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NASA NTRS1991

Nd-142/Nd-144 in SNCs and early differentiation of a heterogeneous Martian mantle

Sm/Nd correlated variations in Nd-142/Nd-144 have been observed for mineral phases of achondrites from decay of live Sm-146 in the early solar system. Crystallization ages of shergottites-nakhlites-Chassigny (SNC) meteorites are less than or = 1.3 Ga, so variations of Nd-142/Nd-144 among mineral phases of the SNC's are not expected. However, if SNC's were derived from source reservoirs of differing Sm/Nd ratios, established while Sm-146 was still alive, and which remained isolated except for magma extraction, then variations in Nd-142/Nd-144 would exist among individual SNC meteorites. Rb-Sr and U-Pb isotopic data for the shergottites imply differentiation of their parent planet approximately 4.6 Ga ago. The confirmation of the conclusion that the nakhlites and shergottites were derived from different source regions, and that, consequently, the shergottite parent body (SPB) mantle was heterogeneous is presented.

Nyquist, L. E.↗
NASA NTRS1994

ALH84001, a cumulate orthopyroxenite member of the Martian meteorite clan

ALH84001, originally classified as a diogenite, is a coarse-grained, cataclastic, orthopyroxenite meteorite related to the martian (SNC) meteorites. The orthopyroxene is relatively uniform in composition, with a mean composition of Wo3.3En69.4Fs27.3. Minor phases are euhedral to subhedral chromite and interstitial maskelynite, An31.1Ab63.2Or5.7, with accessory augite, Wo42.2En45.1Fs12.7, apatite, pyrite and carbonates, Cc11.5Mg58.0Sd29.4Rd1.1. The pyroxenes and chromites in ALH84001 are similar in composition to these phases in EETA79001 lithology a megacrysts but are more homogeneous. Maskelynite is similar in composition to feldspars in the nakhlites and Chassigny. Two generations of carbonates are present, early (pre-shock) strongly zoned carbonates and late (post-shock) carbonates. The high Ca content of both types of carbonates indicates that they were formed at moderately high temperature, possibly approximately 700 C. ALH84001 has a slightly LREE-depleted pattern with La 0.67x and Lu 1.85x CI abundances and with a negative Eu anomaly (Eu/Sm 0.56x CI). The uniform pyroxene composition is unusual for martian meteorites, and suggests that ALH84001 cooled more slowly than did the shergottites, nakhlites of Chassigny. The nearly monomineralic composition, coarse-grain size, homogeneous orthopyroxene and chromite compositions, the interstitial maskelynite and apatite, and the REE pattern suggest that ALH84001 is a cumulate orthopyroxenite containing minor trapped, intercumulus material.

Mittlefehldt, David W.↗
NASA NTRS2006

Pyroxenes in Martian meteorites as petrogenetic indicators

Pyroxenes in Martian meteorites are important recorders of petrogenetic processes. Understanding the details of pyroxene major and minor element compositional variations can provide important insights into those processes. A combination of careful petrographic analysis of natural samples and experimental crystallization studies can lead to better understanding of the processes that gave rise to these samples on Mars. In addition, experimentally determined major, minor and trace element partition coefficients are important for using natural pyroxenes to estimate the compositions of the melts from which they crystallized and the oxidation conditions that prevailed during crystallization. We will report on minor element (Al, Ti, Cr) zoning in nakhlite pyroxenes and in synthetic pyroxenes that we have grown for the purposes of determining pyroxene/melt partition coefficients for Sr and REE. The natural pyroxenes have patchy Al zoning that, by analogy with our experimental pyroxenes, we interpret as sector zoning. The irregular patchy nature of the zoning is probably the result of the vagaries of growth kinetics and local environment during crystal growth. More slowly cooled nakhlites have the most distinct bimodal zoning, with one mode having Al2O3 around 0.5-0.6 wt%, and the other around 0.9 %. Average Al content increases with increasing cooling rate. This feature is puzzling, since the cumulus pyroxenes were almost certainly present at the time of eruption. Al and Ti are strongly correlated, but Cr is completely decoupled from those elements. The synthetic pyroxenes are distinctly sector zoned in Al and Ti, and the sector-to-sector variation in Al within a single crystal has important effects on trace element partition coefficients. Trivalent REE are strongly correlated with Al, while divalent elements (Sr, Eu+2) show a significantly weaker correlation. For example, as the Al2O3 content varies from 0.3 to 0.6 wt % from one sector to another, D(Gd) increases by approx.80% while D(Sr) and D(Eu) only increase by 20-30% at oxygen fugacities near IW. The different Al dependency of D for trivalent REE vs. divalent Eu and Sr considerably complicates the calibration of the Eu oxybarometer.

