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At least 91 records · Page 5

Continued investigation of kinetic aspects of bone mineral metabolism

The total body calcium in humans was determined by measuring expired Ar-37 after neutron irradiation. The excretion of Ar-37 from humans was found to be much slower than the excretion from rats and dogs, and to be related to the age of a person. A study of the uniformity of the Ar-37 production throughout the thickness of the body was studied using phantoms. The results indicate that it should be possible to obtain a uniformity within plus or minus 3% for the production of Ar-37 per unit of calcium by using a bilateral irradiation. New low background, large volume proportional counters were developed and constructed, for more sensitive measurement of Ar-37 in the expired air from patients. A new irradiation enclosure was developed for measuring total body calcium in rats by the Ar-37 method. With this enclosure the Ar-37 production per gram of calcium is constant with a standard deviation of plus or minus 2.8% for any size rat between 100 and 500 grams. The use of Na-22 as measure of bone replacement in the fractured femur of a dog was not successful.

Palmer, H. E.↗

Lunar evolution - The first 600 million years

From a stepwise-heating experiment on neutron-irradiated samples of whole rock and a plagioclase separate, an Ar-40/Ar-39 age of 4.26 plus or minus 0.02 G.y. was determined for the Apollo 17 troctolite 76535. This rock is believed to have formed as a result of very slow cooling at a depth of 10 to 40 km, and hence furnishes direct evidence that the moon was chemically zoned before 4.26 G.y. The age of the rock is associated with the Serenitatis Basin forming event. The formation of the Serenitatis Basin is then deduced to have occurred 4.26 plus or minus 0.02 G.y. ago, about 300 m.y. before the Imbrium event. It appears that the major basin forming era on the near side of the moon lasted longer than 300 m.y. The grouping of many lunar rock ages at 3.9 to 4.0 G.y. is most likely due to the fact that the Imbrium ejecta predominates all highland landing sites.

Husain, L.↗

Regional measurement of body nitrogen

Studies of methods for determining changes in the muscle mass of arms and legs are described. N-13 measurements were made in phantom and cadaver parts after neutron irradiation. The reproducibility in these measurements was found to be excellent and the radiation dose required to provide sufficient activation was determined. Potassium-40 measurements were made on persons who lost muscle mass due to leg injuries. It appears that K-40 measurements may provide the most accurate and convenient method for determining muscle mass changes.

Palmer, H. E.↗

K/Ar dating of lunar soils. II

An attempt is made to identify those K/Ar techniques which extract the most reliable chronological information from lunar soils and to define the situations in which the best data are obtainable. Results are presented for determinations of the exposure and K/Ar ages of five lunar soil samples, which were performed by applying correlation techniques for a two-component argon structure to stepwise-heated and neutron-irradiated aliquots of grain-sized separates. It is found that ages deduced from Ar-40/surface-correlated Ar-36 vs K-40/surface-correlated Ar-36 and analogous plots of data from grain-sized separates appear to be the best available K/Ar ages of submature to mature lunar soils, that ages deduced from Ar-40 vs Ar-36 and analogous plots which assume a uniform K content can be significantly in error, and that stepwise-heating (Ar-40)-(Ar-39) experiments yield useful information only for simple immature soils where the K-Ar systematics are dominated by a single component.

Alexander, E. C., Jr.↗

The realities of recoil - Ar-39 recoil out of small grains and anomalous age patterns in Ar-39-Ar-40 dating

Excess Ar-39 in olivine from neutron-irradiated mixtures of olivine and K-rich glass was measured to determine the amount of Ar-39 transferred by recoil out of the glass and into the surrounding olivine grains. It was found that a total of 9.0% of the total Ar-39 recoiled out of the 3-micron glass grains and 2.45% out of the 15-micron glass grains. The mean depth of Ar-39 depletion of the surface of the glass grains was 0.1 micron.

Huneke, J. C.↗

Remote in-situ elemental analysis systems for underwater application

The systems approach, theoretical measurement calculations, and preliminary measurements to be used in monitoring and mapping pollutants (such as traces of heavy metals) in the Chesapeake Bay are discussed. A neutron gamma-ray method is under development for demonstrating the system. The excitation source to be used is a machine accelerator using a deuterium/tritium reaction to produce 14-MeV neutrons. The neutrons excite characteristic gamma ray emission from the neutron irradiated surface. The discrete line emission produced can be used to infer both qualitative and quantitative elemental composition. A data preprocessor will accumulate, digitize, store, format, and prepare the data for transmission which can be accomplished by telephone, microwave, and possibly satellite link to central processors.

Trombka, J. I.↗

Laser Ar-39-Ar-40 study of Apollo 17 basalts

Three Apollo 17 basalts were studied by the laser Ar-39-Ar-40 method. The 70215 basalt has a normal well-behaved Ar-39-Ar-40 release pattern; the 70017 basalt has a disturbed release pattern which indicates a limited intermediate maximum age followed by a broad low-age region; and the 75035 basalt has a pattern initially similar to 70017 that is followed by a high-temperature maximum age. The laser study shows that all mineral systems in 70215 have small and uniform temperature losses, while the laser-determined ages for 70017 and 75035 are, apparently, primarily controlled by the minerals containing mesostasis inclusions. It is possible that the drop in ages observed by the conventional Ar-39-Ar-40 method was due not only to recoil of Ar-39 during neutron irradiation but also to gas loss from some minerals. It is suggested that the plagioclases are the best minerals to use for a reliable age.

