabler for distributed wind energy industry advancement. While utility-scale wind turbines benefit from reliable and continuous supervisory control and data acquisition (SCADA)-based monitoring platforms, monitoring of the U.S. fleet of distributed wind (DW) turbines has been more inconsistent, unreliable, and sometime difficult to access. Without fleet monitoring data, the industry will never understand and thus work to improve turbine under-performance and reliability issues. For the DW industry to scale up, attract investors, and boost credibility, fleetwide monitoring must be robust and reliable, select data must be made accessible to stakeholders, and the data must be in a format useful to users. To help move the industry toward a more standardized, accessible stream of monitoring data, this distributed wind monitoring best practices report attempts to cover topics including key monitoring channels, hardware, communication strategies, and accessibility. Strategic engagement with DW original equipment manufacturers (OEMs), service providers, lab and university researchers, testing organization, certification bodies, end users and solar photovoltaic (PV) monitoring experts has enabled a better understanding of the current state-of-the-art of monitoring and aided in articulating this set of best practices that will guide OEMs toward harmonized monitoring strategies, aimed at a future goal of achieving accessible performance and operational data for the entire fleet of U.S. distributed wind turbines.

17 WIND ENERGY↗

Assessment of Condition Monitoring Methods and Technologies for Inservice Inspection and Testing of Nuclear Power Plant Components

This report was prepared for the U.S. Nuclear Regulatory Commission (NRC) to explore the application of advanced technologies toward meeting the current and future regulatory requirements for maintenance and condition monitoring of structures, systems, and components. The advanced technologies considered in this work are advanced sensors and instrumentation, data analytics, machine learning and artificial intelligence (ML/AI), physics-based models, and digital twins (DT). The interest in the application of advanced technologies for condition monitoring in nuclear power plants continues to grow, and current and future licensees are expected to implement advanced technologies as part of their inservice inspection (ISI) and inservice testing (IST) programs. This report delineates the outcomes of an exploratory investigation into the implementation of advanced condition monitoring technologies to address ISI and IST requirements. A thorough review was conducted of the existing regulatory requirements for ISI and IST, along with an analysis of associated industry practices. Additionally, a state-of-the-art assessment was performed on advanced condition monitoring technologies frequently employed in non-nuclear sectors. This research incorporated two nuclear-specific case studies to illustrate the application of these technologies within the current nuclear fleet. The report provides an exhaustive discussion on the technical challenges, considerations, and opportunities associated with the deployment of advanced condition monitoring technologies. The following are key considerations in the application of advanced technologies for the ISI and IST of nuclear power plant components: • Developing adequate verification and validation procedures to confirm the functional and non-functional requirements, • Developing technical capabilities to conduct real-time asset condition monitoring, • Establishing guidance and protocol for modeling and simulation tools to continuously meet regulatory requirements, • Addressing trustworthiness, explainability, and interpretability of ML/AI methods, • Evaluating maintenance activities to maintain an adequate safety margin and avoid undesirable conditions, • Establishing cybersecure condition monitoring programs associated with a computer-based software system, and • Establishing standardized evaluation metrics for advanced condition monitoring programs. Interest in the use of advanced technologies for condition monitoring in ISI and IST programs continues to grow, and the technology is expected to experience rapid and wide industry adoption in the near future. Adoption of advanced technologies for condition monitoring could have novel and unique impacts on regulatory activities associated with ISI and IST programs. The NRC is continuing to explore the regulatory aspects of advanced technologies as part of ISI and IST programs by pursuing additional research in this technical area.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

