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NASA NTRS1990

The 3 micron spectrum of NGC 4565

Researchers spectrum of NGC 4565 is essentially featureless. The absence of the 3.0 micron feature (Tau 3.0 less than 0.05) implies that the extinction to the nucleus does not arise to a significant degree in molecular clouds. Researchers deduce Tau 3.0/A sub V less than 0.01, compared with approx. 0.022 for GC-IRS7. These results support the conclusion (McFadzean et al. 1989) that the 3.0 micron absorption in the GC-IR sources is due to the presence of ice in a (probably single) foreground molecular cloud. The 3.4 micron feature is also weak or absent in the researchers spectrum of NGC 4565 (Tau 3.4 less than or equal to 0.07), hence, Tau 3.4/A sub V less than or equal to 0.016, compared with approx. 0.008 towards GC-IRS7. The absence of the feature in NGC 4565 at the signal-to-noise level of the current observations is consistent with a probable moderate degree of extinction towards the nucleus. The observations of NGC 4565 provide a useful comparison for studies of dust in the Galaxy. Limits have been set on the strengths of the 3.0 and 3.4 micron features in NGC 4565. The absence of 3.0 micron absorption is significant, and supports the view that the feature at this wavelength in the Galactic Centre is due to water-ice absorption in a foreground molecular cloud. The non-detection of the 3.4 micron absorption is less surprising and provides indirect support for the association between this feature and the diffuse interstellar medium. The current spectrum probably represents the best that can be achieved with a single-detector instrument within reasonable integration times. It will clearly be of interest in the future to obtain spectra of higher signal-to-noise, as a positive detection of the 3.4 micron feature in an external galaxy, even at a low level, would be of considerable astrophysical significance.

Adamson, A. J.↗
NASA NTRS1989

Three-micron spectroscopy of highly reddened field stars

Broad absorption features centered at 3.45 microns and at 3.0-3.0 microns towards a number of late-type supergiants in the vicinity of the galactic center were repeatedly reported. Here, 2.0 to 2.5 and 3.0 to 4.0 micron spectra are presented for field late-type highly reddened (A sub V is approximately 17-27) stars located in different regions of the galactic plane more than 20 deg away from the galactic center direction. The observations, made with the 3.6, 2.2, and 1.0 m ESO telescopes at La Silla, Chile, consists of CVF spectra with resolution lambda/delta lambda is approximately or equal to 100 and IRSPEC spectra with resolution lambda/delta lambda is approximately or equal to 700. In the direction of the most highly reddened stars, definitive detections of the 3.45 and the 3.0 to 3.1 micron absorption features are reported. The 3.45 micron feature was attributed to absorption arising in a vibrational transition resulting from the C-H stretching in organic compounds, while the 3.0 to 3.1 micron broader feature are tentatively attributed to O-H bonds. The observations strongly support that the agent producing the 3.45 micron feature, presumably organic molecules, is an important component of the diffuse interstellar medium and is not characteristic only of the galactic center environment.

Tapia, Mauricio↗
NASA NTRS1991

Search for Vega-like nearby stars with 12 micron excess

The identification of Vega-like main-sequence stars with 10-micron excess would permit important measurements of the spatial extent of the radiating material with ground-based telescopes. In fact, 55 of the 548 nearby A, F, G, and K dwarfs with IRAS catalog magnitudes at 12 microns appear to have excess 12-micron flux. However, for only two of these stars, Beta Pic and Zeta Lep, was it possible, using small-aperture photometry at 2.2 and 10 microns, to verify that the 12-micron excess is with high likelihood associated with the star. For the remaining stars the apparent 12-micron color of the 106 A, F, G, and K stars in the observing program is only 0.02 mag. Excess flux due to a Vega-like cloud which may surround some of the sources in the observing program, like Alpha Lyrae, is thus typically not detectable at 10 microns.

Aumann, Hartmut H.↗
NASA NTRS1994

The 3.2-3.6 micron spectra of monoceros R2/IRS-3 and Elias 16

We have obtained 3.2-3.6 micron spectra, with a resolution lambda/delta-lambda approximately 750, of the protostar Mon R2/IRS-3 and of Elias 16, a background K giant behind the Taurus molecular cloud. A feature at 3,482 microns (2872/cm), with a full width at half-maximum of 0.09 microns (76/cm), is clearly seen in Mon R2/IRS-3. This feature is not detected in Elias 16. The 3.482 micron feature in Mon R2/IRS-3 is similar to a feature at 3.466-3.478 microns (2875-2885/cm) detected by Allamandola et al. in four protostars and attributed by these authors to a CH stretch in hydrocarbons dominated by sp3-bonded carbon. Neither Mon R2/IRS-3 nor Elias 16 shows absorption at 3.540 microns (2825/cm), which has been detected in two of the four protostars observed by Allamandola et al. and attributed by them to CH3OH ice. Our limit on CH3OH ice toward Elias 16 is compared to models of gas-grain chemistry in dark clouds. Our results confirm those of Allamandola et al. that at this resolution the 3.4 micron absorption due to dust in molecular clouds has very different spectral structure than that due to dust in the diffuse interstellar medium.

