Measurement of heat pump processes induced by laser radiation
A series of experiments was performed in which a suitably tuned CO2 laser, frequency doubled by a Tl3AsSe37 crystal, was brought into resonance with a P-line or two R-lines in the fundamental vibration spectrum of CO. Cooling or heating produced by absorption in CO was measured in a gas-thermometer arrangement. P-line cooling and R-line heating could be demonstrated, measured, and compared. The experiments were continued with CO mixed with N2 added in partial pressures from 9 to 200 Torr. It was found that an efficient collisional resonance energy transfer from CO to N2 existed which increased the cooling effects by one to two orders of magnitude over those in pure CO. Temperature reductions in the order of tens of degrees Kelvin were obtained by a single pulse in the core of the irradiated volume. These measurements followed predicted values rather closely, and it is expected that increase of pulse energies and durations will enhance the heat pump effects. The experiments confirm the feasibility of quasi-isentropic engines which convert laser power into work without the need for heat rejection. Of more immediate potential interest is the possibility of remotely powered heat pumps for cryogenic use, such applications are discussed to the extent possible at the present stage.