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Results for “Polar Metals”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Study of polyphenyl ether fluid /5P4E/ in operating elastohydrodynamic contacts by infrared emission spectroscopy

Infrared emission spectra of 5P4E polyphenyl ether were obtained from an operating elastohydrodynamic sliding contact at different speeds and loads by Fourier emission microspectrophotometry. The spectra were found to be polarized with respect to the direction of the conjunction line, especially at high shear rates. Film and metal surface temperatures were calculated from the spectra, and film thicknesses were determined under various operating conditions. Changes of polarized band structure above a critical shear rate, at which the slope of the film temperature versus shear curve changes abruptly and at which the film thickness assumes a minimum value, are consistent with a transition of the lubricant from a viscous liquid to a viscoelastic liquid or to an elastic solid.

Lauer, J. L.↗
NASA NTRS1988

Radar investigation of asteroids and planetary satellites

The aim is to make radar reconnaissance of near-Earth asteroids, mainbelt ateroids, the Galilean satellites, the Martian satellites, and the largest Saturnian satellites, using the Arecibo 13-cm and the Goldstone 3.5-cm systems. Measurements of echo strength, polarization, and delay/Doppler distribution of echo power provide information about dimensions, spin vector, large-scale topography, cm-to-m-scale morphology, and surface bulk density. The observations also yield refined estimates of target orbital elements. Radar signatures were measured for 31 mainbelt asteroids and 16 near-Earth asteroids since this task began eight years ago. The dispersion in asteroid radar albedoes and circular polarization ratios is extreme, revealing huge differences in surface morphologies, bulk densities, and metal concentration. For the most part, correction between radar signature and VIS/IR class is not high. Many near-Earth asteroids have extremely irregular, nonconvex shapes, but some have polar silhouettes that appear only slightly noncircular. The signatures of 1627 Ivar, 1986 DA, and the approximately 180-km mainbelt asteroid 216 Kleopatra suggest bifurcated shapes. Observational milestones during 1987 and 1988 are noted.

Ostro, Steven J.↗
NASA NTRS1986

UV laser deposition of metal films by photogenerated free radicals

A novel photochemical method for liquid-phase deposition of metal films is described. In the liquid phase deposition scheme, a metal containing compound and a metal-metal bonded carbonyl complex are dissolved together in a polar solvent and the mixture is irradiated using a UV laser. The optical arrangement consists of a HeCd laser which provides 7 mW of power at a wavelength of 325 nm in the TEM(OO) mode. The beam is attenuated and may be expanded to a diameter of 5-20 mm. Experiments with photochemical deposition of silver films onto glass and quartz substrates are described in detail. Mass spectrometric analysis of deposited silver films indicated a deposition rate of about 1 A/s at incident power levels of 0.01 W/sq cm. UV laser-induced copper and palladium films have also been obtained. A black and white photograph showing the silver Van Der Pauw pattern of a solution-deposited film is provided.

Montgomery, R. K.↗
NASA NTRS1991

THz dichroic plates for use at high angles of incidence

The design of a high frequency dichroic plate consisting of an electrically thick self supporting metallic mesh that can be used in a linearly polarized quasi-optical system at high angles of incidence is described. The measured and computed performance of a 2.5-inch aperture mesh is given. This mesh has a 3-dB cutoff frequency of 875 GHz and less than 0.75 dB of transmission loss from 950-1350 GHz at incidence angles of 0, 30, and 45 degrees. The results of a multimode waveguide analysis corroborate the measured data.

Siegel, Peter H.↗
NASA NTRS1992

A theoretical study of the positive and dipositive ions of M(NH3)n and M(H2O)n for M = Mg, Ca, or Sr

The structure and binding energies are determined for many of the M(H2O)n(+) and M(H2O)n(2+) species, for n = 1-3 and M = Mg, Ca, or Sr. The trends are explained in terms of metal sp or sd-sigma hybridization and core polarization. The M(NH3)n(+) systems, with M = Mg or Sr, are also studied. For the positive ions, the low-lying excited states are also studied and compared with experiment. The calculations suggest an alternative interpretation of the SrNH3(+) spectrum.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1993

Ultraviolet spectropolarimetry of the Be star PP Carinae with the Wisconsin Ultraviolet Photo-Polarimeter Experiment

We present the first ultraviolet spectropolarimetric observations of the Be star PP Car, obtained with the Wisconsin Ultraviolet Photo-Polarimeter Experiment (WUPPE) aboard the Astro 1 mission. Usable polarization data were obtained from 1400 to 2330 A, along with a good spectrum from 1400 to 3200 A. These data show a lower polarization shortward of the Balmer jump than had been predicted by standard models, and a broad UV polarization dip around 1900 A is seen. These results are in agreement with those found from the WUPPE observations of two other Be stars, Xi Tau and Pi Aqr, which were published earlier. All these observations are an important probe of the Be circumstellar envelopes and demonstrate the need for the inclusion of metal-line effects in circumstellar disk models of Be star UV polarization.

