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At least 91 records · Page 5

Observations of neutral atoms in the Rho Ophiuchi cloud

New observations of lines from neutral atoms in the lines of sight to three stars in the Rho Oph cloud are combined with literature data to look for evidence of density-enhanced regions with higher elemental depletions than those characterizing the cloud as a whole. The depletions inferred from neutral species, however, are comparable to those measured directly from observations of ions, suggesting that no strong density enhancements exist in the observed lines of sight. This conclusion is supported by electron densities derived from the observed ionization fractions, which also show no evidence for a strong variation of density with depth in the cloud. It appears that the overall density (and overall level of depletion) in the cloud is higher than in typical diffuse clouds, despite the apparent lack of strong condensations with enhanced relative depletions.

Snow, T. P.↗

Removal of High Specific Activity Fission Products from Uranyl Sulfate Waste Solutions

The Savannah River National Laboratory (SRNL) is currently providing support to SHINE Medical Technologies (SHINE) which plans to deploy a low energy, accelerator-based neutron source to fission low enriched U in a uranyl sulfate target solution for 99 Mo production. The 99 Mo is initially separated from the fission products and target solution by an extraction column. Subsequent washing of the column will generate waste solutions containing residual U and fission product activity. A small number of high specific activity fission products (e.g., 90 Sr, 137 Cs, and 144 Ce) in these streams will likely control the classification of the low level waste (LLW). If a sufficient amount of the high specific activity isotopes are separated from the SHINE waste streams and concentrated into a waste form, it would be possible to treat a majority of the wash solutions from the column operations as a lower class of LLW (Class A versus Class B or C or Class B versus Class C). The high specific activity fission product elements could then be dispositioned as a much smaller volume of waste rather than requiring the disposal of the entire waste stream at the higher waste classification. The Savannah River Site (SRS) has experience with using monosodium titanate (MST) and crystalline silicotitanate (CST) to remove Cs and Sr from high salt content waste solutions generated during the reprocessing of nuclear fuels and targets. Both of these materials have worked very well for their intended purposes at the SRS where the fission product elements are removed from highly alkaline waste. On the other hand, SHINE waste streams from the extraction column contain H 2 SO 4 which makes the solution acidic. Additionally, the SRS waste streams do not contain other fission product elements such as transition metals or lanthanides because they precipitate upon neutralization of the SRS waste and are not present in the supernate which is dispositioned as LLW following treatment. As such, there are inherent differences between SHINE and SRS waste treatment strategies. Savannah River National Laboratory was tasked with performing scoping studies to see if MST and CST would remove Sr, Cs, and Ce from an acidic mixed metal simulant solution. Batch contact experiments were performed using MST and two CST type materials. The MST material is a 15 wt % powder in 0.15 M NaOH slurry. The MST showed low adsorption for elements of interest from acidic solution. Furthermore, the powder size makes MST non-ideal for column operations. A CST IE-911 ion exchange material had high Cs adsorption, moderate Sr, and marginal Ce adsorption. Based on adsorption of all species, the ion exchange capacity was found to be 0.032 meq/mL. A bench-top column experiment to measure elemental breakthrough curves was performed using CST IE-911 where chromatographic separations of the mixed simulant were expected to occur. While most elements behaved as expected, the lanthanide series, containing Ce, broke though the column earlier than expected. The second CST material, CST R9120, displayed high adsorption for all elements in the acidic mixed simulant solutions in a batch contact study, and had a calculated loading capacity of 0.091 meq/mL. Future studies to develop a waste treatment flowsheet should focus on CST R9120 to treat SHINE waste solutions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Characterization of Minnesota lunar simulant for plant growth

