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Explosives and pyrotechnic propellants for use in long term deep space missions

Explosives and pyrotechnic propellant materials which will withstand heat sterilization cycling at 125 C and ten year deep space aging under 10 to the minus 6th power torr and 66 C have been selected. The selection was accomplished through a detailed literature survey and an analytical evaluation of the physicochemical properties of the materials. The chemical components of the electroexplosive devices used in U.S. missiles and spacecraft were categorized into primary explosives, secondary explosives, and propellant ingredients. Kinetic data on such parameters as thermal decomposition and sublimation were obtained for these materials and used as a basis for the ten year life prediction. From these experimental data and some analytical calculations, a listing of candidate materials for deep space missions was made.

Gorzynski, C. S., Jr.

Measurement and analysis of force-time outputs of pyrotechnic nuts

The dynamic loadings produced by two standard pyrotechnic nuts were compared with loadings produced by four recently developed low-shock nuts. The nuts were manufactured by separate contractors. Each nut was given a number designation, the number having no special significance. The results show that the use of the Hopkinson bar to measure force-time outputs of the nuts at stud and housing sides aided greatly in understanding the events occurring in the nuts. Acceleration data appear to be dependable, for the most part, but of more limited value. The low-shock designs show considerable improvement over the standard designs above 4,000 Hz when the results are plotted in shock spectrum form. They involve some penalties with regard to weight and cost.

Neubert, V. H.

Optically thick line widths in pyrotechnic flares

Experimentally determined sodium line widths for pyrotechnic flares are compared with simple analytical, optically-thick-line-shape calculations. Three ambient pressure levels are considered (760, 150 and 30 torr) for three different flare compositions. The measured line widths range from 1.3 to 481 A. The analytic procedure emphasizes the Lorentz line shape as observed under optically-thick conditions. Calculated widths are in good agreement with the measured values over the entire range.

Douda, B. E.

Explosive and pyrotechnic aging demonstration

The survivability was experimentally verified of fine selected explosive and pyrotechnic propellant materials when subjected to sterilization, and prolonged exposure to space environments. This verification included thermal characterization, sterilization heat cycling, sublimation measurements, isothermal decomposition measurements, and accelerated aging at a preselected elevated temperature. Temperatures chosen for sublimation and isothermal decomposition measurements were those in which the decomposition processess occurring would be the same as those taking place in real-time aging. The elevated temperature selected (84 C) for accelerated aging was based upon the parameters calculated from the kinetic data obtained in the isothermal measurement tests and was such that one month of accelerated aging in the laboratory approximated one year of real-time aging at 66 C. Results indicate that HNS-IIA, pure PbN6, KDNBF, and Zr/KC10 are capable of withstanding sterilization. The accelerated aging tests indicated that unsterilized HNS-IIA and Zr/KC104 can withstand the 10 year, elevated temperature exposure, pure PbN6 and KDNBF exhibit small weight losses (less than 2 percent) and B/KC104 exhibits significant changes in its thermal characteristics. Accelerated aging tests after sterilization indicated that only HNS-IIA exhibited high stability.

Rouch, L. L., Jr.

High G pyrotechnic shock simulation using metal-to-metal impact

A technique for simulating high g level pyrotechnic shocks is described and the results of applying the technique to obtain the MIL-STD-1540A shock spectrum with a maximum acceleration of 18,000g at 2,000 Hz are presented. Designing the resonant beam and plate on which the test unit is mounted, and generating a proper impulsive load on them, were the essentials of the technique. One dimensional stress wave and Euler equations were employed in the design. A metal pendulum hammer was used to generate the impulsive load.

Bai, M.

Pyrotechnic shock at the orbiter/external tank forward attachment

During the initial certification test of the forward structural attachment of the space shuttle orbiter to the external tank, pyrotechnic shock from actuation of the separation device resulted in structural failure of the thermal protection tiles surrounding the attachment. Because of the high shock associated with the separation bolt, the development of alternative low shock separation designs was initiated. Two concepts that incorporate a 5.08 centimeter frangible nut as the release device were developed and tested.