McKay, Gordon↗
NASA NTRS2016

The Germanium Dichotomy in Martian Meteorites

Germanium is a moderately volatile and siderophile element that follows silicon in its compatibility during partial melting of planetary mantles. Despite its obvious usefulness in planetary geochemistry germanium is not analyzed routinely, with there being only three prior studies reporting germanium abundances in Martian meteorites. The broad range (1-3 ppm) observed in Martian igneous rocks is in stark contrast to the narrow range of germanium observed in terrestrial basalts (1.5 plus or minus 0.1 ppm). The germanium data from these studies indicates that nakhlites contain 2-3 ppm germanium, while shergottites contain approximately 1 ppm germanium, a dichotomy with important implications for core formation models. There have been no reliable germanium abundances on chassignites. The ancient meteoritic breccia, NWA 7533 (and paired meteorites) contains numerous clasts, some pristine and some impact melt rocks, that are being studied individually. Because germanium is depleted in the Martian crust relative to chondritic impactors, it has proven useful as an indicator of meteoritic contamination of impact melt clasts in NWA 7533. The germanium/silicon ratio can be applied to minerals that might not partition nickel and iridium, like feldspars. We report germanium in minerals from the 3 known chassignites, 2 nakhlites and 5 shergottites by LAICP- MS using a method optimized for precise germanium analysis.

Humayun, M.↗
NASA NTRS2017

Lead in Martian Meteorites-- Observations and Inconsistencies: I. Chassigny

The history of Pb isotope analyses of the martian meteorites (SNC) and their interpretations is laden with difficulties. Two different analytical groups have interpreted their ancient (≥ 4 Ga) shergottite Pb ages as primary [1-5]. A Nakhla age of approximately 4.3 Ga has been interpreted to be primary as well [2]. This is in stark contrast to the young (≤ 1.4 Ga) crystallization ages defined by the Rb-Sr, Sm-Nd, Lu-Hf, and KAr systems [6]. Possibly, a better interpretation for the ancient Pb ages is that they reflect the formation times of the various SNC source regions [7]. A difficulty in dealing with Pb is that terrestrial contamination is ubiquitous, unlike the other chronometer systems noted above. This issue is complicated by the fact that radioactive decay causes localized mineral damage. So washing and leaching to remove Pb contamination tends to remove in situ radiogenic Pb. This issue is further compounded because U and Th are often concentrated in phosphates and other minor phases, so the leaching process tends to remove these, especially phosphates. Another difficulty is that it is not clear whether the observed Pb isotopic variation in leachates, residues, and ion-microprobe analyses is due to terrestrial or to indigenous martian Pb contamination [e.g., 8]. A third difficulty is that the shergottites on the one hand, and the nakhlites and chassignites on the other, appear to have come from separate source regions with different chemical compositions [e.g., 7]. Thus, it is expected that their Pb isotopic characteristics would be different. And even if all these meteorite types came from the same source region, their igneous ages differ considerably. The nakhlites and chassignites are ~1.4 Ga and the shergottites are ≤ 600 Ma [e.g., 6]. This age difference alone should assure that the two distinct SNC groups have differing Pb isotopic signatures.