Schaeffer, O. A.↗

I-Xe dating of silicate and troilite from IAB iron meteorites

Silicate and troilite inclusions from IAB iron meteorites were dated by the I-Xe technique. Silicate samples from inclusions in the Copiapo, Landes, Woodbine, Pitts and Mundrabilla meteorites and troilite samples from Pitts and Mundrabilla were subjected to neutron irradiation and the xenon isotope ratios produced were determined. Well-defined I-Xe ages were obtained for Woodbine, Copiapo, Landes and Mundrabilla and are found to be within 3.7 million years of the Bjurbole meteorite, suggesting a close relationship to the stone chondrites. The analysis of troilite from Pitts suggests an age of 17 million years older than Bjurbole, while Mundrabilla troilite is observed to predate Mundrabilla silicate. The abundances of Ga, Ge and Ni are found to be correlated with I-Xe ages, supporting the validity of the I-Xe dating method. The results are considered to favor a nebular model of meteorite formation.

Niemeyer, S.↗

The reaction Mg/n, alpha/Ne at 14.1 and 14.7 MeV - Cross sections and implications for meteorites

Mass spectroscopic analysis of neutron-irradiated targets of natural magnesium yields cross sections of 59 + or - 14, 160 + or - 8, and 11.0 + or - 3.3 mb for Ne-20, Ne-21 and Ne-22, respectively, at 14.1 MeV and of 94 + or - 8, 152 or - 12, and 13.0 + or - 2.0 mb at 14.7 Mev. Using these cross sections, calculations modeling cosmic ray interactions in stony meteoroids of radii 20 and 26 cm predict that between the surface and the center the Ne-22/Ne-21 ratio falls more than 10% while the Ne-21 production rate rises about 30%. Calculations are compared with published neon measurements for the Keyes and St. Severin meteorites.

Reedy, R. C.↗

High power thyristors with 5 kV blocking voltage. Volume 1: Development of high-voltage-thyristors (4.5 kV) with good dynamic properties

Using neutron irradiated silicon with considerably lower spread in resistivity as compared to conventionally doped silicon it was possible to produce power thyristors with breakdown voltages between 3.5 kV and 5.5 kV. The thyristor pellets have a diameter of 50 mm. Maximum average on-state currents of 600 to 800 A can be reached with these elements. The dynamic properties of the thryistors could be improved to allow standard applications up to maximum repetitive voltages of 4.5 kV.

Lock, K.↗

I-Xe age and trapped Xe components of the Murray /C-2/ chondrite

A neutron-irradiated bulk sample of the Murray (C-2) carbonaceous chondrite was etched with H2O2 and then divided into colloidal and non-colloidal fractions. The H2O2 treatment removed about 80% of the trapped Xe and greatly increased variations in the Xe-129/Xe-132 ratio measured in stepwise heating. The colloid showed very little excess Xe-129, but the anti-colloid gave a fairly good I-Xe correlation corresponding to formation 3.7 + or - 2.1 m.y. after Bjurbole. Variations in the trapped Xe component were also observed; most notably the 550 C anti-colloid fraction has large deficiencies relative to AVCC at the heavy isotopes.

Niemeyer, S.↗

Ar-39/Ar-40 systematics of Allende inclusions

A laser microprobe was used to measure the Ar isotopic contents of individual mineral grains in four neutron-irradiated Allende samples: two coarse-grained Ca-Al-rich inclusions; one fine-grained Ca-Al-rich inclusion; and one sample with matrix and miscellaneous chondrules. The following K-Ar ages (G.y.) were obtained after degassing low Ar retentive sites by preheating the samples for one hour at 675 C: matrix, 3.5 + or - 0.2; three miscellaneous chondrules, 4.4 + or - 0.1, 4.0 + or - 0.1, and 4.4 + or - 0.1; and the fine-grained inclusion, 4.5 + or - 0.2. The minerals in the coarse-grained Ca-Al-rich inclusions have ubiquitous chlorine, less than 10 ppm K and apparent ages ranging upwards from 4.6 G.y. to well over 10 G.y. Possible explanations for these apparent ages are atmospheric contamination, the decay of K-40 prior to the formation of the solar system, and the trapping of radiogenic Ar-40 lost by the matrix.

Herzog, G. F.↗

Advanced development of double-injection, deep-impurity semiconductor switches

Deep-impurity, double-injection devices, commonly refered to as (DI) squared devices, represent a class of semiconductor switches possessing a very high degree of tolerance to electron and neutron irradiation and to elevated temperature operation. These properties have caused them to be considered as attractive candidates for space power applications. The design, fabrication, and testing of several varieties of (DI) squared devices intended for power switching are described. All of these designs were based upon gold-doped silicon material. Test results, along with results of computer simulations of device operation, other calculations based upon the assumed mode of operation of (DI) squared devices, and empirical information regarding power semiconductor device operation and limitations, have led to the conculsion that these devices are not well suited to high-power applications. When operated in power circuitry configurations, they exhibit high-power losses in both the off-state and on-state modes. These losses are caused by phenomena inherent to the physics and material of the devices and cannot be much reduced by device design optimizations. The (DI) squared technology may, however, find application in low-power functions such as sensing, logic, and memory, when tolerance to radiation and temperature are desirable (especially is device performance is improved by incorporation of deep-level impurities other than gold.