This report contains the groundwater and surface water monitoring data obtained during calendar year (CY) 2019 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12. The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system, shown as Plant North. The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Background information in Section 2 of this report outlines the hydrogeologic framework for groundwater and surface water quality monitoring at Y-12 and includes an overview of the groundwater contamination in each hydrogeologic regime. Section 3 provides details regarding the groundwater and surface water sampling and analysis activities implemented under the Y-12 GWPP, including sampling locations and frequency, sample collection and handling, field measurements and laboratory analytes, quality assurance (QA)/quality control (QC) sampling, data management, and data quality assessment (DQA). However, the equivalent QA/QC or DQA information for the groundwater and surface water data associated with the monitoring programs implemented by UCOR are not included in this report and instead are deferred to referenced programmatic plans and reports issued by OREM and UCOR. Section 4 of this report presents a summary evaluation of the CY 2019 monitoring data with regard to the respective objectives of surveillance monitoring and exit pathway/perimeter monitoring. The evaluation is based primarily on the analytical results for the following principal groundwater contaminants at Y-12: nitrate, uranium, gross alpha activity, gross beta activity, and volatile organic compounds (VOCs). Section 5 summarizes the most significant findings with respect to the principal contaminants along with recommendations for any proposed changes to the ongoing groundwater and surface water quality monitoring performed under the Y-12 GWPP. Technical reports and plans cited in the narrative sections of the report are listed in Section 6. Narrative sections of this report reference several appendices. Figures (maps and diagrams) and data tables (excluding data summary tables incorporated in the narrative sections) are in Appendix A and Appendix B, respectively. Appendix C contains construction details for each well sampled during CY 2019 by either the Y-12 GWPP or UCOR, along with schematic diagrams for wells equipped with Westbay™ multiport sampling equipment or Barcad® pump systems. Appendix D supports the background summary discussion in Section 2 and provides more detailed information about the hydrogeologic framework for groundwater and surface water monitoring at Y-12, including the primary sources of groundwater contamination in each hydrogeologic regime. Results for all field measurements and laboratory analyses obtained by the Y-12 GWPP and UCOR are presented in Appendix E, which also includes the sample numbers for the QA/QC samples associated with groundwater and surface water monitoring performed by the Y-12 GWPP.

54 ENVIRONMENTAL SCIENCES↗

Optimizing long-term monitoring of radiation air-dose rates after the Fukushima Daiichi Nuclear Power Plant

Radiation air dose rates near the Fukushima Daiichi Nuclear Power Plant (FDNPP) have been steadily decreasing over the past eight years since the release of radioactive elements in March 2011. Currently, the radiation monitoring program is expected to transition to long-term monitoring after most of the remediation activities are completed. The main long-term monitoring objectives are to (1) confirm the continuing reduction of contaminant and hazard levels, (2) provide assurance for the public, (3) accumulate the basic datasets for scientific knowledge and future preparation, and (4) detect changes or anomalies in contaminant mobility (if they occur), or any unexpected processes or events. In this work, we have developed a methodology for optimizing the monitoring locations of radiation air dose-rate monitoring. Our approach consists of three steps in order to determine monitoring locations in a systematic manner: (1) prioritizing the critical locations, such as schools or regulatory requirement locations, (2) diversifying locations that cover the key environmental controls that are known to influence contaminant mobility and distributions, and (3) capturing the heterogeneity of radiation air-dose rates across the domain. Therefore, for the second step, we use a Gaussian mixture model to identify the representative locations among multiple environmental variables, such as elevation and land-cover types. For the third step, we use a Gaussian process model to capture and estimate the heterogeneity of air-dose rates across the domain. Employing an integrated dose-rate map derived from Bayesian geostatistical methods as a reference map, we distribute the monitoring locations in such a way as to capture the heterogeneity of the reference map. Our results have shown that this approach allows us to select monitoring locations in a systematic manner such that the heterogeneity of air dose rates is captured by the minimal number of monitoring locations.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

INL Environmental Monitoring Plan (DOE/ID-11088 Rev. 5)

This plan provides a high-level summary of environmental monitoring performed by various organizations within and around the Idaho National Laboratory (INL) Site as required by U.S. Department of Energy (DOE) Order 435.1, Radioactive Waste Management, and DOE Order 458.1, Radiation Protection of the Public and the Environment, Guide DOE/EH-0173T, Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance, and in accordance with 40 Code of Federal Regulations (CFR) 61, National Emission Standards for Hazardous Air Pollutants. The purpose of these orders is to 1) implement sound stewardship practices that protect the air, water, land, and other natural and cultural resources that may be impacted by DOE operations, and 2) to establish standards and requirements for the operations of DOE and DOE contractors with respect to protection of the environment and members of the public against undue risk from radiation. This plan describes the organizations responsible for conducting environmental monitoring across the INL Site, the rationale for monitoring, the types of media being monitored, where the monitoring is conducted, and where monitoring results can be obtained. Detailed monitoring procedures, program plans, or other governing documents used by contractors or agencies to implement requirements are referenced in this plan. This plan covers all planned monitoring and environmental surveillance. Non-routine activities such as special research studies and characterization of individual sites for environmental restoration are outside the scope of this plan.