Processing of lunar regolith into a plant growth medium is crucial in the development of a regenerative life support system for a lunar base. Plants, which are the core of such a system, produce food and oxygen for humans and, at the same time, consume carbon dioxide. Because of the scarcity of lunar regolith, simulants must be used to infer its properties and to develop procedures for weathering and chemical analyses. The Minnesota Lunar Simulant (MLS) has been identified to date as the best available simulant for lunar regolith. Results of the dissolution studies reveal that appropriately fertilized MLS can be a suitable medium for plant growth. The techniques used in conducting these studies can be extended to investigate the suitability of actual lunar regolith as a plant growth medium. Dissolution experiments were conducted using the MLS to determine its nutritional and toxicity characteristics for plant growth and to develop weathering and chemical analysis techniques. Two weathering regimes, one with water and one with dilute organic acids simulating the root rhizosphere microenvironment, were investigated. Elemental concentrations were measured using inductively-coupled-plasma (ICP) emission spectrometry and ion chromatography (IC). The geochemical speciation model, MINTEQA2, was used to determine the major solution species and the minerals controlling them. Acidification was found to be a useful method for increasing cation concentrations to meaningful levels. Initial results indicate that MLS weathers to give neutral to slightly basic solutions which contain acceptable amounts of the essential elements required for plant nutrition (i.e., potassium, calcium, magnesium, sulfur, zinc, sodium, silicon, manganese, copper, chlorine, boron, molybdenum, and cobalt). Elements that need to be supplemented include carbon, nitrogen, and perhaps phosphorus and iron. Trace metals in solution were present at nontoxic levels.

Oglesby, James P.↗

Deformation of a line-element in the phase space at the triangular libration point

The flow in the projection of the phase space into the configuration space is presented in the neighborhood of a neutrally (or critically) stable equilibrium point in the restricted problem of three bodies. The projection is a line-element every point of which has zero initial velocity. After the elapse of various times the mapping (the rotations and elongations) of the line-element is described showing chaotic behavior.

Szebehely, V.↗

Solid-phase isotope harvesting of 88 Zr from a radioactive ion beam facility

During routine operation of the Facility for Rare Isotope Beams (FRIB), radionuclides will accumulate in both the aqueous beam dump and along the beamline in the process of beam purification. These byproduct radionuclides, many of which are far from stability, can be collected and purified for use in other scientific applications in a process called isotope harvesting. In this work, the viability of 88 Zr harvesting from solid components was investigated at the National Superconducting Cyclotron Laboratory. A secondary 88 Zr beam was stopped in a series of collectors comprised of Al, Cu, W, and Au foils. Here, this work details irradiation of the collector foils and the subsequent radiochemical processing to isolate the deposited 88 Zr (and its daughter 88 Y) from them. Total average recovery from the Al, Cu, and Au collector foils was (91.3 ± 8.9) % for 88 Zr and (95.0 ± 5.8) % for 88 Y, respectively, which is over three times higher recovery than in a previous aqueous-phase harvesting experiment. The utility of solid-phase isotope harvesting to access elements such as Zr that readily hydrolyze in near-neutral pH aqueous conditions has been demonstrated for application to harvesting from solid components at FRIB.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Monodisperse Single-Material Granular Tribocharging Modeling and Experimental Validation

Charge transfer between insulating grains has been a topic of interest for many years as this phenomenon is extremely important to many areas in industry. Of particular interest to NASA is the behavior of electrically insulative dust grains such as those found on the lunar surface. Whether poured from a scoop during sample collection activities, agitated inside a drum via mining robots, or fluidized by a gas plume, particle-particle interactions between similar granular materials will be widespread on the Moon. Designers hope to have a predictive model for how dust grains are charged, transported, and deposited on flight systems to better understand issues electrostatics may cause in future missions. While difference in work function is often seen as a driver for charge transfer between two materials, this is an incomplete representation for insulative particles. Other asymmetries in the system can also lead to charge being transferred: one such being the difference between static vs dynamic particles. Experiments performed under vacuum in the Electrostatics and Surface Physics Laboratory (ESPL) clearly show that particles having more contacts with other particles tend to charge positively and particles having fewer contacts tend to charge negatively, despite being made from the same material. During these experiments, monodisperse (population of single diameter) spherical particles were held in a reservoir which was then elevated at one end to slope into a Faraday cup used to measure bulk charge of the grains. Care was taken to limit the number of spheres bouncing out of the cup, to isolate the beads from the container itself so that only grain-to-grain interactions occurred, and to assure neutrality of the beads before the experiment began. A discrete element method (DEM) modeling package already incorporating many granular mechanics interactions was augmented to include the electrostatic behaviors seen in experiments. The model can reproduce the experimental results above by tracking the number of contacts between pairs of individual grains and applying a charge transfer condition related to this contact parameter. The experimental results as well as their incorporation into the improved modeling suite will be discussed. Future work includes adding additional asymmetries into the experiments/model such as polydisperse populations of spherical particles and irregularly shaped grains.

granular↗

Monodisperse Single-Material Granular Tribocharging Modeling and Experimental Validation

