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25 Years of Contamination Control on the James Webb Space Telescope

The James Webb Space Telescope (JWST) has actively been in process since 1996, and at last, on Christmas Day 2021, it launched. This launch was the fulfillment of an astounding level of work performed by thousands of people across the globe in dozens of disciplines. From the start, effective contamination control (CC) was considered essential for the JWST mission due to the large, exposed optics and tight sensitivity required to measure first light and faint signals at the dawn of the universe. This presentation will present the JWST mission and requirements overview, including mission requirements that led to optimizing performance for collecting light in the Near Infrared (NIR, 0.6μm) – Mid Infrared (MIR, 29μm) range. Molecular films absorb in the IR bands and can alter thermal emissivity, resulting in increased noise at the longer wavelengths (MIRI). Particles increase light scatter and background noise levels at the shorter wavelengths (NIRSpec, NIRCam and FGS). The passively cooled design of JWST led to an open architecture for the optical telescope element (OTE), presenting the challenge of maintaining cleanliness throughout assembly, integration, and test in a multitude of environments for over 2 decades. The presentation will describe CC for the mission starting with the first architecture in 1996, then introducing the specific areas of contamination control developed and advanced to keep JWST clean at an unsurpassed level of cleanliness.

Contamination Control↗
NASA NTRS1986

The molecular content of interacting and isolated galaxies The effect of environment on the efficiency of star formation

Molecular gas observations of merging/interacting and isolated galaxies are presented in order to study the relationship between environment and the efficiency of star formation. The two galaxy samples differ primarily in their IR properties and are quite similar in their molecular gas contents. The ratios of IR luminosity to H2 mass have a mean value of 78 and 12 solar luminosity/solar mass for interacting and isolated galaxies, respectively. The highest star formation efficiencies (SFEs) appear to occur in the merging and interacting pairs. The SFE in merging/interacting galaxies is greater than that found in the spiral arms of M51 and may be roughly proportional to the rate of cloud-cloud collisions in the interacting systems.

Young, Judith S.↗
NASA NTRS1987

Mass outflows associated with young stellar objects

Properties of optical and molecular outflows associated with young stellar objects are discussed with emphasis placed on new results concerning outflow energetics, collimating structures, and the relationship between the outflow properties and the magnetic field geometry characterizing the host molecular clouds. Particular consideration is given to the IRAS observations of YSO mass outflows, which reveal extended far-IR emission associated with high-velocity molecular gas and in which a number of disk-like structures associated with YSO outflow sources were resolved. The disk axes appeared to lie along the direction of molecular outflows or stellar jets. The mass outflows showed a remarkable tendency to align along the direction of the magnetic fields which thread their host molecular clouds, suggesting that the cloud magnetic field must play an important role in determining the flattening (and perhaps the rotation) of protostellar structures.

Strom, Stephen E.↗
NASA NTRS2005

IR Spectroscopy and Photo-Chemistry of Extraterrestrial Ices

Dense molecular clouds from which planetary systems form and the outer Solar System are both cold environments dominated by ices. Infrared (IR) spectroscopy is used to probe these ices, but the IR absorptions of molecules depend on the conditions. As a result appropriate lab data is needed to correctly fit spectra of extraterrestrial ices. Such fits have shown that most of these ices are composed primarily of H2O, but also contain 1-10 percent of other simple molecules such as CO2, CO, CH4, & NH3;. We shall present near IR spectra of ice mixtures of relevance to icy outer Solar System bodies and show that they still hold surprises, such as the Cheshire cat-like CO2 (2v3) overtone near 2.134 micrometers (4685 cm-1) that is absent from spectra of pure CO2 but present in H2O-CO2 mixtures.