Jones, J. H.↗
NASA NTRS2021

Chapter 3: Petrologic Evolution of Martian Volcanism and Clues from Meteorites

The formation and evolution of the Martian surface, and ultimately the fate of its various volcanic regions, are revealed in the chemistry of Martian meteorites, and the mineralogy of the crust. The interpretation of the chemistry from remote sensing instrumentation from orbiters and landers/rovers has been strongly influenced by our knowledge of geochemical processes on Earth, the Moon, and other asteroidal, rocky bodies [1]. The composition, and thus evolution, of the Martian crust has been resultant from SNC (shergottite –nakhlite –chassignite) meteorites, which are the igneous counterpart of rocks of Martian origin [2, 3, 4]. These meteorites are chemically similar to terrestrial basalts and cumulates, with the exception of higher concentrations of iron and other volatile elements (i.e., phosphorous, chlorine, chalcophile) [5]. From Tuff et al. [2], most Martian meteorites have relatively young crystallization ages ranging from 1.4 billion years to 180 million years ago [6]. These are considered to be derived from young, usually lightly-cratered volcanic regions, such as the Tharsis volcanic region [6, 7]. Though mainly basaltic in composition, surface rocks are richer in nickel and sulfur with lower manganese/iron ratios than Martian meteorites [2], which can be explained by the differences in oxygen fugacity during melting of the sulfur-rich mantle [2, 8]. From this difference, Martian meteorites are tied to surface rocks through an early (3.7 billion years ago) oxidation of the uppermost mantle, producing the more recent volcanic rocks [2]. The variety of compositions from basaltic, olivine volcanic rocks through pyroxene-cumulate nakhlites and peridotite chassignites, enable the hypothetical reconstructions of the silicic evolution of Mars similar to techniques used on Earth [2, 5, 9]. In this chapter, we will explore the basic Martian composition of the crust and mantle in regards to volcanic regions, the crustal components of the North-South dichotomy, and more detail of the SNC meteorites in relation to the evolution of the mantle for volcanism.

C Ahrens↗
NASA NTRS1977

Genesis of the Angra dos Reis and other achondritic meteorites

Major, minor, and trace element abundances were determined in seven Angra dos Reis samples, which included whole rocks, fassaite (clinopyroxene), olivine, and whitlockite separates, via sequential instrumental neutron activation analysis. The rare earth element abundance patterns and the trace element abundance patterns of this achondritic meteorite are discussed. A two-stage crystal-liquid fractionation model with source material containing olivine, orthopyroxene, and clinopyroxine is presented for the genesis of Angra dos Reis. Multilinear regression analysis was used to estimate possible composition and properties of the parent magmas. Angra dos Reis was compared with other achondrites, cumulate eucrites and nakhlites in particular. It is thought that the unique Angra dos Reis could not be related to those achondrites by crystal-liquid fractionation of the same parent body.

Ma, M.-S.↗
NASA NTRS1980

Meteoritic material at four Canadian impact craters

Eleven impact melt and six basement rock samples from four craters were analyzed by neutron activation for Au, Co, Cr, Fe, Ge, Ir, Ni, Os, Pd, Re and Se. Wanapitei Lake, Ontario: the impact melts show uniform enrichments corresponding to 1-2% C1-chondrite material. Interelement ratios (Co/Cr, Ni/Cr, Ni/Ir) suggest that the impacting body was a C1-, C2-, or LL-chondrite. Nicholson Lake, North West Territory: Ni, Cr and Co are distinctly more enriched than Ir and Au which tentatively suggests an olivine-rich achondrite (nakhlite or ureilite). Gow Lake, Saskatchewan and Mistastin, Labrador: small enrichments in Ir and Ni; both the low Ir/Ni ratios and low Cr content suggest iron meteorites, but the signals are too weak for conclusive identification. A tentative comparison of meteoritic signatures at 10 large, greater than or equal to 4 km craters and their presumed celestial counterparts (13 Apollo and Amor asteroids) shows more irons and achondrites among known projectile types, and a preponderance of S-type objects, having no known meteoritic equivalent, among asteroids. It is not yet clear that these differences are significant, in view of the tentative nature of the crater identifications and the limited statistics.

Wolf, R.↗
NASA NTRS1982

SNC meteorites - Igneous rocks from Mars

It is argued that SNC (shergottite, nakhlite, chassignite) meteorites are ejecta from Mars. The mineralogy and chemistry of these objects is discussed, including rare earth element content, potassium/uranium ratios, oxidation state, oxygen isotopes, ages and isotopic evolution, magnetism, shock and texture. The possibility of SNC's deriving from Mercury, Venus, earth, moon, or a eucrite parent body is argued against. Mercury is too volatile-poor and anhydrous, Venus's atmosphere too thick and hot and its gravitational field too large, earth's oxygen isotope content too different from that of SNC's, the moon too different isotopically and chemically, and the ages of eucrites too different. Models suggest that SNC's could have escaped from Mars's gravitational field, and their composition supports Martian origin. Statistically, they could have reached the earth within their measured shock ages. Objections to the hypothesis are also discussed.

