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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
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NASA NTRS1985

Operation of a microchannel plate counting system in a mass spectrometer

A multiplier detector system has been developed as part of a mass spectrometer in an ion counting mode. During its operation ions striking a microchannel plate release pulses of electrons which are accelerated to a phosphor layer. The resulting flash of light is carried by a fiber-optic bundle to a photodiode array. The detector simultaneously counts ions throughout a mass spectrum covering more than 30 amu. It extends the mass spectrometer's operation toward low count rates for trace gas analysis. Each mass peak can be independently measured at count rates between 0.1 and 1000 counts/s. Higher rates on a few peaks do not blind the entire detector. The detector's capabilities have been demonstrated by measuring Kr and Xe isotopes in air at natural abundances. The mass spectrometer, detector, and readout electronics are sufficiently compact to permit use in a balloon-borne experiment.

Murphy, D. M.↗
NASA NTRS1983

Laboratory Automation of a Quadrupole Mass Spectrometer

Efforts directed toward interfacing an LSI II bus of a PDP 11/23 desktop computer with a quadrupole mass spectrometer for the purpose of providing a convenient system whereby mass spectral data, of the products of thermal decomposition, may be rapidly acquired and processed under programmed conditions are described. The versatility and operations of the quadrupole mass spectrometer are discussed as well as the procedure for configurating the LSI II bus of the PDP 11/23 desktop computer for interfacing with the quadrupole mass spectrometer system. Data from the mass filter and other units of the spectrometer are digitally transferred to the computer whereupon mass spectral data and related data are generated.

Thompson, J. M.↗
NASA NTRS2008

Calculations for Calibration of a Mass Spectrometer

A computer program performs calculations to calibrate a quadrupole mass spectrometer in an instrumentation system for identifying trace amounts of organic chemicals in air. In the operation of the mass spectrometer, the mass-to-charge ratio (m/z) of ions being counted at a given instant of time is a function of the instantaneous value of a repeating ramp voltage waveform applied to electrodes. The count rate as a function of time can be converted to an m/z spectrum (equivalent to a mass spectrum for singly charged ions), provided that a calibration of m/z is available. The present computer program can perform the calibration in either or both of two ways: (1) Following a data-based approach, it can utilize the count-rate peaks and the times thereof measured when fed with air containing known organic compounds. (2) It can utilize a theoretical proportionality between the instantaneous m/z and the instantaneous value of an oscillating applied voltage. The program can also estimate the error of the calibration performed by the data-based approach. If calibrations are performed in both ways, then the results can be compared to obtain further estimates of errors.

Lee, Seungwon↗
NASA NTRS2002

Driving a quadrupole mass spectrometer via an isolating stage

Driving a quadrupole mass spectrometer includes obtaining an air core transformer with a primary and a secondary, matching the secondary to the mass spectrometer, and driving the primary based on first and second voltage levels. Driving of the primary is via an isolating stage that minimizes low level drive signal coupling.

Chutjian, Ara↗
NASA NTRS2012

Mass Spectrometers in Space!

Exploration of our solar system over several decades has benefitted greatly from the sensitive chemical analyses offered by spaceflight mass spectrometers. When dealing with an unknown environment, the broadband detection capabilities of mass analyzers have proven extremely valuable in determining the composition and thereby the basic nature of space environments, including the outer reaches of Earth s atmosphere, interplanetary space, the Moon, and the planets and their satellites. Numerous mass analyzer types, including quadrupole, monopole, sector, ion trap, and time-of-flight have been incorporated in flight instruments and delivered robotically to a variety of planetary environments. All such instruments went through a rigorous process of application-specific development, often including significant miniaturization, testing, and qualification for the space environment. Upcoming missions to Mars and opportunities for missions to Venus, Europa, Saturn, Titan, asteroids, and comets provide new challenges for flight mass spectrometers that push to state of the art in fundamental analytical technique. The Sample Analysis at Mars (SAM) investigation on the recently-launch Mars Science Laboratory (MSL) rover mission incorporates a quadrupole analyzer to support direct evolved gas as well as gas chromatograph-based analysis of martian rocks and atmosphere, seeking signs of a past or present habitable environment. A next-generation linear ion trap mass spectrometer, using both electron impact and laser ionization, is being incorporated into the Mars Organic Molecule Analyzer (MOMA) instrument, which will be flown to Mars in 2018. These and other mass spectrometers and mission concepts at various stages of development will be described.

