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At least 91 records · Page 5

Weathered stony meteorites from Victoria Land, Antarctica, as possible guides to rock weathering on Mars

Parallel studies of Martian geomorphic features and their analogs on Earth continue to be fruitful in deciphering the geologic history of Mars. In the context of rock weathering, the Earth-analog approach is admirably served by the study of meteorites recovered from ice sheets in Antarctica. The weathering environment of Victoria Land possesses several Mars-like attributes. Four of the five Antarctic meteorites being studied contain rust and EETA79005 further possesses a conspicuous, dark, weathering rind on one side. Secondary minerals (rust and salts) occur both on the surfaces and interiors of some of the samples and textural evidence indicates that such secondary mineralization contributed to physical weathering (by salt riving) of the rocks. Several different rust morphologies occur and emphasis is being placed on identifying the phase compositions of the various rust occurrances. A thorough understanding of terrestrial weathering features of the meteorites is a prerequisite for identifying possible Martian weathering features (if such features exist) that might be postulated to occur in some meteorites.

Gooding, J. L.↗

Search for Sugars and Related Compounds in Residues Produced from the UV Irradiation of Astrophysical Ice Analogs

A large variety and number of organic compounds of prebiotic interest have been detected in meteorites. Among them, one sugar (dihydroxyacetone) as well as several sugar acids and sugar alcohols have been detected in Murchison and Murray [1]. Their presence in meteorites, along with amino acids, amphiphiles, and nucleobases [2-6], strongly suggests that molecules essential to life can form abiotically under astrophysical conditions. This hypothesis is supported by laboratory studies on the formation of complex organic molecules from the ultraviolet (UV) irradiation of astrophysical ice analogs (H2O, CO, CO2, CH3OH, CH4, NH3, etc.). These studies show that the organic residues recovered at room temperature after the UV irradiation of such ice mixtures contain amino acids [7-9], amphiphiles [4], nucleobases [10-13], and other organic complex organic compounds [14-16]. However, no systematic search for the presence of sugars, sugar acids, and sugar alcohols in laboratory residues have been reported to date, despite the fact that those compounds are involved in a large number of biological processes. Only a limited number of small (less than or equal to 3 carbon atoms) sugar derivatives such as glycerol and glyceric acid have been detected in residues [14-16]. In this work, we show results obtained from the systematic search for sugars and sugar-related compounds in organic residues produced from the UV irradiation of simple CH3OH and H2O+CH3OH ices, and more astrophysically relevant ice mixtures containing H2O, CH3OH, CO, and NH3. The results are compared with measurements of sugars and related compounds in primitive meteorites.

Murchison and Murray↗

Characterizing water/rock interaction in simulated comet nuclei via calorimetry: Tool for in-situ science, laboratory analysis, and sample preservation

Although results from the Giotto and Vega spacecraft flybys of comet P/Halley indicate a complex chemistry for both the ices and dust in the nucleus, carbonaceous chondrite meteorites are still regarded as useful analogs for the rocky components. Carbonaceous chondrites mixed with water enable simulation of water/rock interactions which may occur in cometary nuclei. Three general types of interactions can be expected between water and minerals at sub-freezing temperatures: heterogeneous nucleation of ice by insoluble minerals; adsorption of water vapor by hygroscopic phases; and freezing and melting point depression of liquid water sustained by soluble minerals. Two series of experiments were performed in a differential scanning calorimeter (DSC) with homogenized powders of the following whole-rock meteorites and comparison samples: Allende (CV3), Murchison (CM2), Orgueil (CI), Holbrook (L6), and Pasamonte (eucrite) meteorites as well as on peridotite (PCC-1, USGS), saponite (Sap-Ca-1, CMS), montmorillonite (STx-1, CMS), and serpentine (Franciscan Formation, California). Results are briefly discussed.

Allton, Judith H.↗

Tracing Oxygen Fugacity in Asteroids and Meteorites Through Olivine Composition

Olivine absorptions are known to dominate telescopic spectra of several asteroids. Among the meteorite collection, three groups (excluding Martian meteorites), the pallasites, brachinites, and R group chondrites are plausible analogs to olivine-rich asteroids in that they are dominated by olivine. These meteorite groups have distinct petrologic origins. The primitive achondrite brachinites (which include both depleted and undeleted subgroups) are products of relatively minor differentiation and evolved in oxidizing environments. R chondrites are also thought to have formed in high oxygen states, but are closely related to ordinary chondrites (yet with their own distinct compositions and oxygen isotopic signatures). In contrast, pallasites, widely thought to be mantle components from much more evolved bodies, formed in more reducing environments. Petrologic indicators that are identifiable in spectral data must be used in order to infer the petrologic history of asteroids from surveys of their actual population. As discussed below, olivine composition (e.g. Fa#) can provide key constraints in exploring the origin and significance of olivine dominated asteroids.

