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NASA NTRS2003

Ocean Optics Protocols for Satellite Ocean Color Sensor Validation: Special Topics in Ocean Optics Protocols and Appendices - Volume 6

This document stipulates protocols for measuring bio-optical and radiometric data for the Sensor Intercomparison and Merger for Biological and Interdisciplinary Oceanic Studies (SIMBIOS) Project activities and algorithm development. The document is organized into 6 separate volumes as Ocean Optics Protocols for Satellite Ocean Color Sensor Validation, Revision 4. Volume I: Introduction, Background and Conventions; Volume II: Instrument Specifications, Characterization and Calibration; Volume III: Radiometric Measurements and Data Analysis Methods; Volume IV: Inherent Optical Properties: Instruments, Characterization, Field Measurements and Data Analysis Protocols; Volume V: Biogeochemical and Bio-Optical Measurements and Data Analysis Methods; Volume VI: Special Topics in Ocean Optics Protocols and Appendices. The earlier version of Ocean Optics Protocols for Satellite Ocean Color Sensor Validation, Revision 3 (Mueller and Fargion 2002, Volumes 1 and 2) is entirely superseded by the six volumes of Revision 4 listed above.

Mueller, J. L.↗

NASA NTRS2003

Ocean Optics Protocols for Satellite Ocean Color Sensor Validation: Inherent Optical Properties: Instruments, Characterizations, Field Measurements and Data Analysis Protocols - Volume 4

Mueller, J. L.↗

NASA NTRS2003

Ocean Optics Protocols for Satellite Ocean Color Sensor Validation, Revision 4, Volume IV: Inherent Optical Properties: Instruments, Characterizations, Field Measurements and Data Analysis Protocols

This document stipulates protocols for measuring bio-optical and radiometric data for the Sensor Intercomparision and Merger for Biological and Interdisciplinary Oceanic Studies (SIMBIOS) Project activities and algorithm development. The document is organized into 6 separate volumes as Ocean Optics Protocols for Satellite Ocean Color Sensor Validation, Revision 4. Volume I: Introduction, Background, and Conventions; Volume II: Instrument Specifications, Characterization and Calibration; Volume III: Radiometric Measurements and Data Analysis Methods; Volume IV: Inherent Optical Properties: Instruments, Characterization, Field Measurements and Data Analysis Protocols; Volume V: Biogeochemical and Bio-Optical Measurements and Data Analysis Methods; Volume VI: Special Topics in Ocean Optics Protocols and Appendices. The earlier version of Ocean Optics Protocols for Satellite Ocean Color Sensor Validation, Revision 3 is entirely superseded by the six volumes of Revision 4 listed above.

Mueller, J. L.↗

NASA NTRS2004

Optical Modeling Activities for the James Webb Space Telescope (JWST) Project: Determining Image Motion and Wavefront Error Over an Extended Field of View with a Segmented Optical System - II

This is part two of a series on the optical modeling activities for JWST. Starting with the linear optical model discussed in part one, we develop centroid and wavefront error sensitivities for the special case of a segmented optical system such as JWST, where the primary mirror consists of 18 individual segments. Our approach extends standard sensitivity matrix methods used for systems consisting of monolithic optics, where the image motion is approximated by averaging ray coordinates at the image and residual wavefront error is determined with global tip/tilt removed. We develop an exact formulation using the linear optical model, and extend it to cover multiple field points for performance prediction at each instrument aboard JWST. This optical model is then driven by thermal and dynamic structural perturbations in an integrated modeling environment. Results are presented.

Howard, Joseph M.↗

NASA NTRS2005

Optical Air Flow Measurements for Flight Tests and Flight Testing Optical Air Flow Meters

Optical air flow measurements can support the testing of aircraft and can be instrumental to in-flight investigations of the atmosphere or atmospheric phenomena. Furthermore, optical air flow meters potentially contribute as avionics systems to flight safety and as air data systems. The qualification of these instruments for the flight environment is where we encounter the systems in flight testing. An overview is presented of different optical air flow measurement techniques applied in flight and what can be achieved with the techniques for flight test purposes is reviewed. All in-flight optical airflow velocity measurements use light scattering. Light is scattered on both air molecules and aerosols entrained in the air. Basic principles of making optical measurements in flight, some basic optical concepts, electronic concepts, optoelectronic interfaces, and some atmospheric processes associated with natural aerosols are reviewed. Safety aspects in applying the technique are shortly addressed. The different applications of the technique are listed and some typical examples are presented. Recently NASA acquired new data on mountain rotors, mountain induced turbulence, with the ACLAIM system. Rotor position was identified using the lidar system and the potentially hazardous air flow profile was monitored by the ACLAIM system.