54 ENVIRONMENTAL SCIENCES↗

Assessment of Baseline Monitoring Data for the Remote-Handled Low-Level Waste Disposal Facility at Idaho National Laboratory

The purpose of this document is to summarize environmental monitoring data collected at the Remote-Handled Low-Level Waste (RHLLW) Disposal Facility during the first four years of facility operations (FY 2019 through FY 2022). This summary provides a “baseline” condition for the facility, which can be used to distinguish contaminant releases from the RHLLW Disposal Facility from pre existing contamination as well as potential future releases from other sources (i.e., upgradient aquifer sources), as specified in the facility monitoring plan. Sufficient data has been collected over the first four years of operation of the RHLLW Disposal Facility to establish baseline conditions for future compliance monitoring of aquifer wells and performance monitoring of vadose zone lysimeters. Except for seven elevated tritium measurements from lysimeter HFEF-South believed to have been impacted by waste disposals, all data was deemed appropriate for establishing baseline concentrations. Monitoring of the aquifer detected indicator analytes gross alpha and gross beta and target analytes tritium and C-14. There were a few C-14 detections prior to an increase in the required detection level (RDL) after the first round of sampling. I-129 and Tc-99 were not detected above RDLs in aquifer samples. Lysimeter samples detected indicator analytes gross alpha and gross beta and target analyte tritium. Target analytes C-14, I-129, and Tc-99 were not detected above RDLs in lysimeter samples. Except for tritium, baseline concentrations of indicator and target analytes measured during the first four years of RHLLW facility operations are expected to represent conditions through the expected 20 year operating period of the facility. Elevated tritium in the aquifer, a result of past discharges of tritium at upgradient facilities, showed a decline over the first four years of operations, and levels are expected to continue to decline with time as a result of dilution and decay. Current tritium levels in lysimeter samples may be elevated due to tritium in the water applied during construction and infiltration testing of the facility. As a result, tritium concentrations in lysimeters may decline with time as a result of dilution and decay. Statistical measures (i.e., mean, standard deviation, and 99% upper confidence level [UCL]) were calculated for all detected analytes using the four years of concentration data. These measures will be used to evaluate future monitoring results and to demonstrate the facility is performing, or not performing, as established in the facility performance assessment (PA). Future monitoring results will also be combined with the baseline data in this report to further establish temporal trends and natural variability in the measurements. Based on the data collected during the baseline period, it is recommended the gross alpha action level for performance monitoring increase from 10 to 20 pCi/L due to several baseline measurements exceeding the preliminary action level of 10. An action level of 20 pCi/L is slightly greater than the 99% UCL, is protective of the aquifer, and would reduce unnecessary sampling. It is also recommended that tritium be added to the lysimeter analyte list for post-baseline period monitoring. Tritium, while not a dose concern, is a good tracer that can provide valuable information on water flow in and around the RHLLW Disposal Facility. Recommendations for a tritium action level are provided if considered necessary.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Panel Session 100: An Integrated Systems-Based Monitoring Approach

This panel focused on recent advancements in monitoring and remaining challenges associated with the implementing cost-effective monitoring approaches for complex DOE sites. Monitoring presents one of the largest, long-term costs for environmental remediation and site stewardship within the DOE because contamination at complex sites will likely be present for tens to hundreds of years into the future. Integration of monitoring with predictive modeling is an approach that can reduce long-term monitoring costs as well as support the effective monitoring design and data interpretation for managing a site toward closure and long-term stewardship. Panelists with presentations: Autonomous Electrical Geophysical Monitoring of Contaminated Sites (Tim Johnson); Systems Based Long-Term Monitoring for DOE Legacy Management (David Shafer); Long-Term Systems Based Monitoring (Anderson Ward)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Designing monitoring networks for local earthquakes

