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At least 91 records · Page 5

Backside damage-gettering in cast polycrystalline silicon

The technique of backside-damage gettering improves the performance of short minority-carrier diffusion length, large-grain (grain diameter greater than 1 to 2 mm), cast polycrystalline silicon. On average, increases of nearly 20 percent in short-circuit current, 10 mV in open-circuit voltage, and 15 percent in peak-power were obtained by heat-treating 300 micron thick polycrystalline wafers at 1000 C in flowing nitrogen for 5 hours. Additional measurements of the bulk and space-charge recombination current components indicate that this improvement results from a significant increase in the minority-carrier diffusion length due to gettering of impurities from the bulk.

Culik, J.↗

Modeling of the WSTF frictional heating apparatus in high pressure systems

In order to develop a computer program able to model the frictional heating of metals in high pressure oxygen or nitrogen a number of additions have been made to the frictional heating model originally developed for tests in low pressure helium. These additions include: (1) a physical property package for the gases to account for departures from the ideal gas state; (2) two methods for spatial discretization (finite differences with quadratic interpolation or orthogonal collocation on finite elements) which substantially reduce the computer time required to solve the transient heat balance; (3) more efficient programs for the integration of the ordinary differential equations resulting from the discretization of the partial differential equations; and (4) two methods for determining the best-fit parameters via minimization of the mean square error (either a direct search multivariable simplex method or a modified Levenburg-Marquardt algorithm). The resulting computer program has been shown to be accurate, efficient and robust for determining the heat flux or friction coefficient vs. time at the interface of the stationary and rotating samples.

Skowlund, Christopher T.↗

Grain surface features of Apollo 17 orange and black glass

Lunar soil sample 74220 and core samples 74001/2 consist mainly of orange glass droplets, droplet fragments, and their crystallized equivalents. These samples are now generally accepted to be pyroclastic ejecta from early lunar volcanic eruptions. It has been known that they contain surface coatings and material rich in volatile condensable phases including S, Zn, F, Cl, and many volatile metals. Meyer summarizes the voluminous published chemical data and calculates the volatile enrichment ratios for most of the surface condensates. In an attempt to more completely understand this enrichment of surface volatiles, we have searched for carbon and carbon-bearing phases on droplet surfaces. We have reviewed many of our existing photomicrographs and energy dispersive analysis (EDX) of grain surfaces and have reexamined some of our older SEM mounts using an improved EDXA system capable of light element detection and analysis (oxygen, nitrogen, and carbon). In addition, we have made fresh mounts using procedures which should minimize carbon contamination or extraneous carbon x-rays and have analyzed for carbon.

Mckay, David S.↗

Significant Tropospheric O3 Production from Extratropical Forest Fires:When? When Not?

There is significant controversy on whether extratropical fires contribute importantly to widespread ozone productionabsent the addition of urban pollutant nitrogen oxides (Jaffe and Widger, 2012, Singh et al., 2012,2013). Wereport a significant range of O3 production early in the fire plume history and report controls on which notable O3production occurs. The current data set is the airborne observations made on board NASAs highly instrumentedDC-8 aircraft during the ARCTAS (2008) and SEAC4RS (2013) campaigns within the Western United States. Aclear analysis of fire emissions was aided considerably by MERET (a Mixed Effects Regressions Emissions Technique).This technique allows consistent emission factors and enhancement ratios for O3 for individual aircraftsamples largely free from uncertainties resulting from mixing and entrainment which plague many published estimates.(Yokelson et al, 2013, Chatfield and Andreae, 2016). We find support for the reasonable idea that the ratioof nitrogen oxides (NOx) to volatile organic carbon (VOC) emissions controls new O3 production. The evidence isfor significant O3 production from high-fuel-nitrogen fuels (as evidenced by acetonitrile) and extremely hot largefires (like the Yosemite Rim Fire of 2013 which we analyze), while others do not. VOC emissions factors varysignificantly from fire to fire (and from different samples in the Rim Fire). Relative CO production (aka modifiedcombustion efficiency) is only one factor describing VOC emissions factors.

Chatfield, R.↗

Further studies of the new component of cosmic rays at low energies

Recent observations with cosmic ray telescopes aboard the Pioneer 10 space probe have revealed an anomalous spectrum of nitrogen and oxygen nuclei relative to other nuclei such as carbon in the quiet time cosmic radiation below about 40 MeV/nuc. These observations are extended with additional data from Pioneer 10 and considerable new data from an identical telescope aboard Pioneer 11. In addition to the enhancement of nitrogen and oxygen nuclei observed earlier, the intensity of neon is enhanced as well. The spectra of boron, magnesium, and silicon appear to be similar to that of carbon. Data on the isotopic composition, solar modulation, and radial gradient of these nuclei are presented.

Webber, W. R.↗

Plant features measurements for robotics

Initial studies of the technical feasibility of using machine vision and color image processing to measure plant health were performed. Wheat plants were grown in nutrient solutions deficient in nitrogen, potassium, and iron. An additional treatment imposed water stress on wheat plants which received a full complement of nutrients. The results for juvenile (less than 2 weeks old) wheat plants show that imaging technology can be used to detect nutrient deficiencies. The relative amount of green color in a leaf declined with increased water stress. The absolute amount of green was higher for nitrogen deficient leaves compared to the control plants. Relative greenness was lower for iron deficient leaves, but the absolute green values were higher. The data showed patterns across the leaf consistent with visual symptons. The development of additional color image processing routines to recognize these patterns would improve the performance of this sensor of plant health.