Max P Bernstein↗
NASA NTRS1990

Parsec-Scale Penetration of UV into Molecular Clouds: CII 158 Micron Mapping of W3, NGC 1977, and NGC 2023

The spatial distribution of the 158 microns CII fine structure line in the galactic sources W3, NGC 1977, and NGC 2023 is mapped. The emission arises from warm (100 to 300 K), dense photodissociation regions at the surface of molecular gas. In all three sources, the emission extends over parsec scales or greater. For W3 and NGC 1977, where the UV source/molecular cloud geometry presents an edge on view of the variation of CII intensity into the molecular gas, two dimensional models of the CII emission which include the effects of gas clumping and scattering by dust on the transport of UV photons are constructed. The observed CII distribution and intensity is well modeled by a clumpy or filamentary distribution to the molecular gas, with a clump/interclump gas density ratio of 100 or more, which allows deep penetration of carbon ionizing UV photons into the clouds. The penetration of UV into clumped molecular clouds may also explain the extended far IR continuum emission from these sources. The total luminosity of CII emission from a clumpy molecular cloud with adjacent or embedded octave band stars can be as much as an order of magnitude higher than the CII luminosity of a uniform cloud. In addition, the extended penetration of UV into molecular clouds will affect the abundances of atomic and molecular species and increase the fractional ionization of interclump gas and UV illuminated clump surfaces.

Howe, J. E.↗
NASA NTRS1990

Molecular clouds associated with luminous far-infrared sources in the outer Galaxy

The stellar content and physical properties of the molecular clouds associated with 21 bright far-IR sources in the outer Galaxy have been determined through C-12O, C-13O, 6-cm radio continuum, and IRAS observations. The molecular cloud masses range from 200 to about 10,000 solar masses. The far-IR luminosity-to-mass ratio for these clouds has a mean value of 6.8 solar luminosity/solar masses and shows no correlation with the cloud mass, a result similar to that found for more massive clouds in the inner Galaxy. The radio continuum survey of the 21 bright far-IR sources indicates that most of these regions probably have a single, massive star providing most of the ionization. The cloud masses derived from virial and LTE analyses are in agreement, supporting the assumptions commonly made in their calculations, and a tight, near-linear correlation is found between the C-12O luminosity and the cloud mass. The H2 column density and integrated C-12O intensity are also correlated on a point-by-point basis, although the scatter is larger than the C-12O luminosity-cloud mass relation.

Carpenter, John M.↗
NASA NTRS1989

Shocked molecular hydrogen in the bipolar outflow NGC 2071

Maps of the emission from the v = 1-0 S(1) line of molecular hydrogen in the bipolar outflow of NGC 2071 are presented. The line emission is shown to peak at six positions distributed irregularly along two lobes which are parallel to, but offset about 20 arcsec from, the lobes of the high-velocity CO-line emission. The energetics and composition of the high-velocity gas support a model in which the driving agent is a bipolar atomic wind which arises from the vicinity of the central IR sources and shocks the surrounding molecular cloud, evacuating a cavity within it.

Burton, Michael G.↗
NASA NTRS1989

Young stellar objects in the Monoceros OB1 molecular cloud

Detailed results of an IRAS survey of a large portion of the Monoceros OB1 molecular cloud for discrete far-IR sources are presented. IRAS spectral energy distributions are constructed for 27 of the 30 sources identified in the region. Many are bright class I energy distributions, indicating that star formation is still occurring in the complex which produced the visible cluster, NGC 2264. Far-IR luminosities are calculated for each source, and the bolometric luminosity functions for class I and class II sources in the Mon OB1 cloud are found to be significantly different. Of all class I and II sources more luminous than 5 solar, 50 percent of class I sources are more luminous than 60 solar while only 4 percent of class II sources are. An attempt is made to determine the type of young stellar object in the cloud with which molecular outflows are associated.

Margulis, Michael↗
NASA NTRS1991

Quantum mechanical calculations to chemical accuracy

The accuracy of current molecular-structure calculations is illustrated with examples of quantum mechanical solutions for chemical problems. Two approaches are considered: (1) the coupled-cluster singles and doubles (CCSD) with a perturbational estimate of the contribution of connected triple excitations, or CCDS(T); and (2) the multireference configuration-interaction (MRCI) approach to the correlation problem. The MRCI approach gains greater applicability by means of size-extensive modifications such as the averaged-coupled pair functional approach. The examples of solutions to chemical problems include those for C-H bond energies, the vibrational frequencies of O3, identifying the ground state of Al2 and Si2, and the Lewis-Rayleigh afterglow and the Hermann IR system of N2. Accurate molecular-wave functions can be derived from a combination of basis-set saturation studies and full configuration-interaction calculations.