Bjorkman, K. S.↗
NASA NTRS1972

Electrochemical approach for passivating steel and other metals and for the simultaneous production of a biocide to render water potable

Potentiostatic polarization curves indicated that the cathodic reactions in deaerated KI-I2 water solutions were due to iodine reduction and hydrogen evolution. In the presence of oxygen an additional reduction wave appeared. Anodic polarization curves revealed that iodine could be produced in the region of potential from +600 to +1000 nv vs. SCE.

Source record↗
NASA NTRSDate not supplied

All-Metal Antennas for Applications in Extreme Space Environments

The feasibility of an all-metal antenna for transmission of science data by spacecraft, landers, and rovers operating in the extreme environment of space is investigated. The all-metal antenna is of the short backfire type with a waveguide feed and generates a linearly polarized radiation. The investigation includes the modeling, design, fabrication, and characterization of the antenna. The paper summarizes the preliminary results. Potential applications of an all-metal antenna include communication systems required to operate in the extreme hot environment of Mercury and Venus, extreme cold and high radiation environment of Jupiter’s icy moon, and Artemis missions that involve human/robotic exploration and long-term presence on the Moon.

Extreme Environment↗
NASA NTRSDate not supplied

All-Metal Antennas for Applications in Extreme Space Environments

The feasibility of an all-metal antenna for transmission of science data by spacecraft, landers, and rovers operating in the extreme environment of space is investigated. The all-metal antenna is of the short backfire type with a waveguide feed and generates a circularly polarized radiation. The investigation includes the modeling, design, fabrication, and characterization of the antenna. The paper summarizes the preliminary results. Potential applications of an all-metal antenna include communication systems required to operate in the extreme hot environment of Venus and in the extreme cold and high radiation environment of Jupiter’s icy moon.

Antennas↗
NASA NTRS1992

Poly(1,3,4-oxadiazoles) via aromatic nucleophilic displacement

Poly(1,3,4-oxadiazoles) (POX) are prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl) 1,3,4-oxadiazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The polymerizations are carried out in polar aprotic solvents such as sulfolane or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperatures under nitrogen. The di(hydroxyphenyl) 1,3,4-oxadiazole monomers are synthesized by reacting 4-hydroxybenzoic hydrazide with phenyl 4-hydrobenzoate in the melt and also by reacting aromatic dihydrazides with two moles of phenyl 4-hydroxybenzoate in the melt. This synthetic route has provided high molecular weight POX of new chemical structure, is economically and synthetically more favorable than other routes, and allows for facile chemical structure variation due to the large variety of activated aromatic dihalides which are available.

Connell, John W.↗
NASA NTRS1992

Measurement of the magnetic anisotropy energy constants for magneto-optical recording media

Measurement of the magneto-optical polar Kerr effect is performed on rare earth-transition metal (RE-TM) amorphous films using in-plane fields. From this measurement and the measurement of the saturation magnetization using a vibrating sample magnetometer (VSM), the magnetic anisotropy constants are determined. The temperature dependence is presented of the magnetic anisotropy in the range of -175 to 175 C. The results show a dip in the anisotropy near magnetic compensation. This anomaly is explained based on the finite exchange coupling between the rare earth and transition metal subnetworks.

Hajjar, R. A.↗
NASA NTRS1993

Di(hydroxyphenyl)- 1,2,4-triazole monomers

The di(hydroxyphenyl)- 1,2,4-triazole monomers were first synthesized by reacting bis (4-hydroxyphenyl) hydrazide with aniline hydrochloride at 250 C in the melt and also by reacting 1,3 or 1,4-bis- (4-hydroxyphenyl)- phenylene- dihydrazide with 2 moles of aniline hydrochloride in the melt. Purification of the di(hydroxyphenyl)- 1,2,4-triazole monomers was accomplished by recrystallization. Poly (1,2,4-triazoles) (PT) were prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl)- 1,2,4-triazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The reactions were carried out in polar aprotic solvents such as sulfolane or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperatures under nitrogen. This synthetic route has provided high molecular weight PT of new chemical structure, is economically and synthetically more favorable than other routes, and allows for facile chemical structure variation due to the availability of a large variety of activated aromatic dihalides.

