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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Halogenated Dibenzo[ f , h ]quinoxaline Units Constructed 2D‐Conjugated Guest Acceptors for 19% Efficiency Organic Solar Cells

Abstract Halogenation of Y‐series small‐molecule acceptors (Y‐SMAs) is identified as an effective strategy to optimize photoelectric properties for achieving improved power‐conversion‐efficiencies (PCEs) in binary organic solar cells (OSCs). However, the effect of different halogenation in the 2D‐structured large π‐fused core of guest Y‐SMAs on ternary OSCs has not yet been systematically studied. Herein, four 2D‐conjugated Y‐SMAs (X‐QTP‐4F, including halogen‐free H‐QTP‐4F, chlorinated Cl‐QTP‐4F, brominated Br‐QTP‐4F, and iodinated I‐QTP‐4F) by attaching different halogens into 2D‐conjugation extended dibenzo[ f , h ]quinoxaline core are developed. Among these X‐QTP‐4F, Cl‐QTP‐4F has a higher absorption coefficient, optimized molecular crystallinity and packing, suitable cascade energy levels, and complementary absorption with PM6:L8‐BO host. Moreover, among ternary PM6:L8‐BO:X‐QTP‐4F blends, PM6:L8‐BO:Cl‐QTP‐4F obtains a more uniform and size‐suitable fibrillary network morphology, improved molecular crystallinity and packing, as well as optimized vertical phase distribution, thus boosting charge generation, transport, extraction, and suppressing energy loss of OSCs. Consequently, the PM6:L8‐BO:Cl‐QTP‐4F‐based OSCs achieve a 19.0% efficiency, which is among the state‐of‐the‐art OSCs based on 2D‐conjugated Y‐SMAs and superior to these devices based on PM6:L8‐BO host (17.70%) and with guests of H‐QTP‐4F (18.23%), Br‐QTP‐4F (18.39%), and I‐QTP‐4F (17.62%). The work indicates that halogenation in 2D‐structured dibenzo[ f , h ]quinoxaline core of Y‐SMAs guests is a promising strategy to gain efficient ternary OSCs.

14 SOLAR ENERGY↗
DOE OSTI2024

Analysis of dislocation configurations in SiC crystals through X-ray topography aided by ray tracing simulations

Silicon carbide as a wide bandgap semiconductor is of great research interest for its widespread deployment in a range of electronic and optoelectronic devices, particularly in power electronics. However, defects in silicon carbide crystals are still major concerns that is hampering the development of high-performance devices. X-ray topography, particularly using the synchrotron beam has been instrumental in characterizing and analyzing defect configurations in silicon carbide crystals to optimize crystal growth as well as understand the effect of defects on device performance. Here, in recent years, the use of ray-tracing simulation technique based on the orientation contrast mechanism to simulate contrast of defects observed on actual X-ray topographs has proven to be an effective approach to investigate the nature of crystallographic defects in various semiconductors. This review discusses the principle of ray-tracing simulation and its application and modifications to incorporate the effects of surface relaxation and photoelectric absorption to better simulate different dislocations observed in 4H–SiC as well as 6H–SiC crystals of various orientations. The adaptation to weak beam topography and plane wave topography is also discussed. The application of ray-tracing simulation in dislocation characterization of silicon carbide of different polytypes is systematically reviewed including different types of dislocations observed in both off-axis wafers and axial-sliced samples through synchrotron X-ray topography under various beam conditions, recording geometries and reflections. The result of ray-tracing simulation is further utilized in other studies including the investigation of effective penetration depth of all types of dislocations lying on the basal plane on grazing-incidence X-ray topography.

Engineering↗
NASA NTRS1986

A survey of nearby stars for the perturbatative effects of extrasolar planetary systems

A new photoelectric astrometric system, the Multichannel Astrometric Photometer (MAP), was developed, and it was used in a regular observing program designed to detect extrasolar planetary systems. The 76-cm refractor of the Allegheny Observatory was fully renovated to make it suitable as the observing instrument for the MAP. The MAP itself was designed, constructed and tested in actual operation. A data analysis system was developed and tested.

Gatewood, G. D.↗
NASA NTRS1972

High resolution obtained by photoelectric scanning techniques.

Several applications of linear scanning of different types of objects are described; examples include double stars, satellites, the Red Spot of Jupiter and a landing site on the moon. This technique allows one to achieve a gain of about an order of magnitude in resolution over conventional photoelectric techniques; it is also effective in providing sufficient data for removing background effects and for the application of deconvolution procedures. Brief consideration is given to two-dimensional scanning, either at the telescope or of electronographic images in the laboratory. It is suggested that some of the techniques described should be given serious consideration for space applications.