Sellgren, K.↗
NASA NTRS1994

The effect of grain mantles and grain shape upon the 9.7 and 18 micron silicate features

Absorption and polarization cross sections are calculated for spheroidal silicate grains in the wavelength regime 7-22 microns in order to investigate the effect of changes in grain composition upon the 9.7 micron and 18 micron bands. The addition of mantles is found to be incompatible with 9.7 micron absorption data unless the mantles are relatively thin and transparent. Comparison with polarization data for BN and AFGL 2591 suggests an additional absorbing component is present, possibly as inclusions within the silicate grains, in order to account for the relatively strong short-wavelength wing seen in the 9.7 micron band toward both objects. The high 18 micron polarization observed toward BN (R(sub 18/10) = 0.75) cannot be reproduced by the addition of a mantle or by varying the grain shape and implies silicates with a stronger 18 micron band than has been previously assumed in interstellar grain models.

O'Donnell, James E.↗
NASA NTRS1994

Detection of the overtone of the 3.3 micron emission feature in IRAS 21282+5050

The 1.6-1.8 micron spectrum of the planetary nebula, IRAS 21282+5050, a strong emitter of the unidentified interstellar bands, contains a 0.02 micron wide eimission feature centered at 1.680 micron, which is well matched by laboratory spectra of the 0-2 CH stretching mode in polycyclic aromatic hydrocarbons (PAHs). We identify the new feature as the overtone of the well-known 3.3 micron band. In view of the high excitation required for emission in this band, the identification indicates that the emission is by free molecules rather than molecular moieties in solid dust grains. Modeling of the intensity ratio of the 2-0 to 1-0 band implied that the PAHs emitting in these bands contain about 60 carbon atoms. It is inferred that the nu = 2-1 hot band of the CH stretching mode occurs at about 3.43 micron and contributes to the long-wavelength shoulder of the 3.40 micron feature. The main 3.40 micron feature probably is due to aliphatic sidegroups on PAH molecules.

Geballe, T. R.↗
NASA NTRS1995

The 11 Micron Emissions of Carbon Stars

A new classification scheme of the IRAS LRS carbon stars is presented. It comprises the separation of 718 probable carbon stars into 12 distinct self-similar spectral groupings. Continuum temperatures are assigned and range from 470 to 5000 K. Three distinct dust species are identifiable: SiC, alpha:C-H, and MgS. In addition to the narrow 11 + micron emission feature that is commonly attributed to SiC, a broad 11 + micron emission feature, that is correlated with the 8.5 and 7.7 micron features, is found and attributed to alpha:C-H. SiC and alpha:C-H band strengths are found to correlate with the temperature progression among the Classes. We find a spectral sequence of Classes that reflects the carbon star evolutionary sequence of spectral types, or alternatively developmental sequences of grain condensation in carbon-rich circumstellar shells. If decreasing temperature corresponds to increasing evolution, then decreasing temperature corresponds to increasing C/O resulting in increasing amounts of carbon rich dust, namely alpha:C-H. If decreasing the temperature corresponds to a grain condensation sequence, then heterogeneous, or induced nucleation scenarios are supported. SiC grains precede alpha:C-H and form the nuclei for the condensation of the latter material. At still lower temperatures, MgS appears to be quite prevalent. No 11.3 micron PAH features are identified in any of the 718 carbon stars. However, one of the coldest objects, IRAS 15048-5702, and a few others, displays an 11.9 micron emission feature characteristic of laboratory samples of coronene. That feature corresponds to the C-H out of plane deformation mode of aromatic hydrocarbon. This band indicates the presence of unsaturated, sp(sup 3), hydrocarbon bonds that may subsequently evolve into saturated bonds, sp(sup 2), if, and when, the star enters the planetary nebulae phase of stellar evolution. The effusion of hydrogen from the hydrocarbon grain results in the evolution in wavelength of this 11.9 micron emission feature to the 11.3 micron feature.