Charge transfer between insulating grains has been a topic of interest for many years as this phenomenon is extremely important to many areas in industry. Of particular interest to NASA is the behavior of electrically insulative dust grains such as those found on the lunar surface. Whether poured from a scoop during sample collection activities, agitated inside a drum via mining robots, or fluidized by a gas plume, particle-particle interactions between similar granular materials will be widespread on the Moon. Designers hope to have a predictive model for how dust grains are charged, transported, and deposited on flight systems to better understand issues electrostatics may cause in future missions. While difference in work function is often seen as a driver for charge transfer between two materials, this is an incomplete representation for insulative particles. Other asymmetries in the system can also lead to charge being transferred: one such being the difference between static vs dynamic particles. Experiments performed under vacuum in the Electrostatics and Surface Physics Laboratory (ESPL) clearly show that particles having more contacts with other particles tend to charge positively and particles having fewer contacts tend to charge negatively, despite being made from the same material. During these experiments, monodisperse (population of single diameter) spherical particles were held in a reservoir which was then elevated at one end to slope into a Faraday cup used to measure bulk charge of the grains. Care was taken to limit the number of spheres bouncing out of the cup, to isolate the beads from the container itself so that only grain-to-grain interactions occurred, and to assure neutrality of the beads before the experiment began. A discrete element method (DEM) modeling package already incorporating many granular mechanics interactions was augmented to include the electrostatic behaviors seen in experiments. The model can reproduce the experimental results above by tracking the number of contacts between pairs of individual grains and applying a charge transfer condition related to this contact parameter. The experimental results as well as their incorporation into the improved modeling suite will be discussed. Future work includes adding additional asymmetries into the experiments/model such as polydisperse populations of spherical particles and irregularly shaped grains.

electrostatics↗

Aerodynamic roughness measured in the field and simulated in a wind tunnel

This study evaluates how well values of aerodynamic surface roughness, z sub 0, measured over scale models in wind tunnels correlate with values of z sub 0 measured at full scale in the field. A field experiment was conducted in which values of z sub 0 and u* (wind friction speed) were measured over three arrays of non-erodible roughness elements on a dry lake bed. Wind profiles were measured by ten anemometers on a 15 m mast under thermally neutral atmospheric conditions. Values of z sub 0 increased from .00014 m (dry lake bed only) to .026 m with increasing roughness element density. The three roughness element arrays were simulated at 1/10 and 1/20 scale in an open-circuit atmospheric boundary-layer wind tunnel. Velocities were measured with a boundary-layer pitot-tube rake from the same relative position within the scale model arrays as the anemometers were relative to the field arrays. Each array at each scale was sampled three times at five freestream velocities. Average values of z sub 0 for each model array at each scale were compared with full-scale values of z sub 0 obtained in the field. The field vs. wind tunnel correspondence of z sub 0 is found to be z sub 0 field = 0.2661 x (z sub(0 model) x scale(exp -1))exp .8159.

Sullivan, Robert↗

Does inhomogeneous big bang nucleosynthesis produce an inhomogeneous element distribution today?

Inhomogeneous big bang nucleosynthesis (BBN) produces a spatially inhomogeneous distribution of element abundances at $T \sim 10^9$ K , but subsequent element diffusion will tend to erase these inhomogeneities. In this work, we calculate the cosmological comoving diffusion length for the BBN elements. This diffusion length is limited by atomic scattering and is therefore dominated by diffusion when the atoms are neutral, between the redshifts of recombination and reionization. We find that the comoving diffusion length today is $d_{\text{com}} ≈ 70$ pc for all of the elements of interest except 7 Li , for which $d_{\text{com}}$ is an order of magnitude smaller because 7 Li remains ionized throughout the relevant epoch. This comoving diffusion length corresponds to a substellar baryonic mass scale and is roughly equal to the horizon scale at BBN. These results lend support to the possibility that inhomogeneities on scales larger than the horizon at BBN could lead to a spatially inhomogeneous distribution of elements today, while purely subhorizon fluctuations at BBN can result only in a homogeneous element distribution at present.