Rogers, W. F.

Shock response spectra variational analysis for pyrotechnic qualification testing of flight hardware

Shock response spectra data from flight certification tests were analyzed to determine envelope variation with respect to mean values in each axis. An overall variation of + or - 8.61 dB or 169 percent exists for the data. This large variation may be attributed to one or more of the following: (1) Instrumentation problems may exist. (2) Variations in the source charge (blasting caps) such as shape or explosive load may exist. (3) Two blasting caps were used to excite the pyrotechnic plate tester. Delay time between charge firings may have varied. The cause or causes of the variations need to be identified and researched to prevent future pyroshock problems.

Smith, J. L.

Pyrotechnic Tubing Connector

Tool forms mechanical seal at joint without levers or hydraulic apparatus. Proposed tool intended for use in outer space used on Earth by heavily garbed workers to join tubing in difficult environments. Called Pyrotool, used with Lokring (or equivalent) fittings. Piston slides in cylinder when pushed by gas from detonating pyrotechnic charge. Impulse of piston compresses fittings, sealing around butting ends of tubes.

Graves, Thomas J.

Hazard-Free Pyrotechnic Simulator

Simulator evaluates performance of firing circuits for electroexplosive devices (EED's) safely and inexpensively. Tests circuits realistically when pyrotechnic squibs not connected and eliminates risks of explosions. Used to test such devices as batteries where test conditions might otherwise degrade them.

Mcalister, William B., Jr.

Theory Of A Pyrotechnically Driven Device

Report presents relations that predict behavior of pyrolytically operated device. Mathematical analysis motivated by need to evaluate performances of squib-driven release nuts. Analysis takes into account most significant of complicated interrelated processes involved in operation of pyrotechnically driven devices and aids in their design and evaluation of test data.

Richter, Robert

The First NASA Aerospace Pyrotechnic Systems Workshop

Papers from the conference proceedings are presented, and they are grouped by the following sessions: pyrotechnically actuated systems, laser initiation, and modeling and analysis. A fourth session, a panel discussion and open forum, concluded the workshop.

St.cyr, William W.

Advances in laser diodes for pyrotechnic applications

Background information concerning the use of laser diodes in pyrotechnic applications is provided in viewgraph form. The following topics are discussed: damage limits, temperature stability, fiber coupling issues, and small (100 micron) and large (400 micron) fiber results. The discussions concerning fiber results concentrate on the areas of package geometry and electro-optical properties.

Craig, Richard R.

Pyrotechnic modeling for the NSI and pin puller

A discussion concerning the modeling of pyrotechnically driven actuators is presented in viewgraph format. The following topics are discussed: literature search, constitutive data for full-scale model, simple deterministic model, observed phenomena, and results from simple model.

Powers, Joseph M.

Applications catalog of pyrotechnically actuated devices/systems

A compilation of basic information on pyrotechnically actuated devices/systems used in NASA aerospace and aeronautic applications was formatted into a catalog. The intent is to provide (1) a quick reference digest of the types of operational pyro mechanisms and (2) a source of contacts for further details. Data on these items was furnished by the NASA Centers that developed and/or utilized such devices to perform specific functions on spacecraft, launch vehicles, aircraft, and ground support equipment. Information entries include an item title, user center name, commercial contractor/vendor, identifying part number(s), a basic figure, briefly described purpose and operation, previous usage, and operational limits/requirements.

Seeholzer, Thomas L.

The 2nd NASA Aerospace Pyrotechnic Systems Workshop

This NASA Conference Publication contains the proceedings of the Second NASA Aerospace Pyrotechnics Systems Workshop held at Sandia National Laboratories, Albuquerque, New Mexico, February 8-9, 1994. The papers are grouped by sessions: (1) Session 1 - Laser Initiation and Laser Systems; (2) Session 2 - Electric Initiation; (3) Session 3 - Mechanisms & Explosively Actuated Devices; (4) Session 4 - Analytical Methods and Studies; and (5) Session 5 - Miscellaneous. A sixth session, a panel discussion and open forum, concluded the workshop.

William W St. Cyr