Goebel, J. H.↗
NASA NTRS1995

The 11 Micron Emissions of Cabon Stars

A new classification scheme of the IRAS LRS carbon stars is presented. It comprises the separation of 718 probable carbon stars into 12 distinct self-similar spectral groupings. Continuum temperatures are assigned and range from 470 to 5000 K. Three distinct dust species are identifiable: SiC, alpha:C-H, and MgS. In addition to the narrow 11 + micron emission feature that is commonly attributed to SiC, a broad 11 + micron emission feature, that is correlated with the 8.5 and 7.7 micron features, is found and attributed to alpha:C-H. SiC and alpha:C-H band strengths are found to correlate with the temperature progression among the Classes. We find a spectral sequence of Classes that reflects the carbon star evolutionary sequence of spectral types, or alternatively developmental sequences of grain condensation in carbon-rich circumstellar shells. If decreasing temperature corresponds to increasing evolution, then decreasing temperature corresponds to increasing CIO resulting in increasing amounts of carbon rich dust, namely alpha:C-H. If decreasing the temperature corresponds to a grain condensation sequence, then heterogeneous, or induced nucleation scenarios are supported. SiC grains precede alpha:C-H and form the nuclei for the condensation of the latter material. At still lower temperatures, MgS appears to be quite prevalent. No 11.3 micron PAH features are identified in any of the 718 carbon stars. However, one of the coldest objects, IRAS 15048-5702, and a few others, displays an 11.9 micron emission feature characteristic of laboratory samples of coronene. That feature corresponds to the C-H out of plane deformation mode of aromatic hydrocarbon. This band indicates the presence of unsaturated, sp(sup 3), hydrocarbon bonds that may subsequently evolve into saturated bonds, sp(sup 2), if, and when, the star enters the planetary nebulae phase of stellar evolution. The effusion of hydrogen from the hydrocarbon grain results in the evolution in wavelength of this 11.9 micron emission feature to the 11.3 micron feature.

Goebel, J. H.↗
NASA NTRS2000

Sensitivity of MODIS 2.1 micron Channel for Off-Nadir View Angles for Use in Remote Sensing of Aerosol

Remote sensing of aerosol over land, from MODIS will be based on dark targets using mid-IR channels 2.1 and 3.9 micron. This approach was developed by Kaufman et al (1997), who suggested that dark surface reflectance in the red (0.66 micron -- rho(sub 0.66)) channel is half of that at 2.2 micron (rho(sub 2.2)), and the reflectance in the blue (0.49 micron - rho(sub 0.49)) channel is a quarter of that at 2.2 micron. Using this relationship, the surface reflectance in the visible channels can be predicted within Delta.rho(sub 0.49) approximately Delat.rho(sub 0.66) approximately 0.006 from rho(sub 2.2) for rho(sub 2.2) <= 0.10. This was half the error obtained using the 3.75 micron and corresponds to an error in aerosol optical thickness of Delat.tau approximately 0.06. These results, though applicable to several biomes (e.g. forests, and brighter lower canopies), have only been tested at one view angle - the nadir (theta = 0 deg). Considering the importance of the results in remote sensing of aerosols over land surfaces from space, we are validating the relationships for off-nadir view angles using Cloud Absorption Radiometer (CAR) data. The CAR data are available for channels between 0.3 and 2.3 micron and for different surface types and conditions: forest, tundra, ocean, sea-ice, swamp, grassland and over areas covered with smoke. In this study we analyzed data collected during the Smoke, Clouds, and Radiation - Brazil (SCAR-B) experiment to validate Kaufman et al.'s (1997) results for non-nadir view angles. We will show the correlation between rho(sub 0.472), rho(sub 0.675), and rho(sub 2.2) for view angles between nadir (0 deg) and 55 deg off-nadir, and for different viewing directions in the backscatter and forward scatter directions.

Gatebe, C. K.↗
NASA NTRS2000

Spectral Anomalies in the 11 and 12 micron Region From the Mariner Mars 7 Infrared Spectrometer

Two hundred-forty infrared spectra acquired by the 1969 Mariner Mars 7 Infrared Spectrometer (IRS), spanning the wavelength region 1.8-14.4 micron (5550-690/cm), have recently been recovered and calibrated in both wavelength and intensity. An examination of these IRS spectra has revealed absorptions at 11.25 and 12.5 micron that have not previously been reported for Mars. A search of the literature and spectral data bases shows that materials that exhibit a doublet at 11.25 and 12.5 micron are rare. In this paper we examine potential causes for these features and include a detailed discussion of carbonates, goethite, CO2 ice, and water ice. CO2 ice and water ice measured in transmission do not exhibit bands that match those recorded at 11.25 and 12.5 micron for Mars, which indicates that CO2 or water ice clouds are not the source of these features. Since these bands show no clear correlation with atmospheric path length, they are most likely caused by a surface material. In the IRS database they appear to be exceptionally intense in the western part of the Hellas basin. Goethite exhibits bands that are a good spectral match, but confirming whether goethite causes the features will require additional studies of the 20-50 micron region. These studies will require laboratory measurements of weathering coatings and an examination of spectra recorded of Mars by the 1971 Mariner Mars Infrared Interferometer Spectrometer (IRIS; 5-50 micron 2000200/cm) and the 1996 Thermal Emission Spectrometer (TES; 6-50 micron 1667-200/cm).