Jentink, Henk W.↗

NASA NTRS2021

Modeling the Prompt Optical Emission of GRB 180325A: The Evolution of a Spike from the Optical to Gamma Rays

The transition from prompt to afterglow emission is one of the most exciting and least understood phases in gamma-ray bursts (GRBs). Correlations among optical, X-ray, and gamma-ray emission in GRBs have been explored, to attempt to answer whether the earliest optical emission comes from internal and/or external shocks. We present optical photometric observations of GRB 180325A collected with the TAROT and RATIR ground-based telescopes. These observations show two strong optical flashes with separate peaks at ∼50 and ∼120 s, followed by a temporally extended optical emission. We also present X-rays and gamma-ray observations of GRB 180325A, detected by the Burst Alert Telescope and X-ray Telescope, on the Neil Gehrels Swift observatory, which both observed a narrow flash at ∼80 s. We show that the prompt gamma-ray and X-ray early emission shares similar temporal and spectral features consistent with internal dissipation within the relativistic outflow (e.g., by internal shocks or magnetic reconnection), while the early optical flashes are likely generated by the reverse shock that decelerates the ejecta as it sweeps up the external medium.

R. L. Becerra↗

DOE OSTI2021

Deep Optical Switching on Subpicosecond Timescales in an Amorphous Ge Metamaterial

Active nanostructured optical components show promise as potential building blocks for novel light-based computing and data processing architectures. However, nanoscale all-optical switches that have low activation powers and high-contrast ultrafast switching have been elusive so far. Here, pump–probe measurements performed on amorphous-Ge-based micro-resonator metasurfaces that exhibit strong resonant modes in the mid-infrared are reported. Relative change is observed in transmittance of ΔT/T ≈ 1 with picosecond (down to τ ≈ 0.5 ps) free carrier relaxation rates, obtained with very low pump fluences of 50 μJ cm –2 . In this work, these observations are attributed to efficient free carrier promotion, affecting light transmittance via high quality-factor optical resonances, followed by an increased electron–phonon scattering of free carriers due to the amorphous crystal structure of Ge. Full-wave simulations based on a permittivity model that describes free-carrier damping through crystal structure disorder find excellent agreement with the experimental data. These findings offer an efficient and robust platform for all-optical switching at the nanoscale.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Helicity-Preserving Metasurfaces for Magneto-Optical Enhancement in Ferromagnetic [Pt/Co] N Films

Not provided.

Materials Science↗

DOE OSTI2023

Linear and Non-linear Optical Characterization of Glass and Sapphire for Optical Instrumentation of Advanced Fission Reactors

The linear and nonlinear optical properties of glass and sapphire are investigated to determine the material’s suitability to support optical instrumentation for advanced fission reactors. A post-irradiation examination experiment consisting of a Z-scan, measuring nonlinear optical absorption and refraction, and a spectrometer, measuring linear optical absorption was developed and used. Radiation-induced negative nonlinear optical absorption was observed for the first time in fused silica, sapphire, and borosilicate glass under both types of thermal annealing conditions and the respective effects of thermal annealing are reported.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2021

Measuring accurate optical constants of uranium minerals for use in optical modeling of infrared spectra

Knowledge of the bulk optical constants n and k of solids or liquids allows researchers to accurately predict the absorption, reflection, and scattering properties of materials for different physical forms. Indeed, chemically complex materials such as minerals can have an almost limitless variety of morphologies, particle sizes, shapes, and compositions, but the optical properties of such species can be predicted if the optical constants are known. For species such as minerals, however, there can be additional challenges due to e.g. hydration or dehydration during the course of the optical constants measurement. Here, we describe the protocols to obtain the bulk optical constants n and k of uranium-bearing minerals and ores such as uraninite or autunite. If quality n and k data are at hand, the (infrared) reflectance spectra can be predicted for different particle sizes and morphologies and the modeling results for various scenarios can be derived.