Brinckerhoff, William B.↗
NASA NTRS2009

Autonomously Calibrating a Quadrupole Mass Spectrometer

A computer program autonomously manages the calibration of a quadrupole ion mass spectrometer intended for use in monitoring concentrations and changes in concentrations of organic chemicals in the cabin air of the International Space Station. The instrument parameters calibrated include the voltage on a channel electron multiplier, a discriminator threshold, and an ionizer current. Calibration is achieved by analyzing the mass spectrum obtained while sweeping the parameter ranges in a heuristic procedure, developed by mass spectrometer experts, that involves detection of changes in signal trends that humans can easily recognize but cannot necessarily be straightforwardly codified in an algorithm. The procedure includes calculation of signal-to-noise ratios, signal-increase rates, and background-noise-increase rates; finding signal peaks; and identifying peak patterns. The software provides for several recovery-from-error scenarios and error-handling schemes. The software detects trace amounts of contaminant gases in the mass spectrometer and notifies associated command- and-data-handling software to schedule a cleaning. Furthermore, the software autonomously analyzes the mass spectrum to determine whether the parameters of a radio-frequency ramp waveform are set properly so that the peaks of the mass spectrum are at expected locations.

Lee, Seungwon↗
NASA NTRS1986

Solar wind control of the Geomagnetic Mass Spectrometer

Evidence from Dynamics Explorer retarding-ion mass-spectrometer data collected between 1981 and 1983 for the mass dispersion of ionospheric plasma in the polar cap, known as the Geomagnetic Mass Spectrometer, is discussed, and implications of this new source of ionospheric ions for the magnetosphere are considered. A localized source of energization of ionspheric H(+), He(+), O(+) and N(+) ions in the polar cusp yields a source of upswelling plasma that is transported into the magnetosphere, and equal heating of the ion species results in field-aligned flow velocities which are inversely proportional to the square root of the ion mass. The present phenomenon is produced by the resulting velocity filter effect of solar-driven ExB ion convection. The influence of solar wind conditions on the outflow via the polar cap ExB convection pattern is also discussed.

Waite, J. H., Jr.↗
NASA NTRS1982

Instrument manual for the retarding ion mass spectrometer on Dynamics Explorer-1

The retarding ion mass spectrometer (RIMS) for Dynamics Explorer-1 is an instrument designed to measure the details of the thermal plasma distribution. It combines the ion temperature determining capability of the retarding potential analyzer with the compositional capabilities of the mass spectrometer and adds multiple sensor heads to sample all directions relative to the spacecraft ram direction. This manual provides a functional description of the RIMS, the instrument calibration, and a description of the commands which can be stored in the instrument logic to control its operation.

Fields, S. A.↗
NASA NTRSDate not supplied

Dragonfly mass spectrometer titan environment optical damage testing

The Dragonfly Mass Spectrometer (DraMS) being developed at NASA’s Goddard Space Flight Center will use a solid-state 266-nm pulsed Nd:YAG laser perform compositional analysis on the surface of Titan. Due to the high fluence of the focused pulse energy on the laser’s beam steering unit (BSU) and the mass spectrometer window, the damage threshold of these optics in a Titan atmosphere needed to be characterized. This paper details the test setup and the successful demonstration of testing the highest fluence optics for the expected mission duration of 2 million laser pulses in a Titan-relevant atmosphere.