Sunshine, J. M.↗

Phyllosilicate absorption features in main-belt and outer-belt asteroid reflectance spectra

Absorption features having depths up to 5 percent are identified in high-quality, high-resolution reflectance spectra of 16 dark asteroids in the main belt and in the Cybele and Hilda groups. Analogs among the CM2 carbonaceous chondrite meteorites exist for some of these asteroids, suggesting that these absorptions are due to iron oxides in phyllosilicates formed on the asteroidal surfaces by aqueous alteration processes. Spectra of ten additional asteroids, located beyond the outer edge of the main belt, show no discernible absorption features, suggesting that aqueous alteration did not always operate at these heliocentric distances.

Vilas, Faith↗

Determining the composition of olivine on asteroidal surfaces

Olivine was remotely identified as a major component on many S- and A-type asteroids based on qualitative analyses of broad absorption features near 1.0 micron in their telescopic reflectance spectra. Laboratory studies showed that this diagnostic olivine absorption feature is composed of three individual absorption bands resulting from electronic transitions of Fe(+2) in distorted M1 and M2 sites. Both the overall absorption feature and each of the individual absorption bands are also known to vary systematically as a function of olivine composition. Thus, it should be possible to remotely determine the composition of olivine present on the surfaces of the various olivine-rich asteroids. However, extrapolation of laboratory studies to compositional interpretation of asteroid spectra is complicated by several factors: observational noise; lower spectral resolution; compositional heterogeneities (including the presence of other phases such as pyroxenes and/or metal); and the effects of alteration processes. In order to address such complex problems, a quantitative approach to spectral analysis, the modified Gaussian model (MGM) was developed by Sunshine et al., which deconvolves spectra into their constituent absorption bands. The MGM, a refinement of the Gaussian model, more accurately adheres to the physical processes involved in electronic transition absorptions. Under the MGM, each spectrum is modeled in log reflectance and energy as a sum of absorption bands superimposed onto a baseline or continuum. Each absorption band is described by three model parameters (center, width, and strength) which can be interpreted and used to infer composition. One of the strengths of the MGM is that it allows compositional information to be extracted directly from measured spectra and is therefore complementary to other approaches to modeling asteroid spectra which require the use of meteorites and/or terrestrial samples as spectral analogs. A quantitative understanding of the properties of olivine absorptions was established by using the MGM to analyze a laboratory suite of spectra spanning a full range of olivine compositions.

Sunshine, Jessica M.↗

Lunar and Planetary Science XXXV

The 35th Lunar and Planetary Science Conference covered topics on Mars, planetary origins, planetary analog studies, education,chondrite studies, and meteorite composition. Over 1000 reports were presented at the conference in over 100 sessions. Each session, and presentations,was processed separately for the database.

Source record↗

More shock recovery experiments on mesosiderite analogs

Mesosiderites, a small but unique group of stony-iron meteorites with affinities to howardites, eucrites, and pallasites, remain enigmatic in terms of their petrogenesis. They are composed of approximately equal weight proportions of Fe-Ni metal plus troilite and gabbroic, basaltic, and orthopyroxenitic materials. The metal and silicates, which display variable grain sizes and shapes, are delicately intermingled, forming irregular grain boundaries that have been attributed to a wide range of origins from subsolidus metamorphism to supersolidus igneous processes. Perhaps the most relevant question regarding the petrogenesis of mesosiderites is: what is the source and duration of heating that could produce the unequilibrated textures and chemistry of these meteorites? A leading candidate appears to be impacts of metallic core fragments with a differentiated asteroidal surface. This provides not only a suitable source of heat, but also the metal component uniquely required by mesosiderites. A series of shock recovery experiments on mesosiderite analogs has been continued. Textural and chemical similarities have been found that support an impact-derived origin for these unusual meteorites.