Hall, J. S.↗
NASA NTRS1988

Effects of Galactic absorption on soft X-ray surveys

A bias in the spectral distribution of X-ray sources detected in X-ray surveys is discussed which is due to the combination of the intrinsic characteristics of X-ray telescopes and the effects of low-energy photoelectric absorption within the Galaxy. A statistical method for obtaining information on the average spectrum of X-ray sources detected in well-defined surveys is presented. This method can be applied to surveys performed with X-ray telescopes working at relatively soft X-ray energies, such as Einstein, Exosat, and Rosat.

Zamorani, G.↗
NASA NTRS1983

Interstellar photoelectric absorption cross sections, 0.03-10 keV

An effective absorption cross section per hydrogen atom has been calculated as a function of energy in the 0.03-10 keV range using the most recent atomic cross section and cosmic abundance data. Coefficients of a piecewise polynomial fit to the numerical results are given to allow convenient application in automated calculations.

Morrison, R.↗
NASA NTRS1974

Removal of seeing and instrumental blur effects from astronomical scanner observations

The Phillips-Twomey method for solving simultaneous integral equations is applied to the problem of removing blur effects arising from atmospheric and instrumental sources from astronomical observations made with photoelectric area-scanning instruments. Details of the method and the effects of observational errors on the quality of the results are discussed in the context of applications to actual observations of stars and the planet Saturn.

Clements, A. E.↗
NASA NTRS1976

The diameter and thermal inertia of 433 Eros

Radiometry of Eros at 10 and 20 micrometers demonstrates that the thermal conductivity of the upper centimeter of the surface is approximately as low as that of the moon, suggesting that the asteroid has a regolith of highly porous rocky material. When combined with photoelectric photometry, these infrared measurements yield an effective diameter of Eros at maximum light of 22 plus or minus 2 km and a geometric albedo of 0.18 plus or minus 0.03.

Morrison, D.↗
NASA NTRS1989

Gamma rays, X-rays, and optical light from the cobalt and the neutron star in SN 1987A

Recent developments in modeling the X-ray and gamma-ray emission from SN 1987A are discussed by taking into account both the decaying cobalt and the buried neutron star. The light curve and the spectra evolution of X-rays and gamma-rays are well modeled up to day of about 300 if mixing of Co-56 into hydrogen-rich envelope is assumed. However, the 16-28 keV flux observed by Ginga declines very slowly, whereas the spherical mixing model predicts that the flux should have decreased by a large factor at t greater than 300d. It is shown that this problem can be solved if the photoelectric absorption of X-rays is effectively reduced as a result of the formation of chemically inhomogeneous clumps. Based on the adopted hydrodynamical model and the abundance distribution, predictions are offered for future optical, X-ray, and gamma-ray light curves by taking into account other radioactive sources and various types of the central source, e.g., a buried neutron star accreting the reinfalling material or an isolated pulsar.

Kumagai, Shiomi↗
NASA NTRS2012

Comparison of Square and Radial Geometries for High Intensity Laser Power Beaming Receivers

In an effort to further advance a realizable form of wireless power transmission (WPT), high intensity laser power beaming (HILPB) has been developed for both space and terrestrial applications. Unique optical-to-electrical receivers are employed with near infrared (IR-A) continuous-wave (CW) semiconductor lasers to experimentally investigate the HILPB system. In this paper, parasitic feedback, uneven illumination and the implications of receiver array geometries are considered and experimental hardware results for HILPB are presented. The TEM00 Gaussian energy profile of the laser beam presents a challenge to the effectiveness of the receiver to perform efficient photoelectric conversion, due to the resulting non-uniform illumination of the photovoltaic cell arrays. In this investigation, the geometry of the receiver is considered as a technique to tailor the receiver design to accommodate the Gaussian beam profile, and in doing so it is demonstrated that such a methodology is successful in generating bulk receiver output power levels reaching 25 W from 7.2 sq cm of photovoltaic cells. These results are scalable, and may be realized by implementing receiver arraying and utilizing higher power source lasers to achieve a 1.0 sq m receiver capable of generating over 30 kW of electrical power. This type of system would enable long range optical "refueling" of electric platforms, such as MUAV s, airships, robotic exploration missions and provide power to spacecraft platforms which may utilize it to drive electric means of propulsion. In addition, a smaller HILPB receiver aperture size could be utilized to establish a robust optical communications link within environments containing high levels of background radiance, to achieve high signal to noise ratios.

Raible, Daniel E.↗