Bauschlicher, Charles W., Jr.↗
NASA NTRS2012

The Atomic to Molecular Transition in the Interstellar Medium

Study of H2 in UV and IR continues to surprise us with complexity of excitation state, OPR, and role in astrochemistry. Atomic H in molecular clouds is a very powerful tool suggesting that they are not "young" but that it takes millions of years to convert primarily atomic hydrogen clouds to 99.9% molecular form. Laboratory data suggests that H2 formation is efficient over broader range of temperatures than thought to be the case a few years ago, but range is still limited. Issues of complex grain morphology and surface structure make this a very difficult field in which to obtain definitively meaningful results. Ongoing and future observations of CI and CII will improve our understanding of the structure of clouds, their total mass, and how they have evolved and will continue to do so.

interstellar medium↗
NASA NTRS1977

Infrared studies of star formation

Infrared observations at wavelengths of a few microns to 1 mm are reviewed which pertain to the problem of star formation. The data considered include observations of large gas and dust clouds within which stars may be forming and detailed studies of individual objects within these clouds. Stages of star formation are outlined, the IR luminosity of forming stars is examined, and criteria for selecting interstellar regions for IR studies are discussed along with the importance of dust in the IR energy distributions of star-formation regions. Detailed results, including IR maps, are evaluated for the Orion Molecular Cloud 1 (OMC-1), W3, OMC-2, Mon R2, RCW 57, M17, CRL 2591, and NGC 7538. Some general properties of star-formation regions are summarized, and observational techniques for IR astronomy are described. It is noted that the discovery of possible pre-main-sequence (PMS) objects in the densest central portions of larger clouds supports the generally accepted premise of gravitational collapse as the driving mechanism for the star-formation process and that the observed properties of possible PMS objects agree qualitatively with the predictions of detailed models based on gravitational collapse.

Werner, M. W.↗
NASA NTRS1981

Mean molecular weight and hydrogen abundance of Titan's atmosphere

The 200-600/cm continuum opacity in the troposphere and lower stratosphere of Titan is inferred from thermal emission spectra from the Voyager 1 IR spectrometer (IRIS). The surface temperature and mean molecular weight are between 94 and 97 K and between 28.3 and 29.2 AMU, respectively. The mole fraction of molecular hydrogen is 0.002 + or - 0.001, which is equivalent to an abundance of approximately 0.2 + or - 0.1 km amagat.

Samuelson, R. E.↗
NASA NTRS1976

One arc-minute resolution maps of the Orion Nebula at 20, 50, and 100 microns

The paper presents maps of the central regions of the Orion Nebula which are based on observations made at wavelengths of 20, 50, and 100 microns with a resolution of 1 arcmin. The 50- and 100-micron observations were made with the NASA 91-cm Airborne Infrared Telescope. The principal far-IR features observed include a sharp emission peak near the position of the IR cluster, about 1 arcmin northwest of the Trapezium; a ridge of emission that is elongated north-south about this peak; and a barlike feature running northeast to southwest about 2 arcmin southeast of the Trapezium. The following conclusions are reached about the nature of the far-IR emission: (1) the total luminosity (between 10 and 1000 microns) of the IR cluster exceeds the solar luminosity by a factor of at least 120,000; (2) heating by both the IR cluster and the Trapezium stars is important in producing the central emission ridge; (3) the IR cluster is located within the molecular cloud; (4) the Trapezium stars are no more than 0.1 pc from that cloud; and (5) the bar of emission southeast of the Trapezium can be identified with an optically visible ionization front.