79 ASTRONOMY AND ASTROPHYSICS↗

Enhanced tuneable rotatory power in a rotating plasma

We report that the gyrotropic properties of a rotating magnetized plasma are derived analytically. Mechanical rotation leads to a new cutoff for wave propagation along the magnetic field, and polarization rotation above this cutoff is the sum of the classical magneto-optical Faraday effect and the mechanico-optical polarization drag. Exploiting the very large effective group index near the cutoff, we expose here that polarization drag can be 10 4 larger than Faraday rotation at GHz frequency. The rotation leads to weak absorption while allowing direct frequency control, demonstrating the unique potential of rotating plasmas for nonreciprocal elements. The very large rotation frequency of a dense non-neutral plasma could enable unprecedented gyrotropy in the THz regime.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

In situ gas and ion measurements at comet Halley

The Giotto space probe's neutral mass spectrometer experiment has determined the abundances and the chemical, elemental and isotopic compositions of gases and low energy ions in the coma of comet Halley. Preliminary results show water predominating, at about 80 percent by volume, with a density of 4.7 x 10 to the 7th molecules/cu cm at 1000 km and a photodestruction scale length of 39,000 km. Limits on the abundances of CO2, NH3 and CH4 relative to H2O are also obtained. An ion temperature change observation indicates a contact surface location at 47,000 + or - 200 km.

Krankowsky, D.↗

Coordinated videomagnetograph observations by the Big Bear and Huairou Observatories

A videomagnetograph patterned after the BBSO system was installed at Huairou in 1987, and five days of coordinated observing were carried out from September 24 to 29, 1987. The data were combined to make a continuous movie of the fields abound a stable spot. A 57 hour magnetograph run with two seven hour gaps were achieved from 2330 UT, September 24 to 0830 UT, September 27. The frames were reregistered and justified to eliminate the change of scale with meridian distance. The intensities were corrected for cosine effect. Preliminary examination of the data shows continuous decrease of the total magnetic field during this period by more than 50 percent. The principal loss of flux appears to be due to cancellation at the main neutral line. Some flux disappears due to fragmentation, which makes the elements fall below the threshold, while only a tiny loss due to diffusion can be detected. It is planned to continue this program during Max 1991, including transverse field measurements as well. Several long runs were already obtained in 1988.

Wang, Haimin↗

Risk-Averse Control of Fractional Diffusion with Uncertain Exponent

In this paper, we introduce and analyze a new class of optimal control problems constrained by elliptic equations with uncertain fractional exponents. We utilize risk measures to formulate the resulting optimization problem. We develop a functional analytic framework, study the existence of solution and rigorously derive the first-order optimality conditions. Additionally, we employ a sample-based approximation for the uncertain exponent and the finite element method to discretize in space. Further, we prove the rate of convergence for the optimal risk neutral controls when using quadrature approximation for the uncertain exponent and conclude with illustrative examples.

finite element method↗

Factors in the design of spacecraft utilizing multiple electric thrusters

An analysis has been performed which describes the electrical interactions between simultaneously operating ion thrusters and between the ion thrusters and a spacecraft bus. The problem is reduced to a relatively simple equivalent circuit including all leakage paths. The influence of the various circuits elements on a spacecraft potential is studied. A thruster grounding scheme is introduced which is designed to minimize the electrical interactions and includes protection for both thrusters and spacecraft from possible damage due to neutralizer failure. The paper includes the results of various experiments which have been conducted to quantitatively define the elements of the equivalent circuit.

Fitzgerald, D. J.↗

EVA Assembly of Large Space Structure Neutral Buoyancy, Zero-Gravity Simulation: NASA-LaRC Nestable Columns and Joints

The film depicts an extravehicular activity (EVA) that involved the assembly of six "space-weight" columns into a regular tetrahedral cell by a team of two "space"-suited test subjects. This cell represents the fundamental "element" of a tetrahedral truss structure. The tests were conducted under simulated zero-gravity conditions, achieved by neutral buoyancy in water. The cell was assembled on an "outrigger" assembly aid off the side of a mockup of the Shuttle Orbiter cargo bay. Both manual and simulated remote manipulator system (RMS) modes were evaluated. The simulated RMS was used only to transfer stowed hardware from the cargo bay to the work sites. Articulation limits of the pressure suit and zero gravity could be accommodated by work stations with foot restraints. The results of this study have confirmed that astronaut EVA assembly of large, erectable space structur is well within man's capabilities.

