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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Kinetics and continuum emission of negative atomic ions in partially ionized plasmas

Kinetics and continuum emission of negative ions are studied in stationary atomic hydrogen, nitrogen, and oxygen plasmas. The intensity of the negative-ion emission was found to be neglibible when compared to those of bound-bound and free-bound emission at low and medium particle densities. However, the negative-ion continuum emission can contribute significantly in certain parts of the emission spectrum at high particle densities.

Soon, W. H.↗
NASA NTRS1972

Atomic processes in astrophysics.

Studies of particle excitation processes in the solar corona are reviewed, covering electron affinities, negative ion experiments using two-photon laser and drift tube techniques, geometrical hindrance in molecular ion formation, negative ion-molecule reactions, and negative ions in the ionosphere and astrophysics. Aspects of forbidden atomic transitions are also discussed, including the calculation of transition probabilities, the Fe II problem, and magnetic quadrupole radiation in a relativistic approximation.

Garstang, R. H.↗
NASA NTRS1961

Semiempirical Theories of the Affinities of Negative Atomic Ions

The determination of the electron affinities of negative atomic ions by means of direct experimental investigation is limited. To supplement the meager experimental results, several semiempirical theories have been advanced. One commonly used technique involves extrapolating the electron affinities along the isoelectronic sequences, The most recent of these extrapolations Is studied by extending the method to Include one more member of the isoelectronic sequence, When the results show that this extension does not increase the accuracy of the calculations, several possible explanations for this situation are explored. A different approach to the problem is suggested by the regularities appearing in the electron affinities. Noting that the regular linear pattern that exists for the ionization potentials of the p electrons as a function of Z, repeats itself for different degrees of ionization q, the slopes and intercepts of these curves are extrapolated to the case of the negative Ion. The method is placed on a theoretical basis by calculating the Slater parameters as functions of q and n, the number of equivalent p-electrons. These functions are no more than quadratic in q and n. The electron affinities are calculated by extending the linear relations that exist for the neutral atoms and positive ions to the negative ions. The extrapolated. slopes are apparently correct, but the intercepts must be slightly altered to agree with experiment. For this purpose one or two experimental affinities (depending on the extrapolation method) are used in each of the two short periods. The two extrapolation methods used are: (A) an isoelectronic sequence extrapolation of the linear pattern as such; (B) the same extrapolation of a linearization of this pattern (configuration centers) combined with an extrapolation of the other terms of the ground configurations. The latter method Is preferable, since it requires only experimental point for each period. The results agree within experimental error with all data, except with the most recent value of C, which lies 10% lower.

Edie, John W.↗
NASA NTRS1993

Continued improvment of large area, in situ sputter deposition of superconducting YBCO thin films

The deposition of thin films of superconducting YBa2Cu3O7-x onto substrates of up to 3-in diameter by an integrated off-axis sputtering is reported. The substrate is located above the center of an 8-in-diameter YBCO planar target, and, in conjunction with a negative ion shield, negative ion effects are avoided. A large radiant heater provides backside, noncontact heating of the bare substrates. YBCO films have been grown on polished 1-cm2 MgO and LaAlO3 substrates with Tc = 90 K or greater, Jc = 2.5 x 10 exp 6 A/sq cm or greater at 77 K, and microwave surface resistance Rs less than 0.4 micro-ohm at 77 K and 10 GHz. The films have a very smooth surface morphology. Uniformity data for LaAlO3 substrates are less than +/-5 percent in Rs. Thickness uniformity results for 3-in substrates indicate less than 10 percent variation. The growth of epitaxial insulating films for use with YBCO films and application of the YBCO films in microwave devices are briefly discussed.

Truman, J. K.↗
NASA NTRS1978

Nonneutral and quasi-neutral diffusion of weakly ionized multiconstituent plasma

A theory is developed for quasi-neutral and nonneutral ambipolar diffusion in a weakly ionized multiconstituent plasma. Magnetic field effects are disregarded. The effects of negative ions and various positive and negative ion diffusion coefficients are identified. It is found that the presence of negative ions leads to enhanced electron diffusion and a retarded diffusion of positive ions. In some cases electrons may be forcibly propelled from the area of perturbations in ionic concentrations. The ambipolar electric field is observed to cause negative ions to flow in a countergradient fashion where the gradient is small. Electrons tend toward a more homogeneous spatial distribution in the nonneutral case than in the quasi-neutral case.