Werner, M. W.↗
NASA NTRS1989

Stable isotope laser spectroscopy

Recent advances in semiconductor laser technology have produced a reliable lightweight device ideally suited for a spacecraft high resolution molecular spectrometer. Lead-salt tunable diode lasers (TDL) emit in several spectral modes, each with a very narrow linewidth of -0.0003/cm. This spectral resolution is much narrower than typical Doppler broadened molecular linewidths in the mid-IR range. Thus it is possible to detect individual rotational lines within the vibrational band and measure their intensity, which can be used to determine gas concentration. The narrow spectral lines of any impurity gas tend to lie between the narrow lines of the gas of interest. This represents a major advantage over the accepted gas chromatograph mass spectrometer (GCMS) technique for measuring gas concentrations and isotope ratios. The careful and extensive gas purification procedures required to remove impurities for reliable GCMS measurements will not be required for an IR laser gas analysis. The infrared laser gas analysis technique is being developed to measure stable isotopic ratios of gases such as CO2, CH4, N2O, and NH3. This will eventually lead to development of instruments capable of in situ istopic measurements on planets such as Mars. The carbon (C-12, C-13) isotope ratio is indicative of the type of carbon fixation mechanisms (e.g., photosynthesis, respiration) in operation on a planet, while the nitrogen (N-14, N-15) isotope ratio can probably be used to date nitrogen-bearing Martian samples. The absorbance ratio of two adjacent lines of CO2 in the 2300/cm (4.3 micron) region of the spectrum was measured. The precision of the measurement is presently better than 1 percent and significant improvement is anticipated as rapid sweep-integration techniques and computer controlled data acquistion capabilities are incorporated.

Becker, J. F.↗
NASA NTRS1991

A second outflow from L1551/IRS 5?

The detection of previously unreported high-velocity emission in the L1551 moleculaar cloud is reported. This emission may represent high-velocity molecular gas deflected out of the IRS 5 outflow or may indeed represent another independent outflow whose origin is IRS 5 or L1551NE. This region is revealed to be far more complex than previously suspected.

Moriarty-Schieven, G. H.↗
NASA NTRS1991

High-resolution CO observations of luminous infrared galaxies with large L(ir)/L(B) ratios - IRAS 10173 + 0828, Zw 049.057, IRAS 17208 - 0014

The Owens Valley mm-wave interferometer has been used for high-resolution (about 3-7 arcsec) mapping of CO emission in three luminous IRAS galaxies: IRAS 17208 - 0014, 15107 + 0724, and IRAS 10173 + 0828. These galaxies are among the most extreme, in terms of their L(ir)/L(B) ratio, for objects in the IRAS Bright Galaxy Surveys. The CO emission detected in the three galaxies originates from a single region centered on the IRAS emission peak. These observations have shown that these galaxies have similar values for the global L(ir)/M(H2) ratio, for the surface density of molecular gas in their central regions and for the extinction toward the nucleus (above 300 mag). A high L(ir)/L(B) ratio seems to be a good predictor for both a high global L(ir)/M(H2) ratio and very large central H2 surface densities.

Planesas, P.↗
NASA NTRS1977

The energetics of molecular clouds. I - Methods of analysis and application to the S255 molecular cloud

Observations of the S255 molecular cloud in the radio lines of CO, (C-13)O, and H2O as well as in the IR region from 12 to 20 microns are presented. These results show that an extended molecular cloud is associated with the optically visible H II regions S255 - S257, both the kinetic temperature and molecular density are enhanced in an area centered on a compact near-IR source, this source is also coincident with an OH and an H2O maser (within the errors), and the IR source exhibits the silicon absorption feature. First-order techniques which allow physical properties of molecular clouds to be estimated and the energetics of the gas and dust in the clouds to be analyzed are developed and applied to S255. It is concluded that: (1) the gas cooling rate is much less than the dust cooling rate; (2) the primary energy flow is in the IR through dust emission over a range of temperatures; (3) the near-IR source is apparently responsible for the local peak in gas kinetic temperature; and (4) the exciting stars of nearby H II regions appear to be the primary heat sources for the overall molecular cloud.

Evans, N. J., II↗