Miles, Gaines E.↗

Inhibiting Wet Oxidation of Ammonia

Simple modification of wet-oxidation process for treating organicwaste reduces loss of fixed nitrogen, potentially valuable byproduct of process. Addition of sufficient sulfuric acid to maintain reaction pH below 3 greatly reduces oxidation of ammonia to free nitrogen. No equipment modification required.

Onisko, D. B. L.↗

Stable isotopic biogeochemistry of carbon and nitrogen in a perennially ice-covered Antarctic lake

Lake Hoare (77 degrees 38' S, 162 degrees 53' E) is an amictic, oligotrophic, 34-m-deep, closed-basin lake in Taylor Valley, Antarctica. Its perennial ice cover minimizes wind-generated currents and reduces light penetration, as well as restricts sediment deposition into the lake and the exchange of atmospheric gases between the water column and the atmosphere. The biological community of Lake Hoare consists solely of microorganisms -- both planktonic populations and benthic microbial mats. Lake Hoare is one of several perennially ice-covered lakes in the McMurdo Dry Valleys that represent the end-member conditions of cold desert and saline lakes. The dry valley lakes provide a unique opportunity to examine lacustrine processes that operate at all latitudes, but under an extreme set of environmental conditions. The dry valley lakes may also offer a valuable record of catchment and global changes in the past and present. Furthermore, these lakes are modern-day equivalents of periglacial lakes that are likely to have been common during periods of glacial maxima at temperate latitudes. We have analyzed the dissolved inorganic carbon (DIC) of Lake Hoare for delta 13C and the organic matter of the sediments and sediment-trap material for delta 13C and delta 15N. The delta 13C of the DIC indicates that 12C is differentially removed in the shallow, oxic portions of the lake via photosynthesis. In the anoxic portions of the lake (27-34 m) a net addition of 12C to the DIC pool occurs via organic matter decomposition. The dissolution of CaCO3 at depth also contributes to the DIC pool. Except near the Canada Glacier where a substantial amount of allochthonous organic matter enters the lake, the organic carbon being deposited on the lake bottom at different sites is isotopically similar, suggesting an autochthonous source for the organic carbon. Preliminary inorganic carbon flux calculations suggest that a high percentage of the organic carbon fixed in the water column is remineralized as it falls through the water column. At nearby Lake Fryxell, the substantial (relative to Lake Hoare) glacial meltstream input overprints Fryxell's shallow-water biological delta 13C signal with delta 13C-depleted DIC. In contrast, Lake Hoare is not significantly affected by surface-water input and mixing, and therefore the delta 13C patterns observed arise primarily from biological dynamics within the lake. Organic matter in Lake Hoare is depleted in 15N, which we suggest is partially the result of the addition of relatively light inorganic nitrogen into the lake system from terrestrial sources.

NASA Program Exobiology↗

International Space Station (ISS) Gas Logistics Planning in the Post Shuttle Era

Over its life the International Space Station (ISS) has received gas (nitrogen, oxygen, and air) from various sources. Nitrogen and oxygen are used in the cabin to maintain total pressure and oxygen partial pressures within the cabin. Plumbed nitrogen is also required to support on-board experiments and medical equipment. Additionally, plumbed oxygen is required to support medical equipment as well as emergency masks and most importantly EVA support. Gas are supplied to ISS with various methods and vehicles. Vehicles like the Progress and ATV deliver nitrogen (both as a pure gas and as air) and oxygen via direct releases into the cabin. An additional source of nitrogen and oxygen is via tanks on the ISS Airlock. The Airlock nitrogen and oxygen tanks can deliver to various users via pressurized systems that run throughout the ISS except for the Russian segment. Metabolic oxygen is mainly supplied via cabin release from the Elektron and Oxygen Generator Assembly (OGA), which are water electrolyzers. As a backup system, oxygen candles (Solid Fuel Oxygen Generators-SFOGs) supply oxygen to the cabin as well. In the past, a major source of nitrogen and oxygen has come from the Shuttle via both direct delivery to the cabin as well as to recharge the ISS Airlock tanks. To replace the Shuttle capability to recharge the ISS Airlock tanks, a new system was developed called Nitrogen/Oxygen Recharge System (NORS). NIORS consists of high pressure (7000 psi) tanks which recharge the ISS Airlock tanks via a blowdown fill for both nitrogen and oxygen. NORS tanks can be brought up on most logistics vehicles such as the HTV, COTS, and ATV. A proper balance must be maintained to insure sufficient gas resources are available on-orbit so that all users have the required gases via the proper delivery method (cabin and/or plumbed).