Kirkland, Laurel E.↗
NASA NTRS2013

High-Power Single-Mode 2.65-micron InGaAsSb/AlInGaAsSb Diode Lasers

Central to the advancement of both satellite and in-situ science are improvements in continuous-wave and pulsed infrared laser systems coupled with integrated miniaturized optics and electronics, allowing for the use of powerful, single-mode light sources aboard both satellite and unmanned aerial vehicle platforms. There is a technological gap in supplying adequate laser sources to address the mid-infrared spectral window for spectroscopic characterization of important atmospheric gases. For high-power applications between 2 to 3 micron, commercial laser technologies are unsuitable because of limitations in output power. For instance, existing InP-based laser systems developed for fiber-based telecommunications cannot be extended to wavelengths longer than 2 micron. For emission wavelengths shorter than 3 micron, intersubband devices, such as infrared quantum cascade lasers, become inefficient due to band-offset limitations. To date, successfully demonstrated singlemode GaSb-based laser diodes emitting between 2 and 3 micron have employed lossy metal Bragg gratings for distributed- feedback coupling, which limits output power due to optical absorption. By optimizing both the quantum well design and the grating fabrication process, index-coupled distributed-feedback 2.65-micron lasers capable of emitting in excess of 25 mW at room temperature have been demonstrated. Specifically, lasers at 3,777/cm (2.65 micron) have been realized to interact with strong absorption lines of HDO and other isotopologues of H2O. With minor modifications of the optical cavity and quantum well designs, lasers can be fabricated at any wavelength within the 2-to-3-micron spectral window with similar performance. At the time of this reporting, lasers with this output power and wavelength accuracy are not commercially available. Monolithic ridge-waveguide GaSb lasers were fabricated that utilize secondorder lateral Bragg gratings to generate single-mode emission from InGaAsSb/ AlInGaAsSb multi-quantum well structures. The device fabrication utilizes etched index-coupled gratings in the top AlGaAsSb cladding of the laser chip along the ridge waveguide, whereas commercial lasers that emit close to this wavelength include loss-coupled metal gratings that limit the output power of the laser. Semiconductor-laser-based spectrometers can be used to replace gas sensors currently used in industry and government. With the availability of high-power laser sources at mid-infrared wavelengths, sensors can target strong fundamental gas absorption lines to maximize instrument sensitivity.

Frez, Clifford F.↗
NASA NTRS1974

Bidirectional reflectance measurement of zinc oxide in 0.25 to 2.5 microns spectrum

An experimental apparatus was designed and used to measure the bidirectional reflectance of zinc oxide in the spectrum 0.25 to 2.5 microns. The nonspecular reflectance is essentially Lambert for wavelengths above 0.40 microns with the most deviation occuring for large source zenith angles. Below 0.400 microns the nonspecular reflectance is greater than Lambert in all directions and is greatest in the forward and backscatter directions. The ratio of the specular component to the nonspecular component at a zenith of 0 degrees was found to increase with source zenith and wavelength for wavelengths above 0.400 microns. Below 0.400 microns this ratio increases as wavelengths decrease. The variation of bidirectional reflectance with wavelength was found to have the characteristics absorption for Zn0 for wavelength below 0.400 microns.

Scott, R. L., Jr.↗
NASA NTRS1976

16-25 micron spectroscopy of the Trapezium and BN-KL source in Orion

Spectrophotometric observations from 16 to 25 microns of the Trapezium and the Becklin-Neugebauer-Kleinmann-Low (BN-KL) object in Orion are reported. These observations were obtained with a liquid-helium-cooled grating spectrometer. The observations of the Trapezium show a relatively flat spectrum between 16 and 25 microns, which is consistent with a 20-micron emission peak similar to that previously found at 10 microns. The BN-KL source has a smooth spectrum over the same range, showing little absorption such as characterizes the 10-micron spectrum of this source. This lack of a deep 20-micron absorption is attributed to complex radiative-transfer processes within the molecular cloud.