Wood, C. A.↗
NASA NTRS1983

Mineralogy and chemistry of planets and meteorites

The data collection and the interpretation with respect to the mineralogy of meteoritic and terrestrial samples are summarized. The key conclusion is that the Moon underwent a series of melting episodes with complex crystal-liquid differentiation. It was not possible to determine whether the Moon melted completely or only partially. The stage is now set for a systematical geochemical and geophysical survey of the Moon. Emphasis was moved to meteorites in order to sort out their interrelationships from the viewpoint of mineral chemistry. Several parent bodies are needed for the achondrites with different chemical properties. Exploration of Mars is required to test ideas based on the possible assignment of shergottites, nakhlites and chassignite to this planet. Early rocks on the Earth have properties consistent with a heavy bombardment and strong volcanic activity prior to 4 billion years ago.

Source record↗
NASA NTRS1982

SNC meteorites - Evidence against an asteroidal origin

About 1.3 billion years ago, on one or more distant planetary bodies, silicate melts formed and produced cumulate rocks which eventually made their way to earth. Nine of these rocks have been recovered. Three distinct groups are involved, including shergottites, nakhlites, and chassignites (abbreviated as SNC). The young crystallization ages and other chemical features of SNC meteorites have prompted several workers to suggest that the specimens may be samples of igneous rock, ejected from the surface of Mars during an impact event. Others have rejected the Martian origin of SNC meteorites in favor of a more traditional asteroidal parent body. The present investigation shows that the petrologic, geochemical, and isotopic evidence is inconsistent with an asteroidal origin for SNC meteorites. It is found that the characteristics of SNC meteorites argue convincingly against their origin in a planetary object as small as the largest asteroid. That these meteorites may be fragments of the Martian surface still remains the most likely possibility.

Ashwal, L. D.↗
NASA NTRS1983

Do oblique impacts produce Martian meteorites

It is pointed out that several achondritic meteorites, classified as shergottites, nakhlites, and chassignites, have a number of unusual characteristics. Following the suggestion of Wood and Ashwal (1981) these meteorites are collectively referred to as SNC meteorites. The major element compositions of the SNC meteorites are, in general, distinct from those of other meteorites and lunar samples, and similar to certain terrestrial rocks. The geochemical and geochronological characteristics of the SNC meteorites strongly imply that their parent body was on the order of lunar size or larger and geologically active. Serious attention must be given to the hypothesis of a Martian origin of the SNC meteorites and to dynamic processes capable of delivering Martian meteorites to earth. In connection with the present investigation, it is suggested that oblique impacts of large meteoroids can produce ejecta which is entrained with the ricocheting projectile and accelerated to velocities in excess of Martian escape velocity.

Nyquist, L. E.↗
NASA NTRS1984

Cosmic ray exposure of SNC meteorites and constraints on their derivation from Mars

There is chemical, mineralogical, and isotopic evidence that several rare meteorites originated from the planet Mars. The eight specimens (4 sphergottites, 3 nakhlites, and 1 chassignite) possess a variety of characteristics that suggest a mutual relationship. It can be predicted with reasonable confidence that these SNC meteorites were exposed to cosmic rays at relatively shallow depths for three distinct periods of time during the past approximately 10 million years. Within the context of a Martian origin, this implies that either relatively large objects were ejected from Mars at a common time and underwent three disruptive events in space or that three ejection events occurred within the past approximately 10 million years on restricted segments of Martian terrain with 1300 million year-old rocks. If mechanisms can be identified which satisfy the geochemical properties of SNC meteorites, as well as their cosmic ray exposure, and dynamical problems associated with ejection out of a large gravity field, then the case for the SNC meteorites being samples of Mars can become stronger.

Bogard, D. D.↗
NASA NTRS1984

The oblique impact hypothesis and relative probabilities of lunar and Martian meteorites

The suggestion by Nyquist (1983) that shergottites and possibly other SNC (shergottites, nakhlites, and Chassigny) meteorites were launched from the Martian surface by the oblique impact of large meteoroids is further evaluated in the context of the subsequent discovery of a lunar meteorite. It is demonstrated that within calculational uncertainties and the current poorly known fall statistics of lunar and probable Martian meteorites, the oblique impact hypothesis provides a satisfactory explanation of the relative abundances of lunar, Martian, and other meteorites. It is noted that these results support the oblique-impact-on-Mars origin of SNC meteorites and satisfactorily explain the occurrence of a lunar meteorite.

