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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Advanced Oxide Material Systems For 1650 C Thermal/Environmental Barrier Coating Applications

Advanced thermal/environmental barrier coatings (T/EBCs) are being developed for low emission SiC/SiC ceramic matrix composite (CMC) combustor and vane applications to extend the CMC liner and vane temperature capability to 1650 C (3000 F) in oxidizing and water-vapor containing combustion environments. The 1650 C T/EBC system is required to have better thermal stability, lower thermal conductivity, and improved sintering and thermal stress resistance than current coating systems. In this paper, the thermal conductivity, water vapor stability and cyclic durability of selected candidate zirconia-/hafnia-, pyrochlore- and magnetoplumbite-based T/EBC materials are evaluated. The test results have been used to downselect the T/EBC coating materials, and help demonstrate advanced 1650OC coatings feasibility with long-term cyclic durability.

Zhu, Dongming↗
NASA NTRS1978

Isotopic anomalies in solar system material - What can they tell us

Three relatively recently discovered anomalies are considered. The goal of isotopic research is to understand what phenomena are responsible for the observed isotopic anomalies, and thereby to determine the initial solar system isotopic composition. Until recently there has been no measured isotopic ratios which could not be understood in the context of reasonable physical or chemical processes acting to alter a uniform initial solar isotopic composition. This situation changed in 1969 with the discovery by Black and Pepin of an unusual neon isotopic composition in certain carbonaceous meteories. This unusual composition was later designated as Neon E. An unusual or anomalous oxygen isotopic composition was discovered by Clayton et al. (1973). A magnesium isotopic anomaly was discovered by Gray and Compston (1974), and Lee and Papanastassiou (1974). The three isotopic anomalies are discussed, emphasizing particularly the experimental evidence, possible causes for the observed isotopic composition and finally, possible implications of these anomalies with regard to models of solar system formation and evolution.

Black, D. C.↗
NASA NTRS1985

Outer solar system materials - Ices and color systematics

Our program of VJHK colorimetric observations and spectrophotometry is reviewed and updated. Attention is given to the probable connections between VJHK colors and the ratios of bright ices and dark soils on many outer solar system small bodies' surfaces. VJHK color systematics may clarify ice/soil behaviors in bodies too faint for high resolution spectra. Comets appear colored by soils most closely resembling D-class Trojan asteroid soils. Our recent model of comet surface properties, involving weakly-bonded ice/soil regoliths, helps explain comet eruptive phenomena. The work suggests the importance of considering ices in the context of their intimate mixture with non-volatile soils.

Hartmann, W. K.↗
NASA NTRS2004

Advanced Oxide Material Systems for 1650 C Thermal/Environmental Barrier Coating Applications

Advanced thermal and environmental barrier coatings (TEBCs) are being developed for low-emission SiC/SiC ceramic matrix composite (CMC) combustor and vane applications to extend the CMC liner and vane temperature capability to 1650 C (3000 F) in oxidizing and water-vapor-containing combustion environments. The advanced 1650 C TEBC system is required to have a better high-temperature stability, lower thermal conductivity, and more resistance to sintering and thermal stress than current coating systems under engine high-heat-flux and severe thermal cycling conditions. In this report, the thermal conductivity and water vapor stability of selected candidate hafnia-, pyrochlore- and magnetoplumbite-based TEBC materials are evaluated. The effects of dopants on the materials properties are also discussed. The test results have been used to downselect the TEBC materials and help demonstrate the feasibility of advanced 1650 C coatings with long-term thermal cycling durability.

Zhu, Dong-Ming↗
NASA NTRS1990

Design and development of a space station hazardous material system for assessing chemical compatibility

As the Space Station nears reality in funding support from Congress, NASA plans to perform over a hundred different missions in the coming decade. Incrementally deployed, the Space Station will evolve into modules linked to an integral structure. Each module will have characteristic functions, such as logistics, habitation, and materials processing. Because the Space Station is to be user friendly for experimenters, NASA is anticipating that a variety of different chemicals will be taken on-board. Accidental release of these potentially toxic chemicals and their chemical compatibility is the focus of this discourse. The Microgravity Manufacturing Processing Facility (MMPF) will contain the various facilities within the U.S. Laboratory (USL). Each facility will have a characteristic purpose, such as alloy solidification or vapor crystal growth. By examining the proposed experiments for each facility, identifying the chemical constituents, their physical state and/or changes, byproducts and effluents, those payloads can be identified which may contain toxic, explosive, or reactive compounds that require processing or containment in mission peculiar waste management systems. Synergistic reactions from mixed effluent streams is of major concern. Each experiment will have it own data file, complete with schematic, chemical listing, physical data, etc. Chemical compatibility information from various databases will provide assistance in the analysis of alternate disposal techniques (pretreatment, separate storage, etc.). Along with data from the Risk Analysis of the Proposed USL Waste Management System, accidental release of potentially toxic and catastrophic chemicals would be eliminated or reduced.