Rowan, L. R.↗

Complex Organics from Laboratory Simulated Interstellar Ices

Many of the volatiles in interstellar dense clouds exist in ices surrounding dust grains. The low temperatures of these ices (T < 50 K) preclude most chemical reactions, but photolysis can drive reactions that produce a suite of new species, many of which are complex organics. We study the UV and proton radiation processing of interstellar ice analogs to explore links between interstellar chemistry, the organics in comets and meteorites, and the origin of life on Earth. The high D/H ratios in some interstellar species, and the knowledge that many of the organics in primitive meteorites are D-enriched, suggest that such links are plausible. Once identified, these species may serve as markers of interstellar heritage of cometary dust and meteorites. Of particular interest are our findings that UV photolysis of interstellar ice analogs produce molecules of importance in current living organisms, including quinones, amphiphiles, and amino acids. Quinones are essential in vital metabolic roles such as electron transport. Studies show that quinones should be made wherever polycyclic aromatic hydrocarbons are photolyzed in interstellar ices. In the case of anthracene-containing ices, we have observed the production of 9-anthrone and 9,10 anthraquinone, both of which have been observed in the Murchison meteorite. Amphiphiles are also made when mixed molecular ices are photolyzed. These amphiphiles self-assemble into fluorescent vesicles when placed in liquid water, as do Murchison extracts. Both have the ability to trap an ionic dye. Photolysis of plausible ices can also produce alanine, serine, and glycine as well as a number of small alcohols and amines. Flash heating of the room temperature residue generated by such experiments generates mass spectral distributions similar to those of IDPs. The detection of high D/H ratios in some interstellar molecular species, and the knowledge that many of the organics, such as hydroxy and amino acids, in primitive meteorites are D-enriched provides evidence for a connection between intact organic material in the interstellar medium and in meteorites. Thus, some of the oxidized aromatics, amphiphiles, amino acids, hydroxy acids, and other compounds found in meteorites may have had an interstellar ancestry and not solely a product of parent body aqueous alteration. Such compounds should also be targeted for searches of organics in cometary dust.

Dworkin, J. P.↗

Infrared reflectance spectra of asteroids - A search for water of hydration

Infrared reflectance spectra have shown the presence of an absorption feature in the 3-4 micron region for seven C and U asteroids. By comparison with laboratory spectra of terrestrial silicates and meteorites, it is concluded that this band is probably due to water in the form of hydrated salts and silicates (clay minerals), implying that the surface material of these asteroids may be analogous to the CI and CM carbonaceous chondritic meteorites. The presence of other hydrated minerals, however, cannot be ruled out. The depths of the water bands in the spectra vary from asteroid to asteroid, though no asteroid spectrum shows a band as deep as was detected on 1 Ceres. On four other C asteroids, no water band was detected. The implications of these observations for the mineralogy of these asteroids are discussed

Lebofsky, L. A.↗

Arcjet Ablation of Stony and Iron Meteorites

A test campaign was conducted placing meteorites in the 60 MW plasma Arcjet Interaction Heating Facility at NASA Ames Research Center, with the aim to achieve flight-relevant conditions for asteroid impacts in Earth's atmosphere and to provide insight into how meteoritic materials respond to extreme entry heating environments. The test conditions at heat flux of 4000 W/m2 and 140 kPa stagnation pressure are comparable to those experienced by a 30-meter diameter asteroid moving at 20 km/s velocity at 65 km altitude in the Earth's atmosphere. Test objects were a stony type H5 ordinary chondrite (Tamdakht) and an iron type IAB-MG meteorite (Campo Del Cielo), and included the terrestrial analogs Dense Flood Basalt and Fused Silica. All samples were exposed for only a few seconds in the plasma stream. Significant melt flow and vaporization was observed for both the stony and iron meteorites during exposure. Mass loss from spallation of fragments was also observed. Vapor emitted atomic lines from alkali metals and iron, but did not emit the expected MgO molecular band emissions. The meteoritic melts flowed more rapidly, indicating lower viscosity, than those of Fused Silica. The surface recession was mapped. The effective heat of ablation derived from this showed that ablation under these conditions occurred in the melt-dominated regime. Ablation parameters have an effect on ground damage estimates. A bias in ablation parameters towards the melt-dominated regime would imply that impacting asteroids survive to lower altitude, and therefore could possibly have airbursts with a larger ground damage footprint.