Matt Mullin↗
NASA NTRS1989

Hot oxygen geocorona as inferred from neutral exospheric models and mass spectrometer measurements

Summer hot oxygen densities of 10,000-30,000 per cubic cm at 1100 km (or 100,000-300,000 at 550 km) for low to moderate solar activities are inferred from differences between satellite drag and mass-spectrometer-based models. At high solar activities, densities at 925 km from 100,000-400,000 (or 5 x 10 to the 5th to 2 x 10 to the 6th at 550 km) are inferred from a limited number of Dynamics Explorer mass spectrometer measurements. The densities are of the same order as those reported previously from ground-based optical measurements. It is pointed out that a detailed theoretical calculation of the hot oxygen distribution consistent with the cool populations in mass-spectrometer-based models would provide the basis for a more complete interpretation of mass spectrometer data and of high-altitude differences between drag-based and mass-spectrometer-based models. It is concluded that hot oxygen could be providing the major contribution to satellite drag in the summer lower exosphere during low solar activity.

Hedin, A. E.↗
NASA NTRS1979

Study and evaluation of impulse mass spectrometers for ion analysis in the D and E regions of the ionosphere

Theoretical and numerical analyses were made of planar, cylindrical and spherical electrode time-of-flight mass spectrometers in order to optimize their operating conditions. A numerical analysis of potential barrier gating in time-of-flight spectrometers was also made. The results were used in the design of several small mass spectrometers. These were constructed and tested in a laboratory space simulator. Detailed experimental studies of a miniature cylindrical electrode time of flight mass spectrometer and of a miniature hemispherical electrode time of flight mass spectrometer were made. The extremely high sensitivity of these instruments and their ability to operate at D region pressures with an open source make them ideal instruments for D region ion composition measurements.

Kendall, B. R.↗
NASA NTRS2008

Simulation of a Miniature, Low-Power Time-of-Flight Mass Spectrometer for In Situ Analysis of Planetary Atmospheres

We are implementing nano- and micro-technologies to develop a miniaturized electron impact ionization mass spectrometer for planetary science. Microfabrication technology is used to fabricate the ion and electron optics, and a carbon nanotube (CNT) cathode is used to generate the ionizing electron beam. Future NASA planetary science missions demand miniaturized, low power mass spectrometers that exhibit high resolution and sensitivity to search for evidence of past and present habitability on the surface and in the atmosphere of priority targets such as Mars, Titan, Enceladus, Venus, Europa, and short-period comets. Toward this objective, we are developing a miniature, high resolution reflectron time-of-flight mass spectrometer (Mini TOF-MS) that features a low-power CNT field emission electron impact ionization source and microfabricated ion optics and reflectron mass analyzer in a parallel-plate geometry that is scalable. Charged particle electrodynamic modeling (SIMION 8.0.4) is employed to guide the iterative design of electron and ion optic components and to characterize the overall performance of the Mini TOF-MS device via simulation. Miniature (less than 1000 cubic centimeters) TOF-MS designs (ion source, mass analyzer, detector only) demonstrate simulated mass resolutions greater than 600 at sensitivity levels on the order of 10(exp -3) cps/molecule N2/cc while consuming 1.3 W of power and are comparable to current spaceflight mass spectrometers. Higher performance designs have also been simulated and indicate mass resolutions approximately 1000, though at the expense of sensitivity and instrument volume.

King, Todd T.↗
NASA NTRS1972

Lunar orbital mass spectrometer experiment

A lunar orbital mass spectrometer carried by the Apollo 16 command and service module was used to detect the lunar atmosphere and to search for active lunar volcanism. The experimental procedure and results are described.

Hodges, R. R.↗
NASA NTRS1984

Double focusing ion mass spectrometer of cylindrical symmetry

A mass spectrometer consisting of an electric sector followed by a magnetic sector is described. The geometry is a cylindrically symmetric generalization of the Mattauch-Herzog spectrometer (1934). With its large annular entrance aperture and a position-sensitive detector, the instrument provides a large geometric factor and 100-percent duty factor, making it appropriate for spacecraft experiments.

Coplan, M. A.↗