Nyquist, L. E.↗
NASA NTRS1986

The 10Be contents of SNC meteorites

Several authors have explored the possibility that the Shergottites, Nakhlites, and Chassigny (SNC) came from Mars. The spallogenic gas contents of the SNC meteorites have been used to: constrain the sizes of the SNC's during the last few million years; to establish groupings independent of the geochemical ones; and to estimate the likelihood of certain entries in the catalog of all conceivable passages from Mars to Earth. The particular shielding dependence of Be-10 makes the isotope a good probe of the irradiation conditions experienced by the SNC meteorites. The Be-10 contents of nine members of the group were measured using the technique of accelerator mass spectrometry. The Be-10 contents of Nakhla, Governador Valadares, Chassigny, and probably Lafayette, about 20 dpm/kg, exceed the values expected from irradiation of the surface of a large body. The Be-10 data therfore do not support scenario III of Bogard et al., one in which most of the Be-10 in the SNC meteorites would have formed on the Martian surface; they resemble rather the Be-10 contents found in many ordinary chondrites subjected to 4 Pi exposures. The uncertainties of the Be-10 contents lead to appreciable errors in the Be-10 ages, t(1) = -1/lambda ln(1 Be-10/Be-10). Nonetheless, the Be-10 ages are consistent with the Ne-21 ages calculated assuming conventional, small-body production rates and short terrestrial ages for the finds. It is believed that this concordance strengthens the case for at least 3 different irradiation ages for the SNC meteorites. Given the similar half-thicknesses of the Be-10 and Ne-21 production rates, the ratios of the Be-10 and Ne-21 contents do not appear consistent with common ages for any of the groups. In view of the general agreement between the Be-10 and Ne-21 ages it does not seem useful at this time to construct multiple-stage irradiation histories for the SNC meteorites.

Pal, D. K.↗
NASA NTRS1986

The Shergotty consortium and SNC meteorites - An overview

The key up-to-date findings on the Shergotty and other SNC meteorites are summarized. The Martian origin of these meteorites is strongly suggested by the evidence of trapped noble gases and nitrogen compositions in glasses of the EETA 79001 meteorite, which compare well with the results of the Martian atmosphere investigation by the Viking spacecraft. Age-dating and exposure scenarios suggest two possibilities for the ejection of SNC meteorites: (1) ejection as a large (larger than 6 m) body by a single impact on Mars and then multiple breakup in the asteroidal belt, at about 11 Myr for Chassigny and nakhlites, at 2.5 Myr for Shergotty, Zagami and ALHA 77005, and at 0.6 Myr for EETA 79001; and (2) ejection of small (less than 0.5 m) objects by multiple impacts on the Martian terrain at 11, 2.5, and 0.6 Myr, with no breakup in space.

Laul, J. C.↗
NASA NTRS1986

Magnetic studies on Shergotty and other SNC meteorites

The results of a study of basic magnetic properties of meteorites within the SNC group, including the four known shergottites and two nakhlites, are presented. An estimate is made of the strength of the magnetic field which produced the remanent magnetization of the Shergotty meteorite, for the purpose of constraining the choices for the parent body of these SNC meteorites. Remanence measurements in several subsamples of Shergotty and Zagami meteorites reveal a large variation in intensity that does not seem to be related to the abundance of remanence carriers. The other meteorites carry only weak remanence, suggesting weak magnetizing fields as the source of their magnetic signal. A paleointensity experiment on a weakly magnetized subsample of Shergotty revealed a low temperature component of magnetization acquired in a field of 2000 gammas, and a high temperature component reflecting a paleofield strength of between 250 and 1000 gammas. The weak field environment that these meteorites seem to reflect is consistent with either a Martian or asteroidal origin, but inconsistent with a terrestrial origin.

Cisowski, S. M.↗
NASA NTRS1986

Effect of an impact-generated gas cloud on the acceleration of solid ejecta

A hypothesis that vaporization of a large amount of volatiles such as H2O and CO2 in the Martian surface by the impact of a large object could have accelerated solid ejecta to earth is examined. A hydrodynamic model is used to approximate a hemispherical gas cloud expanding into an atmosphere and entraining solid ejecta. Account is taken of the target material, the impactor materials, mass vaporized, impact velocity, drag coefficient, and crater sizes. A Martian crater larger than 30 km diam is found to be a necessary remnant of any impact that could have produced the shergottites, nakhlites and Chassigny meteorites which have been found on earth and possess similarities to analyzed Martian rocks.

Vickery, Ann↗