Hanes, M. H.↗

I-Xe systematics in LL chondrites

A stepwise heating analysis of Ar and Xe data from five neutron-irradiated whole rock LL chondrites (Soko Banja, Alta Ameen, Tuxtuac, Guidder, and Olivenza) is presented, emphasizing the complicated thermal history of ordinary chondrites. None of the present meteorites show a well-defined (Ar-40)-(Ar-39) apparent age plateau comprised of more than two release fractions. Most of the samples are found to yield well-defined high-temperature correlations between Xe-129/Xe-130 and Xe-128/Xe-130, and thus determinations of I-129/I-127 and Xe-129/Xe-130 at the time of isotopic closure for Xe. As in the case of other ordinary chondrites, the I-Xe systematics for LL chondrites correlate neither with a metamorphic grade nor with chronologies based opon other methods.

Bernatowicz, T. J.↗

The early solar system abundance of Pu-244 as inferred from the St. Severin chondrite

The isotopic composition of Xe released in stepwise heating of neutron-irradiated samples of the St. Severin chondrite was measured. This analysis shows that at the time of formation of most chondritic meteorites, approximately 4.56 x 10 to the 9th yr ago, the atomic ratio of Pu-244/U-238 was 0.0068 + or - 0.0010 in chondritic meteorites. This value is believed to be more reliable that inferred from earlier analyses of St. Severin and is the best estimate for the early solar system abundance of Pu-244. The comparison of Xe compositions between irradiated and unirradiated samples shows that the composition of trapped (ambient) Xe in St. Severin has a significantly lower value of Xe-136/Xe-130 than average carbonaceous chondrites.

Hudson, G. B.↗

Heavy-element abundances from a neutron burst that produces Xe-H

We examine quantitatively the suggestion that the heavy anomalous isotopes of Xe-HL found in meteoritic diamonds were produced by a short intense neutron burst and then implanted into the diamonds. Using a large nuclear reaction network we establish one (out of many) neutron irradiation hostories that successfully reproduces the heavy isotopes of Xe-HL, and then evaluate what that same history would produce in every heavy element. This has become more relevant following recent measurement of anomalous Ba and Sr in those same diamond samples. Therefore we offer these calculations as a guide to the anomalies to be expected in all elements if this scenario is correct. We also discuss several other aspects of the problem, especially the established contradictions for Ba, the observed Kr pattern, the near normalcy of Xe-129 and some related astrophysical ideas. In particular we argue from p-process theory that the observed deficit of Kr-78 in correlation with Xe-(124-126) excess implicates Type II supernovae as the diamond sources.

Howard, W. M.↗

Rhenium-osmium isotope systematics of ordinary chondrites and iron meteorites

Using negative thermal ionization mass spectrometry, Re and Os abundances were determined by isotope dilution and Os-187/Os-186 measured in 11 ordinary chondrites, and also in 1 IIB and 3 IIIB irons. In addition, Os-186/Os-188 and Os-189/Os-188 ratios were precisely determined for 3 unspiked ordinary chondrites as a means of constraining the intensity of any neutron irradiation these meteorites may have experienced.

Walker, R. J.↗

Noble gas isotopes and halogens in volatile-rich inclusions in diamonds

Application of the (40)Ar-(39)Ar method and noble gas studies to diamonds has increased our understanding of their age relationships to the host kimberlite or lamproite, and of the source and composition of volatile-rich fluids in the upper mantle. The properties of diamond (inert, high mechanical strength and low gas diffusivities) means they are especially useful samples for studying gases trapped deep within the earth (less than 150 km) as they are unlikely to have undergone loss or exchange of entrapped material since formation. Volatile-rich fluids (H2O-CO2) are important agents for metasomatic processes in the upper mantle, and the noble gases and halogens preferentially partition into this phase leading to a strong geochemical coherence between these groups of elements. The abundances of the halogens in the major reservoirs of the Earth shows a marked progression from chlorine, concentrated in the oceans, through to iodine which, through its affinity to organic material, is concentrated mainly in sediments. Abundances in the upper mantle are low. This is particularly true for iodine which is of special interest in view of its potential significance as an indicator of sediment recycling and by way of its link to (129)Xe amomalies in the mantle through the low extinct isotope (129)I. Extensions of the (40)Ar-(39)Ar technique enable measurements of halogens and other elements (K, Ca, Ba, U) by production of noble gas isotopes from these species during neutron irradiation. Samples analyzed in this way include 15 coated stones from an unknown source in Zaire, 3 boarts from the Jwaneng and 1 boart from the Orapa kimberlites, both in Botswana.

Burgess, Raymond↗