Leonard, Daniel J.↗

Design and test of porous-tungsten mercury vaporizers

Future use of large size Kaufman thrusters and thruster arrays will impose new design requirements for porous plug type vaporizers. Larger flow rate coupled with smaller pores to prevent liquid intrusion will be desired. The results of testing samples of porous tungsten for flow rate, liquid intrusion pressure level, and mechanical strength are presented. Nitrogen gas was used in addition to mercury flow for approximate calibration. Liquid intrusion pressure levels will require that flight thruster systems with long feed lines have some way (a valve) to restrict dynamic line pressures during launch.

Kerslake, W. R.↗

Dissociation-excitation reactions of argon metastables with carbon dioxide.

Results of a study showing that a metastable argon-carbon dioxide reaction results in dissociation of carbon dioxide and electronic excitation of one of the products, carbon monoxide or oxygen. A flow system using a 2450-MHz discharge was used to produce metastable argon atoms. Metastable argon in the afterglow was confirmed by adding nitrogen to the afterglow. Without addition of carbon dioxide no argon line emission, or any other emission, is observed from the reaction zone. Absence of argon line emission produced by recombination indicates the absence of charged species.

Starr, W. L.↗

Design and test of porous-tungsten mercury vaporizers.

Future use of large size Kaufman thrusters and thruster arrays will impose new design requirements for porous plug type vaporizers. Larger flow rate coupled with smaller pores to prevent liquid intrusion will be desired. This paper presents the results of testing samples of porous tungsten for flow rate, liquid intrusion pressure level, and mechanical strength. Nitrogen gas was used in addition to mercury flow for approximate calibration. Liquid intrusion pressure levels will require that flight thruster systems with long feed lines have some way (a valve) to restrict dynamic line pressures during launch.

Kerslake, W. R.↗

The effect of photochemical models on calculated equilibria and cooling rates in the stratosphere

Simplified models were developed for radiative heating and cooling and for ozone photochemistry in the region 22-60 km. The latter permit the inclusion of nitrogen and hydrogen reactions in addition to simple oxygen reactions. The simplicity of the scheme facilitates the use of a wide variety of cooling and reaction rates. It is shown that joint radiative-photochemical equilibrium is appropriate to the mean state of the atmosphere between 35 and 60 km. The relaxation of perturbations from joint radiative-photochemical equilibrium was also investigated. In all cases the coupling between temperature dependent ozone photochemistry and radiation lead to a reduction of the thermal relaxation time from its purely radiative value. The latter, which amounts to about 10 days, is reduced to 2-4 days at heights of 31-35 km. This greatly enhances the dissipation of waves traveling through the stratosphere.

Blake, D.↗

MSIS-86 thermospheric model

The MSIS-86 empirical model of thermospheric temperature, density and composition uses new temperature and composition data from the Dynamics Explorer satellite to improve the representation of polar region morphology over that in the MSIS-83 model. Terms were added or changed to better represent seasonal variations in the polar regions under both quiet and magnetically disturbed conditions. Local time variations in the magnetic activity effect were added. In addition a new species, atomic nitrogen, was added to the previous list of N2, O2, He, O, H, and Ar covered by the model.

Hedin, Alan E.↗

Simulation and control of a Space Station air revitalization system

A computer simulation tool is written to investigate simulation and control of a Space Station air revitalization system. Candidate subsystems for various air revitalization roles in the Space Station have been and continue to be tested. However, integration and control of these subsystems into an effective system which revitalizes the air in all habitable areas needs to be evaluated. From such an evaluation, the size of subsystems, size and location of accumulators, and decisions on bussing of carbon dioxide, hydrogen, oxygen, and nitrogen can be affected. In addition, various control approaches can be assessed. The computer simulation model is described and its applications are presented.

Yanosy, James L.↗

Heterogeneous chemistry related to Antarctic ozone depletion: Reaction of ClONO2 and N2O5 on ice surfaces

Laboratory studies of heterogeneous reactions of possible importance for Antarctic ozone depletion were performed. In particular, the reactions of chlorine nitrate (ClONO2) and dinitrogen pentoxide (N2O5) were investigated on ice and HCl/ice surfaces. These reactions occur on the surfaces of polar stratospheric clouds (PSCs) over Antarctica. One reaction transforms the stable chlorine reservoir species (ClONO2 and HCl) into photochemically active chlorine in the form of HOCl and Cl2. Condensation of HNO3 in the reactions removes odd nitrogen from the stratosphere, a requirement in nearly all models of Antarctic ozone depletion. Other reactions may also be important for Antarctic ozone depletion. Like the reactions of chlorine nitrate, these reactions deplete odd nitrogen through HNO3 condensation. In addition, one reaction converts a stable chlorine reservior species (HCl) into photochemically active chlorine (ClNO2). These reactions were studied with a modified version of a Knudsen cell flow reactor.

Tolbert, Margaret A.↗

A computer control system for the alternating gradient magnetometer

An alternating gradient magnetometer was interfaced to a computer for the automation of data taking. Using a fast Fourier transform analysis system data can be acquired and processed in real time. Data are stored on disk and can be recalled for plotting and further analysis. With the addition of a simple liquid nitrogen cryostat, magnetization measurements can be performed in the range from 300 to 77 K. Results are reported on three different types of piezoelectric transducers.

Garland, Michael M.↗