Abstract Seismic networks are essential for monitoring local earthquakes in connection to industrial activities, including wastewater injection and CO2 sequestration. Because these networks are typically deployed for short periods of time at specific sites, it is beneficial to develop best practices for efficient and effective installation and monitoring. Such standards are available for regional earthquake and microseismic monitoring, but not readily available for local scale (tens of kilometer scale) monitoring. Once the region of interest has been determined, the key parameters for establishing a network are available monitoring station locations, site noise, and site utility. Networks should be designed based on the project monitoring goals for earthquake magnitude and density. Herein, a network was established at the Patterson and Hartland Oil Fields in western Kansas in association with a US Department of Energy CarbonSAFE carbon capture and sequestration research project. We employed observations from an analog local network, the Wellington Earthquake Monitoring Network in south-central Kansas, to assess site noise and estimate earthquake detection thresholds for the Patterson and Hartland fields. Noise from oil production facilities was evaluated, concluding that oil lease sites are suitable for monitoring small local earthquakes (M1-M3). The network was designed to have a magnitude of completeness of M1 while using station locations on existing field operator leases. Fifteen months of continuous network operation demonstrates reliable and efficient local earthquake monitoring and provides best practices recommendations for similar operations.

58 GEOSCIENCES↗

Rapid monitoring of fermentations: a feasibility study on biological 2,3-butanediol production

2,3-butanediol (2,3-BDO) is an economically important platform chemical that can be produced by the fermentation of sugars using an engineered strain of Zymomonas mobilis . These fermentations require continuous monitoring and modification of fermentation conditions to maximize 2,3-BDO yields and minimize the production of the undesired coproducts glycerol and acetoin. Because of the time required for sampling and off-line chromatographic measurement of fermentation samples, the ability of fermentation scientists to modify fermentation conditions in a timely manner is limited. The goal of this study was to test if near-infrared spectroscopy (NIRS) along with multivariate statistics could reduce the time needed for this analysis and enable real-time monitoring and control of the fermentation. In this work we developed partial least squares (PLS) calibration models to predict the concentrations of glucose, xylose, 2,3-BDO, acetoin, and glycerol in fermentations via NIRS using two different spectrometers and two different spectroscopy modalities. We first evaluated the feasibility of rapid NIRS monitoring through experiments where we measured the signals from each analyte of interest and built NIRS-based PLS models using spectra from synthetic samples containing uncorrelated concentrations of these analytes. All analytes showed unique spectral signatures, and this initial modeling showed that all analytes could be detected simultaneously. We then began work with samples from laboratory fermentation experiments and tested the feasibility of regression model development across two spectral collection modalities (at-line and on-line) and two instruments: a laboratory-grade instrument and a low-cost instrument with a more limited spectral range. All modalities showed promise in the ability to monitor Z. mobilis fermentations of glucose and xylose to 2,3-BDO. The low-cost instrument displayed a lower signal-to-noise ratio than the laboratory-grade instrument, which led to comparatively lower performance overall, but still provided sufficient accuracy to monitor fermentation trends. While the ease of use of on-line monitoring systems was favored as compared to at-line systems due to the lack of sampling required and potential for automated process control, we observed some decrease in performance due to the additional complexity of the sample matrix. We have demonstrated that NIRS combined with multivariate analysis can be used for at-line and on-line monitoring of the concentrations of glucose, xylose, 2,3-BDO, acetoin, and glycerol during Z. mobilis fermentations. The decrease in signal-to-noise ratio when using a low-cost spectrometer led to greater prediction error than the laboratory-grade spectrometer for at-line monitoring. The on-line monitoring modality showed great promise for real time process control via NIRS.

09 BIOMASS FUELS↗

Monitoring installation of partially occluded subassemblies in modular construction factories using BIM, ray tracing, and computer vision

Modular and offsite construction methods are being increasingly adopted due to the advantages they offer in terms of project completion time, quality, and energy-efficiency. Despite these advantages, the current state of monitoring systems in modular construction factories highly relies on labor-intensive, subjective, and error-prone observational methods. A large body of research has aimed to automate the monitoring process using an array of sensors, such as IMUs and RFIDs, during the past two decades. Recently, computer vision-based methods have gained increasing interest as a non-intrusive technology to monitor the process inside modular construction factories. However, partial occlusion challenges have impeded their practical application on a large scale. This challenge is specifically important for monitoring the installation of subassemblies since they can obstruct the view of the monitoring camera, especially those that enable long-term monitoring like closed-circuit television (CCTV) fixed-view surveillance cameras. Here, this paper aims to address this challenge by proposing a novel computer vision-based method to monitor the installation of new subassemblies inside modular factories in highly occluded scenes. The proposed methodology identifies the subassemblies in the CCTV video footage using computer vision, analyzes the occlusions using BIM and ray casting techniques, and estimates the progress of assembly by comparing the BIM model with the detected subassemblies in the video. The proposed methodology was successfully validated on surveillance videos captured from a volumetric modular construction factory in the U.S., achieving 93% accuracy in identifying the installation of subassemblies. The results from this research show that the integration of BIM and computer vision is a promising method for monitoring the installation processes inside modular factories under severe occlusion.