Forrest, W. J.↗
NASA NTRS1978

Infrared observations of the galactic center. III - 2.2 micron spectroscopy

Observations of the B-gamma line at 2.17 microns are presented for the central few parsecs of the galactic-center region. The surface-brightness distribution of the line with 3.3- and 6.6-arcsec resolution has been sampled in 25 locations. The results show that the ionized gas is concentrated within the central parsec of the galactic-center region; the fine-scale structure seen at 10 microns does not appear to be present in the ionized gas. For the central parsec (20 arcsec) the equivalent width of the B-gamma line is, within large uncertainties, independent of the 2-micron continuum flux; for radial distances of the order of 30 arcsec the line equivalent width drops significantly. A comparison of the B-gamma line strength with radio observations shows that the 2.2-micron extinction is consistent with the 2.7 mag determined from the reddening of late-type stars. Observations of the CO band at 2.3 microns in the central 30 arcsec are also presented; they strengthen the interpretation that the 2-micron flux arises from late-type giant stars.

Neugebauer, G.↗
NASA NTRS1978

Venus - The 17- to 38-micron spectrum

A far-IR emission spectrum of Venus covering the wavelength range from 17 to 38 microns is examined which was obtained on five nights at an altitude of 14 km with the 30-cm telescope of the NASA Lear Jet. The spectrum is found to be characterized by an overall continuum level with noticeable absorption shortward of 20 microns and longward of 30 microns as compared with a 245-K blackbody. The continuum level is taken as implying a continuous source of opacity in the Venusian atmosphere over the entire range from 17 to 38 microns with increased opacity shortward of 20 microns and longward of 30 microns. It is shown that a haze of sulfuric acid droplets can provide the necessary opacity and explain the observed depressions. A pressure level of roughly 200 mb is deduced for this spectrum.

Reed, R. A.↗
NASA NTRS1978

Observations of the 51.8 micron forbidden O III emission line in Orion

This letter reports observations of the 51.8-micron fine-structure transition p2: 3P(2) - 3P(1) for doubly ionized oxygen. The observed line strength in the Orion Nebula is (5 + or - 3) by 10 to the -15th power W/sq cm, in good agreement with the theoretical predictions of Simpson (1975). The observations are also consistent with the predicted line position, 51.8 microns. The line lies close to an atmospheric water-vapor feature at 51.7 microns but is sufficiently distant so that corrections for this feature are straightforward. Observations of the 51.8-micron forbidden O III line are particularly important, since the previously discovered 88-micron line from the same ion also is strong. This pair of lines should therefore yield new data about densities in observed H II regions; or else, if density data already are available from radio or other observations, the lines can be used to determine the differential dust absorption between 52 and 88 microns in front of heavily obscured regions.

Melnick, G.↗
NASA NTRS1979

The 4 to 8 micron spectrum of the galactic center

Observations of the complex Sgr A W(N) with a 28-arcsec beam and 1.5% spectral resolution are reported. Neither unidentified absorption features at 6.0 and 6.8 microns nor emission features at 6.2 and 7.7 microns were detected. The absence of the absorption features demonstrates that they are not characteristic of general interstellar extinction. The absence of emission features suggests that there is considerable distance between the ionized gas and the molecular clouds. The absence of 6.2- and 7.7-micron emission features also suggests that a feature previously seen at 3.3-3.4 microns is an absorption at 3.4 microns, and this absorption is apparently characteristic of interstellar extinction. The strength of the forbidden Ar II emission indicates an overabundance of argon. CO absorption seen at 4.67 microns indicates that saturation effects are not large, and there is evidently a large velocity dispersion in the line of sight to the infrared sources.

Willner, S. P.↗
NASA NTRS1979

Absolute spectral energy distribution of quasi-stellar objects from 0.3 to 10 microns

Energy distributions of 24 quasrs have been measured from 0.3 to 10 microns. In addition, optical emission-line strengths have been obtained for 35 quasars. The sample includes quasars discovered from both radio and optical surveys. Over the observed range of wavelengths the energy distributions are roughly characterized by a power law of slope -1, but there are vast differences in the shapes of individual spectra. In the rest frame the average slope between 1 and 3 microns is significantly steeper than the average slope between 0.3 and 1 micron; the power emitted at 0.3 and 3 microns is significantly greater than that emitted around 1 micron. On the basis of arguments of variability and the shape of the energy distribution between optical and radio wavelengths, it is concluded that the bulk of the radiation in the observed range results from nonthermal processes. Some contribution from thermal emission from dust cannot be ruled out and may explain the break in the spectra at 1 micron seen in many quasars.

Neugebauer, G.↗