NASA NTRS2024
Spacecraft in low Earth orbit (LEO) are subjected to harsh environmental conditions, including radiation (cosmic rays, ultraviolet (UV), x-ray and charged particle radiation), micrometeoroids and orbital debris, temperature extremes, thermal cycling, and atomic oxygen (AO). These environmental exposures can result in erosion, embrittlement and optical property degradation of susceptible materials threatening spacecraft performance and durability. To increase our understanding of environmental effects such as AO erosion and radiation induced embrittlement of spacecraft materials, NASA Glenn Research Center developed a series of experiments that were flown as part of the Materials International Space Station Experiment (MISSE) missions on the exterior of the International Space Station (ISS). Recently, four Glenn experiments with 365 flight samples were flown on ISS’s MISSE-Flight Facility (MISSE-FF). These experiments are the Polymers and Composites Experiment-1 (PCE-1) flown as part of the MISSE-9 mission, the PCE-2 flown as part of the MISSE-10 mission, the PCE-3 flown as part of the MISSE-12 and MISSE-15 missions, and the PCE-4 flown as part of the MISSE-13 mission. Each of these experiments included passive contamination witness samples in each flight direction for post-flight molecular contamination analyses. A total of 13 contamination flight samples were flown. The post-flight analyses of the PCE 1-4 contamination samples include X-ray Photoelectron Spectroscopy (XPS) analyses (surface and ion sputter depth analyses) and optical properties (total reflectance, total transmittance and solar absorptance). This paper provides results of post-flight analyses of the PCE 1-4 contamination samples and their corresponding control samples. Knowledge of on-orbit contamination is important for the PCE 1-4 flight data interpretation.