Asteroid↗

Arcjet Ablation of Stony and Iron Meteorites

A test campaign was conducted placing meteorites in the 60 MW plasma Arcjet Interaction Heating Facility at NASA Ames Research Center, with the aim to achieve flight-relevant conditions for asteroid impacts in Earth's atmosphere and to provide insight into how meteoritic materials respond to extreme entry heating environments. The test conditions at heat flux of 4000 W/m2 and 140 kPa stagnation pressure are comparable to those experienced by a 30-meter diameter asteroid moving at 20 km/s velocity at 65 km altitude in the Earth's atmosphere. Test objects were a stony type H5 ordinary chondrite (Tamdakht) and an iron type IAB-MG meteorite (Campo Del Cielo), and included the terrestrial analogs Dense Flood Basalt and Fused Silica. All samples were exposed for only a few seconds in the plasma stream. Significant melt flow and vaporization was observed for both the stony and iron meteorites during exposure. Mass loss from spallation of fragments was also observed. Vapor emitted atomic lines from alkali metals and iron, but did not emit the expected MgO molecular band emissions. The meteoritic melts flowed more rapidly, indicating lower viscosity, than those of Fused Silica. The surface recession was mapped. The effective heat of ablation derived from this showed that ablation under these conditions occurred in the melt-dominated regime. Ablation parameters have an effect on ground damage estimates. A bias in ablation parameters towards the melt-dominated regime would imply that impacting asteroids survive to lower altitude, and therefore could possibly have airbursts with a larger ground damage footprint.

Arcjet↗

Weathering of stony meteorites in Antarctica

Weathering produces undesirable physical, chemical, and isotopic changes that might disturb the records of cosmochemical evolution that are sought in meteorites. Meteorites are physically disintegrated by crack propagation phenomena, including ice riving and secondary mineral riving, and are probably abraded by wind that is laden with ice crystals or dust particles. Chemical weathering proceeds by oxidation, hydration, carbonation, and solution and produces a variety of secondary minerals and mineraloids. Differential weathering under freezing conditions is discussed, as well as, the mineralogy of weathering products. Furthermore, the use of Antarctic alteration of meteorites could be used as an excellent analog for weathering on Mars or on cometary bodies.

Gooding, J. L.↗

Micrometeorite pre-solar diamonds from Greenland cryoconite?

An acid-resistant residue prepared from Greenland cryoconite has been investigated to determine whether the micrometeorite component within the cryoconite contains pre-solar material analogous to that found in primitive chondritic meteorites. The residue has been analyzed for carbon content and stable isotopic comparison, by electron probe micro-analysis (EPMA) for major element chemistry and then by a combination of X-ray diffraction (XRD) and transmission electron microscopy (TEM) to elucidate the structure of any constituent mineral phases. The cryoconite sample, which was collected ca. 25 km inland of the ice margin at the latitude of Sondre Stromfjord on the west coast of Greenland, was processed following procedures used on bulk meteorite samples for the isolation of pre-solar dust components.

Yates, P. D.↗

Chemical and physical studies of type 3 chondrites 12: The metamorphic history of CV chondrites and their components

The induced thermoluminescence (TL) properties of 16 CV and CV-related chondrites, four CK chondrites and Renazzo (CR2) have been measured in order to investigate their metamorphic history. The petrographic, mineralogical and bulk compositional differences among the CV chondrites indicate that the TL sensitivity of the approximately 130 C TL peak is reflecting the abundance of ordered feldspar, especially in chondrule mesostasis, which in turn reflects parent-body metamorphism. The TL properties of 18 samples of homogenized Allende powder heated at a variety of times and temperatures, and cathodoluminescence mosaics of Axtell and Coolidge, showed results consistent with this conclusion. Five refractory inclusions from Allende, and separates from those inclusions, were also examined and yielded trends reflecting variations in mineralogy indicative of high peak temperatures (either metamorphic or igneous) and fairly rapid cooling. The CK chondrites are unique among metamorphosed chondrites in showing no detectable induced TL, which is consistent with literature data that suggests very unusual feldspar in these meteorites. Using TL sensitivity and several mineral systems and allowing for the differences in the oxidized and reduced subgroups, the CV and CV-related meteorites can be divided into petrologic types analogous to those of the ordinary and CO type 3 chondrites. Axtell, Kaba, Leoville, Bali, Arch and ALHA81003 are type 3.0-3.1, while ALH84018, Efremovka, Grosnaja, Allende and Vigarano are type 3.2-3.3 and Coolidge and Loongana 001 are type 3.8. Mokoia is probably a breccia with regions ranging in petrologic type from 3.0 to 3.2. Renazzo often plots at the end of the reduced and oxidized CV chondrite trends, even when those trends diverge, suggesting that in many respects it resembles the unmetamorphosed precursors of the CV chondrites. The low-petrographic types and low-TL peak temperatures of all samples, including the CV3.8 chondrites, indicates metamorphism in the stability field of low feldspar (i.e., less than 800 C) and a metamorphic history similar to that of the CO chondrites but unlike that of the ordinary chondrites.

