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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1972

An experimental and theoretical evaluation of increased thermal diffusivity phase change devices

This study was to experimentally evaluate and mathematically model the performance of phase change thermal control devices containing high thermal conductivity metal matrices. Three aluminum honeycomb filters were evaluated at five different heat flux levels using n-oct-adecane as the test material. The system was mathematically modeled by approximating the partial differential equations with a three-dimensional implicit alternating direction technique. The mathematical model predicts the system quite well. All of the phase change times are predicted. The heating of solid phase is predicted exactly while there is some variation between theoretical and experimental results in the liquid phase. This variation in the liquid phase could be accounted for by the fact that there are some heat losses in the cell and there could be some convection in the experimental system.

White, S. P.↗

NASA NTRS1990

Computation of solid/liquid phase change including free convection - Comparison with data

A computational model is presented for solid/liquid phase-change energy transport including free convection fluid flow in the liquid phase. The computational model considers the velocity components of all nonliquid control volumes to be zero but fully solves the coupled mass-momentum problem within the liquid. The thermal energy model includes the entire domain and employs an enthalpy-like model and a recently developed method for handling the phase-change interface nonlinearity. Convergence studies are performed and comparisons made with experimental data for two different problems. Grid independence is achieved, and the comparison with experimental data indicates excellent quantitative prediction of the melt fraction evolution. Qualitative data are also provided as velocity vector and isotherm plots. The computational costs incurred are quite low by comparison with other models.

Schneider, G. E.↗

NASA NTRS1972

A study of the liquid-vapor phase change of mercury based on irreversible thermodynamics.

The object of this work is to determine the transport coefficients which appear in linear irreversible-thermodynamic rate equations of a phase change. An experiment which involves the steady-state evaporation of mercury was performed to measure the principal transport coefficient appearing in the mass-rate equation and the coupling transport coefficient appearing in both the mass-rate equation and the energy-rate equation. The principal transport coefficient sigma, usually termed the 'condensation' or 'evaporation' coefficient, is found to be approximately 0.9, which is higher than that measured previously in condensation-of-mercury experiments. The experimental value of the coupling coefficient K does not agree with the value predicted from Schrage's kinetic analysis of the phase change. A modified kinetic analysis in which the Onsager reciprocal law and the conservation laws are invoked is presented which removes this discrepancy but which shows that the use of Schrage's equation for predicting mass rates of phase change is a good approximation.

Adt, R. R., Jr.↗

NASA NTRS1992

An experimental study of growth and phase change of polar stratospheric cloud particles

This report describes the progress made on understanding phase changes related to solutions which may comprise Polar Stratospheric Clouds. In particular, it is concerned with techniques for investigating specific classes of metastability and phase change which may be important not only in Polar Stratospheric Clouds but in all atmospheric aerosols in general. While the lower level atmospheric aerosol consists of mixtures of (NH4)(SO4)2, NH4HSO4, NaCl among others, there is evidence that aerosol at PSC levels is composed of acid aerosol, either injected from volcanic events (such as Pinatubo) or having diffused upward from the lower atmosphere. In particular, sulfuric acid and nitric acid are known to occur at PSC levels, and are suspected of catalyzing ozone destruction reactions by adsorption on surfaces of crystallized particles. The present study has centered on two approaches: (1) the extent of supercooling (with respect to ice) and supersaturation (with respect to hydrate) and the nature of crystal growth in acid solutions of specific molality; and (2) the nature of growth from the vapor of HNO3 - H2O crystals both on a substrate and on a pre-existing aerosol.

Hallett, John↗

NASA NTRS1993

Phase-change composites TES for nickel-hydrogen batteries

Viewgraphs of a discussion on phase-change composites thermal energy storage (TES) for nickel-hydrogen batteries are presented. Topics covered include Ni-H2 thermal control problems; passive thermal control with TES; phase-change composites (PCC); candidate materials; design options; fabrication and freeze-melt cycling; thermal modeling; system benefits; and applications.