97 MATHEMATICS AND COMPUTING↗

Economic assessment of seismic monitoring for underground hydrogen storage

Underground hydrogen storage (UHS) plays a key role in the energy landscape. However, like other subsurface engineering technologies, UHS may cause leakage into the groundwater or atmosphere and possibly induce local seismicity. To reduce these risks, seismic monitoring could be a viable technique to track the UHS plume, detect leakages, and locate induced seismicity events. Seismic monitoring has been proposed to safely monitor UHS, but research in this area is still new and requires field studies. Lab and theoretical studies have demonstrated the validity of seismic monitoring for UHS. Therefore, it is imperative to analyze the economic feasibility of seismic monitoring for UHS. Hence, we develop a cost model and open-source Python code for seismic monitoring that considers types of seismometers, comprehensive operational scenarios, detection thresholds, and long-term leakage monitoring. A case study is further provided to validate the cost model on reservoir simulations of UHS. We find that the levelized cost for a 10-year operating UHS site will range on the order of ∼0.003 $\$$/kg. The methods developed in this study could also be applied to the monitoring of groundwater, gas, and/or wastewater injection.

08 HYDROGEN↗

Detecting fractures and monitoring hydraulic fracturing processes at the first EGS Collab testbed using borehole DAS ambient noise

Enhanced geothermal systems (EGS) require cost-effective monitoring of fracture networks. We validate the capability of using borehole distributed acoustic sensing (DAS) ambient noise for fracture monitoring using core photos and core logs. The EGS Collab project has conducted 10 m scale field experiments of hydraulic fracture stimulation using 50–60 m deep experimental wells at the Sanford Underground Research Facility (SURF) in Lead, South Dakota. The first EGS Collab testbed is located at 1616.67 m (4850 ft) depth at SURF and consists of one injection well, one production well, and six monitoring wells. All wells are drilled subhorizontally from an access tunnel called a drift. The project uses a single continuous fiber-optic cable installed sequentially in the six monitoring wells to record DAS data for monitoring hydraulic fracturing during stimulation. We analyze 60 s time records of the borehole DAS ambient noise data and compute the noise root-mean-square (rms) amplitude on each channel (points along the fiber cable) to obtain DAS ambient noise rms amplitude depth profiles along the monitoring wellbore. Our noise rms amplitude profiles indicate amplitude peaks at distinct depths. We compare the DAS noise rms amplitude profiles with borehole core photos and core logs and find that the DAS noise rms amplitude peaks correspond to the locations of fractures or lithologic changes indicated in the core photos or core logs. We then compute the hourly DAS noise rms amplitude profiles in two monitoring wells during three stimulation cycles in 72 h and find that the DAS noise rms amplitude profiles vary with time, indicating the fracture opening/growth or closing during the hydraulic stimulation. Our results demonstrate that borehole DAS passive ambient noise can be used to detect fractures and monitor fracturing processes in EGS reservoirs.

58 GEOSCIENCES↗

Innovative Strategies for Long-Term Monitoring of Complex Groundwater Plumes at DOE’s Legacy Sites (Workshop Report)