Congo, Richard T.↗
NASA NTRS1991

Advanced fiber/matrix material systems

Work completed in Phase 1 of the NASA Advanced Composite Technology program is discussed. Two towpreg forms (commingled yarns and fused powder towpregs) are being characterized under the program. These towpregs will be used to evaluate textile fabrication technologies for advanced aircraft composite structures. The unique characteristic of both of these material forms is that both fiber and matrix resin are handled in a single operation such as weaving, braiding, or fiber placement. The evaluation of both commingled and fused powder towpreg is described. Various polymer materials are considered for both subsonic and supersonic applications. Polymers initially being evaluated include thermoplastic polyimides such as Larc-TPI and New-TPI, thermoplastics such as PEEK and PEKEKK as well as some toughened crosslinked polyimides. Preliminary mechanical properties as well as tow handling are evaluated.

Hartness, J. Timothy↗
NASA NTRS1992

Application of advanced material systems to composite frame elements

A three phase program has been conducted to investigate DuPont's Long Discontinuous Fiber (LDF) composites. Additional tests were conducted to compare LDF composites against toughened thermosets and a baseline thermoset system. Results have shown that the LDF AS4/PEKK offers improved interlaminar (flange bending) strength with little reduction in mechanical properties due to the discontinuous nature of the fibers. In the third phase, a series of AS4/PEKK LDF C-section curved frames (representing a typical rotorcraft light frame) were designed, manufactured and tested. Specimen reconsolidation after 'stretch forming' and frame thickness were found to be key factors in this light frame's performance. A finite element model was constructed to correlate frame test results with expected strain levels determined from material property tests. Adequately reconsolidated frames performed well and failed at strain levels at or above baseline thermoset material test strains. Finally a cost study was conducted which has shown that the use of LDF for this frame would result in a significant cost savings, for moderate to large lot sizes compared with the hand lay-up of a thermoset frame.

Llorente, Steven↗
NASA NTRS1977

UH cosmic rays and solar system material - The elements just beyond iron

The nucleosynthesis of cosmic-ray elements between the iron peak and the rare-earth region is examined, and compositional changes introduced by propagation in interstellar space are calculated. Theories on the origin of elements heavier than iron are reviewed, a supernova model of explosive nucleosynthesis is adopted for the ultraheavy (UH) cosmic rays, and computational results for different source distributions are compared with experimental data. It is shown that both the cosmic-ray data and the nucleosynthesis calculations are not yet of sufficient precision to pinpoint the processes occurring in cosmic-ray source regions, that the available data do provide boundary conditions for cosmic-ray nucleosynthesis, and that these limits may apply to the origin of elements in the solar system. Specifically, it is concluded that solar-system abundances appear to be consistent with a superposition of the massive-star core-helium-burning s-process plus explosive-carbon-burning synthesis for the elements from Cu to As and are explained adequately by the s- and r-processes for heavier elements.

Wefel, J. P.↗
DOE OSTI2020

Additive Manufacturing of Energy Harvesting Material System for Active Wireless MEMS Sensors

Combustion systems make up a large sum of the world’s yearly energy production despite advances in renewable energy sources. Precise control of pressure and temperature in combustion chambers allows for lower carbon emissions, and overall higher efficiency. Wireless temperature and pressure sensors are critical for the operation of combustion chambers. Energy harvesters have emerged as a viable way to power wireless sensors when heat and mechanical energy are available. Lithium niobate (LNB), barium titanate (BTO), and lead zirconate titanate (PZT) pyroelectric ceramics were studied and fabricated through additive manufacturing (AM) for use as energy harvesting structures in combustion environments. The electric power generation potential of LNB and PZT ceramics was studied by varying the temperature from 50 to 60 °C and by introducing cyclic compression loads of 2000 N amplitude. It was found that thermal energy conversion had the highest output of 500 nW and that combined thermal and mechanical conversion did not increase the harvesting potential because of the competing contributions of both effects. Powder bed and slurry extrusion AM methods were used to fabricate BTO and PZT ceramic structures. Optimization of the powder-based binder jetting method produced BTO ceramics with a relative density of 36.77% a piezoelectric coefficient of 153 pC/N. The density of the ceramics increased up to 56% when increasing the saturation of binder in the powder to because of liquid phase sintering. Finally, PZT structures were manufactured through AM and fin features were added to the design to enhance the heat transfer along the material. The harvested power density of the flat samples was 3.643 μW/cm 3 and of the finned samples was 3.034 μW/cm3. This research paves the ways for the development of self-powered wireless sensors in critical areas of operation such as combustion.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2023

Enhanced electrolysis performance through hierarchical nanoparticle formation in the BaCo 0.4 Fe 0.4 Zr 0.1 Y 0.1 O 3-δ cathode materials system

This study demonstrated that the activity of a triple conducting BaCo 0.4 Fe 0.4 Zr 0.1 Y 0.1 O 3-δ (BCFZY0.1) air cathode was improved by in situ formation BCFZY0.1 nanoparticles (NPs). The NPs, directly formed from the reaction of BCFZY0.1 with H 2 O and CO 2 from air under electrolysis measurements conditions, were uniformly distributed in a porous BCFZY0.1 framework. At 600 °C, the current density increased and reached a plateau of 1.12 A/cm 2 with the hierarchical BCFZY0.1 cathode under electrolysis conditions within 400 h operation. Distribution of Relaxation Time (DRT) measurements found that the polarization resistance decreased over time as NPs were formed. Furthermore, SEM and TEM results confirm the nanoparticle formation, and the chemical and structural features were assigned to a BCFZY0.1 phase.

08 HYDROGEN↗