Knowles, Timothy R.↗

NASA NTRS1993

On the penetration of the 660 km phase change by mantle downflows

We present a simple analytic model of the interaction of cold convective downwelling currents with an endothermic phase change. The model describes the ponding and lateral spreading of downflows along the phase transition interface. A simple comparison of the vertical forces on the ponding material provides a necessary condition for a downflow to penetrate the phase boundary. This condition is fundamentally dependent on the geometry of the downflow. For planar downwellings, the model predicts a minimum ponding time before the structure can penetrate the phase boundary. For columnar (axisymmetric) downflows, there is no minimum time of spreading required before penetration can proceed. The model thus provides an explanation for the observation that in numerical models of three-dimensional convection with an endothermic phase change, cylindrical downflows penetrate the phase interface while planar ones do not. Since descending slabs in the Earth's mantle display a wide spectrum of geometries between planar and cylindrical (given various trench curvatures, as well as intersections of two or more subduction zones), this phenomenon may explain, in part, why some slabs appear to extend into the lower mantle while others are deflected at the 660 km discontinuity.

Bercovici, David↗

NASA NTRS1991

A computational model for the analysis of diffusive binary alloy solid/liquid phase change energy transport

A model is presented for the prediction of solid/liquid, binary alloy, phase change energy transport. The model incorporates only one-dimensional, diffusive transport of both energy and species but is not inherently limited in any way to such a restriction. The model incorporates a previously developed algorithm for single constituent phase change energy transport and is applied to the energy transport as well as the species transport aspects of the problem. The model is applied to four example cooling problems and is shown to perform exceedingly well from an algorithmic point of view.

Schneider, G. E.↗

DOE OSTI2024

Post-processing of phase change material in a zero-change commercial silicon photonic process

Integration of phase change material (PCM) with photonic integrated circuits can transform large-scale photonic systems by providing non-volatile control over phase and amplitude. The next generation of commercial silicon photonic processes can benefit from the addition of PCM to enable ultra-low power, highly reconfigurable, and compact photonic integrated circuits for large-scale applications. Despite all the advantages of PCM-based photonics, today’s commercial foundries do not provide them in their silicon photonic processes yet. We demonstrate the first-ever electrically programmable PCM device that is monolithically post-processed in a commercial foundry silicon photonics process using a few fabrication steps and coarse-resolution photolithography. These devices achieved 1.4 dB/μm of amplitude switching contrast using a thin layer of 12.5 nm GeSbTe in this work. We have also characterized the reconfiguration speed as well as repeatability of these devices over 20,000 switching cycles. Our solution enables non-volatile photonic VLSI systems that can be fabricated at low cost and high reliability in a commercial foundry process, paving the way for the development of non-volatile programmable photonic integrated circuits for a variety of emerging applications.

Optics↗

DOE OSTI2024

Additive Manufacturing of Thermal Energy Storage Composites with Microencapsulated Phase Change Materials Supported in a Multi-Polymer Matrix

Advanced manufacturing techniques, such as additive manufacturing (AM), that can directly integrate phase change materials (PCMs) have garnered interest in recent years due to their potential for development of highly efficient thermal energy storage architectures. Complex, high surface area geometries embedded with PCMs that are only feasible with AM can improve thermal management with reduced material waste. Our work focuses on developing composite filaments with microencapsulated phase change materials (MEPCM) bound within a single or dual polymer matrix that can be processed through standard filament extruders and additively manufactured using off-the-shelf 3D printers. Polymer powders, rather than polymer pellets, were key to homogenously mixed filaments achieving high MEPCM loadings with no deterioration in thermal energy storage (TES) capability during extrusion. Composite filaments contain upwards of 60 wt% MEPCM and were printed without loss in feature resolution, print speed, or layer adhesion. Storage enthalpies of printed composites range from 100 - 130 kJ/kg, which were within 5% of the theoretical enthalpy based on weight fraction of MEPCM and maintained enthalpies within 1% over 500 thermal cycles. We can reliably manufacture low density, high surface area structures like 15% gyroid infill, along with dense, compact pucks at a 100% concentric infill. Prints were also scalable to a 900 cm3 honeycomb infill heat exchanger model that has an estimated energy storage capacity of 9 Wh.

3D printing↗

NASA NTRS1992

Finite element developments for two dimensional multiple-interface phase change problems

Finite element developments for multiple phase change problems in two-dimensional models are presented for the first time. The enthalpy method is used to simulate latent heat release in conjunction with fixed grid techniques. An unconditionally stable implicit method is used for the time integration. The effects of boundary conditions and the different phase regions on the multiple phase front developments are examined for numerous examples. Discussions and conclusions are appropriately addressed.