Connell, John W.↗
NASA NTRS2000

Efficient color display using low-absorption in-pixel color filters

A display system having a non-absorbing and reflective color filtering array and a reflector to improve light utilization efficiency. One implementation of the color filtering array uses a surface plasmon filter having two symmetric metal-dielectric interfaces coupled with each other to produce a transmission optical wave at a surface plasmon resonance wavelength at one interface from a p-polarized input beam on the other interface. Another implementation of the color filtering array uses a metal-film interference filter having two dielectric layers and three metallic films.

Wang, Yu↗
NASA NTRS1980

Radar observations of Saturn's rings at intermediate tilt angles

The 12.6-cm-wavelength radar observations of Saturn's rings, corresponding to ring-plane tilt angles of 18.2, 11.7, and 5.6 degrees, respectively, are reported. Measurements of geometric albedo and circular polarization ratio are used to investigate acceptable ring models and radar scattering properties of individual particles. Attention is given to the dependence of the rings' polarization properties on wavelength or tilt angle, or both. All large-particle monolayer models of Saturn's rings are ruled out; however, extended-layer models postulating ice or metal particles are compatible with the radar albedo measurements and are less severely restricted by the polarization data.

Ostro, S. J.↗
NASA NTRS1999

Non-Equilibrium Superconductivity and Magnetic Pair Breaking in Perovskite Half-Metallic Ferromagnet-Insulator-Superconductor (F-I-S) Heterostructures

The effect of spin-polarized quasiparticle currents on the critical current density (J-c) of cuprate superconductors is studied in perovskite F-I-S heterostructures as a function of insulator thickness and of underlying magnetic materials. A pulsed current technique is employed to minimize extraneous Joule heating on the superconductor. At temperatures near T-c, F-I-S samples with insulator thicknesses\1e2nm show precipitous decrease in J_c as current injection (I_m) is increased. In contrast, J_c in a controlled sample with a substituted non-magnetic material (N-I-S) exhibit no dependence on I_m. Similarly, a F-I-S sample with a 10 mn insulating barrier also show little J_c effect versus I_m. At low temperatures with I_m = 0, significant suppression of J-c is observed only in the thin barrier F-I-S samples, although T_c and the normal-state resistivity of all samples are comparable. These phenomena can be attributed to the Cooper pair breaking induced by externally-injected and internally-reflected spin-polarized quasiparticle currents. We estimate an order of magnitude range for the spin diffusion length of 100 nm to 100\ mum.

Fu, C.-C.↗
NASA NTRS1995

Broadband Venetian-Blind Polarizer With Dual Vanes

Improved venetian-blind polarizer features optimized tandem, two-layer vane configuration reducing undesired reflections and deformation of radiation pattern below those of prior single-layer vane configuration. Consists of number of thin, parallel metal strips placed in path of propagating radio-frequency beam. Offers simple way to convert polarization from linear to circular or from circular to linear. Particularly useful for beam-wave-guide applications.

Conroy, Bruce L.↗
NASA NTRS1986

Electrochemical corrosion studies

The objective was to gain familiarity with the Model 350 Corrosion Measurement Console, to determine if metal protection by grease coatings can be measured by the polarization-resistance method, and to compare corrosion rates of 4130 steel coated with various greases. Results show that grease protection of steel may be determined electrochemically. Studies were also conducted to determine the effectiveness of certain corrosion inhibitors on aluminum and steel.

Knockemus, W. W.↗
NASA NTRS1989

Calibration of polarimetric radar systems

A practical technique is proposed for calibrating single-antenna polarimetric radar systems using a metal sphere plus any second target with a strong cross-polarized radar cross section. It is shown that all magnitudes and phases (relative to one of the like-polarized linear polarization configurations) of the radar transfer function can be calibrated without knowledge of the scattering matrix of the second target. Comparison of values measured (using this calibration technique) for a tilted cylinder at X-band with theoretical values shows agreement with + or - 0.3 dB in magnitude and + or - 5 deg in phase. The technique is particularly useful for calibrating a radar under field conditions because it does not require careful alignment of calibration targets.

Sarabandi, K.↗