Most remaining Department of Energy (DOE) sites will require extended periods of institutional control, especially at complex groundwater sites where attenuation-based strategies have been implemented to facilitate closure. The current practice of monitoring—obtaining and analyzing contaminant concentration in groundwater samples at numerous wells—will account for a large portion of the projected life-cycle at these DOE sites unless a new approach is adopted. State-of-the-art technologies are being developed, including in situ sensors, geophysics, radiation mapping, numerical modeling and AI/ML. These technologies can optimize monitoring strategies in space and time, provide spatially extensive information at vulnerable regions and/or provide more continuous monitoring at lower cost. As part of DOE’s Office of Environmental Management (DOE-EM’s) efforts to advance long-term monitoring systems, an in-person/virtual hybrid workshop was hosted by Savannah River National Laboratory (SRNL) on January 24 and 25, 2023, in Augusta, Georgia. Because DOE-EM’s complex sites will eventually be transferred to DOE’s Office of Legacy Management (DOE-LM), representatives of DOE-LM were important participants in the workshop. The purpose of the workshop was to identify challenges and opportunities for deploying advanced technologies for long-term monitoring at DOE sites. The key questions during the workshop were: 1) the regulatory acceptance of replacing a process that traditionally has used laboratory sampling and analysis of groundwater samples, and 2) the application of this strategy to the southwestern arid sites that include many of the remaining DOE-EM and DOE-LM complex groundwater plumes. Characteristics common to most arid sites present both limitations and opportunities for advanced technologies. DOE-EM has funded a National Laboratory team from SRNL, Lawrence Berkeley National Laboratory (LBNL), and Pacific Northwest National Laboratory (PNNL) to establish the overarching framework of long-term monitoring by systematically combining advanced hardware and software technologies. This project is titled “Advanced Long-Term Environmental Monitoring Systems (ALTEMIS)” and is sponsored by the DOE-EM Technology Development Program. The multi-laboratory team is currently developing and testing innovative monitoring strategies, including the use of in situ groundwater sensors, geophysics, drone/satellite-based remote sensing, reactive transport modeling, and artificial intelligence/machine learning (AI/ML). The project’s demonstration testbed is at the Savannah River Site (SRS) F-Area Seepage Basins, where a well-characterized complex groundwater plume composed of uranium and other radionuclides is in the latter stages of remediation. The workshop included more than 70 participants, presentations, a field visit to F-Area, breakout working groups, and large group discussion. Participants developed recommendations on five topics: in situ sensors, spatially integrative tools, challenges to regulatory acceptance, AI/ML strategies, and transitioning sites to DOE-LM.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Benchmark Analysis for the Optical Dilatometry Method Using Silicon Carbide Temperature Monitors

The main objective of this project was to conduct a benchmark analysis for the optical dilatometry method by using NSUF’s SiC temperature monitors: two (2) SiC temperature monitors provided by NSUF’s BSU-8242 experiment and two (2) SiC temperature monitors provided by NSUF’s GE-Hitachi experiment. Per the BSU-8242 experiment, KGT-3597 and KGT-3591 had a design temperature of 400°C and an exposure of 3 dpa. Per the GE-Hitachi experiment, KGT-3341 and KGT-3336 had a design temperature of 290°C +/- 50°C and an exposure of 0.5–1 dpa. The KGT-3336 SiC monitor was split into two pieces during the decontamination process, making the dilatometry method the only way to analyze both those pieces. The BSU-8242 monitors revealed peak irradiation temperatures under the design temperature, and the GE-Hitachi monitors revealed peak irradiation temperatures within the design temperature range. The optical dilatometry method measured the peak irradiation temperature of BSU-8242 KGT-3597 to be 330°C, while the resistivity method measured the peak irradiation temperature of BSU-8242 KGT-3591 to be 320°C +/- 20°C. The optical dilatometry method measured the peak irradiation temperatures of the pieces of GE-Hitachi KGT-3336 to be 260°C (for the larger piece) and 220°C (for the smaller piece), while the resistivity method measured the peak irradiation temperature of GE-Hitachi KGT-3341 to be 300°C, with an accuracy range of -50°C to +20°C. Both methods of SiC temperature monitor analysis produced very similar peak irradiation temperatures for each pair of SiC passive monitors from the two experiments, BSU-8242 and GE-Hitachi. The results show dilatometry method to be a reliable and less time-intensive process for determining irradiation temperatures from passive SiC thermometry.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Monitored Fluctuating Hydrodynamics

We introduce a hydrodynamic framework for describing monitored classical stochastic processes. We study the conditional ensembles for these monitored processes—i.e., we compute spacetime correlation functions conditioned on a fixed, typical measurement record. In the presence of global symmetries we show that these conditional ensembles can undergo measurement-induced “sharpening” phase transitions as a function of the monitoring rate; moreover, even weak monitoring can give rise to novel critical phases, derived entirely from a classical perspective. We give a simple hydrodynamic derivation of the known “charge-fuzzy phase” for weakly monitored diffusive many-body quantum systems. We show that although the unmonitored symmetric and asymmetric exclusion processes are in different universality classes of transport, the fluctuations in their conditional ensembles flow to the same fixed point with emergent relativistic invariance under monitoring. On the other hand, weakly monitored systems with non-Abelian symmetries enter a novel strongly coupled fixed point with nontrivial dynamical exponent, which we characterize. Our formalism naturally accounts for monitoring general observables, such as currents or density gradients, and allows for a direct calculation of information-theoretic diagnostics of sharpening transitions, including the Shannon entropy of the measurement record.

