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Results for “Polymer synthesis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Effects Of Irradiation By Electrons On Two Polyimides

Polyimides of new class, known as polyetherimides, used for composites and castings. Study undertaken to compare effects of electron radiation, in doses expected for 30-year missions in geosynchronous orbit, on molecular structures and tensile properties of two commercially available polyimides: polypyromellitimide and polyetherimide. Findings helpful in development of new polymers that endure radiation, leading to synthesis of polymers not having methyl groups or other moieties that are sources of hydrogen, inhibiting self-mending. Significance of study for polymer industry relating to structures in outer space considerable.

Long, Edward R., Jr.↗
NASA NTRS1975

Synthesis and evaluation of polymers for use in early warning fire alarm devices

Conjugated polyacetylene polymers and one condensation polyene, all containing a high degree of conjugated unsaturation, were synthesized. These polymers were characterized by chemical analysis and by thermogravimetric analysis, as well as for their film-forming capability and gas/polymer interactions. It was found that those that had a high degree of conjugated unsaturation and had resonance - stabilizing groups were very thermally stable to 200 C, e.g., poly(dicyanoacetylene), poly(ethynylferrocene) and poly(phenylacetylene); while those with labile moieties, such as poly(p-formamidophenylacetylene), among others, suffered some degradation when heated in air. When subjected to gas/polymer interaction effects, the greatest change in electrical conductance was observed when ammonia was used as the gas and poly(p-nitrophenylacetylene) was the detector. Other polymers showed similar behavior. For example, poly(ethynylcarborane), considered to be an electron acceptor also showed a change in electrical conductance when exposed to ammonia, while poly(ethynylpyridine) and poly(ethylidenepyridazine) responded to carbon monoxide. However, for "fire gases" (gases from smoldering cotton), poly(ethynylferrocene) was the most responsive. Thus, the concept of polymers with different electronegativities forming charge-transfer complexes with different gases was found to be operable.

Byrd, N. R.↗
NASA NTRS1978

Synthesis of thermally stable polymers

The reaction of bis triazo linediones with divinyl esters and substituted styrenes was investigated. Twenty new polymers were derived via reaction of two previously synthesized bis triazol linediones and four new bis atriazol linediones with eight styrenes. The structure and polymer properties of these thermally stable polymers was examined. The reaction of triazo linediones with enol esters was also considered.

Butler, G. B.↗
NASA NTRS1994

Synthesis Of Benzoxazole Monomers And Polymers

Di(hydroxyphenyl)benzoxazoles synthesized, then polymerized with aromatic dihalides. In comparison with previous routes to synthesis of polybenzoxazoles, this is simpler and more economical. New polybenzoxazoles may prove useful as adhesives, coatings, films, membranes, molding compounds, and composite matrices.

Hergenrother, Paul M.↗
NASA NTRS1986

Synthesis of a further improved porous polymer for the separation of nitrogen, oxygen, argon, and carbon monoxide by gas chromatography

A further improvement has been made in the synthesis of an N-type porous polymer for the separation of permanent gases. Changing the ratios of reactants and diluting the Hi-DVB with styrene led to a porous polymer gas chromatographic packing which is superior to commercial products and to the author's own previously reported custom-made polymer.

Pollock, G. E.↗