Hill, R. J.↗
NASA NTRS2018

Production of Negative Hydrogen Ions Within the MMS Fast Plasma Investigation Due to Solar Wind Bombardment

The particle data delivered by the Fast Plasma Investigation instrument aboard National Aeronautics and Space Administration's Magnetospheric Multiscale (MMS) mission allow for exceptionally high-resolution examination of the electron and ion phase space in the near-Earth plasma environment. It is necessary to identify populations which originate from instrumental effects. Using Fast Plasma Investigation's Dual Electron Spectrometers, we isolate a high-energy (approximately kiloelectron volt) beam, present while the spacecraft are in the solar wind, which exhibits an azimuthal drift with period associated with the spacecraft spin. We show that this population is consistent with negative hydrogen ions H− generated by a double charge exchange interaction between the incident solar wind H+ ions and the metallic surfaces within the instrument. This interaction is likely to occur at the deflector plates close to the instrument aperture. The H− density is shown to be approximately 0.2-0.4% of the solar wind ion density, and the energy of the negative ion population is shown to be 70% of the incident solar wind energy. These negative ions may introduce errors in electron velocity moments on the order of 0.2-0.4% of the solar wind velocity and significantly higher errors in the electron temperature.

Magnetospheric Multiscale↗
NASA NTRS1991

Negative thermal ion mass spectrometry of osmium, rhenium, and iridium

This paper describes a technique for obtaining, in a conventional surface ionization mass spectrometer, intense ion beams of negatively charged oxides of Os, Re, and Ir by thermal ionization. It is shown that the principal ion species of these ions are OsO3(-), ReO4(-), and IrO2(-), respectively. For Re-187/Os-187 studies, this technique offers the advantage of isotopic analyses without prior chemical separation of Re from Os.

Creaser, R. A.↗
NASA NTRS1987

Field-Reversal Source for Negative Halogen Ions

Large zero-energy electron-attachment cross sections result in intense ion beams. Concept for producing negative halogen ions takes advantage of large cross sections at zero kinetic energy for dissociative attachment of electrons to such halogen-containing gases as SF6, CFCI3, and CCI4.

Chutjian, A.↗
NASA NTRS1995

The effects of CO2 on the negative reactant ions of IMS

In the presence of CO2, the negative reactant ions of ion mobility spectrometry (IMS) are ion clusters of CO4(-) and CO3(-). Methyl salicylate is ionized by the CO4(-)(H2O(n))(N2(m)) reactant ions, but not by the CO3(-)(H2O(n))(N2(m)) reactant ions. While the CO4(-) ions are formed by direct association, the CO3(-) ions require additional energy to be formed. The additional energy is provided by either excited neutral gas molecules in a metastable state or UV (ultraviolet) radiation.

Spangler, Glenn E.↗
NASA NTRS1986

Electrostatic beam instabilities in a positive/negative ion plasma

This paper examines the linear theory of electrostatic waves and instabilities in an unmagnetized, homogeneous Vlasov plasma. The first configuration considered is that of a stable plasma with three Maxwellian components: electrons, positive ions, and negative ions. The dispersion properties of the lightly damped ion modes are studied as a function of relative electron density and relative component temperatures. The second configuration considered is that of a tenuous electron-ion beam with drift speed streaming through a negative/positive ion plasma. If the beam is very tenuous, an electron beam instability is excited; if the beam is more dense, the instability becomes Buneman-like with parabolic dispersion. The thresholds and maximum growth rates of these instabilities are described as functions of the beam density and drift speed.

Galvez, Miguel↗
NASA NTRS1993

Theory and operation of a three-gate time-of-flight velocity analyzer

Theoretical considerations and test results are presented for a new-type velocity analyzer for incident fast neutral particles, positive ions, and negative ions. Velocity analysis is carried out by means of a pulsed, three-gate time-of-flight (TOF) technique capable of eliminating alias velocities (harmonics) to sixth order. In addition the design and operation are presented of a four-element ion lens system, with small spherical and chromatic aberrations, suitable for interfacing a large-diameter ion beam from the TOF section with a subsequent mass analyzer.

Martus, K. E.↗
NASA NTRS1983

New calculation of the properties of the positronium ion

The positronium negative ion Ps(-), the system composed of two electrons and a positron, has been reinvestigated theoretically. Using a Hylleraas wave function with two nonlinear parameters and more than 200 linear terms, excellent values of binding energy and annihilation lifetime of the particle-stable 1Se ground state have been obtained. In addition, the question of stability of the 3Pe state discussed by Mills has been examined and it is agreed with his conclusion that the state is probably not stable against breakup into Ps(n = 2) + e(-). Improved limits on the critical 'positron' mass for binding the 3Pe state have also been obtained.

Bhatia, A. K.↗
NASA NTRS1994

A future, intense source of negative hydrogen ions

By directly heating lithium hydride in a vacuum, up to 18 micro-A/sq cm of negative hydrogen has been obtained from the crystal lattice. The amount of ion current extracted and analyzed is closely related to the temperature of the sample and to the rate at which the temperature is changed. The ion current appears to be emission limited and saturates with extraction voltage. For a fixed extraction voltage, the ion current could be maximized by placing a grid between the sample surface and the extraction electrode. Electrons accompanying the negative ions were removed by a magnetic trap. A Wein velocity filter was designed and built to provide definitive mass analysis of the extracted ion species. This technique when applied to other alkali hydrides may produce even higher intensity beams possessing low values of emittance.

Siefken, Hugh↗