Guimon, R. Kyle↗

Observations and Laboratory Data of Planetary Organics

Many efforts are underway to search for evidence of prebiotic materials in the outer solar system. Current and planned Mars missions obtain remote sensing observations that can be used to address the potential presence of prebiotic materials. Additional missions to, and continuing earth-based observations of, more distant solar system objects will also provide remote sensing observations that can be used to address the potential presence of prebiotic materials. I will present an overview of on-going observations, associated laboratory investigations of candidate materials, and theoretical modeling of observational data. In the past the room temperature reflectance spectra of many residues created from HC-bearing gases and solids have been reported. The results of an investigation of what effect temperatures more representative of outer solar system surfaces (50-140K) have on the reflectance spectra of these residues, and the associated interpretations, will be presented. The relatively organic-rich Tagish Lake Meteorite has been suggested as a spectral analog for Dtype asteroids. Using a new approach that relies upon iterative use of Hapke theory and Kraniers-Kronig analysis the optical constants of TLM were estimated. The approach and results of the analysis will be presented. Use of optical constants in scattering theories, such as the Hapke theory, provide the ability to determine quantitative estimates of the relative abundances and grain sizes of candidate surface components. This approach has been applied to interpret the reflectance spectra of several outer solar system surfaces. A summary will be provided describing the results of such modeling efforts.

Roush, Ted L.↗

Sugar Derivatives in Residues Produced from the UV Irradiation of Astrophysical Ice Analogs

A large variety of organic compounds of astrobiological and prebiotic interest have been detected in carbonaceous meteorites. These include amino acids, carboxylic acids, amphiphiles, functionalized nitrogen heterocycles such as nucleobases, functionalized polycylic aromatic hydrocarbons such as quinones, and sugar derivatives. The sugar derivatives identified in the Murchison and Murray meteorites are mainly sugar alcohols and sugar acids, and only the smallest sugar (dihydroxyacetone) has been detected. The presence of such a variety of organics in meteorites strongly suggests that molecules essential to life can form abiotically under astrophysical conditions. This hypothesis is further supported by laboratory studies in which astrophysical ice analogs (mixtures of H2O, CO, CO2, CH3OH, CH4, NH3, etc.) are subjected to ultraviolet (UV) irradiation at low temperature (<15 K) to simulate cold interstellar environments. These studies show that the organic residues recovered at room temperature after irradiation contain amino acids, amphiphiles, nucleobases, sugar derivatives, as well as other complex organic compounds. The finding of such compounds under plausible interstellar conditions is consistent with the presence of organic compounds in meteorites. Until very recently, no systematic search for the presence of sugar derivatives in laboratory residues had been carried out. The detection of ribose, the sugar constituent of RNA in all living systems, as well as other sugars, sugar alcohols, and sugar acids have been recently reported in one organic residue produced from the UV irradiation of an H2O:CH3OH:NH3 (10:3.5:1) ice mixture at 80 K. In this work, we present a detailed study of organic residues produced from the UV irradiation ice mixtures of several starting compositions (containing H2O, CH3OH, CO, CO2, and/or NH3) at <15 K for their sugar derivative content. Our results confirm the presence of all 3C‒5C sugar alcohols, several 3C‒5C sugars, and all 3C‒4C sugar acids (in decreasing order of abundances) in the residues. The higher abundances of sugar alcohols in these residues suggest a pathway in which sugar alcohols are formed first, while the formation of sugars and sugar acids require more steps. Finally, our results are compared with the detection of sugars derivatives in primitive meteorites.

Astrophysical Ice Analogs↗

Chlorine Abundances in Martian Meteorites

Chlorine measurements made in martian surface rocks by robotic spacecraft typically give Chlorine (Cl) abundances of approximately 0.1-0.8%. In contrast, Cl abundances in martian meteorites appear lower, although data is limited, and martian nakhlites were also subjected to Cl contamination by Mars surface brines. Chlorine abundances reported by one lab for whole rock (WR) samples of Shergotty, ALH77005, and EET79001 range 108-14 ppm, whereas Cl in nakhlites range 73-1900 ppm. Measurements of Cl in various martian weathering phases of nakhlites varied 0.04-4.7% and reveal significant concentration of Cl by martian brines Martian meteorites contain much lower Chlorine than those measured in martian surface rocks and give further confirmation that Cl in these surface rocks was introduced by brines and weathering. It has been argued that Cl is twice as effective as water in lowering the melting point and promoting melting at shallower martian depths, and that significant Cl in the shergottite source region would negate any need for significant water. However, this conclusion was based on experiments that utilized Cl concentrations more analogous to martian surface rocks than to shergottite meteorites, and may not be applicable to shergottites.

Bogard, D.D.↗