infrared (IR) spectroscopy, optical constants, ura↗

DOE OSTI2024

Development of an immersion fiber optic Raman probe for real-time analysis of molten materials

This study presents an advancement in high-temperature Raman spectroscopy, specifically for analyzing molten materials. It introduces an approach by integrating a fiber-optic Raman probe with a copper block protection system designed to endure extreme thermal conditions. The copper block features an open port designed to accommodate an external telescope with a 3 cm focal length, enabling Raman spectra collection in challenging high-temperature environments. A built-in gas channel ensures a continuous flow of argon gas to prevent flux intrusion. The robust copper block acts as a reliable shield, safeguarding the fiber-optic Raman probe within molten materials. This enhancement maintains the probe's integrity and significantly improves its resilience, making it ideal for rigorous investigations of molten substances. This advancement is particularly relevant in metallurgy, where flux materials impact production quality and efficiency. The ability to acquire Raman signals under elevated thermal conditions offers opportunities for studying molecular dynamics, compositional changes, and chemical interactions within molten substances. This introduced direct immersion probing technique has implications, benefiting both scientific and industrial fields. It holds promise for advancing research and exploration in various contexts, from fundamental scientific inquiries to practical applications in metallurgical processes, where flux materials are critical for optimizing production quality and efficiency. Furthermore, this approach enhances the capabilities of high-temperature Raman spectroscopy, making it a valuable tool for investigating molten materials and their properties in diverse settings.

Argon↗

DOE OSTI2021

Optical Cycling Functionalization of Arenes

Closed, laser-induced optical transitions (“optical cycling transitions”) of molecules can be used for state preparation and measurement in quantum information science and quantum sensing. Increasingly complex molecular species supporting optical cycling can provide new capabilities for quantum science, and it is not clear if there is a limit on their size or complexity. We explore Ca–O–L molecular constructs to support the optical cycling center, Ca, with ligands, L, being arenes. We find that L can be as large as coronene (i.e., CaOC 24 H 11 ) without losing the diagonality of the Franck–Condon factor (FCF). Furthermore, L can be substituted with electron-withdrawing groups to improve the FCF. Larger L, beyond ~7 rings, can disrupt the diagonality of the FCF by closing the HOMO–LUMO ligand electronic state gap and reordering with the local states on the cycling center. Altogether, we find that optical cycling can be retained for arenes, and we offer a principle for their design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1971

Preferential polymerization and adsorption of L-optical isomers of amino acids relative to D-optical isomers on kaolinite templates.

Experiments on the polymerization of the L- and D-optical isomers of aspartic acid and serine using kaolinite as a catalyst showed that the L-optical isomers were polymerized at a much higher rate than the D-optical isomers; racemic (DL-) mixtures were polymerized at an intermediate rate. The peptides formed from the L-monomers were preferentially adsorbed by the clay. In the absence of kaolinite, no significant or consistent difference in the behavior of the L- and D-optical isomers was observed. In experiments on the adsorption of L- and D-phenylalanine by kaolinite, the L-optical isomer was preferentially adsorbed.

Jackson, T. A.↗

NASA NTRS1982

Performance of an optical relay satellite using Reed-Solomon coding over a cascaded optical PPM and BPSK channel

The nature of the optical/microwave interface aboard the relay satellite is considered. To allow for the maximum system flexibility, without overburdening either the optical or RF channel, demodulating the optical on board the relay satellite but leaving the optical channel decoding to be performed at the ground station is examined. The occurrence of erasures in the optical channel is treated. A hard decision on the erasure (i.e., the relay selecting a symbol at random in case of erasure occurrence) seriously degrades the performance of the overall system. Coding the erasure occurrences at the relay and transmitting this information via an extra bit to the ground station where it can be used by the decoder is suggested. Many examples with varying bit/photon energy efficiency and for the noisy and noiseless optical channel are considered. It is shown that coding the erasure occurrences dramatically improves the performance of the cascaded channel relative to the case of hard decision on the erasure by the relay.