classical statistical mechanics↗

Stray-Capacitance As a Simple Tool for Monitoring and Locating Heat Generation Demonstrated in Three Superconducting Magnets

Real-time monitoring of heat loads in cryogenic systems is critical for many applications, particularly high field magnets. In this work, we demonstrated that by monitoring changes in the capacitance of local probes consisting of thin metal strips with a porous glass fiber dielectric, boiling helium from as little as 0.1 J of deposited heat can be located by an analysis of the response speed and amplitude in nearby probes. We further implemented stray-capacitance monitoring of a magnet's metal support structures, a more global probe of the magnet volumes, in three high temperature superconducting Bi-2212 magnet types. Global structural stray-capacitance monitoring was evaluated for a single racetrack coil, a common coil dipole, and a canted cosine theta winding, showing a quench response comparable to voltage signals without inductive effects. The response of the local and global probes was compared in the single racetrack coil with well-known quench properties. Monitoring the cool-down of the common coil dipole demonstrated the added benefit of the global stray-capacitance as a liquid level monitor. This simple method of monitoring the capacitance has proven to be a versatile and robust technique for monitoring and locating heat.

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Guidance for Monitoring Passive Groundwater Remedies Over Extended Time Scales

Passive remediation can be appropriate where natural processes and actions such as institutional controls mitigate exposure to contaminated groundwater, achieving remedial action objectives and protectiveness of human health and the environment. Monitored natural attenuation (MNA) is a prevalent passive remediation strategy supported by a regulatory framework and monitoring design guidance. However, long-term passive remedies are usually selected in combination with at least one active remedy, such as source removal, in situ treatment, or pump-and-treat, functioning as a complementary method for achieving remediation objectives and meeting the applicable statutory and regulatory requirements. However, MNA and existing monitoring guidance primarily target situations where the remedial action objectives are met within a few decades. When time scales for passive remediation extend to many decades (50 years or more), a corresponding change in monitoring strategy is needed to adapt to the extended time scale. This document provides guidance for implementing an extended-scale monitoring (ESM) approach appropriate for long-duration passive remediation. Extended-scale is defined in this document with respect to time (i.e., a long duration of remediation) and a large enough physical scale such that downstream receptors will not be impacted within the remediation timeframe. ESM applies to slow-moving groundwater contaminant plumes and emphasizes monitoring primarily for potential exposure pathways. For this approach, the primary monitoring objective is to demonstrate that the plume diminishes before reaching the receptor zone or point of compliance and/or a receptor does not receive concentrations above the compliance limit. While the overall objectives of protecting human health and the environment are the same as for plumes where remediation can occur over a shorter time period, the time scales between decisions are longer and the dynamics of plume evolution are slower. To this end, a scenario-based strategy is described for different plume and source conditions, defining a containment and receptor zones. The containment zone is the area where the risk of exposure to groundwater contamination can be mitigated (e.g., through institutional controls) during the remediation time period. The receptor zone is defined as the area where exposure to groundwater contamination cannot be mitigated and compliance concentration standards must be met. Within the containment zone, slow plume migration may occur, leading to concentrations that exceed compliance standards. However, where distance to the receptor zone is large relative to plume migration and attenuation rate, this approach can be protective of the receptor zone. Selection of a long-duration passive remedy needs to be based on sufficient understanding of contaminant sources, hydrogeology, and contaminant plumes. A strong technical basis, supported by predictive analysis, is recommended to substantiate that contamination is expected to stay within the containment zone during the active remediation and attainment phase of the remedy, and diminish to meet compliance standards within the extended timeframe prior to reaching the receptor zone (e.g., many decades or even centuries). The ESM approach is based on verification of plume behavior and not on detailed plume dynamics. Monitoring is conducted to confirm expected behavior with an emphasis on exposure pathways to verify that plumes remain contained in areas where the protectiveness objectives can be met. ESM should not be adopted if there is significant risk of the plume extending beyond the containment zone. Given the slow movement within the containment zone, less frequent sampling is required relative to approaches used for conventional-scale remediation.

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