Ouyang, Tianhong↗

DOE OSTI2025

Wood template-supported phase change material composites for durable and form-stable thermal energy storage in buildings

Here, to reduce and shift peak energy loads in buildings, phase change materials (PCMs) with high transition enthalpies and transition temperatures near human thermal comfort are desirable for thermal energy storage (TES). Traditional solid/liquid PCMs suffer from leakage during thermal cycling, requiring encapsulation that lowers heat storage capacity. Wood templates (WTs), with porous and hierarchical structures, provide natural encapsulation scaffolds for PCM containment. Polyethylene glycol (PEG) is a compatible PCM with WTs, but when infiltrated alone, ~30 wt% of PEG binds to wood with no detectable phase change, limiting TES efficiency. To address this, we developed a method to (1) improve the form stability of balsa and pine-based composites (BWT + PCMs and PWT + PCMs) and (2) reduce inactive PCM within the composites to ~10 wt%. BWT + PCMs exhibit transition properties upwards of 114.2 J/g at 25.4 degrees C, with no degradation after 1000 thermal cycles, and similar stiffness compared to raw balsa. Meanwhile, PWT + PCMs exhibit 25 % higher storage efficiency with the addition of poly(ethylene glycol) diacrylate compared to solely PEG-infiltrated PWT. PWT + PCM retains 84 % of raw pine's mechanical stiffness, sufficient for light-duty construction. Our shape-stabilized WT + PCM composites enrich the functionality of wood materials as both ideal TES material candidates and light-duty building construction applications.

25 ENERGY STORAGE↗

NASA NTRS2024

Development of Cryogenic Phase Change Materials for Lunar Sample Return

One of the scientific goals of NASA’s Artemis missions is to return regolith samples from the lunar surface. To maintain scientific integrity of these samples, including any volatiles that may exist, cryogenic stowage is desired. FROSTE (Frozen Return Of Samples To Earth) is the element of the Moon to Mars architecture that is tasked with developing and advancing concepts related to this goal. Both active and passive solutions are being considered, but active solutions (cryo-coolers) have high mass and cost penalties. Phase change materials (PCMs) are commonly used as passive thermal management solutions, particularly for sensitive scientific samples. However, there are currently no PCMs capable of providing cooling at the cryogenic temperatures needed to enable lunar sample return with volatiles intact (<120 K). FROSTE has identified two possible candidate materials that could fill this gap. Testing is required to verify the thermal performance of these materials, as well as gain experience with their handling characteristics. We are conducting this testing at the Marshall Space Flight Center’s Space Environmental Effects laboratory, in vacuum, with liquid nitrogen providing cooling ability below the freezing point of the materials. In this talk, we will present an overview of the FROSTE program element and share results from the initial development testing of two cryogenic phase change materials.

phase change material↗

NASA NTRS1970

Phase change instability in the mantle

Earth upper mantle phase change instability, discussing temperature gradient, transformation influence on fluid, olivine-spinel phase flow patterns and tectonics

Oxburgh, E. R.↗

NASA NTRS1999

Numerical Modeling of Three-Dimensional Fluid Flow with Phase Change

We present a numerical method to compute phase change dynamics of three-dimensional deformable bubbles. The full Navier-Stokes and energy equations are solved for both phases by a front tracking/finite difference technique. The fluid boundary is explicitly tracked by discrete points that are connected by triangular elements to form a front that is used to keep the stratification of material properties sharp and to calculate the interfacial source terms. Two simulations are presented to show robustness of the method in handling complex phase boundaries. In the first case, growth of a vapor bubble in zero gravity is studied where large volume increase of the bubble is managed by adaptively increasing the front resolution. In the second case, growth of a bubble under high gravity is studied where indentation at the rear of the bubble results in a region of large curvature which challenges the front tracking in three dimensions.