TESTS↗

High-resolution IUE observations of interstellar absorption lines in the Vela supernova remnant

Ultraviolet spectra of 45 stars in the vicinity of the Vela supernova remnant were recorded by the short-wavelength echelle spectrograph aboard the International Ultraviolet Explorer (IUE). Over one-third of the stars show interstellar absorption lines at large radial velocities (greater than 60 km/s). The mapping of these high-velocity components in the sky suggests the motions are chaotic, rather than from a coherent expansion of the remnant material. In accord with earlier conclusions from Copernicus data, the gas at high velocity exhibits higher than normal ionization and shows substantially less depletion of nonvolatile elements than normal interstellar material at low velocities. Relatively strong lines from neutral carbon in the two excited fine-structure states indicate that the neutral clouds within the remnant have had their pressures enhanced by the passage of the blast wave from the supernova. Also, the remnant seems to show a significant enhancement in the abundances of low-velocity Si IV, C IV, and N V over those found in the general interstellar medium.

Jenkins, E. B.↗

Abundances of interstellar atoms from ultaviolet absorption lines

The equivalent widths of interstellar absorption lines of Mg II, P II, Cl I and II, Mn II, Fe II, Cu II, and Ni II, obtained in a Copernicus survey of Bohlin et al (1983) have been analyzed to yield column densities along the lines of sight. The measured depletions are clearly correlated with n sub H, the mean hydrogen column density along the line of sight. Depletions also seem to be weakly correlated with various ratios of hydrogen to extinction by dust grains and also variations of extinction with wavelength, although part of these effects are a secondary result of the correlation with n sub H. The apparent coupling of depletion to the mean density are interpreted in terms of an idealized model due to Spitzer (1985), where each element has one value of depletion in the low-density, warm, neutral gas and an enhanced, different value in cold clouds. The difference of apparent depletions for Mg, P, Cl, Mn, and Fe between warm and cold clouds averages 0.44 + or - 0.12 (rms) dex, and, after an allowance for observational errors is made, the scatter of individual depletions from the overall trend predicted by method is only about 0.10 dex. The identification of the observed apparent depletions with actual ones, while very likely, is not entirely secure, because of the possible presence of highly saturated compoents with very narrow profiles and the possible contamination of the results by H II regions.

Jenkins, E. B.↗

Global Patterns of Tectonism on Titan from Mountain Chains and Virgae

This research is based on the exploration of tectonic patterns on Titan from a global perspective. Several moons in the outer solar system display patterns of surface tectonic features that imply global stress fields driven or modified by global forces. Patterns such as these are seen in Europa's tidally induced fracture patterns, Enceladus's tiger stripes, and Ganymede's global expansion induced normal fault bands. Given its proximity to Saturn, as well as its eccentric orbit, tectonic features and global stresses may be present on Titan as well. Titan displays possible tectonic structures, such as mountain chains along its equator (Radebaugh et al. 2007), as well as the unexplored dark linear streaks termed virgae by the IAU. Imaged by Cassini with the RADAR instrument, mountain chains near the equator are observed with a predominante east-west orientation (Liu et al. 2012, Mitri et al. 2010). Orientations such as these can be explained by modifications in the global tidal stress field induced by global contraction followed by rotational spin-up. Also, due to Titan's eccentric orbit, its current rotation rate may be in an equilibrium between tidal spin-up near periapsis and spin-down near apoapsis (Barnes and Fortney 2003). Additional stress from rotational spin-up provides an asymmetry to the stress field. This, combined with an isotropic stress from radial contraction, favors the formation of equatorial mountain chains in an east-west direction. The virgae, which have been imaged by Cassini with both the Visual and Infrared Mapping Spectrometer (VIMS) and Imaging Science Subsystem (ISS) instruments, are located predominately near 30 degrees latitude in either hemisphere. Oriented with a pronounced elongation in the east-west direction, all observed virgae display similar characteristics: similar relative albedos as the surrounding terrain however darkened with an apparent neutral absorber, broken-linear or rounded sharp edges, and connected, angular elements with distinct, linear edges. Virgae imaged during northern latitude passes are oriented with their long dimensions toward Titan's antiSaturn point. If the virgae are of tectonic origin, for instance if the turn out to be i.e. grabens, they could serve as markers to Titan's global stress field. Using them in this way allows for a mapping of global tectonic patterns. These patterns will be tested for consistency against the various sources of global stress and orientations of mountain chains. By determining what drives Titan's tectonics globally, we will be able to place Titan within the context of the other outer planet icy satellites.

Cook, C.↗