Divsalar, D.↗

NASA NTRS1986

Spread spectrum fiber-optic local area network using optical processing

Spread spectrum code division multiple access (CDMA) allows asynchronous multiple access to a local area network (LAN) with no waiting. The additional bandwidth required by spread spectrum can be accommodated by using a fiber-optic channel and incoherent optical signal processing. New CDMA sequences are designed specifically for optical processing. It is shown that increasing the number of chips per bit, by using optical processing, allows an increase in capacity of a CDMA LAN. An experiment is performed demonstrating the performance of an optical CDMA LAN, operating at 100 Mbd with three users.

Prucnal, P. R.↗

NASA NTRS1986

Methods for estimating the optical constants of atmospheric hazes based on complex optical measurements

The methods of multifrequency laser sounding (MLS) are the most effective remote methods for investigating the atmospheric aerosols, since it is possible to obtain complete information on aerosol microstructure and the effective methods for estimating the aerosol optical constants can be developed. The MLS data interpretation consists in the solution of the set of equations containing those of laser sounding and equations for polydispersed optical characteristics. As a rule, the laser sounding equation is written in the approximation of single scattering and the equations for optical characteristics are written assuming that the atmospheric aerosol is formed by spherical and homogeneous particles. To remove the indeterminacy of equations, the method of optical sounding of atmospheric aerosol, consisting in a joint use of a mutifrequency lidar and a spectral photometer in common geometrical scheme of the optical experiment was suggested. The method is used for investigating aerosols in the cases when absorption by particles is small and indicates the minimum necessary for interpretation of a series of measurements.

Zuev, V. E.↗

NASA NTRS1991

Nonlinear optical polymers for electro-optic signal processing

Photonics is an emerging technology, slated for rapid growth in communications systems, sensors, imagers, and computers. Its growth is driven by the need for speed, reliability, and low cost. New nonlinear polymeric materials will be a key technology in the new wave of photonics devices. Electron-conjubated polymeric materials offer large electro-optic figures of merit, ease of processing into films and fibers, ruggedness, low cost, and a plethora of design options. Several new broad classes of second-order nonlinear optical polymers were developed at the Navy's Michelson Laboratory at China Lake, California. Polar alignment in thin film waveguides was achieved by electric-field poling and Langmuir-Blodgett processing. Our polymers have high softening temperatures and good aging properties. While most of the films can be photobleached with ultraviolet (UV) light, some have excellent stability in the 500-1600 nm range, and UV stability in the 290-310 nm range. The optical nonlinear response of these polymers is subpicosecond. Electro-optic switches, frequency doublers, light modulators, and optical data storage media are some of the device applications anticipated for these polymers.

Lindsay, Geoffrey A.↗

NASA NTRS1997

New Constraints on Simultaneous Optical Emission from Gamma-Ray Bursts Measured by the Livermore Optical Transient Imaging System Experiment

LOTIS is a gamma-ray burst optical counterpart search experiment located near Lawrence Livermore National Laboratory in California. Since operations began in 1996 October, LOTIS has responded to five triggers as of 1997 July 30, which occurred during good weather conditions. GR-B 970223 (BATSE trigger 6100) was an exceptionally strong burst, lasting approx. 30 s with a peak at approx. 8 s. LOTIS began imaging the error box approx. 11 s after the burst began and achieved simultaneous optical coverage of 100% of the region enclosed by the BATSE 3 sigma error circle and the interplanetary network annulus. No optical transients were observed brighter than the m{}_{V} approx.11 completeness limit of the resulting images, providing a new upper limit on the ratio of simultaneous optical to gamma-ray fluence of R-{L) less than 1.1 x 10 logical and {-4} and on the ratio of simultaneous optical (at 700 mn) to gamma-ray (at 100 keV) flux density of R-{F} less than 305 for a B-type spectrum and R-{F} less than 475 for an M-type spectrum.

Park, H. S.↗