Esmaeeli, Asghar↗

NASA NTRS1973

Heat transfer phase change paint test (OH-42) of a Rockwell International SSV orbiter in the NASA/LRC Mach 8 variable density wind tunnel

Phase change paint tests of a Rockwell International .00593-scale space shuttle orbiter were conducted in the Langley Research Center's Variable Density Wind Tunnel. The test objectives were to determine the effects of various wing/underbody configurations on the aerodynamic heating rates and boundary layer transition during simulated entry conditions. Several models were constructed. Each varied from the other in either wing cuff radius, airfoil thickness, or wing-fuselage underbody blending. Two ventral fins were glued to the fuselage underside of one model to test the interference heating effects. Simulated Mach 8 entry data were obtained for each configuration at angles of attack ranging from 25 to 40 deg, and a Reynolds number variation of one million to eight million. Elevon, bodyflap, and rudder flare deflections were tested. Oil flow visualization and Schlieren photographs were obtained to aid in reducing the phase change paint data as well as to observe the flow patterns peculiar to each configuration.

Jones, R.↗

NASA NTRS2016

A Comparative Analysis of Phase-Change Wastewater Processing Approaches for Microgravity

Two phase-change wastewater processing candidates, the ISS Vapor Compression Distillation (VCD) System and the Cascade Distiller System (CDS), are compared based on dynamic modeling of both technologies. Differences in fluid handling and energy recovery for the technologies are described and contrasted. Model predictions are presented showing how temperatures, pressures, and compositions vary locally within each distiller. These dynamic variations are difficult to observe experimentally and have implications regarding non-condensable buildup and salt precipitation potential. Alternative architectures involving VCD and CDS components are analyzed in terms of predicted performance and equivalent system mass (ESM). The addition of a downstream brine processor to increase water recovery is also evaluated. Options for reducing overall ESM are discussed, including the possibility of developing a single precipitation-tolerant primary wastewater processor.

Lange, Kevin↗

DOE OSTI2026

Challenges and Opportunities for HVAC + Phase Change Material Thermal Energy Storage in Buildings

Phase-change material (PCM) thermal-energy storage (TES) integrated with HVAC and domestic hot water (DHW) can shift a large share of building thermal loads. By flattening and shifting loads, PCM TES reduces peak electricity use, eases stress on local and grid infrastructure, and lowers costs. It can also defer costly upgrades to service panels, distribution, and transmission. Higher energy density relative to chilled or hot water storage makes PCM TES practical for small, space limited, and retrofit projects, while packaged HVAC-integrated systems expand cost-effective load shifting to commercial buildings that previously lacked options. Despite this promise, deployment faces barriers. This paper presents challenges, opportunities, and lessons learned from lab and field integrations of PCM TES with packaged HVAC systems. Key challenges include misalignment between default heat pump controls tuned for direct-to-load operation and TES charge/discharge objectives, PCM properties that diverge from manufacturer claims and evolve with cycling, and high integration and deployment costs with off-the-shelf products. These studies underscore the need for factory built, integrated systems that arrive as prepackaged modules with proven controls, reducing design and installation effort and delivering predictable performance across projects. The paper outlines steps to enable viable and scalable PCM TES HVAC and DHW systems, including 1) validated methods that can be used to characterize PCM properties and TES system performance, 2) supervisory controls that optimize charge/discharge scheduling, and 3) factory integrated packaging that eliminates bespoke field engineering.

Dutton, Spencer↗

NASA NTRS1992

Phase change energy storage for solar dynamic power systems

This paper presents the results of a transient computer simulation that was developed to study phase change energy storage techniques for Space Station Freedom (SSF) solar dynamic (SD) power systems. Such SD systems may be used in future growth SSF configurations. Two solar dynamic options are considered in this paper: Brayton and Rankine. Model elements consist of a single node receiver and concentrator, and takes into account overall heat engine efficiency and power distribution characteristics. The simulation not only computes the energy stored in the receiver phase change material (PCM), but also the amount of the PCM required for various combinations of load demands and power system mission constraints. For a solar dynamic power system in low earth orbit, the amount of stored PCM energy is calculated by balancing the solar energy input and the energy consumed by the loads corrected by an overall system efficiency. The model assumes an average 75 kW SD power system load profile which is connected to user loads via dedicated power distribution channels. The model then calculates the stored energy in the receiver and subsequently estimates the quantity of PCM necessary to meet peaking and contingency requirements. The model can also be used to conduct trade studies on the performance of SD power systems using different storage materials.

Chiaramonte, F. P.↗